CN208022781U - A kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow - Google Patents
A kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow Download PDFInfo
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- CN208022781U CN208022781U CN201820188352.8U CN201820188352U CN208022781U CN 208022781 U CN208022781 U CN 208022781U CN 201820188352 U CN201820188352 U CN 201820188352U CN 208022781 U CN208022781 U CN 208022781U
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Abstract
The utility model discloses a kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow, described device is that it is mainly followed in series to form by homogeneous pond, anoxic denitrification pond, No.1 sedimentation basin, micro- oxygen nitrosation film mud coupling pond, No. two sedimentation basins, Anammox film mud coupling pond, the aerobic film mud coupling bed of multiple-effect reinforcing, No. three sedimentation basins；The sludge of No.1 sedimentation basin precipitation flow to anoxic denitrification pond water inlet front end by blowback；The sludge of No. two sedimentation basins precipitation flow to micro- oxygen nitrosation film mud coupling pond water inlet front end by blowback；The sludge that No. three sedimentation basins precipitate strengthens aerobic film mud coupling bed water inlet front end by pump reflux to multiple-effect, and partly treated, and waste water is used as water outlet.The utility model not only has the anti-load impact of high ammonia nitrogen and a high disposal load-bearing capacity, and to temperature fluctuation, toxicant it is adaptable, be easy to restore after being suppressed, have both the distinguishing features such as operating cost is low and sludge yield is few.
Description
Technical field
The utility model belongs to water-treatment technology field, and in particular to a kind of high ammonia nitrogen treatment of Organic Wastewater dress of continuous flow
It sets, different types of high ammonia nitrogen such as the applicable coking wastewater of the utility model, landfill leachate, sludge-digestion liquid, gourmet powder waste water
Organic wastewater.
Background technology
At present tradition and compared with the wastewater biological denitrificaion technique of mainstream be nitrification-denitrification process.There are the problem of it is as follows：
For high ammonia-nitrogen wastewater, in order to realize NH4 +- N is to NOXThe conversion of-N, nitrifying process need to increase oxygen-supplying amount to tie up
The activity of ammonia oxidizing bacteria and nitrite-oxidizing bacteria is held, this can undoubtedly increase the capital expenditure of processing system and oxygen supply power
Expense；For high ammonia nitrogen organic wastewater, the higher phenomenon of high ammonia-nitrogen wastewater generally existing raw water pH value is not directly suitable for giving birth to
Object processing needs to add acid and carries out neutralization adjusting to raw wastewater, while can reduce the balance basicity in waste water.And in Practical Project
In, often aoxidize 1mg NH4 +- N is NOX- N need to consume 7.1mg basicity, and follow-up nitrifying process needs a large amount of basicity, commonly required
When basicity deficiency, it usually needs additionally add a large amount of basicity and carry out inorganic carbon source during additional nitration, this is one very big
Processing cost.
There are a large amount of free ammonias in high ammonia-nitrogen wastewater, research shows that：The meeting when influent ammonium concentration is higher than 500mg/L
Toxic effect is produced to nitrobacteria activity, the processing capacity so as to cause entire processing system declines to a great extent, or even can lead
Entire biochemical treatment system is caused to collapse completely；It is as follows that there are problems in conventional waste water treatment process：High ammonia nitrogen (such as landfill leachate
1000~8000mg/L of ammonia nitrogen concentration) limitation, lead to not the treating capacity for improving entire biochemical system.General Practical Project mistake
Cheng Zhong mostly uses greatly tap water and is diluted to raw wastewater, and originally water dilution method not only increases treatment scale, investment, running cost
With, and it is unfavorable for effective operation of biochemical device.The concentration that nutrient matrix is reduced after raw water dilution, is unfavorable for carrying for MLSS
Height is unfavorable for hard-degraded substance and the removal of COD.
When handling the relatively low high ammonia-nitrogen wastewaters of C/N, organic carbon source there is a serious shortage of be its nitric efficiency not improving
Barrier, it is desirable to provide sufficient outer carbon source maintains the heterotrophic denitrification of denitrifying bacterium, to realize NOX- N is to N2Turn
Change.Traditional biological denitrification process there are the problem of it is as follows：It needs to expend a large amount of energy and carbon source.
Compared with traditional heterotrophic denitrifying Bacteria, autotrophy anaerobic ammonia oxidizing bacteria has low, micro- without additional carbon, sludge yield
The features such as bioactivity is high, matrix affinity is high, therefore the novel autotrophic denitrification technique based on Anammox principle has work
Skill flow is short, floor space is small, capital expenditure is few, saves zmount of oxygen consumption, reduces carbon emission, and excess sludge is few, is not necessarily to external carbon
Many advantages, such as source, at present but anaerobic ammonia oxidation process is less there are continuity run technique and stable operation is difficult.With ring
Border pollute getting worse, after anaerobic ammonia oxidizing bacteria denitrogenation ammonia nitrogen residual volume it is more be faced with water outlet nitrate nitrogen and ammonia nitrogen concentration it is higher and
It cannot be satisfied the problem of increasingly strict wastewater discharge standard.Cause to be discharged ammonia nitrogen and total nitrogen reason for Exceeding to include following several points：
First, organic matter is necessarily contained in practical raw wastewater, result of study shows the presence of organic matter for nitrococcus and anaerobism ammonia
There is oxidation bacteria strong inhibiting effect, excessively high organic matter can lead to the collapse of anaerobic ammonia oxidation process；Secondly as anaerobism
The ammonia nitrogen and nitrite nitrogen ratio of ammonia oxidation bacteria consumption are 1：1.3, it is difficult to adjust the two ratio in real nitrosation process
To suitable ratio, during engineering operation, anaerobic ammonium oxidation tank water outlet undoubtedly will appear remaining higher nitrite nitrogen or
Ammonia nitrogen concentration causes the nitrogen of water outlet can be much exceeded；Again, according to the achievement in research of Broda, anaerobic ammonia oxidizing bacteria is theoretical
The ammonia nitrogen and nitrite nitrogen ratio of upper consumption are 1：1, the ammonia nitrogen of anaerobic ammonia oxidizing bacteria consumption and nitrite nitrogen ratio are in practice
1：1.3,0.3 share having more is converted into nitrate nitrogen by nitrococcus, therefore traditional Anammox can not make final outflow water
Qualified discharge；Finally, it is influenced by water quality and extraneous other conditions, the limitation of Anammox nitric efficiency can cause water outlet
Ammonia nitrogen and nitrite nitrogen residual volume.
As seen through the above analysis, there are no a kind of both high in terms of the processing of ammonia nitrogen in high density organic wastewater at present
The device of effect, reliable and energy saving, economic stabilization.All there is shortcoming and defect places for various processing units, therefore develop one
Kind process route is reasonable, the nitrogen rejection facility of economical and efficient is very necessary.
Utility model content
The utility model is related to a kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow, it is proposed that a kind of completely new high ammonia nitrogen
Technologies for Organic Wastewater Treatment.Processing procedure is without adding any acid-base modifier, organic carbon source and inorganic carbon source, basicity dosage
It is less, it solves the problems, such as continuous flow Anammox, not only there is the anti-load impact of high ammonia nitrogen and high disposal load-bearing capacity, but also
To temperature fluctuation, toxicant it is adaptable, be easy to restore after being suppressed, have both operating cost is low and sludge yield is few etc.
Distinguishing feature.
To achieve the above object, the utility model provides a kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow, feature
Be, it mainly by homogeneous pond, anoxic denitrification pond, No.1 sedimentation basin, micro- oxygen nitrosation film mud coupling pond, No. two sedimentation basins,
Aerobic film mud coupling bed is strengthened in Anammox film mud coupling pond, multiple-effect, No. three sedimentation basins are followed in series to form；No.1 sedimentation basin
The sludge of precipitation flow to anoxic denitrification pond water inlet front end by blowback；The sludge of No. two sedimentation basins precipitation flow to micro- oxygen Asia by blowback
Nitrify film mud coupling pond water inlet front end；The sludge of No. three sedimentation basins precipitation by pump reflux to multiple-effect strengthen aerobic film mud couple bed into
Water front end, the excess sludge that No. three sedimentation basins generate are emitted into homogeneous pond；After the clear nitrification liquid part processing of No. three sedimentation basins
Waste water homogeneous pond is flow to by blowback, treated for part waste water is as water outlet.
The multiple-effect is strengthened aerobic film mud coupling bed and is at least made of thtee-stage shiplock aerobic mud film coupling pond.
Mud film coupling pond is to be coupled in integrated reaction by suspension sludge microbe and carrier organism membrane micro
Pond.
The high ammonia nitrogen organic waste-water treating apparatus of a kind of continuous flow that the utility model is proposed and conventional waste water treatment process
It compares, advantage is to couple pond using film mud to substitute traditional activated sludge tank, be ensure that at the efficient low-consume of system
Reason ability；For influent ammonium concentration fluctuation to subsequent biochemical treating capacity and stability influence, replaced using technique final outflow water
Dilution water source for tap water as raw water remains the basicity amount in raw water while reducing pH value of waste water, eliminates acid
Throwing device reduces a ton water process expense, alleviates the noxious materials such as ammonia nitrogen and acts on subsequent biochemical system shock, carries significantly
The high processing capacity of system；A large amount of excess sludge is will produce for traditional handicraft, using residual sludge reflux to homogeneous pond
Method, can not only eliminate the generation of traditional residual sludge quantity, but also removal effect of the system to pollutant can be increased in advance；
For former Organic substance in water can to the potential Inhibitory Effect of follow-up nitrosation and Anammox nitric efficiency, nitrosation,
Anammox reaction process needs more inorganic carbon sources (basicity), and pond is coupled as micro- oxygen nitrosation film mud using anoxic film mud
The leading portion processing pond for coupling pond is not only reasonably utilized technique and generates basicity, greatly reduces the basicity dosage of system, and
And organic matter is alleviated to the potential Inhibitory Effect of follow-up nitrosation and Anammox nitric efficiency, it ensure that nitrous
The efficient denitrification of change-Anammox；The water outlet nitrogen anti-ammonia nitrogen impact energy not up to standard with system is reacted for Anammox
The present situations such as power is low are coupled using high load capacity aerobic film mud coupling pond/aerobic film mud of middle rate aerobic film mud coupling pond/underload
The triple effect in pond biological reinforced process film mud coupling pond substitutes traditional primary activity sludge-tank, utilizes variety classes in different ponds and dense
The microorganism of degree improves the anti-impact force of system, increases the treatment effeciency of system, while utilizing nitrifier and simultaneous nitrification and denitrification nitre
Change the standard water discharge discharge that bacterium ensures system.
The applicable coking wastewater of the utility model, landfill leachate, sludge-digestion liquid, gourmet powder waste water etc. are different types of high
Ammonia nitrogen organic wastewater, processing procedure without adding any acid-base modifier, organic carbon source and inorganic carbon source, basicity dosage compared with
It is few, not only there is the anti-load impact of high ammonia nitrogen and high disposal load-bearing capacity, but also to the adaptability of temperature fluctuation, toxicant
By force, it is easy to restore after being suppressed, has both the distinguishing features such as operating cost is low and sludge yield is few.
Description of the drawings
Fig. 1 is a kind of high ammonia nitrogen organic waste-water treating apparatus schematic diagram of continuous flow of the utility model.
In figure：0, pipeline, 1, homogeneous pond, 2, anoxic denitrification pond, 3, No.1 sedimentation basin, 4, the coupling of micro- oxygen nitrosation film mud
Pond, 5, No. two sedimentation basins, 6, Anammox film mud couple pond, 7, triple effect strengthens aerobic film mud coupling bed (including high load capacity is good
Oxygen film mud couples pond 7 ' and middle rate aerobic film mud coupling pond 7 " and middle rate aerobic film mud couples pond 7 " '), 8, No. three precipitations
Pond, A, pump (A1, A2, A3, A4)；
Specific implementation mode
1 the utility model is described in further detail below in conjunction with the accompanying drawings.
The utility model is a kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow, it is mainly by homogeneous pond 1, the anti-nitre of anoxic
Change pond 2, No.1 sedimentation basin 3, micro- oxygen nitrosation film mud couples the sedimentation basin 5 of pond 4, two, Anammox film mud couples pond 6, more
Effect is strengthened aerobic film mud coupling 7, No. three sedimentation basins 8 of bed and is followed in series to form；The sludge that No.1 sedimentation basin 3 precipitates is by pumping A1 reflux
To the water inlet front end of anoxic denitrification pond 2；The sludge of No. two sedimentation basins 5 precipitation is back to micro- oxygen nitrosation film mud coupling by pumping A2
The water inlet front end of pond 6；The sludge of No. three sedimentation basins 8 precipitation is back to the aerobic film mud coupling bed water inlet front end of multiple-effect reinforcing by pumping A3
7 " ', the excess sludge that No. three sedimentation basins 8 generate is emitted into homogeneous pond 1；After No. three 8 clear nitrification liquid part of sedimentation basin processing
Waste water be back to homogeneous pond by pumping A4, treated for part waste water is as water outlet.
The multiple-effect is strengthened aerobic film mud coupling bed 7 and is at least made of thtee-stage shiplock aerobic mud film coupling pond, and then successively
Constitute high load capacity aerobic film mud coupling pond 7 ', middle rate aerobic film mud coupling pond 7 ", underload aerobic film mud coupling pond 7 " '.
The utility model is that a kind of processing step of the high ammonia nitrogen organic waste-water treating apparatus of continuous flow is as follows：
(1) mud film coupling pond (4,6,7) is to be coupled in by suspension sludge microbe and carrier organism membrane micro
The reaction tank of one；
(2) homogeneous pond 1：It after raw water is mixed with the nitrification liquid that No. three sedimentation basins 8 flow back, carries out being sufficiently mixed dilution, nitrify
The control of liquid reflux ratio will make the ammonia nitrogen waste water concentration of homogeneous pond processing water outlet be consistently lower than 700mg/L；Hydraulic detention time
For 2h~for 24 hours；The residual sludge reflux of No. three sedimentation basins 8 can not only eliminate the generation of traditional residual sludge quantity to homogeneous pond 1,
And removal effect to raw water pollutant can be increased；
(3) anoxic denitrification pond 2 and No.1 sedimentation basin 3：Waste water after mixed diluting carries out instead through anoxic denitrification pond 2
Nitrify denitrification reaction, while a large amount of basicity of yield；Hydraulic detention time is 1h~8h；The sludge reflux that No.1 sedimentation basin 3 flows back
To 2 strain of anoxic denitrification pond, it can fully ensure that the amount of the denitrification flora of domestication and single denitrification function advantage are efficient
Property.No.1 reflux ratio is 5%~100%；Enter next processing unit after anoxic denitrification pond 2 is handled；
(4) micro- oxygen nitrosation film mud coupling pond 4 and No. two sedimentation basins 5：When waste water couples pond 4 through micro- oxygen nitrosation film mud,
Hydraulic detention time be 2h~30h, filler packing ratio be 10%~70%, temperature be 25~35 DEG C, dissolved oxygen be 1.0mg/L~
3.5mg/L completes the nitrosation cumulative process to ammonia nitrogen using basicity in waste water, strives for ammonia nitrogen contained in water outlet and Asia
The mass ratio of nitrate nitrogen is up to 1：1~1：1.4, the accumulation of nitrite is completed, No. two reaction water outlets of sedimentation basin 5, which enter, to be detested
Anaerobic ammonium oxidation film mud couples pond 6；No. two 5 sludge refluxes of sedimentation basin to micro- oxygen nitrosation film mud couples 4 leading portion of pond, No. two sludge
Reflux ratio is 5%~100%；
(5) Anammox film mud couples pond 6：Hydraulic detention time be 4h~30h, filler packing ratio be 20%~
70%；Under the action of the microorganisms such as anaerobic ammonia oxidizing bacteria and fungal component, using in waste water nitrite nitrogen and ammonia nitrogen complete from
Support Anammox denitrification process；Reaction water outlet enters multiple-effect and strengthens aerobic film mud coupling bed 7；
(6) multiple-effect strengthens aerobic film mud coupling bed 7：Hydraulic detention time HRT is 4h~48h, and filler packing ratio is 20%
~70%, dissolved oxygen is 1.5mg/L~4.0mg/L, special for micropopulation body function in influent quality descending concentrations and each pond
Property different feature, setting multiple-effect strengthens aerobic film mud and couples bed, high load capacity aerobic film mud coupling pond 7 ', middle rate aerobic film mud
Couple the aerobic film mud of pond 7 ", underload and couple pond 7 " ' ammonia nitrogen and total nitrogen that remove various concentration respectively, improves the anti-load punching of system
The nitrification efficiency and synchronous nitration and denitrification efficiency of ability and system are hit, reaction water outlet enters No. three sedimentation basins；
(7) No. three sedimentation basins 8：The sludge of No. three sedimentation basins 8 precipitation strengthens aerobic film mud by pump reflux to multiple-effect and couples bed 7
Intake front end, and No. three return sludge ratios are 20%~100%；Self-compiling program control system regulates and controls according to the different sludge quantities of precipitation
Return sludge ratio is 20%~100%；For part clarification and effluent as water outlet, part clarification and effluent is back to homogeneous pond 1 as dilute
The water source released, mixed liquid recycle ratio are controlled 50%~1000%.
Above-described embodiment is only the technical concepts and features for illustrating the utility model, and its object is to allow be familiar with technique
Personage can understand the content of the utility model and implement according to this, the protection model of the utility model can not be limited with this
It encloses.It is all according to equivalent change or modification made by the spirit of the present invention essence, should all be covered in the utility model and protect
Within the scope of.
Claims (3)
1. a kind of high ammonia nitrogen organic waste-water treating apparatus of continuous flow, which is characterized in that it is mainly by homogeneous pond, anoxic denitrification
Pond, No.1 sedimentation basin, micro- oxygen nitrosation film mud coupling pond, No. two sedimentation basins, Anammox film mud coupling pond, multiple-effect are strengthened
Oxygen film mud coupling bed, No. three sedimentation basins are followed in series to form；The sludge of No.1 sedimentation basin precipitation flow to anoxic denitrification by blowback
Pond water inlet front end；The sludge of No. two sedimentation basins precipitation flow to micro- oxygen nitrosation film mud coupling pond water inlet front end by blowback；No. three heavy
The sludge of shallow lake pond precipitation strengthens aerobic film mud coupling bed water inlet front end by pump reflux to multiple-effect, and the residue that No. three sedimentation basins generate is dirty
Mud is emitted into homogeneous pond；Treated the clear nitrification liquid part of No. three sedimentation basins waste water flow to homogeneous pond by blowback, at part
Waste water after reason is as water outlet.
2. the high ammonia nitrogen organic waste-water treating apparatus of continuous flow as described in claim 1, it is characterised in that：The multiple-effect is strengthened
Oxygen film mud coupling bed is at least made of thtee-stage shiplock aerobic mud film coupling pond.
3. the high ammonia nitrogen organic waste-water treating apparatus of continuous flow as described in claim 1, it is characterised in that：The mud film couples pond
To be coupled in integrated reaction tank by suspension sludge microbe and carrier organism membrane micro.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108083439A (en) * | 2018-02-02 | 2018-05-29 | 安徽华骐环保科技股份有限公司 | The denitrification joint Anammox treatment process and its device of a kind of high ammonia nitrogen organic wastewater of continuous flow |
| CN108101219A (en) * | 2018-02-02 | 2018-06-01 | 安徽华骐环保科技股份有限公司 | A kind of high ammonia nitrogen organic wastewater treatment process of continuous flow and its device |
| CN115403143A (en) * | 2022-08-08 | 2022-11-29 | 江苏裕隆环保有限公司 | Low-carbon treatment system and process for realizing deep denitrification of high-ammonia-nitrogen wastewater |
-
2018
- 2018-02-02 CN CN201820188352.8U patent/CN208022781U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108083439A (en) * | 2018-02-02 | 2018-05-29 | 安徽华骐环保科技股份有限公司 | The denitrification joint Anammox treatment process and its device of a kind of high ammonia nitrogen organic wastewater of continuous flow |
| CN108101219A (en) * | 2018-02-02 | 2018-06-01 | 安徽华骐环保科技股份有限公司 | A kind of high ammonia nitrogen organic wastewater treatment process of continuous flow and its device |
| CN115403143A (en) * | 2022-08-08 | 2022-11-29 | 江苏裕隆环保有限公司 | Low-carbon treatment system and process for realizing deep denitrification of high-ammonia-nitrogen wastewater |
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