CN207877367U - A kind of combined type catalytic ozonation reaction unit - Google Patents

A kind of combined type catalytic ozonation reaction unit Download PDF

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Publication number
CN207877367U
CN207877367U CN201820140874.0U CN201820140874U CN207877367U CN 207877367 U CN207877367 U CN 207877367U CN 201820140874 U CN201820140874 U CN 201820140874U CN 207877367 U CN207877367 U CN 207877367U
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China
Prior art keywords
ozone
tower
communicated
catalytic
water
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Expired - Fee Related
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CN201820140874.0U
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Chinese (zh)
Inventor
王宇世
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Zhongyi Environmental Protection Technology (Dalian) Co., Ltd.
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王宇世
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Abstract

The utility model discloses a kind of combined type catalytic ozonation reaction unit, including ozone generator, wastewater collection tank, level-one ozone catalytic reaction tower, secondary ozone catalytic tower, effluent collection case and ozone breaker, the ozone generator is communicated in the ozone distribution device being arranged in the level-one ozone catalytic reaction tower and secondary ozone catalytic tower bottom, the wastewater collection tank is communicated in the water inlet water-distributing device on the level-one ozone catalytic reaction tower top by waste water lifting pump, reaction tower water inlet/outlet connecting pipe is communicated in the bottom of the level-one ozone catalytic reaction tower and the secondary ozone catalytic tower, the top of the level-one ozone catalytic reaction tower and the secondary ozone catalytic tower is communicated in the ozone breaker by mesh mist eliminator.Combined type catalytic ozonation reaction unit described in the utility model is not likely to produce secondary pollution, and equipment operating cost is low, and water treatment efficiency is good.

Description

A kind of combined type catalytic ozonation reaction unit
Technical field
The utility model belongs to waste water advanced oxidization processing technology field, and in particular to a kind of combined type catalytic ozonation Reaction unit.
Background technology
High-level oxidation technology also known as does advanced oxidation processes, to generate the hydroxyl radical free radical (OH) with Strong oxdiative ability With the characteristics of, under the reaction conditions such as high temperature and pressure, electricity, sound, light irradiation, catalyst, macromolecular hardly degraded organic substance is made to be oxidized to Less toxic or nontoxic small-molecule substance.
According to the difference of the mode and reaction condition that generate free radicals, photochemical oxidation, catalytic wet oxygen can be classified as Change, sonochemical oxidation, ozone oxidation, electrochemical oxidation, Fenton oxidation etc..Currently, part industrial applications The processes such as Fenton catalysis oxidations, wet oxidation, supercritical oxidation there are ton water investment height, high energy consumption, operating cost height, Treatment effect is unstable, generates the problems such as secondary pollution.
For example, application No. is 201621122826.6 patent documents to disclose a kind of Fenton for Chinese utility model patent Fluidization wastewater treatment equipment, which is characterized in that including collecting-tank, pre-treatment tower, fluidization reaction tower, finishing column, medicament Preparation system and clear water reserviors;Collecting-tank is connect by pipeline with the injection water inlet of pre-treatment tower;Collecting-tank and pre-treatment tower It sprays and is provided with sequentially connected first water pump, first pipe mixer, second pipe mixer in the connecting pipe of water inlet And first flowmeter;First pipe mixer is connect by pipeline with the outlet of the coagulant storagetank of medicament preparation system;The It is provided with the first metering pump in the connecting pipe that the coagulant storagetank of one pipe-line mixer and medicament preparation system exports;Second Pipe-line mixer is connect by pipeline with the outlet of the flocculant storagetank of medicament preparation system;Second pipe mixer and medicament It is provided with the second metering pump in the connecting pipe of the flocculant storagetank outlet of preparation system.
The prior art provides a kind of Fenton fluidizations wastewater treatment equipment, and i.e. there are technologies as described above for the device Problem.
Based on technical problem as above of the existing technology, it is anti-that the utility model provides a kind of combined type catalytic ozonation Answer device.
Utility model content
The utility model provides a kind of combined type catalytic ozonation reaction unit, and the combined type catalytic ozonation is anti- Device is answered to be not likely to produce secondary pollution, equipment operating cost is low, and water treatment efficiency is good.
The utility model is achieved by the following technical solution:
A kind of combined type catalytic ozonation reaction unit, including ozone generator, wastewater collection tank, level-one ozone catalytic Reaction tower, secondary ozone catalytic tower, effluent collection case and ozone breaker, the ozone generator, which is communicated in, to be arranged in institute State the ozone distribution device of level-one ozone catalytic reaction tower and secondary ozone catalytic tower bottom, the wastewater collection tank The water inlet water-distributing device on the level-one ozone catalytic reaction tower top, the connection of reaction tower Inlet and outlet water are communicated in by waste water lifting pump Pipe is communicated in the bottom of the level-one ozone catalytic reaction tower and the secondary ozone catalytic tower, the level-one ozone catalytic The top of reaction tower and the secondary ozone catalytic tower is communicated in the ozone breaker by mesh mist eliminator, described The wastewater outlet of secondary ozone catalytic tower is communicated in the effluent collection case.
Further, the combined type catalytic ozonation reaction unit further includes backwash water pump and backwash wind turbine, described Backwash water pump is communicated in the cycle water inlet inlet duct and water outlet receipts for being arranged and reacting tower bottom in the level-one ozone catalytic Between header, the backwash wind turbine is communicated in the cycle water inlet inlet duct.
Further, the combined type catalytic ozonation reaction unit further includes circulator and jet stream getter device, The waterpower defoaming device on secondary ozone catalytic tower top is arranged to be catalyzed the secondary ozone by circulator Water in reaction tower carries out cycle defoaming treatment, and the water outlet of the circulator is communicated in the jet stream getter device, described Jet stream getter device is communicated in the ozone tail gas pipe for being connected to mesh mist eliminator with the ozone breaker and cycle water inlet Between inlet duct.
Further, the middle part of the level-one ozone catalytic reaction tower and the middle part of the secondary ozone catalytic tower are equal It is installed with catalyst and support system.
Further, it is additionally provided with backwash water in the level-one ozone catalytic reaction tower and collects weir, the backwash water is collected Weir is arranged between the water inlet water-distributing device and the catalyst and support system, and backwash water collection weir passes through described anti- It washes out water overflow pipe and is communicated in the wastewater collection tank.
Further, the ozone generating-device by ozone air inlet pipe be communicated in setting it is anti-in the level-one ozone catalytic The ozone distribution device of secondary ozone catalytic tower bottom described in Ying Tahe.
Further, the waste water lifting pump is communicated in the water inlet water-distributing device by wastewater inlet pipe.
Further, the wastewater outlet of the secondary ozone catalytic tower is communicated in the water outlet by being discharged overflow pipe Collecting box.
Further, the backwash water pump is communicated in the cycle water inlet inlet duct by backwash water inlet pipe;It is described anti- It washes wind turbine and the cycle water inlet inlet duct is communicated in by backwash air inlet pipe.
Further, the jet stream getter device is by being communicated in the cycle water inlet inlet duct air water communicating pipe.
Compared with prior art, the superior effect of the utility model is:
1, combined type catalytic ozonation reaction unit described in the utility model, by being equipped with level-one ozone catalytic Reaction tower, secondary ozone catalytic tower and ozone generator keep combined type catalytic ozonation described in the utility model anti- It answers device to use two-stage series structure, and loads ozone catalyst, and combine air water circulating technology, substantially increase ozone Utilization ratio reduces the ozone dosage of ton water, reduces ton water investment and an energy consumption;
2, combined type catalytic ozonation reaction unit described in the utility model, by be equipped with mesh mist eliminator and Waterpower defoaming device enables combined type catalytic ozonation reaction unit described in the utility model effectively to avoid generating tail The problem of gas foam is carried secretly and waste water foam is carried secretly.
Description of the drawings
Fig. 1 is the schematic diagram of combined type catalytic ozonation reaction unit described in embodiment 1 in the utility model.
Reference numeral is as follows:
1- ozone generators, 2- wastewater collections tank, 3- level-one ozone catalytics reaction tower, 4- secondary ozones catalytic tower, 5- effluent collections case, 6- ozone breakers, 7- ozone distribution device, 8- waste water lifting pumps, 9- water inlets water-distributing device, 10- reactions Tower water inlet/outlet connecting pipe, 11- mesh mist eliminators, 12- backwash water pumps, 13- backwashes wind turbine, 14- cycle water inlets inlet duct, 15- Circulator, 16- jet streams getter device, 17- waterpower defoaming device, 18- ozone tail gas pipe, 19- catalyst and support system, 20- backwash waters collect weir, 21- backwashes are discharged overflow pipe, 22- ozone air inlet pipe, 23- wastewater inlet pipes, 24- are discharged overflow pipe, 25- backwashes water inlet pipe, 26- backwashes air inlet pipe, 27- air water communicating pipes.
Specific implementation mode
Specific embodiment of the present invention is described in further detail below.
Embodiment 1
As shown in Fig. 1, a kind of combined type catalytic ozonation reaction unit, including ozone generator 1, wastewater collection tank 2, level-one ozone catalytic reaction tower 3, secondary ozone catalytic tower 4, effluent collection case 5 and ozone breaker 6, the ozone hair Raw device 1 is communicated in the ozone cloth being arranged in the level-one ozone catalytic reaction tower 3 and 4 bottom of secondary ozone catalytic tower Device of air 7, the wastewater collection tank 2 are communicated in the water inlet on 3 top of level-one ozone catalytic reaction tower by waste water lifting pump 8 Water-distributing device 9, reaction tower water inlet/outlet connecting pipe 10 are communicated in the level-one ozone catalytic reaction tower 3 and secondary ozone catalysis The top of the bottom of reaction tower 4, the level-one ozone catalytic reaction tower 3 and the secondary ozone catalytic tower 4 passes through silk Net demister 11 is communicated in the ozone breaker 6, the wastewater outlet of the secondary ozone catalytic tower 4 be communicated in it is described go out Water collection tank 5.
In the present embodiment, wastewater collection tank 2 is as pretreatment or the collecting box of bio-chemical effluent;5 conduct of effluent collection case The collection storage device of processed waste water.
The combined type catalytic ozonation reaction unit further includes backwash water pump 12 and backwash wind turbine 13, the backwash water Pump 12, which is communicated in, to be arranged in the cycle water inlet inlet duct 14 of 3 bottom of level-one ozone catalytic reaction tower and the effluent collection Between case 5, the backwash wind turbine 13 is communicated in the cycle water inlet inlet duct 14.
The combined type catalytic ozonation reaction unit further includes circulator 15 and jet stream getter device 16, and setting exists The waterpower defoaming device 17 on 4 top of secondary ozone catalytic tower is catalyzed the secondary ozone by circulator 15 anti- The water in tower 4 is answered to carry out cycle defoaming treatment, the water outlet of the circulator 15 is communicated in the jet stream getter device 16, institute It states jet stream getter device 16 and is communicated in the ozone tail gas pipe 18 for being connected to mesh mist eliminator 11 with the ozone breaker 6 and described Between cycle water inlet inlet duct 14.
In the present embodiment, circulator 15 recycles waste water and tail gas using water circulating pump as power plant.
The middle part of the level-one ozone catalytic reaction tower 3 and the middle part of the secondary ozone catalytic tower 4 are installed with Catalyst and support system 19.
In the present embodiment, catalyst generally uses alundum (Al2O3) or molecular sieve beads as carrier, and load is several Metal oxide with catalytic action or metal oxide containing precious metals;Support system using porous filter plate as catalyst supporting layer, Filter plate bottom sets support post, is connect with tower floor.
It is additionally provided with backwash water in the level-one ozone catalytic reaction tower 3 and collects weir 20, the backwash water is collected weir 20 and set It sets between the water inlet water-distributing device 9 and the catalyst and support system 19, the backwash water collects weir 20 described in Backwash water outlet overflow pipe 21 is communicated in the wastewater collection tank 2.
The ozone generating-device 1 is communicated in by ozone air inlet pipe 22 to be arranged in the level-one ozone catalytic reaction tower 3 With the ozone distribution device 7 of 4 bottom of secondary ozone catalytic tower.
The waste water lifting pump 8 is communicated in the water inlet water-distributing device 9 by wastewater inlet pipe 23.
The wastewater outlet of the secondary ozone catalytic tower 4 is communicated in the effluent collection case by being discharged overflow pipe 24 5。
The backwash water pump 12 is communicated in the cycle water inlet inlet duct 14 by backwash water inlet pipe 25;The backwash wind Machine 13 is communicated in the cycle water inlet inlet duct 14 by backwash air inlet pipe 26.
The jet stream getter device 16 is by being communicated in the cycle water inlet inlet duct 14 air water communicating pipe 27.
It in the present embodiment, can be regularly smelly to the level-one by the backwash water pump 12 and the backwash wind turbine 13 Oxygen catalytic tower 3 is backwashed, and backwash water outlet collects weir 20 by backwash water and drains into wastewater collection tank 2.
The utility model is not limited to the above embodiment, without departing substantially from the substantive content of the utility model, It may occur to persons skilled in the art that any deformation, improvement, replacement each fall within the scope of protection of the utility model.

Claims (10)

1. a kind of combined type catalytic ozonation reaction unit, including ozone generator, wastewater collection tank, level-one ozone catalytic are anti- Answer tower, secondary ozone catalytic tower, effluent collection case and ozone breaker, which is characterized in that the ozone generator connection It is described in the ozone distribution device in the level-one ozone catalytic reaction tower and secondary ozone catalytic tower bottom is arranged Wastewater collection tank is communicated in the water inlet water-distributing device on the level-one ozone catalytic reaction tower top, reaction tower by waste water lifting pump Water inlet/outlet connecting pipe is communicated in the bottom of the level-one ozone catalytic reaction tower and the secondary ozone catalytic tower, and described one The top of grade ozone catalytic reaction tower and the secondary ozone catalytic tower is communicated in the ozone by mesh mist eliminator The wastewater outlet of destructor, the secondary ozone catalytic tower is communicated in the effluent collection case.
2. combined type catalytic ozonation reaction unit according to claim 1, which is characterized in that the combined type ozone Catalytic oxidation reaction device further includes backwash water pump and backwash wind turbine, and the backwash water pump, which is communicated in, to be arranged in the level-one ozone Between the cycle water inlet inlet duct of catalytic tower bottom and the effluent collection case, the backwash wind turbine is communicated in described follow Ring water inlet inlet duct.
3. combined type catalytic ozonation reaction unit according to claim 2, which is characterized in that the combined type ozone Catalytic oxidation reaction device further includes circulator and jet stream getter device, is arranged on secondary ozone catalytic tower top Waterpower defoaming device cycle defoaming treatment is carried out to the water in the secondary ozone catalytic tower by circulator, it is described The water outlet of circulator is communicated in the jet stream getter device, and the jet stream getter device is communicated in mesh mist eliminator and institute It states between the ozone tail gas pipe of ozone breaker connection and cycle water inlet inlet duct.
4. combined type catalytic ozonation reaction unit according to claim 3, which is characterized in that the level-one ozone is urged The middle part at the middle part and the secondary ozone catalytic tower of changing reaction tower is installed with catalyst and support system.
5. combined type catalytic ozonation reaction unit according to claim 4, which is characterized in that the level-one ozone is urged Change and be additionally provided with backwash water in reaction tower and collect weir, the backwash water is collected weir setting in the water inlet water-distributing device and described urged Between agent and support system, the backwash water collects weir and is communicated in the wastewater collection tank by backwash water outlet overflow pipe.
6. combined type catalytic ozonation reaction unit according to claim 5, which is characterized in that the ozone fills It sets to be communicated in by ozone air inlet pipe and be arranged in the level-one ozone catalytic reaction tower and secondary ozone catalytic tower bottom The ozone distribution device in portion.
7. combined type catalytic ozonation reaction unit according to claim 6, which is characterized in that the waste water lifting pump It is communicated in the water inlet water-distributing device by wastewater inlet pipe.
8. combined type catalytic ozonation reaction unit according to claim 7, which is characterized in that the secondary ozone is urged The wastewater outlet for changing reaction tower is communicated in the effluent collection case by being discharged overflow pipe.
9. combined type catalytic ozonation reaction unit according to claim 8, which is characterized in that the backwash water pump is logical It crosses backwash water inlet pipe and is communicated in the cycle water inlet inlet duct;The backwash wind turbine is communicated in described follow by backwash air inlet pipe Ring water inlet inlet duct.
10. combined type catalytic ozonation reaction unit according to claim 9, which is characterized in that the jet stream air-breathing Device is by being communicated in the cycle water inlet inlet duct air water communicating pipe.
CN201820140874.0U 2018-01-28 2018-01-28 A kind of combined type catalytic ozonation reaction unit Expired - Fee Related CN207877367U (en)

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Application Number Priority Date Filing Date Title
CN201820140874.0U CN207877367U (en) 2018-01-28 2018-01-28 A kind of combined type catalytic ozonation reaction unit

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Application Number Priority Date Filing Date Title
CN201820140874.0U CN207877367U (en) 2018-01-28 2018-01-28 A kind of combined type catalytic ozonation reaction unit

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110683630A (en) * 2019-10-31 2020-01-14 四川恩特普环保科技有限公司 High COD wastewater treatment system and method
CN111186901A (en) * 2020-01-24 2020-05-22 辽宁中舟得水环保科技有限公司 Technology for feeding ozone into multistage ozone reaction tower by ejector
CN111777161A (en) * 2020-07-31 2020-10-16 苏州汇博龙环境技术有限公司 Wastewater treatment system and method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110683630A (en) * 2019-10-31 2020-01-14 四川恩特普环保科技有限公司 High COD wastewater treatment system and method
CN111186901A (en) * 2020-01-24 2020-05-22 辽宁中舟得水环保科技有限公司 Technology for feeding ozone into multistage ozone reaction tower by ejector
CN111186901B (en) * 2020-01-24 2022-06-03 辽宁中舟得水环保科技有限公司 Technology for feeding ozone into multistage ozone reaction tower by ejector
CN111777161A (en) * 2020-07-31 2020-10-16 苏州汇博龙环境技术有限公司 Wastewater treatment system and method

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Date Code Title Description
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20190828

Address after: 116081 Xinhongyuan No. 11, No. 2, Unit 2, No. 1, Ganjingzi District, Dalian City, Liaoning Province

Patentee after: Zhongyi Environmental Protection Technology (Dalian) Co., Ltd.

Address before: 116081 Unit 42 # - 1 - 601, Xiangyiyuan, Ganjingzi District, Dalian City, Liaoning Province

Patentee before: Wang Yushi

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180918

Termination date: 20210128

CF01 Termination of patent right due to non-payment of annual fee