CN207845302U - A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment - Google Patents

A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment Download PDF

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Publication number
CN207845302U
CN207845302U CN201721620466.7U CN201721620466U CN207845302U CN 207845302 U CN207845302 U CN 207845302U CN 201721620466 U CN201721620466 U CN 201721620466U CN 207845302 U CN207845302 U CN 207845302U
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CN
China
Prior art keywords
outlet
connect
acid solution
reverse osmosis
osmosis unit
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Expired - Fee Related
Application number
CN201721620466.7U
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Chinese (zh)
Inventor
吴伟
王勇
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Huaneng Qinbei Power Generation Co Ltd
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Huaneng Qinbei Power Generation Co Ltd
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Priority to CN201721620466.7U priority Critical patent/CN207845302U/en
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Expired - Fee Related legal-status Critical Current
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Abstract

The utility model discloses a kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment, including acid solution collecting box, sedimentation basin, filter, reverse osmosis unit and finished product box;The utility model recycles acidic liquid to acid solution collecting box in the net flue of wet desulphurization absorption tower and chimney entry position, acid solution in acid solution collecting box is after precipitation and filtering, it is concentrated using reverse osmosis scheme, the acid solution after concentration can be used for regenerating strong type resin or for selling;Both a large amount of water process acid had been saved, had been economized on resources, cost is reduced, and can be that the flue waste liquid of desulphurization system find rational discharge by way of alleviating the corrosion of desulphurization system, be power plant's creation economic benefit.

Description

A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment
Technical field
The utility model belongs to water-treatment technology field, and specifically a kind of recycling wet desulphurization rear pass, chimney generate Acid hydrophobic male form resin or recirculated water acid adding processing system for reused water processing equipment.
Background technology
Currently, thermal power plant water treatment system male form resin regeneration mostly uses outsourcing industrial sulphuric acid greatly or hydrochloric acid carries out again It is raw, also outsourcing finished product sulfuric acid is used to carry out acid adding processing when cycle alkalinity of water is higher, expends a large amount of technical hydrochloric acid and sulphur every year Acid.It produces these hydrochloric acid and sulfuric acid is needed to consume a large amount of energy while be adversely affected to environment, risk in transit is larger, together When the consumption power plant a large amount of cost of raw material.
Present most of thermal power plants are all made of Limestone-gypsum Wet Flue Gas Desulfurization Process system, the absorption tower outlet after desulfurization Flue gas carries a large amount of acid drop, and main ingredient is sulfuric acid(H2SO4), sulfurous acid(H2SO3), nitric acid(HNO3)And hydrochloric acid (HCl) etc. mixing liquid, concentration is about 0.01mol/l or so, and pH value is between 2~3.The random pool-size of its carrying amount is big Small and desulfurizer performance differs, 600MW units about per hour 10~30t/h, 1000MW unit about per hour 20~ 50t/h.The waste liquid that wet desulfurization system generates needs consumption large quantities of lime stone to be disposed, breaks simultaneously after returning to desulphurization system Bad water balance, these acid solutions can be completely used for the weak male form resin of Direct Regeneration and the processing of recirculated water acid adding after collecting, through overrich It can be used for regenerating strong male form resin after contracting.The recycling of this part waste liquid is conducive to the consumption to save material, together When be conducive to desulphurization system water balance.
Invention content
Goal of the invention:The utility model aim is in view of the deficiencies of the prior art, to provide a kind of desulfurization wastewater recycling use In regenerating resin or the system of circulating water treatment, to save a large amount of cost of raw and processed materials for water treatment system, while saving The disposal costs of a large amount of desulphurization systems, system is succinct, safety and environmental protection.
Technical solution:Desulfurization wastewater recycling described in the utility model is for regenerating resin or the system of circulating water treatment, packet Include acid solution collecting box, sedimentation basin, filter, reverse osmosis unit and finished product box;
The import of the acid solution collecting box is connected by pipeline and the flue on absorption tower, and outlet is connect with sedimentation basin;It is described The solid outlet of sedimentation basin and the material inlet on absorption tower connect, and liquid outlet is connect with filter;The filter filtering is heavy The liquid of shallow lake pond discharge, the outlet of filter is connect with reverse osmosis unit;The reverse osmosis unit carries out concentration to waste water, The concentrated water side discharge outlet of the reverse osmosis unit is connect with finished product box, dilute side discharge outlet and go weak male form resin regeneration system or Recirculated water acid adding processing system is gone to connect;The outlet of the finished product box is connect with male form resin regeneration system is removed.
Further preferably technical solution is the utility model, is also set up between the filter and the reverse osmosis unit There is intermediate maturity case, the import of the intermediate maturity case to be connect with the outlet of the filter, first outlet with it is described reverse osmosis The import of device connects, second outlet with remove weak male form resin regeneration system or recirculated water acid adding processing system gone to connect.
Preferably, the acid solution collecting box is connect by elevator pump and pipeline with sedimentation basin;The of the intermediate maturity case One outlet is connect by high-pressure pump with the reverse osmosis unit, and second outlet is by using pump and removes weak male form resin regeneration system Or recirculated water acid adding processing system is gone to connect;The finished product box is connect by using pump with male form resin regeneration system is removed.
Preferably, the import of the acid solution collecting box is connected by acid solution drain water piping and the flue on absorption tower.
Preferably, the acid solution outlet on the absorption tower is located at wet desulphurization absorption tower chimney gas approach.
Advantageous effect:(1)The utility model recycles Acidic Liquid in the net flue of wet desulphurization absorption tower and chimney entry position To acid solution collecting box, the acid solution in acid solution collecting box is concentrated after precipitation and filtering using reverse osmosis scheme body, is concentrated Acid solution afterwards can be used for regenerating strong type resin or for selling;Both saved a large amount of water process acid, economized on resources, reduce at This, and can be that the flue waste liquid of desulphurization system find rational discharge by way of alleviating the corrosion of desulphurization system, be power plant's creation Economic benefit;
(2)The concentration of acid solution uses reverse osmosis concentration side in the utility model, turns acid solution to reverse osmosis membrane, concentrated water side The liquid of generation is acid solution after concentrating, and for regenerating strong male form resin, the liquid of dilute side can be used for weak male form resin The resin rinse water of regenerative system, or the circulating cooling make-up water of recirculated water acid adding processing system is removed, the acid in reverse osmosis unit Liquid is realized and is all recycled, and does not generate secondary pollution, no waste liquid generates, economical, safe and environment-friendly;
(3)Be additionally provided with intermediate maturity case in the utility model between filter and the reverse osmosis unit, it is intermediate at Acid solution is not concentrated in product case, can be directly used for the resin rinse water of weak male form resin regeneration system, or removes recirculated water The circulating cooling make-up water of acid adding processing system, using flexible can reduce production procedure, to improve production efficiency, be promoted economical Value.
Description of the drawings
Fig. 1 is the structural schematic diagram of the desulfurization wastewater recycling system of the utility model;
In figure, 1- acid solutions collecting box, 2- sedimentation basins, 3- filters, 4- intermediate maturities case, 5- reverse osmosis units, 6- finished products Case, the absorption towers 7-.
Specific implementation mode
Technical solutions of the utility model are described in detail below by attached drawing, but the scope of protection of the utility model It is not limited to the embodiment.
Embodiment:A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment, including acid solution collecting box 1, sedimentation basin 2, filter 3, intermediate maturity case 4, reverse osmosis unit 5 and finished product box 6.
The import of acid solution collecting box 1 is connect by acid solution drain water piping with the flue on absorption tower 7, outlet by elevator pump with Sedimentation basin 2 connects.
The solid outlet of sedimentation basin 2 is connect with the material inlet on absorption tower 7, and liquid outlet is connect with filter 3.
The liquid of 3 filtering settling pond 2 of filter discharge, the outlet of filter 3 are connect with the import of intermediate maturity case 4, in Between the first outlet of finished product box 4 connect with the import of reverse osmosis unit 5 by high-pressure pump, second outlet by using pump with go it is weak Male form resin regeneration system goes recirculated water acid adding processing system to connect.
Reverse osmosis unit 5 carries out concentration to waste water, and the concentrated water side discharge outlet of reverse osmosis unit 5 is connect with finished product box 6, Dilute side discharge outlet with remove weak male form resin regeneration system or recirculated water acid adding processing system gone to connect.
The outlet of finished product box 6 is connect by using pump with male form resin regeneration system is removed.
As described above, although the utility model has been indicated and described with reference to specific preferred embodiment, it must not It is construed to the limitation to the utility model itself.In the spirit and scope for not departing from the utility model that appended claims define Under the premise of, it can various changes can be made in the form and details to it.

Claims (5)

1. a kind of desulfurization wastewater recycling is for regenerating resin or the system of circulating water treatment, which is characterized in that collected including acid solution Case, sedimentation basin, filter, reverse osmosis unit and finished product box;
The import of the acid solution collecting box is connected by pipeline and the flue on absorption tower, and outlet is connect with sedimentation basin;The precipitation The solid outlet in pond and the material inlet on absorption tower connect, and liquid outlet is connect with filter;The filter filtering settling pond The outlet of the liquid of discharge, filter is connect with reverse osmosis unit;The reverse osmosis unit carries out concentration to waste water, described The concentrated water side discharge outlet of reverse osmosis unit is connect with finished product box, dilute side discharge outlet with remove weak male form resin regeneration system or go to follow Ring water acid adding processing system connects;The outlet of the finished product box is connect with male form resin regeneration system is removed.
2. desulfurization wastewater recycling according to claim 1 exists for regenerating resin or the system of circulating water treatment, feature In being additionally provided with intermediate maturity case, the import of the intermediate maturity case and institute between the filter and the reverse osmosis unit State the outlet connection of filter, first outlet connect with the import of the reverse osmosis unit, second outlet with remove weak male form resin Regenerative system goes recirculated water acid adding processing system to connect.
3. desulfurization wastewater recycling according to claim 2 exists for regenerating resin or the system of circulating water treatment, feature In the acid solution collecting box is connect by elevator pump and pipeline with sedimentation basin;The first outlet of the intermediate maturity case passes through height Press pump is connect with the reverse osmosis unit, second outlet by using pump and remove weak male form resin regeneration system or recirculated water gone to add Sour processing system connection;The finished product box is connect by using pump with male form resin regeneration system is removed.
4. desulfurization wastewater recycling according to claim 1 exists for regenerating resin or the system of circulating water treatment, feature In the import of the acid solution collecting box is connected by acid solution drain water piping and the flue on absorption tower.
5. desulfurization wastewater recycling according to claim 1 exists for regenerating resin or the system of circulating water treatment, feature In the acid solution outlet on the absorption tower is located at wet desulphurization absorption tower chimney gas approach.
CN201721620466.7U 2017-11-29 2017-11-29 A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment Expired - Fee Related CN207845302U (en)

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CN201721620466.7U CN207845302U (en) 2017-11-29 2017-11-29 A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201721620466.7U CN207845302U (en) 2017-11-29 2017-11-29 A kind of system that desulfurization wastewater recycling is used for regenerating resin or circulating water treatment

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109824169A (en) * 2019-03-04 2019-05-31 广东益诺欧环保股份有限公司 The method and system of acid solution in a kind of recycling acid waste water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109824169A (en) * 2019-03-04 2019-05-31 广东益诺欧环保股份有限公司 The method and system of acid solution in a kind of recycling acid waste water

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Granted publication date: 20180911

Termination date: 20181129