CN207815831U - A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas - Google Patents

A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas Download PDF

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Publication number
CN207815831U
CN207815831U CN201820124247.8U CN201820124247U CN207815831U CN 207815831 U CN207815831 U CN 207815831U CN 201820124247 U CN201820124247 U CN 201820124247U CN 207815831 U CN207815831 U CN 207815831U
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China
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nitrogen
cold energy
natural gas
rectifying column
argon
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Withdrawn - After Issue
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CN201820124247.8U
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Chinese (zh)
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郝兆龙
曹建喜
杨彩玲
周海波
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Beijing Pioneer Energy Polytron Technologies Inc
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Beijing Pioneer Energy Polytron Technologies Inc
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Abstract

The utility model discloses a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas, which includes liquified natural gas tank, cold energy of liquefied natural gas recovery system, raw argon column, purity nitrogen rectifying column, pure oxygen rectifying column, air cleaning system and dirty nitrogen cold energy recovery system;Pressurize after the refrigerant heat exchange of liquefied natural gas and cold energy of liquefied natural gas recovery system it is outer it is defeated for users to use, cold energy of liquefied natural gas recovery system connect to form refrigerant circulation circuit by pipeline with purity nitrogen rectifying column;Feed back loop is formed between purity nitrogen rectifying column and pure oxygen rectifying column, the bottom of tower of purity nitrogen rectifying column is connected to raw argon column simultaneously;Argon gas is formed between raw argon column and pure oxygen rectifying column and purifies circuit, and air cleaning system forms purging air circuit with dirty nitrogen cold energy recovery system, and dirty nitrogen cold energy recovery system forms dirty nitrogen cold energy recycling circuit with pure oxygen rectifying column and raw argon column.The utility model can realize that space division gas products specific energy consumption reduces by 20% or more.

Description

A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas
Technical field
The utility model is related to a kind of air-seperation systems, and in particular to a kind of cold energy using liquefied natural gas is to air In the system that is detached of oxygen, nitrogen and argon gas.
Background technology
Air separation be by air oxygen and nitrogen carry out separating-purifying storage after carry out subsequent commercial Application.It is empty Main component in gas is oxygen and nitrogen, and the boiling point of the two is different;The technological process of air separation is first compressed air, in advance Cold, purification is cooled further to Celsius subzero 100 more and spends, make liquid air, then utilizes the boiling-point difference of oxygen and nitrogen, Liquid air repeatedly evaporate and condense through rectifying column, makes oxygen and nitrogen separation, liquid oxygen and the liquid nitrogen production purified Product.
Air-seperation system needs a large amount of cryogenic cold energy, conventional liq space division generally use supercharging air cycle or nitrogen Pressurization cycle is reconfigured two high temperature, low-temperature turbine boosting expansion machine refrigeration provides institute's chilling requirement for air separation unit.Therefore, often The low temperature environment for advising air-seperation system is generated by the mechanical refrigeration of electric drive completely, its general power cost accounts for being produced into This 70% or so, while also to consume a large amount of cooling water.
Air-separating technology flow using cold energy of liquefied natural gas is that cold is passed to air segregative line by refrigerant Air cooling unit, the air rectification cell of system cancel the circulating nitrogen gas swell refrigeration unit in traditional space division technique.With tradition Air-seperation system is compared, and the compression energy consumption for cooling of air separation unit, base can be greatly lowered using the cold of liquefied natural gas Originally cooling water is not needed, while liquefied natural gas gasifying expense can also be reduced.Cold energy of liquefied natural gas space division technique can The cold of LNG cold position is made full use of, energy producing level can be used high, energy-saving advantage is notable.
Currently, it is conventional using cold energy of liquefied natural gas space division technique technology for cold energy of liquefied natural gas utilization rate less than 40%, just with shallow cold part, the deep cooling part for being worth bigger does not recycle.
Utility model content
In view of this, the utility model provides a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas, system Two technique units of conventional air swell refrigeration and cryogenic separation are completely separable, it is independently arranged, thoroughly eliminates the phase between the two Mutually interference, the respective technical process of re-optimization obtain largest device efficiency.
A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas, the system include liquified natural gas tank, liquefaction day Right gas cold energy recovery system, argon tank, raw argon column, liquid nitrogen container, purity nitrogen rectifying column, pure oxygen rectifying column, liquid oxygen tank, air purification System and dirty nitrogen cold energy recovery system;
Liquified natural gas tank leads to cold energy of liquefied natural gas recovery system, liquefied natural gas and liquefied natural gas by pipeline Pressurize after the refrigerant heat exchange of cold energy recovery system it is outer it is defeated for users to use, cold energy of liquefied natural gas recovery system by pipeline with it is pure Nitrogen rectifying column connects to form refrigerant circulation circuit, and purity nitrogen rectifying column is connected to by pipeline with liquid nitrogen container;The bottom of tower of purity nitrogen rectifying column It is connected to form feed back loop with the bottom of tower of pure oxygen rectifying column and tower top respectively with tower top, the bottom of tower of purity nitrogen rectifying column while and crude argon Rectifying column is connected to form liquid nitrogen cooling circuit;Argon gas is formed between raw argon column and pure oxygen rectifying column purifies circuit, pure oxygen essence It evaporates tower while being connected to liquid oxygen tank, air cleaning system communicates to form purging air circuit with dirty nitrogen cold energy recovery system, dirty nitrogen cold energy Recovery system forms dirty nitrogen cold energy recycling circuit with pure oxygen rectifying column and raw argon column.
Further, the cold energy of liquefied natural gas recovery system is using in low-temperature circulating working medium recycling liquified natural gas tank The cryogenic cold energies discharged during liquid phase liquefied natural gas gasifying to 28~35 DEG C of room temperature, and by the cold energy in specific operating mode It is passed in piece-rate system from purity nitrogen rectifying tower top heat exchanger under (pressure of 0.4MPa).
Further, the dirty nitrogen cold energy recovery system isolates pure oxygen rectifying column tower top containing a small amount of (1~2%) liquid After the dirty nitrogen part of oxygen is pre-chilled by dirty nitrogen cold energy recovery system to raw air, it is discharged into environment after dirty nitrogen regeneration.
Further, the pure oxygen rectifying column detaches oxygen in raw air, reaches purity requirement (99.99%) The dirty nitrogen of liquid oxygen product and higher degree (98%~99%), liquid oxygen product enter liquid oxygen storage tank as product store, dirty nitrogen into Enter purity nitrogen rectifying column further to detach.
Further, the purity nitrogen rectifying column further detaches the dirty nitrogen that pure oxygen rectifying column generates, and tower top generation reaches The liquid nitrogen product of purity requirement (99.999%) enters liquid nitrogen storage tank and is stored as product.Reflux dirty nitrogen in bottom of tower is with cold energy It returns to pure oxygen rectifying column to continue to detach, while the cold energy of liquefied natural gas is brought into inside pure oxygen rectifying column.
Further, the air cleaning system pre-processes raw air, removes impurity, makes to enter distillation system Air material composition be nitrogen, oxygen, argon gas and other trace amount of foreign gas.
Further, pure oxygen rectifier bottoms are contained liquid argon by the raw argon column and liquid oxygen enters crude argon rectifying Tower, tower top isolate the liquid argon product of high-purity (92%~98%), and bottom of tower high-purity liquid oxygen (94%~96%) product returns Enter liquid oxygen storage tank after liquid oxygen rectifying column.
Advantageous effect:
1, the system optimization of the utility model, independent cooling strengthen low-temperature heat exchange rectifying, space division gas products unit Energy consumption reduces by 20% or more, i.e., by our times advanced level 0.42KWh/m3(O2) it is down to 0.3KWh/m3(O2) below.
2, the operating pressure of the utility model can be developed to 1-1.2MPa from ultralow pressure 0.35MPa to high pressure;
3, liquefied natural gas normal pressure (- 162 DEG C of low temperature) gasifies in Tthe utility model system, it is ensured that whole gasification latent heats are lossless It loses.
4, the utility model chooses best refrigeration working medium and replaces existing nitrogen cycle refrigeration system, by cold contained by LNG by- 162 DEG C are down to -196 DEG C, make liquefaction of nitrogen, it is ensured that the cold energy of liquefied natural gas rate of recovery reaches 90% or more.
5, the system of the utility model mends cold fast, short, the elastic big, flexible adjustment of startup;System cancels turbo-expander, behaviour Make more stable reliable.
6, the utility model uses completely new low-temperature distillation process and equipment, the single rectification column fed using two-phase, it is ensured that It detaches efficient, energy-saving;System footprint substantially reduces, and construction investment is reduced by 30% or more and (advised with same liquid production Mould meter), system green recycles, low-carbon environment-friendly, and energy-saving effect is notable.
7, the product scheme design of the utility model is flexible, need to only adjust the technological parameter of heat exchange rectifying and can meet production It is required that.
Description of the drawings
Fig. 1 is the system composition and fundamental diagram of the utility model.
Specific implementation mode
With reference to the accompanying drawings and examples, the utility model is described in detail.
As shown in Fig. 1, the utility model provides a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas, should System includes liquified natural gas tank, cold energy of liquefied natural gas recovery system, argon tank, raw argon column, liquid nitrogen container, purity nitrogen rectifying Tower, pure oxygen rectifying column, liquid oxygen tank, air cleaning system and dirty nitrogen cold energy recovery system;
Liquefied natural gas enters cold energy recovery system, the liquid in cold energy of liquefied natural gas recovery system from natural gas tank output Change natural gas gasifying, cold energy is passed into the gaseous coolant in cold energy of liquefied natural gas recovery system, gaseous coolant 4 is become by gaseous state For liquid 3;Natural gas 2 after exchanging heat with refrigerant is outer defeated after pressurizeing, for users to use.Liquid refrigerants 3 enters purity nitrogen rectifying column, will The gaseous nitrogen of purity nitrogen rectifying column tower top is cooled to liquid nitrogen 9, and the gasification of liquid refrigerants 4 is that gaseous coolant 4 returns to cold energy of liquefied natural gas Recovery system continues to store cold energy of liquefied natural gas, and liquid nitrogen 9 after cooling is stored in liquid nitrogen container.The charging of purity nitrogen rectifying column is Dirty nitrogen 5 from pure oxygen rectifying column tower top.
Purity nitrogen rectifying column tower bottom distillate is oxygen nitrogen mixing liquid 6, and part nitrogen oxygen mixing liquid 8 enters pure oxygen essence as charging Tower is evaporated, another part nitrogen oxygen mixing liquid 7 enters raw argon column as low-temperature receiver.The oxygen extracted from pure oxygen rectifying column middle and lower part Charging of the argon mixture gas 12 as raw argon column, raw argon column tower top are isolated the higher gas argon of purity 14 and are stored up into argon Tank, bottom of tower are that the higher oxygen argon mixture gas of oxygen content 13 is back in pure oxygen rectifying column.
Air 20 is purified by air cleaning system, and purified air 18 enters dirty nitrogen cold energy recovery system 2 and returns The cold that the dirty nitrogen 15 after cold is provided from pure oxygen rectifying tower top part dirt nitrogen 10 and for raw argon column is received, it is after cooling Cold air 16 enters pure oxygen rectifying column as charging.It isolates liquid oxygen 11 and stores up into liquid oxygen tank, tower top separation in pure oxygen rectifying tower bottom Charging of the part dirt nitrogen 5 gone out as purity nitrogen rectifying column, another part dirt nitrogen 10 is by dirty nitrogen cold energy recovery system and dirty nitrogen 15 Enter air cleaning system after mixing, as the regeneration purge gas 17 of air cleaning system, by the dirty nitrogen of air cleaning system 19 are discharged into air.
In conclusion the above is only the preferred embodiments of the present utility model only, it is not intended to limit the utility model Protection domain.Within the spirit and principle of the utility model, any modification, equivalent replacement, improvement and so on should all wrap Containing being within the protection scope of the utility model.

Claims (6)

1. a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas, which includes liquified natural gas tank, liquefies naturally Gas cold energy recovery system, argon tank, raw argon column, liquid nitrogen container, purity nitrogen rectifying column, pure oxygen rectifying column, liquid oxygen tank, air purification system System and dirty nitrogen cold energy recovery system;
Liquified natural gas tank leads to cold energy of liquefied natural gas recovery system, liquefied natural gas and cold energy of liquefied natural gas by pipeline Pressurize after the refrigerant heat exchange of recovery system it is outer it is defeated for users to use, cold energy of liquefied natural gas recovery system passes through pipeline and purity nitrogen essence It evaporates tower to connect to form refrigerant circulation circuit, purity nitrogen rectifying column is connected to by pipeline with liquid nitrogen container;The bottom of tower of purity nitrogen rectifying column and tower Top is connected to form feed back loop with the bottom of tower of pure oxygen rectifying column and tower top respectively, the bottom of tower of purity nitrogen rectifying column simultaneously with crude argon rectifying Tower is connected to form liquid nitrogen cooling circuit;Argon gas is formed between raw argon column and pure oxygen rectifying column purifies circuit, pure oxygen rectifying column It is connected to liquid oxygen tank simultaneously, air cleaning system communicates to form purging air circuit with dirty nitrogen cold energy recovery system, dirty nitrogen cold energy recycling System forms dirty nitrogen cold energy recycling circuit with pure oxygen rectifying column and raw argon column.
2. a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas as described in claim 1, which is characterized in that described Cold energy of liquefied natural gas recovery system is arrived using liquid phase liquefied natural gas gasifying in low-temperature circulating working medium recycling liquified natural gas tank The cryogenic cold energy discharged during 28~35 DEG C, and the cold energy is passed under the pressure of 0.4MPa from purity nitrogen rectifying tower top heat exchanger Enter in piece-rate system.
3. a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas as claimed in claim 1 or 2, which is characterized in that It is cold by dirty nitrogen that pure oxygen rectifying column tower top is isolated the dirty nitrogen part containing 1~2% liquid oxygen by the dirt nitrogen cold energy recovery system After energy recovery system is pre-chilled to raw air, it is discharged into environment after dirty nitrogen regeneration.
4. a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas as claimed in claim 3, which is characterized in that described Pure oxygen rectifying column detaches oxygen in raw air, obtain liquid oxygen product that purity is 99.99% and purity be 98%~ 99% dirty nitrogen, liquid oxygen product enter liquid oxygen storage tank and store as product, and dirty nitrogen enters purity nitrogen rectifying column and further detaches.
5. a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas as claimed in claim 4, which is characterized in that described Purity nitrogen rectifying column further detaches the dirty nitrogen that pure oxygen rectifying column generates, and tower top generates the liquid nitrogen production for reaching that purity is 99.999% Product enter liquid nitrogen storage tank and are stored as product;Reflux dirty nitrogen in bottom of tower returns to pure oxygen rectifying column with cold energy to be continued to detach, together When the cold energy of liquefied natural gas is brought into inside pure oxygen rectifying column.
6. a kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas as claimed in claim 5, which is characterized in that described Pure oxygen rectifier bottoms are contained liquid argon to raw argon column and liquid oxygen enters raw argon column, and it is 92% that tower top, which isolates purity, ~98% liquid argon product, bottom of tower purity are to enter liquid oxygen storage tank after 94%~96% liquid oxygen product returns to liquid oxygen rectifying column.
CN201820124247.8U 2018-01-24 2018-01-24 A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas Withdrawn - After Issue CN207815831U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108224900A (en) * 2018-01-24 2018-06-29 北京拓首能源科技股份有限公司 A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108224900A (en) * 2018-01-24 2018-06-29 北京拓首能源科技股份有限公司 A kind of oxygen nitrogen and argon piece-rate system using cold energy of liquefied natural gas
CN108224900B (en) * 2018-01-24 2024-01-09 北京拓首能源科技股份有限公司 Oxygen-nitrogen-argon separation system utilizing liquefied natural gas cold energy

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