CN207793119U - The device of continuous production high-quality N- fatty acyl amino-acid salt surfactants - Google Patents
The device of continuous production high-quality N- fatty acyl amino-acid salt surfactants Download PDFInfo
- Publication number
- CN207793119U CN207793119U CN201721842777.8U CN201721842777U CN207793119U CN 207793119 U CN207793119 U CN 207793119U CN 201721842777 U CN201721842777 U CN 201721842777U CN 207793119 U CN207793119 U CN 207793119U
- Authority
- CN
- China
- Prior art keywords
- entrance
- amidation
- column
- mixing arrangement
- acid salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 25
- 238000010924 continuous production Methods 0.000 title claims abstract description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 66
- 238000006243 chemical reaction Methods 0.000 claims abstract description 50
- 230000032683 aging Effects 0.000 claims abstract description 36
- 230000009435 amidation Effects 0.000 claims abstract description 32
- 238000007112 amidation reaction Methods 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 31
- 150000001263 acyl chlorides Chemical class 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 22
- 230000003068 static effect Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000000344 soap Substances 0.000 abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 7
- 229910052708 sodium Inorganic materials 0.000 abstract description 7
- 239000011734 sodium Substances 0.000 abstract description 7
- -1 fatty acyls amino-acid salt Chemical class 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 235000001014 amino acid Nutrition 0.000 description 39
- 150000001413 amino acids Chemical class 0.000 description 25
- 239000000047 product Substances 0.000 description 22
- 239000000463 material Substances 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 12
- 238000011938 amidation process Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 230000004044 response Effects 0.000 description 8
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 235000004279 alanine Nutrition 0.000 description 6
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 5
- 239000004472 Lysine Substances 0.000 description 5
- NQGIJDNPUZEBRU-UHFFFAOYSA-N dodecanoyl chloride Chemical compound CCCCCCCCCCCC(Cl)=O NQGIJDNPUZEBRU-UHFFFAOYSA-N 0.000 description 5
- DKGAVHZHDRPRBM-UHFFFAOYSA-N tertiry butyl alcohol Natural products CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZQXSFZAMFNRZOQ-UHFFFAOYSA-N 2-methylpropan-2-ol;hydrate Chemical compound O.CC(C)(C)O ZQXSFZAMFNRZOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 238000003436 Schotten-Baumann reaction Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229960000074 biopharmaceutical Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 208000012839 conversion disease Diseases 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 125000003630 glycyl group Chemical group [H]N([H])C([H])([H])C(*)=O 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ARBOVOVUTSQWSS-UHFFFAOYSA-N hexadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCC(Cl)=O ARBOVOVUTSQWSS-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The utility model belongs to daily-use chemical industry technical field.Purpose is to provide a kind of concise in technology, the device of the remaining continuous production high-quality N fatty acyls amino-acid salt surfactant of organic solvent-free.It is remained using the N fatty acyl amino-acid salt organic solvent-frees that the device produces, and can effectively improve the conversion ratio of acyl chlorides, reduce the content of sodium soap, improve product quality.Technical solution is：A kind of device of continuous production high-quality N fatty acyl amino-acid salt surfactants, it is characterised in that：Mixing arrangement, heat exchanger and the amidation column that the device is sequentially communicated including the use of pipeline, are then divided into two-way, are respectively connected to the second entrance of mixing arrangement and connect aging device entrance by heater, the aging device is equipped with products export；The first entrance of the mixing arrangement connects ispol entrance parallel with one another, acyl chlorides entrance and liquid caustic soda entrance.
Description
Technical field
The utility model belongs to daily-use chemical industry technical field, specifically continuous production high-quality N- fat acylamino-s
The device of acid salt surfactant.
Background technology
Surfactant is however big at present due to unique application performance, being concerned and applying in numerous areas
Most surfactants belong to petroleum-based sources, due to raw material non-renewable, low chemical safety and refractory organics and
It receives and denounces.
With the continuous development of industrial technology, novel surfactant is come out one after another, and amino acid surfactant is exactly it
In one kind.Due to raw material natural reproducible and its own with excellent surface-active, good calcium soap dispersibility, it is excellent
The advantages such as different bacteriostasis, high security, low irritant, easily biological-degradable and good Environmental compatibility, amino acid surface
Activating agent obtains in fields such as daily use chemicals, food, beverage, bio-pharmaceuticals, mineral floating, metal cleaner, textile printing and dyeing, agriculture breasts
Relatively broad research and application.External manufacturing firm has the Hamposyl series of Dow company, Switzerland's Clariant public
Medialan and the Hostapon series of department, the Amisoft series of Japanese aginomoto；There are lion in Nanjing, Guangzhou in domestic producer
Be bestowed by heaven, profit is inspired confidence in Guangzhou hundred, Shanghai profit contain etc..
The production of amino acid surfactant has enzyme-catalyzed change method, such as Hasmah Bidin have studied through lipase RM
IM is catalyzed palm grease and lysine prepares amino acid surfactant；Also dehydrating condensation method, such as Woodbury have studied
Under hot conditions, aliphatic acid can directly generate corresponding amino acid surfactant with amino acid alkali metal salt.But due to various
Reason, the industrialized production of amino acid surfactant is main at present or indirect method --- chemical synthesis, such as patent CN
104640839B is disclosed according to Schotten- Baumann condensation method principles, using N- acyl amino acid surfactants or
Corresponding acid anhydrides produces N- acyl amino acid surfactants as catalyst；Patent JP11180938 is condensation with water-tert-butyl alcohol
Reaction dissolvent forms stable water/tert-butyl alcohol/active matter ternary system and again secondary clearing, then obtains product by distilation；
US20150126776 uses glycerine as solvent, and alkali or alkaline earth metal oxide, alkali metal methoxide etc. are as catalysis
Agent synthesizes N- fatty acyl amino-acid salts；Patent WO2015026538 better products of color and luster in order to obtain, use methanol as solvent.
Patent CN102311359A and CN105439882A disclose a kind of fatty instead of fat acyl chloride synthesis N- using fatty acid methyl ester
The method of acyl amino acids surfactant.
In existing research and patent document, many improvement and wound have been carried out to the preparation of amino acid surfactant
Newly, it is still current main industrialized production that acyl chlorides is reacted with amino acid condensation.In order to improve reaction conversion ratio and N-
The yield of fatty acid acylamino acid class surfactant needs in technique productions methanol, the tert-butyl alcohol, glycerine etc. is added organic molten
Agent；And although the organic solvent being added have passed through the removing of subsequent technique, but inevitably still have part residual, to product
Quality, using exerting a certain influence.
Utility model content
The purpose of the utility model is to overcome the deficiencies of above-mentioned technology, provide a kind of concise in technology, organic solvent-free residual
Continuous production high-quality N- fatty acyl amino-acid salt surfactants device.The N- fatty acyl ammonia produced using the device
Base hydrochlorate organic solvent-free remains, and can effectively improve the conversion ratio of acyl chlorides, reduces the content of sodium soap, improves product
Quality.
The technical solution of the utility model is：
A kind of device of continuous production high-quality N- fatty acyl amino-acid salt surfactants, it is characterised in that：The dress
Mixing arrangement, heat exchanger and the amidation column being sequentially communicated including the use of pipeline are set, is then divided into two-way, is respectively connected to mix
The second entrance of device and by heater connect aging device entrance, the aging device be equipped with products export；The mixing dress
The first entrance set connects ispol entrance parallel with one another, acyl chlorides entrance and liquid caustic soda entrance.
The amidation column is the overflow column with stirring, and arrival end is located at amidation column bottom, and outlet end is located at amide
Change column upper side.
The mixing arrangement includes static mixer or shear pump.
The aging device is the column reactor suitable for successive reaction, or is the still reaction suitable for intermittent reaction
Device.
Compared with prior art, the utility model has the advantage that：
(1) it in existing N- fatty acyls amido hydrochlorate production technology, needs to add organic solvent, and the utility model does not need
Add organic solvent；So as to avoid in product the problem of organic solvent residual.
(2) solvent production N- fatty acyl amino-acid salts are used water as, reaction system needs to maintain higher pH, but with
The progress of reaction, pH are drastically reduced, and are unfavorable for the progress of amidation process, but the decomposition of side reaction acyl chlorides increases
Add, generate a large amount of sodium soap, influences product quality and performance；The utility model technique uses the amino acid of different isoelectric points
It is compounded, has obtained, with the reaction system for stablizing buffer pH, to keep reacting required higher pH, while can effectively inhibit
The decomposition of acyl chlorides considerably reduces the generation of sodium soap, and 80% can be about reduced compared with unitary system sodium soap.
(3) water law is utilized to produce N- fatty acyl amino-acid salts, with the progress of reaction, amino acid and acyl chlorides persistently disappear
Consumption, can lead to the continuous decrease of pH value of reaction system, need to continue to mend alkali in conventional production and maintain optimum response pH value, therefore compared with
Hardly possible realizes the continuous production of the technique.The utility model technique is compounded using the amino acid of different isoelectric points, is had
There is the raw material reaction system that pH bufferings are adjusted；The reaction simultaneously is flowed back using ratio, and amidation process material is fully mixed with virgin material
It closes, amidation process pH is made to obtain stability contorting；The two collective effect, during effectively can controlling continuous reaction, pH value
Always in best pH value in reaction；Enable continuous production is simple smoothly to implement.
(4) each device in the utility model is conventional components, thus technology maturation, service life are long, and cost is not yet
It is high.
Description of the drawings
Fig. 1 is the knot of continuous production high-quality N- fatty acyls amino-acid salt surfactant device described in the utility model
Structure schematic diagram.
Wherein：A is ispol entrance, and b is acyl chlorides entrance, and c is liquid caustic soda entrance, and d is products export, and 1 is mixing
Device, 2 be heat exchanger, and 3 be delivery pump, and 4 be amidation column, and 5 be heater, and 6 be aging device.
Specific implementation mode
The utility model is compounded amino acid starting material reaction system, can effectively adjust required soda acid ring in reaction process
Border, be it is a kind of it is completely new, suitable for the preparation system of industrialized production high-quality N- fatty acyl amino-acid salts.
A kind of device of continuous production high-quality N- fatty acyl amino-acid salt surfactants, successively including the use of pipeline
Mixing arrangement 1, heat exchanger 2 and the amidation column 4 of connection, are then divided into two-way, are respectively connected to the second entrance of mixing arrangement
And aging device entrance is connected by heater 5, the aging device is equipped with products export；The first entrance of the mixing arrangement connects
Logical ispol entrance a, acyl chlorides entrance b and liquid caustic soda entrance c parallel with one another.
The amidation column is the overflow column with stirring, and arrival end is located at amidation column bottom, and outlet end is located at amide
Change column upper side.
The mixing arrangement includes static mixer or shear pump.
The aging device is the column reactor suitable for successive reaction, or is the still reaction suitable for intermittent reaction
Device.
Using the technique of above-mentioned apparatus continuous production high-quality N- fatty acyl amino-acid salt surfactants, including it is following
Step：
(1) it is mixed to respectively enter a mixing arrangement for reaction mass ispol, acyl chlorides, liquid caustic soda and circulating and recovering material
It is even；
(2) material after mixing enters one by bottom using a delivery pump and carries overflow port after heat exchanger cools down
In amidation column, amidation process is carried out under suitable temperature, pH value；
(3) product after amidation through amidation column overflow port spilling after, a part be used as circulating and recovering material, again into
Enter mixing arrangement and carries out circular response；After the heated device heating of another part, aging reaction is carried out into aging device；The cycle
The mass ratio of reuse material and the material for entering aging device is 2-20:1；
(4) reaction product after aging, that is, object N- fatty acyl amino-acid salts；
Ispol is the aqueous solution or/and amino-acid salt mixture of ispol in the step (1)
Aqueous solution；The mass concentration of aqueous solution is 5-50%；It is preferred that 10-30%.
The ispol is two amino acids and its saline admixture, one type include isoelectric point 7.0 with
Under amino acid and its esters one or more；Another kind of includes amino acid and its esters of the isoelectric point 9.0 or more
It is one or more kinds of；The mass ratio of two amino acids and its saline admixture is 100:1-20.
The isoelectric point is glycine, alanine or glutamic acid in 7.0 amino acid below；The isoelectric point 9.0 with
On amino acid be lysine or arginine.
The reaction mass ispol, acyl chlorides, liquid caustic soda and circulating and recovering material pan feeding flow by amidation
The dischargeable capacity of column determines；It is 2-24h, preferably 4- to generally require mean residence time of the control material in amidation column
10h；
The mass ratio of the pan feeding substance of the ispol and acyl chlorides is 1.0~3.0:1；The liquid caustic soda flow according to
PH value into amidation pre-column reaction system determines；The pH value into amidation pre-column reaction system is 7-12, preferably
For 8-11；The liquid caustic soda flow is automatically controlled by the way that online pH meter is chain, or is manual adjusting control；
The acyl chlorides is the fatty acid chloride of C8-C18, preferably lauroyl chloride, cocounut oil acyl chlorides, palmitoyl chloride；The liquid caustic soda
Mass concentration be 5-50%, preferably 10-32%；
Suitable reaction temperature described in step (2) is 5-50 DEG C, preferably 10-30 DEG C.
Aging temperature described in step (3) be 20-100 DEG C, preferably 40-80 DEG C, ageing time 2-24h, preferably 4-
12h。
The utility model is further illustrated below in conjunction with specific embodiment.
Embodiment 1：Ispol aqueous solution (the wherein mass ratio of alanine and lysine that mass concentration is 20%
It is 100：8), lauroyl chloride, the liquid caustic soda that mass concentration is 20% respectively enter mixing arrangement and are uniformly mixed, and wherein amino acid mixes
The charging rate of the charging rate 108kg/h of object aqueous solution, lauroyl chloride are 40kg/h, and the flow of liquid caustic soda is read according to pH meter
Automatic adjustment controls pH9.5 ± 0.2；The speed of circular response material is 1000kg/h；After cooler cools down, conveying is utilized
Pump, which is transported in amidation column, carries out amidation process, 20 DEG C of controlling reaction temperature, stop of the reaction mass in amidation column
Time is 5h；Product after reaction enters aging kettle by 200kg/h, and control aging temperature is 60 DEG C, ageing time 6h；Remaining
Product after reaction enters mixing arrangement as recycle stock and continues to react.
Embodiment 2：Ispol aqueous solution (the wherein mass ratio of alanine and lysine that mass concentration is 25%
It is 100：10), cocounut oil acyl chlorides, the liquid caustic soda that mass concentration is 15% respectively enter mixing arrangement and are uniformly mixed, and wherein amino acid is mixed
The charging rate 50kg/h of object aqueous solution is closed, the charging rate of acyl chlorides is 36kg/h, and the flow of liquid caustic soda is read automatically according to pH meter
It adjusts, controls pH10.0 ± 0.2；The speed of circular response material is 1000kg/h；After cooler cools down, delivery pump is utilized
It is transported in amidation column and carries out amidation process, 18 DEG C of controlling reaction temperature, when stop of the reaction mass in amidation column
Between be 6h；Product after reaction enters aging kettle by 160kg/h, and control aging temperature is 70 DEG C, ageing time 4h；Remaining
Product after reaction enters mixing arrangement as recycle stock and continues to react.
Embodiment 3：Ispol aqueous solution (the wherein alanine and arginic mass ratio that mass concentration is 15%
It is 100：2), lauroyl chloride, the liquid caustic soda that mass concentration is 32% respectively enter mixing arrangement and are uniformly mixed, and wherein amino acid mixes
The charging rate of the charging rate 152kg/h of object aqueous solution, acyl chlorides are 50kg/h, and the flow of liquid caustic soda reads automatic adjust according to pH meter
Section controls pH10.5 ± 0.2；The speed of circular response material is 1000kg/h；It is defeated using delivery pump after cooler cools down
It is sent in amidation column and carries out amidation process, 15 DEG C of controlling reaction temperature, residence time of the reaction mass in amidation column
For 4h；Product after reaction enters aging kettle by 250kg/h, and control aging temperature is 50 DEG C, ageing time 8h；Remaining reaction
Product afterwards enters mixing arrangement device as recycle stock and continues to react.
Embodiment 4：Ispol aqueous solution (the wherein alanine and arginic mass ratio that mass concentration is 30%
It is 100：1), cocounut oil acyl chlorides, the liquid caustic soda that mass concentration is 15% respectively enter mixing arrangement and are uniformly mixed, and wherein amino acid mixes
The charging rate of object aqueous solution is 48kg/h, and the charging rate of acyl chlorides is 38kg/h, and the speed of circular response material is 1000kg/
h；The flow of liquid caustic soda reads according to pH meter and automatically adjusts, and controls pH10.0 ± 0.2；It is defeated using delivery pump after cooler cools down
It is sent in amidation column and carries out amidation process, control amidation process temperature is 18 DEG C；Reaction mass is in amidation column
Residence time is 6h；Product after reaction enters aging kettle by 150kg/h, and control aging temperature is 65 DEG C, ageing time 6h；
Product after remaining reaction enters mixing arrangement as recycle stock and continues to react.
Comparative example 1：The liquid caustic soda that the third amino acid solution that mass concentration is 20%, lauroyl chloride, mass concentration are 20%
It respectively enters mixing arrangement to be uniformly mixed, wherein the charging rate 88kg/h of alanine aqueous solution, the charging rate of acyl chlorides are
36kg/h, the flow of liquid caustic soda is read according to pH meter to be automatically adjusted, and pH10.0 ± 0.2 is controlled；The speed of circular response material is
1000kg/h；After cooler cools down, it is transported in amidation column using delivery pump and carries out amidation process, controlling reaction temperature
20 DEG C, residence time of the reaction mass in amidation column is 5h；Product after reaction enters aging kettle by 200kg/h, enters
It is 60 DEG C to control aging temperature, ageing time 6h；Product after remaining reaction enters mixing arrangement as recycle stock to be continued
It is reacted.
Comparative example 2：The liquid caustic soda that bad amino acid solution that mass concentration is 20%, cocounut oil acyl chlorides, mass concentration are 32%
Mixing arrangement mixing, wherein the charging rate 76kg/h of lysine solution are respectively enterd, the charging rate of acyl chlorides is 30kg/h,
The flow of liquid caustic soda reads according to pH meter and automatically adjusts, and controls pH10.5 ± 0.2；The speed of circular response material is 1000kg/h；
After cooler cools down, it is transported in amidation column using delivery pump and carries out amidation process, 20 DEG C of controlling reaction temperature, reaction
Residence time of the material in amidation column is 6h；Product after reaction enters aging kettle by 150kg/h, into control aging temperature
Degree is 60 DEG C, ageing time 8h；Product after remaining reaction enters mixing arrangement as recycle stock and continues to react.
1 product test data comparison of table
| Index | Appearance | Color and luster, Hazen | Sodium soap, % |
| Embodiment 1 | Clear | 10 | 0.9 |
| Embodiment 2 | Clear | 12 | 1.1 |
| Embodiment 3 | Clear | 13 | 1.1 |
| Embodiment 4 | Clear | 10 | 0.8 |
| Comparative example 1 | Clear | 30 | 5.4 |
| Comparative example 2 | Clear | 28 | 5.8 |
PH value changes before and after 2 amidation of table
| Index | PH before column | PH after column |
| Embodiment 1 | 9.7 | 9.4 |
| Embodiment 2 | 10.1 | 9.7 |
| Embodiment 3 | 10.6 | 10.1 |
| Embodiment 4 | 10.1 | 9.6 |
| Comparative example 1 | 10.2 | 8.1 |
| Comparative example 2 | 10.5 | 8.3 |
It was found from test data：The color and luster of 4 embodiments is significantly better than comparative example, the sodium soap content of 4 embodiments
Then it is considerably less than comparative example.Obtain satisfactory effect.
Claims (2)
1. a kind of device of continuous production high-quality N- fatty acyl amino-acid salt surfactants, it is characterised in that：The device
Mixing arrangement (1), heat exchanger (2) and the amidation column (4) being sequentially communicated including the use of pipeline, are then divided into two-way, respectively
It accesses the second entrance of mixing arrangement and (5) is connected by heater and connect aging device entrance, the aging device is equipped with products export；
The first entrance of the mixing arrangement is connected ispol entrance (a) parallel with one another, acyl chlorides entrance (b) and liquid caustic soda and is entered
Mouth (c)；
The amidation column is the overflow column with stirring, and arrival end is located at amidation column bottom, and outlet end is located at amidation column
Upper side.
2. the device of continuous production high-quality N- fatty acyl amino-acid salt surfactants according to claim 1,
It is characterized in that：The mixing arrangement includes static mixer or shear pump；The aging device is the pillar suitable for successive reaction
Reactor, or be the tank reactor suitable for intermittent reaction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721842777.8U CN207793119U (en) | 2017-12-26 | 2017-12-26 | The device of continuous production high-quality N- fatty acyl amino-acid salt surfactants |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721842777.8U CN207793119U (en) | 2017-12-26 | 2017-12-26 | The device of continuous production high-quality N- fatty acyl amino-acid salt surfactants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN207793119U true CN207793119U (en) | 2018-08-31 |
Family
ID=63281012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201721842777.8U Active CN207793119U (en) | 2017-12-26 | 2017-12-26 | The device of continuous production high-quality N- fatty acyl amino-acid salt surfactants |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN207793119U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003050A (en) * | 2017-12-26 | 2018-05-08 | 赞宇科技集团股份有限公司 | A kind of technique and device of continuous production high-quality N- fatty acyl amino-acid salt surfactants |
| CN115504898A (en) * | 2022-09-22 | 2022-12-23 | 山东万盛新材料有限公司 | Preparation method of N-acyl acidic amino acid alkali metal salt aqueous solution |
-
2017
- 2017-12-26 CN CN201721842777.8U patent/CN207793119U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003050A (en) * | 2017-12-26 | 2018-05-08 | 赞宇科技集团股份有限公司 | A kind of technique and device of continuous production high-quality N- fatty acyl amino-acid salt surfactants |
| CN108003050B (en) * | 2017-12-26 | 2024-03-08 | 赞宇科技集团股份有限公司 | Process and device for continuously producing high-quality N-fatty acyl amino acid salt surfactant |
| CN115504898A (en) * | 2022-09-22 | 2022-12-23 | 山东万盛新材料有限公司 | Preparation method of N-acyl acidic amino acid alkali metal salt aqueous solution |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108003050A (en) | A kind of technique and device of continuous production high-quality N- fatty acyl amino-acid salt surfactants | |
| JP6931284B2 (en) | How to make taurine | |
| RU2317976C2 (en) | Method of producing aqueous solution of acrylamide utilizing biocatalyst | |
| JP2019513688A5 (en) | ||
| CN207793119U (en) | The device of continuous production high-quality N- fatty acyl amino-acid salt surfactants | |
| CN102775441B (en) | Continuous production method of glyphosate synthetic liquid | |
| CN105541845A (en) | Folic-acid cleaning production technology | |
| CN101161685A (en) | Method for preparing surface sizing fecula by synchronous etherification oxidation semi-dry process | |
| CN110817926A (en) | Method for directly preparing α -hemihydrate gypsum from titanium white waste acid | |
| CN110422830A (en) | The method for preparing calcium monohydrogen phosphate and ammonium chloride using flotation phosphate tailing | |
| CN101671285B (en) | Preparation method of dibenzenesulfonimide | |
| CN108441967A (en) | The method that hydrochloric acid resolving high magnesium phosphorus tailing prepares calcium sulfate crystal whiskers | |
| CN102633699B (en) | Method for preparing DL-methionine | |
| CN110330439A (en) | A kind of zinc-glycine complex and preparation method thereof not introducing foreign ion | |
| CN101462980A (en) | Industrial production method of 2,6-difluorobenzamide | |
| CN110981747B (en) | Production process and device of high-quality betaine surfactant | |
| CN205740834U (en) | A kind of continuous security reaction device being applicable to methyl chloroacetate and trimethylamine reaction | |
| CN106345387B (en) | A kind of continuous reaction apparatus and method of amino acid surfactant | |
| CN205634920U (en) | Utilize device of acid etching solution and alkaline etching liquid preparation oxo -chlorination copper | |
| CN108623488A (en) | A kind of synthetic method of aminomethylbenzoic acid | |
| CN208599727U (en) | The Multifunction cross varying load reaction kettle of white carbon black is prepared for double salt double decompositions | |
| CN104177178B (en) | Anti-blocking agent produced from soybean oil deodorizing distillate as well as production method and application of anti-blocking agent | |
| CN106430247A (en) | Method for preparing high-concentration sodium hydroxide by ultrasonically intensifying sodium sulfate | |
| CN109879786A (en) | A kind of technique of the continuous rapid synthesis methionine of cyanalcohol method | |
| CN100365071C (en) | Method for producing indigo by recycling unreacted raw materials |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240313 Address after: B1-3-231, No. 198 Qidi Road, Economic and Technological Development Zone, Xiaoshan District, Hangzhou City, Zhejiang Province, 311200 Patentee after: Zhejiang Yabrown Technology Co.,Ltd. Country or region after: China Address before: Hangzhou City, Zhejiang province 310009 City Shangcheng District No. 128 Lane Patentee before: ZANYU TECHNOLOGY GROUP CO.,LTD. Country or region before: China Patentee before: JIAXING ZANYU TECHNOLOGY DEVELOPMENT Co.,Ltd. |