CN207680346U - A kind of foul waste gas removing system rotation filler device - Google Patents

A kind of foul waste gas removing system rotation filler device Download PDF

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Publication number
CN207680346U
CN207680346U CN201721035584.1U CN201721035584U CN207680346U CN 207680346 U CN207680346 U CN 207680346U CN 201721035584 U CN201721035584 U CN 201721035584U CN 207680346 U CN207680346 U CN 207680346U
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filler
liquid
waste gas
rotary table
central tube
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CN201721035584.1U
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徐波
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Xi'an He Li Gus Amperex Technology Ltd
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Xi'an He Li Gus Amperex Technology Ltd
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Abstract

The utility model is related to a kind of foul waste gas removing system rotation filler devices, including rotary packed bed, rotary packed bed includes revolving bed main body and transmission device, the inner cavity of revolving bed main body be equipped with can high speed counter-rotating filler rotor, which passes through drive;Filler rotor is equipped with top rotary table and lower rotary table, rotation filler is provided between top rotary table and lower rotary table, the other end of central tube is embedded in rotation filler, the center of top rotary table passes through a central tube, one end of the central tube is connect by pipeline with ionic liquid container, and the outer wall of the other end is equipped with several through-holes thrown away for absorbing liquid.It is flowed from top to bottom by center opening pipe under the action of the absorption liquid that the utility model is realized by ionic liquid is in rotary packed bed middle absorption malodor components is in elevator pump, under rotating centrifugal effect, the renewal rate for accelerating absorption interface while absorbing liquid wetting filler, ensures assimilation effect.

Description

A kind of foul waste gas removing system rotation filler device
Technical field
The utility model belongs to environmentally friendly deodorization field, and in particular to a kind of foul waste gas removing system rotation filler dress It sets.
Background technology
Odor pollution is one of feature pollution of petroleum refining industry, has been recognized by the world today as environmental hazard. It causes the unhappiness of people by the smell of people first, then by stimulating Sensory nerve's system of people, destroys human body new old generation It thanks, to cause nerve and menticide.People are lived in for a long time in stench environment, will cause giddy, insomnia, apocleisis, note Recall the various functions diseases such as power decline and mood agitation, and then influences health.
External advanced country starts to walk early to the Study on treatment technology of odor pollution, and malodorous discharge standard is more demanding.With The raising of domestic residents living standards and the enhancing of environmental consciousness, the ratio that odor pollution is complained have significant rising.It dislikes in China In smelly discharge standard, the most important pollutant hydrogen sulfide of petroleum gas chemical industry, methyl mercaptan, methyl sulfide, methyl disulfide etc. It is listed.
The odor polluting source of petrochemical plant point overhead pollution sources and uncontrollable discharge pollution sources.Overhead pollution sources are mainly Necessary process gas discharge in process of production, such gas is often through large-scale purifier, such as hydramine method, ammonia process or Gypsum focused on after by the chimney of certain altitude, the row up to standard under the premise of meeting state environmental emissioning standard It puts.
In addition it is the main source for refining oil plant area's odor pollution to account for nearly three one-tenth of the uncontrollable discharge source of malodor source sum, these Malodor source is distributed in most of process units based on sewage farm, product purification retracting device and storage tank zone.With containing In sulphur crude oil processing, the increase of various medium sulfur content, the type and concentration of the malodorant of these stench source emissions also increase Add, the run, drip, leak storage tank breathing loss that can't be mainly fully solved on equipment management and manufacturing technology, open-top receptacle Volatilization.Such gas has overall narrow-minded, stench point dispersion, odour concentration height, contains combustible gas component simultaneously, exists easily The features such as firing explosive risk.
For this kind of sulphur-containing exhaust gas, currently used Deodor method has combustion method, solution absorption method, solid absorption Method, biological deodorization method etc., these methods have some limitations and different specific aims.Solid absorption method is in sulphur-containing exhaust gas Using more in deodorization technique, but that there are adsorbents is hardened, and utilization rate is not high, replaces that risk is high, and local temperature increases after mixing oxygen, The deficiencies of being easy to happen safety accident;Although sulphur-containing exhaust gas burning can be the sulfur dioxide of free from extraneous odour by combustion method, due to Waste gas component is complicated, or even contains the hydrocarbonaceous flashed vapour in part, therefore exists and dodge quick-fried equivalent risk;Biological deodorization method mainly utilizes alkali Property solution or microorganism alkalescence Environmental Chemistry absorb, but there are plant area is larger, biological inoculum stability is poor, mating work The deficiencies of journey is more.
The mechanism of solvent absorption is related to mass transfer between multiphase flow, heat transfer and reacts, be chemical industry, the energy, environmental protection, Most basic one of production process in the fields such as material, biochemical industry largely uses packed tower, plate column etc. during these Mass transfer apparatus, and the liquid phase flowing in equipment often relies on gravity to realize.Since liquid flowing is slow under gravitational field, body Product mass tranfer coefficient is small, and the production intensity of space availability ratio and equipment is relatively low.Therefore, this kind of equipment is bulky, the throwing of equipment Money, maintenance cost and energy consumption are higher, are relatively more suitable for large-scale gas purifying technique.
Utility model content
In order to solve the above-mentioned problems in the prior art, the utility model provides a kind of foul waste gas removing system With rotation filler device.The technical problems to be solved in the utility model is achieved through the following technical solutions:
A kind of foul waste gas removing system rotation filler device, including rotary packed bed, it is described rotary packed bed to include Revolving bed main body and transmission device, the inner cavity of the revolving bed main body be equipped with can high speed counter-rotating filler rotor, the filler Rotor passes through drive;The filler rotor is equipped with top rotary table and lower rotary table, between the top rotary table and lower rotary table It is provided with rotation filler, the other end of the central tube is embedded in the rotation filler, and the center of the top rotary table passes through one One end of central tube, the central tube is connect by pipeline with ionic liquid container, and the outer wall of the other end is equipped with several for inhaling Receive the through-hole that liquid is thrown away.
A kind of above-mentioned foul waste gas removing system rotation filler device, the hole of the filler is with up big and down small Structure.
A kind of above-mentioned foul waste gas removing system rotation filler device, the revolving bed main body are equipped with for being connected to The foul waste gas import of malodor source, the gas vent for deodorization after-purification gas to be discharged, the foul waste gas import, gas go out Mouth is respectively positioned on the side wall of the revolving bed main body, and is connected to the inner cavity of the revolving bed main body, the foul waste gas import Positioned at the lower section of the gas vent.
A kind of above-mentioned foul waste gas removing system is additionally provided in revolving bed main body with filler device is rotated for absorbing liquid The liquid inlet of entrance, for be discharged absorb foul gas after ionic liquid liquid outlet, the liquid inlet is located at described The top of liquid outlet.
A kind of above-mentioned foul waste gas removing system rotation filler device, the rotary packed bed rotation filler is gold Belong to twine, becket or ceramic material.
The beneficial effects of the utility model:
1. the absorption liquid that the utility model is realized by ionic liquid is in rotary packed bed middle absorption malodor components exists It is flowed from top to bottom by center opening pipe under the action of elevator pump, under rotating centrifugal effect, absorbs liquid wetting filler Accelerate the renewal rate of absorption interface simultaneously, ensures assimilation effect;
2. the utility model it is rotary packed bed be using under the action of externally-applied magnetic field and centrifugal force field, strengthen mass transfer with it is anti- Answer process.In the filling batch of rotation, liquid is drawn into liquid film, drop or brin under huge shearing force, Huge alternate contact area is produced, overcomes the shortcomings of existing chemical absorption method deodorization process, can greatly improve mass transfer speed Rate reduces equipment size, so that solvent absorption is can be miniaturized, skid, meet petrochemical plant inorganization malodorous discharge source Deodorization demand.
The utility model is described in further details below with reference to accompanying drawings and embodiments.
Description of the drawings
Fig. 1 is the system schematic of foul waste gas removing system.
In figure:1, malodor source;2, stench collects outlet;3, rotary packed bed;4, filler;5, ionic liquid container;6, it follows Ring pumps;7, decontaminated water section or stripping section;8, chimney.
Specific implementation mode
Reach the technological means and effect that predetermined purpose is taken for the utility model is expanded on further, below in conjunction with attached drawing And embodiment, to specific embodiment of the present utility model, structure feature and its effect, detailed description are as follows.
It present embodiments provides one kind and removing system for petrochemical plant foul waste gas, which can be also used for other The deodorization of industrial foul smell and life exhaust gas is particularly suitable for using in low pressure volatilization foul smell.Specifically a kind of high efficiency packing reactor Strengthen mass transfer under the action of externally-applied magnetic field and centrifugal force field with the group technology of high load capacity Ions Absorption liquid and react Process.In the filling batch of rotation, liquid is drawn into liquid film, drop or brin under huge shearing force, production Huge alternate contact area has been given birth to, existing chemical absorption method deodorization process has been overcome the shortcomings of, can greatly improve mass transfer rate, Equipment size is reduced, so that solvent absorption is can be miniaturized, skid, meets the de- of petrochemical plant inorganization malodorous discharge source Smelly demand.
The foul waste gas removing system of the present embodiment includes rotary packed bed, for containing the ionic liquid appearance for absorbing liquid Device, it is rotary packed bed to be connected to equipped with the foul waste gas import being connected to malodor source, with chimney for deodorization after-purification gas to be discharged The gas vent of body, foul waste gas import, gas vent are respectively positioned on rotary packed bed side wall, and foul waste gas import is located at gas The lower section of body outlet;
It is additionally provided with the liquid inlet for absorption liquid entrance on rotary packed bed, absorbs ion after foul gas for discharge The liquid outlet of liquid, liquid inlet are located at the top of liquid outlet;
Liquid outlet is equipped with cycle by pipeline and ionic liquid reservoir between ionic liquid container and liquid inlet Pump, which is delivered to the ionic liquid in ionic liquid container rotary packed bed.The lower end of ionic liquid container is also set There is waste liquid outlet, the waste liquid outlet is for draining into the partial ion liquid for absorbing foul gas in ionic liquid container At sewage disposal.Exhaust gas inlet is connected to malodor source by pipeline.
A kind of above-mentioned foul waste gas removes system, and the lower end of ionic liquid container is additionally provided with outlet, further include with The sewage section or stripping section of outlet connection;
The ionic liquid for having partially absorbed foul gas that ionic liquid container is flowed into through liquid outlet, passes through ionic liquid Container outlet pushes to decontaminated water section or stripping section.
System is removed using the foul waste gas of the present embodiment, the subtractive process of foul waste gas is:Malodor source 1 such as salkali waste slag ladle Or the outlet 2 of flash distillation waste water tank enters rotary packed bed 3 cavity, Ions Absorption liquid passes through rotary filling under the action of pumping 6 The central tube of material bed is distributed from top to bottom, and when rotary packed bed high speed rotation, Ions Absorption liquid is fallen from central tube intermediate openings Go out, soaks filler 4, the hole of preferred filler 4 is up-small and down-big, the foul gas in exhaust gas, as hydrogen sulfide is inhaled on filler surface It takes in into liquid phase, to realize deodorization purpose.Absorb the ionic liquid of foul gas, a part continues cycling through use, one Divide and be sent to 7 downstream wastewater processing sections or stripping section, the purification gas after deodorization, can be straight according to tolerance size and deodorising effect Run in the ionic liquid put or discharged by 15 meters of 8 high points of chimney, and component can be water, can have cushioning effect Strong base-weak acid salt can also be the ionic liquid of weak caustic solution system, and the strong base-weak acid salt with cushioning effect includes following It is one or several kinds of:Such as solution of phenates, phosphate, carbonate, borate, amino-acid salt, pH value is between 7-12;It is weak Alkali soluble liquid system, including following one or several kinds:Such as diglycolamine, ethanolamines, ammonia, two glyceramines, diethyl Propanolamine A kind of technology for the removing of petrochemical plant foul waste gas of equal hydramine dicyandiamide solution or other ionic state alkaline solutions, no The deodorization of sulphur-containing exhaust gas is can only be used to, and can be also used for the deodorization of other industrial foul smell and life exhaust gas.
In the filling batch of rotation, liquid is drawn into liquid film, drop or brin under huge shearing force, Huge alternate contact area is produced, mass transfer rate can be greatly improved, equipment size is reduced, keeps solvent absorption micro- Type, skid;Device can stop to open immediately, and process is without the quick-fried risk of sudden strain of a muscle;By using the chemical absorbing of different performance and proportioning Liquid is, it can be achieved that removing to separate sources, different component foul gas.
It may be noted that the rotary packed bed of the present embodiment can be any structure, as long as can meet exhaust gas deodorization.In order to Keep exhaust gas deodorising effect more preferable, the present embodiment also discloses a kind of rotary packed bed including rotary packed bed, rotation filler Bed includes revolving bed main body and transmission device, the inner cavity of the revolving bed main body be equipped with can high speed counter-rotating filler rotor, The filler rotor passes through drive;It is characterized in that, the filler rotor be equipped with top rotary table and lower rotary table, it is described on The center of turntable passes through a central tube, one end of the central tube to be connect with ionic liquid container by pipeline, the outer wall of the other end It is equipped with several through-holes thrown away for absorbing liquid;
Rotation filler is provided between the top rotary table and lower rotary table, the other end of the central tube is embedded in the rotation In filler, the central tube is thrown away liquid is absorbed, to soak rotation filler.
The present embodiment rotary packed bed realization deodorization process be:It is additionally provided on rotary packed bed and enters for absorbing liquid Liquid inlet, for be discharged absorb foul gas after ionic liquid liquid outlet, liquid inlet is located at the upper of liquid outlet Side;Deodorization ionic liquid enters from central tube top in central tube, and central tube is located at filler center, and central tube is that a kind of carry is opened The pipeline in hole is absorbed liquid and is thrown away from trepanning by the rotation of packed bed, soaks filler, and exhaust gas is from rotary packed bed one Side cavity enters, and by the filler after wetting, gas-liquid contact occurs on filler surface, the malodor components in discarding are shifted by gas phase Absorption process is completed to liquid phase, the solution after exhaust gas is absorbed and quickly completes Surface Renewal under turning effort, fresh solution is led to again It crosses central tube and falls out and be supplemented to filler surface, completion absorbs next time, is recycled with this, accelerates the mass transfer rate of gas liquid reaction, arrive Up to deodorising effect.
In order to make the absorption liquid of the present embodiment be drawn into liquid film, drop or liquid under huge shearing force The preferred filler hole of silk, the present embodiment is up big and down small structure.Meanwhile rotary packed bed rotation filler is preferably metal Twine, becket or ceramic material.
Rotary packed bed structure through this embodiment, in the filling batch of rotation, liquid is in huge shearing masterpiece It is drawn into liquid film, drop or brin under, produces huge alternate contact area, can greatly improve mass transfer rate, Equipment size is reduced, so that solvent absorption is can be miniaturized, skid;Device can stop to open immediately, and process is without the quick-fried risk of sudden strain of a muscle;It is logical The chemical absorbing liquid using different performance and proportioning is crossed, it can be achieved that removing to separate sources, different component foul gas.
Deodorization ionic liquid enters from central tube top in central tube, and central tube is located at filler center, and central tube is a kind of Pipeline with trepanning is absorbed liquid and is thrown away from trepanning by the rotation of packed bed, soaks filler, and exhaust gas is from rotation filler The side cavity of bed enters, and by the filler after wetting, gas-liquid contact occurs on filler surface, the malodor components in discarding are by gas Phase transfer to liquid phase completes absorption process, absorbs the solution after exhaust gas and quickly completes Surface Renewal under turning effort, fresh molten Liquid is fallen out by central tube again is supplemented to filler surface, and completion absorbs next time, is recycled with this, accelerates the mass transfer speed of gas liquid reaction Rate reaches deodorising effect.
It, cannot the above content is specific preferred embodiment further detailed description of the utility model is combined Assert that the specific implementation of the utility model is confined to these explanations.For the ordinary skill of the utility model technical field For personnel, without departing from the concept of the premise utility, a number of simple deductions or replacements can also be made, should all regard To belong to the scope of protection of the utility model.

Claims (5)

1. a kind of foul waste gas removing system rotation filler device, including it is rotary packed bed, it is described rotary packed bed including rotation Rotated bed main body and transmission device, the inner cavity of the revolving bed main body be equipped with can high speed counter-rotating filler rotor, which turns Son passes through drive;It is characterized in that, the filler rotor is equipped with top rotary table and lower rotary table, the top rotary table is under Be provided with rotation filler between turntable, it is described it is rotary packed bed further include central tube, the other end of the central tube is embedded in institute It states in rotation filler, the center of the top rotary table passes through a central tube, one end of the central tube to hold by pipeline and ionic liquid Device connects, and the outer wall of the other end is equipped with several through-holes thrown away for absorbing liquid.
2. foul waste gas removing system rotation filler device as described in claim 1, which is characterized in that the hole of the filler Gap has up big and down small structure.
3. foul waste gas removing system rotation filler device as described in claim 1, which is characterized in that the revolving bed master Body is equipped with the foul waste gas import for being connected to malodor source, the gas vent for deodorization after-purification gas to be discharged, the evil Smelly exhaust gas inlet, gas vent are respectively positioned on the side wall of the revolving bed main body, and are connected to the inner cavity of the revolving bed main body, The foul waste gas import is located at the lower section of the gas vent.
4. foul waste gas removing system rotation filler device as claimed in claim 3, which is characterized in that in revolving bed main body Be additionally provided with for absorb liquid enter liquid inlet, for be discharged absorption foul gas after ionic liquid liquid outlet, it is described Liquid inlet is located at the top of the liquid outlet.
5. foul waste gas removing system rotation filler device as described in claim 1, which is characterized in that the rotation filler The rotation filler of bed is metal twine, becket or ceramic material.
CN201721035584.1U 2017-08-18 2017-08-18 A kind of foul waste gas removing system rotation filler device Active CN207680346U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112013460A (en) * 2019-05-28 2020-12-01 广东美的制冷设备有限公司 Air purifier

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112013460A (en) * 2019-05-28 2020-12-01 广东美的制冷设备有限公司 Air purifier

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