CN207654927U - A kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system - Google Patents
A kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system Download PDFInfo
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- CN207654927U CN207654927U CN201721665449.5U CN201721665449U CN207654927U CN 207654927 U CN207654927 U CN 207654927U CN 201721665449 U CN201721665449 U CN 201721665449U CN 207654927 U CN207654927 U CN 207654927U
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- coke oven
- flue
- flue gas
- denitration
- desulfurization
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- 239000000571 coke Substances 0.000 title claims abstract description 75
- 239000003546 flue gas Substances 0.000 title claims abstract description 56
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 40
- 230000023556 desulfurization Effects 0.000 title claims abstract description 39
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 238000005507 spraying Methods 0.000 claims abstract description 12
- 230000003068 static effect Effects 0.000 claims abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 235000019504 cigarettes Nutrition 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 4
- 238000012946 outsourcing Methods 0.000 claims description 4
- 238000002076 thermal analysis method Methods 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 abstract description 4
- 238000012423 maintenance Methods 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 21
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 7
- 238000010531 catalytic reduction reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- WWILHZQYNPQALT-UHFFFAOYSA-N 2-methyl-2-morpholin-4-ylpropanal Chemical compound O=CC(C)(C)N1CCOCC1 WWILHZQYNPQALT-UHFFFAOYSA-N 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical class [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The utility model is related to a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system, including system flue and the dry desulfurization device, bag filter, SCR denitration device and the booster fan that are successively set on along coke oven flue gas flow direction on system flue；The both ends of the system flue are respectively communicated with the underground flue collector between coke oven and coke oven chimney, and set inlet baffle valve on the system flue of coke oven side, and a mouthful flapper valve is set out on the system flue of coke oven chimney side；Dry desulfurization device is made of desulfurizing agent warehouse, selection by winnowing graded mill and wind turbine；SCR denitration device includes ammonia-spraying grid, static mixer, flue gas flow equalizing device and SCR reactors.The utility model carries out high-efficient purification processing for coke oven flue gas feature, has that desulfurization and dedusting denitration efficiency is high, simple in structure, operation and maintenance are easy, floor space is small, the few feature of equipment investment.
Description
Technical field
The utility model is related to cock-oven gas purifying technical field more particularly to a kind of dry desulfurization, high-efficiency cloth bag are removed
The coke oven flue gas desulfurization and dedusting denitration coprocessing system that dirt and selective-catalytic-reduction denitrified technique are organically blent.
Background technology
In recent years, in order to renovate the air environmental pollutions such as haze, acid rain, gradually stringent control every profession and trade pollutant is arranged for country
It puts.From 1 day January in 2015, existing coal chemical enterprise started strict implement《Coking chemistry emission of industrial pollutants standard》(GB
Emission limit specified in 16171-2012) has made following strict regulations to general regional coke oven chimney smoke discharge：
Grain object concentration of emission is less than or equal to 30mg/m3, machine coke sulfur dioxide emissioning concentration is less than or equal to 50mg/m3, machine coke nitrogen oxides row
It puts concentration and is less than or equal to 500mg/m3.It is executed according to national environmental protection job requirement and to key area《Coking chemistry industrial pollution
Object discharge standard》Special emission limit specified in (GB 16171-2012)：Granular material discharged concentration is less than or equal to 15mg/m3,
Machine coke sulfur dioxide emissioning concentration is less than or equal to 30mg/m3, machine coke discharged nitrous oxides concentration is less than or equal to 150mg/m3.With
Environmental protection standard and law enforcement are further stringent, and flue gases of cock oven pollutant control is extremely urgent.
In order to solve coke oven flue gas problem of environmental pollution, the utility model proposes a kind of new desulfurization and dedusting denitration technology,
It is integrated dry desulfurization, high-effective dust-removing, selective-catalytic-reduction denitrified in one, form " SDS desulfurization by dry method (solvay
Dry solution)+high-efficiency cloth bag dedusting+SCR denitration " technique, realize efficient desulfurizing and dust collecting denitration, meet newest pollution
Object discharge standard.
Invention content
The utility model provides a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system, for coke oven flue gas feature
High-efficient purification processing is carried out, has that desulfurization and dedusting denitration efficiency is high, simple in structure, operation and maintenance are easy, floor space is small, equipment
The characteristics of small investment.
In order to achieve the above object, the utility model is realized using following technical scheme：
A kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system, including system flue and along coke oven flue gas flow direction
Dry desulfurization device, bag filter, SCR denitration device and the booster fan being successively set on system flue；The system
The both ends of flue are respectively communicated with the underground flue collector between coke oven and coke oven chimney, and are set on the system flue of coke oven side
Inlet baffle valve sets out a mouthful flapper valve on the system flue of coke oven chimney side；Dry desulfurization device by desulfurizing agent warehouse,
Selection by winnowing graded mill and wind turbine composition, desulfurizing agent warehouse connect system flue, desulfurizing agent delivery pipe by desulfurizing agent conveyance conduit
Selection by winnowing graded mill and wind turbine are set on road；SCR denitration device includes ammonia-spraying grid, static mixer, flue gas flow equalizing device and SCR anti-
Answer device, ammonia-spraying grid, static mixer and flue gas flow equalizing device along coke oven flue gas flow direction be successively set on SCR reactors into
On mouth pipeline；In addition ammonia-spraying grid is connect with ammonia conveying device, low temperature catalyst is loaded in SCR reactors, and set catalyst
Thermal analysis apparatus.
Underground flue collector between the initial and end both ends of the system flue sets bypass as bypass flue on bypass flue
Flapper valve；The initial and end both ends of system flue are connected on flue by being connected to flue connection and set fast cut valve.The wind turbine upstream
It is additionally provided with outsourcing desulfurizing agent on desulfurizing agent conveyance conduit, mouth is added.
The filter bag of the bag filter uses corrosion-and high-temp-resistant filtrate.
Compared with prior art, the utility model has the beneficial effects that：
1) dry desulfurization is used, reaction efficiency is very high, and discharge rate excessively is seldom, the SO after processing in coke oven flue gas2It can reach
Undetectable discharge capacity can effectively inhibit denitrating catalyst caused by ammonium hydrogen sulfate to be poisoned；
2) system structure is simple, investment cost is few, running resistance is low, convenient operating maintenance；
3) without water consume, whole system is not necessarily to preservative treatment, and smoke temperature drop is small, energy saving, is more suitable for having the hot standby demand of chimney
Coke oven production system uses.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of coke oven flue gas desulfurization and dedusting denitration coprocessing system described in the utility model.
In figure：1. 31. desulfurizing agent warehouse of coke oven 2. coke oven chimney, 3. dry desulfurization device, 32. selection by winnowing graded mill
33. 4. 51. ammonia conveying device of bag filter 5.SCR denitrification apparatus of wind turbine, 52. catalyst thermal analysis apparatus 6. is pressurized
10. exit catch plate valve of wind turbine 7. system flue, 8. by-pass damper valve, 9. inlet baffle valve, 11. fast cut valve
Specific implementation mode
Specific embodiment of the present utility model is described further below in conjunction with the accompanying drawings：
As shown in Figure 1, a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system described in the utility model, including system
Flue 7 and dry desulfurization device 3, bag filter 4, the SCR being successively set on along coke oven flue gas flow direction on system flue 7
Denitrification apparatus 5 and booster fan 6；The both ends of the system flue 7 are respectively communicated with the Main Underground between coke oven 1 and coke oven chimney 2
Flue, and inlet baffle valve 9 is set on the system flue 7 of 1 side of coke oven, on the system flue 7 of 2 side of coke oven chimney
Set out mouthful flapper valve 10；Dry desulfurization device 3 is made of desulfurizing agent warehouse 31, selection by winnowing graded mill 32 and wind turbine 33, desulfurizing agent
Warehouse 31 connects system flue 7 by desulfurizing agent conveyance conduit, and sorting classifying grinding machine 32 and wind turbine are set on desulfurizing agent conveyance conduit
33；SCR denitration device 5 includes ammonia-spraying grid, static mixer, flue gas flow equalizing device and SCR reactors, and ammonia-spraying grid, static state are mixed
Clutch and flue gas flow equalizing device are along the inlet pipeline that coke oven flue gas flow direction is successively set on SCR reactors；Ammonia-spraying grid is another
It is connect outside with ammonia conveying device 51, low temperature catalyst is loaded in SCR reactors, and set catalyst thermal analysis apparatus 52.
Underground flue collector between the initial and end both ends of the system flue 7 sets bypass as bypass flue on bypass flue
Flapper valve 8；The initial and end both ends of system flue 7 are connected on flue by being connected to flue connection and set fast cut valve 11.
It is additionally provided with outsourcing desulfurizing agent on the desulfurizing agent conveyance conduit of 33 upstream of the wind turbine, mouth is added.
The filter bag of the bag filter 4 uses corrosion-and high-temp-resistant filtrate.
Ripe flue gas desulfurization technique includes wet method, semidry method and dry method at present.It is needed for coke oven production, coke oven chimney
Hot standby state must be kept, and temperature must not be less than 135 DEG C.Therefore from the selection of desulfurization technology, Wet technique should not be used.
And dry technique system temperature drop is minimum, meets above-mentioned condition requirement well, is the effective of solution coke oven flue gas desulfurization demand
Means.
The characteristics of coke oven flue gas is that generally relatively low containing sulfur dioxide, nitrogen oxides is higher.Therefore denitrating technique selection compared with
To be important, coke oven flue gas temperature range is 160~300 DEG C, less than conventional scr (selectively urging reduction method) denitrating catalyst
Reaction temperature window (320~420 DEG C).Therefore, how nitrogen oxides in middle low temperature scope effectively removes coke oven flue gas is outstanding
It is important.Relative to coke oven flue gas exhaust temperature, conventional high-temperature denitration window temperature is too high, if to be warming up to 300 DEG C or more
Energy consumption is excessive, and low-temperature denitration technology is more reasonable in.
In order to achieve the purpose that efficient desulfurizing and dust collecting denitration, while meeting the hot standby demand of coke oven chimney, take into account energy-saving effect,
The utility model uses " SDS desulfurization by dry method (solvay dry solution)+high-efficiency cloth bag dedusting+middle cryogenic selective
The process of catalytic reduction method denitration (SCR) ".
Coke oven flue gas is carried out using a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system described in the utility model
The technique of purified treatment is to draw coke oven flue gas into the system flue 7 of flue gas purification system by underground flue collector, successively
Purified treatment is carried out to coke oven flue gas by dry desulfurization device 3, bag filter 4 and SCR denitration device 5, it is burnt that treated
Kiln gas introduces coke oven chimney 2 and discharges；Specifically comprise the following steps：
1) dry desulfurization；
Using dry desulfurizing process, solid SDS desulfurizing agents are injected directly into system flue 7, SDS desulfurizing agents and coke oven
SO in flue gas2Physics and chemical reaction occurs, effectively removes the SO in coke oven flue gas2；
2) bag-type dust；
Bag filter 4 is set on the system flue 7 after dry desulfurization, absorbs SO2Dryness powder afterwards is with coke oven cigarette
Gas enters bag filter 4, further carries out realizing clarifying smoke while desulphurization reaction, it is ensured that dust being capable of minimum discharge；
The filter bag of bag filter 4 selects corrosion-and high-temp-resistant filtrate；
3) SCR denitration；
SCR denitration device 5 is set on system flue 7 after bag filter 4, low-temperature selective catalytic reduction is de- in
Nitre technique, while selecting ammonia as the reducing agent of coke oven flue gas denitration；
First, it is sprayed by the coke oven flue gas of desulfurization and dedusting and the ammonia-spraying grid being arranged in SCR Reactor inlet pipelines
The ammonia come is sufficiently mixed in static mixer, and the flue gas mixed enters from SCR Reactor inlets, equal by flue gas
Stream device is flowed homogeneous to flue gas, and is filtered to sticky particle object (tar, ammonium hydrogen sulfate etc.), to prevent sticky particle object
Being deposited on the low temperature catalyst surface in downstream makes catalyst activity reduce or block, while flue gas flow equalizing device also disassembling cleaning,
It recycles to investment reduction；
Coke oven flue gas enters SCR reactors after flue gas flow equalizing device, and carrying out SCR denitration with low temperature catalyst reacts, and takes off
Except the flue gas after NOx flows to 2 direct emission of coke oven chimney from SCR reactor outlets.
In dry desulfurizing process, for desulfurizing agent without humidifying processing, whole system temperature drop is low, is not required to arrange using additional anti-corrosion
It applies；Due to facilities such as no desulfurizing tower, slurries system, fluid beds, take up an area and save, small investment is safeguarded simple and convenient.Desulfurizing agent can
Using the method being milled online, conventional flowsheet is：Desulfurizing agent-opens bag station-desulfurizing agent warehouse-spiral weighing balance-
Neat stress after selection by winnowing graded mill-nozzle-sulfur-bearing coke oven flue gas-desulfurization.Also the desulfurizing agent that buyable granularity is met the requirements,
Mouth is added from outsourcing desulfurizing agent to be added directly into desulfurizing agent conveyance conduit, is blown into system flue by wind turbine and coke oven flue gas
It is reacted.
The technological process of middle low-temperature selective catalytic reduction method denitration is：Ammonia-ammonia-spraying grid sprays-contains nitre coke oven cigarette
Neat stress after gas-static mixer-flue gas flow equalizing device-SCR reactors-denitration.
By-pass damper valve 8 is set on bypass flue, it is ensured that the normal production of coke oven 1 is not influenced, at desulfurization and dedusting denitration collaboration
The flue gas emission of reason system has contemplated that hot standby condition, even if system is stopped transport suddenly, will not influence coke oven production.In Main Underground cigarette
Fast cut valve 11 is added on road, is met the reasons such as power failure and is caused 6 failure of booster fan that cannot normally be handled to desulfurization and dedusting denitration collaboration
When system discharges coke oven flue gas, it can be quickly switched into the discharge of coke oven chimney 2, while coke oven is cut off by chain control in time and is added
Heating gas, it is ensured that production safety.
The preferable specific implementation mode of the above, only the utility model, but the scope of protection of the utility model is not
Be confined to this, any one skilled in the art within the technical scope disclosed by the utility model, according to this practicality
Novel technical solution and its utility model design are subject to equivalent substitution or change, should all cover the protection model in the utility model
Within enclosing.
Claims (4)
1. a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system, which is characterized in that including system flue and along coke oven cigarette
Flow of air direction is successively set on dry desulfurization device, bag filter, SCR denitration device and supercharging wind on system flue
Machine；The both ends of the system flue are respectively communicated with the underground flue collector between coke oven and coke oven chimney, and close to coke oven side
Inlet baffle valve is set on system flue, and a mouthful flapper valve is set out on the system flue of coke oven chimney side；Dry desulfurization device
It being made of desulfurizing agent warehouse, selection by winnowing graded mill and wind turbine, desulfurizing agent warehouse connects system flue by desulfurizing agent conveyance conduit,
Selection by winnowing graded mill and wind turbine are set on desulfurizing agent conveyance conduit；SCR denitration device includes ammonia-spraying grid, static mixer, flue gas
Current equalizer and SCR reactors, ammonia-spraying grid, static mixer and flue gas flow equalizing device are successively set on along coke oven flue gas flow direction
On the inlet pipeline of SCR reactors；In addition ammonia-spraying grid is connect with ammonia conveying device, filling is low-temperature catalyzed in SCR reactors
Agent, and set catalyst thermal analysis apparatus.
2. a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system according to claim 1, which is characterized in that described
Underground flue collector between the initial and end both ends of system flue sets by-pass damper valve as bypass flue on bypass flue；System cigarette
The initial and end both ends in road are connected on flue by being connected to flue connection and set fast cut valve.
3. a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system according to claim 1, which is characterized in that described
It is additionally provided with outsourcing desulfurizing agent on the desulfurizing agent conveyance conduit of wind turbine upstream, mouth is added.
4. a kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system according to claim 1, which is characterized in that described
The filter bag of bag filter uses corrosion-and high-temp-resistant filtrate.
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| CN201721665449.5U CN207654927U (en) | 2017-12-04 | 2017-12-04 | A kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system |
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|---|---|---|---|
| CN201721665449.5U CN207654927U (en) | 2017-12-04 | 2017-12-04 | A kind of coke oven flue gas desulfurization and dedusting denitration coprocessing system |
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| CN207654927U true CN207654927U (en) | 2018-07-27 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109059568A (en) * | 2018-08-22 | 2018-12-21 | 上海宝钢节能环保技术有限公司 | A kind of coke oven flue air purifying apparatus bypass valve system |
| CN109482049A (en) * | 2019-01-02 | 2019-03-19 | 武汉科林精细化工有限公司 | A kind of coke oven flue gas dry desulfurization denitration purification integral process |
| CN109812829A (en) * | 2019-03-21 | 2019-05-28 | 河北视窗玻璃有限公司 | A kind of flue gas processing device and boiler system |
| CN110841416A (en) * | 2019-12-18 | 2020-02-28 | 中冶焦耐(大连)工程技术有限公司 | A system and process for dust removal, desulfurization and denitrification of flue gas from rotary kiln and shaft kiln |
| CN112516772A (en) * | 2020-12-18 | 2021-03-19 | 中冶焦耐(大连)工程技术有限公司 | Crude benzene tube furnace tail gas cleaning system and process |
| CN113698945A (en) * | 2021-10-19 | 2021-11-26 | 云南煤业能源股份有限公司 | Method for starting desulfurization and denitrification draught fan without stopping heating of coke oven |
| CN114405265A (en) * | 2021-12-31 | 2022-04-29 | 新兴铸管股份有限公司 | Coke oven flue desulfurization and denitrification system |
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2017
- 2017-12-04 CN CN201721665449.5U patent/CN207654927U/en active Active
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109059568A (en) * | 2018-08-22 | 2018-12-21 | 上海宝钢节能环保技术有限公司 | A kind of coke oven flue air purifying apparatus bypass valve system |
| CN109482049A (en) * | 2019-01-02 | 2019-03-19 | 武汉科林精细化工有限公司 | A kind of coke oven flue gas dry desulfurization denitration purification integral process |
| CN109482049B (en) * | 2019-01-02 | 2021-07-23 | 武汉科林化工集团有限公司 | Dry desulfurization, denitrification and purification integrated process for coke oven flue gas |
| CN109812829A (en) * | 2019-03-21 | 2019-05-28 | 河北视窗玻璃有限公司 | A kind of flue gas processing device and boiler system |
| CN110841416A (en) * | 2019-12-18 | 2020-02-28 | 中冶焦耐(大连)工程技术有限公司 | A system and process for dust removal, desulfurization and denitrification of flue gas from rotary kiln and shaft kiln |
| CN112516772A (en) * | 2020-12-18 | 2021-03-19 | 中冶焦耐(大连)工程技术有限公司 | Crude benzene tube furnace tail gas cleaning system and process |
| CN113698945A (en) * | 2021-10-19 | 2021-11-26 | 云南煤业能源股份有限公司 | Method for starting desulfurization and denitrification draught fan without stopping heating of coke oven |
| CN113698945B (en) * | 2021-10-19 | 2024-04-26 | 云南煤业能源股份有限公司 | Method for starting desulfurization and denitrification induced draft fan without stopping heating of coke oven |
| CN114405265A (en) * | 2021-12-31 | 2022-04-29 | 新兴铸管股份有限公司 | Coke oven flue desulfurization and denitrification system |
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