CN207542317U - Complex lithium band process units - Google Patents

Complex lithium band process units Download PDF

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Publication number
CN207542317U
CN207542317U CN201721217123.6U CN201721217123U CN207542317U CN 207542317 U CN207542317 U CN 207542317U CN 201721217123 U CN201721217123 U CN 201721217123U CN 207542317 U CN207542317 U CN 207542317U
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China
Prior art keywords
lithium
band
complex
complex lithium
roller
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CN201721217123.6U
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Chinese (zh)
Inventor
李国华
于申军
冯小平
彭先政
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Avic Innovation Technology Research Institute Jiangsu Co ltd
China Aviation Lithium Battery Co Ltd
China Lithium Battery Technology Co Ltd
CALB Technology Co Ltd
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China Aviation Lithium Battery Co Ltd
China Aviation Lithium Battery Research Institute Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The utility model is related to complex lithium band process units.Complex lithium band process units includes being respectively used to band-like lithium source, the lithium source retractable volume mechanism that solid electrolyte and complex lithium ribbon matrix are wound and unreeled, electrolyte retractable volume mechanism and complex lithium band retractable volume mechanism, it further includes to be arranged between unreeling structure and rolling-up mechanism and be used for band-like lithium source, solid electrolyte and the doubling roller of complex lithium ribbon matrix fitting, during fitting, band-like solid electrolyte is between band-like lithium source and band-like complex lithium ribbon matrix, mend the cathode power supply part that lithium device further includes the anode power supply part for being electrically connected with band-like lithium source and is electrically connected with complex lithium ribbon matrix.The utility model provides a kind of new technology of complex lithium band production, it is realized by electrochemical method and lithium layer is electroplated in complex lithium ribbon matrix, not only the thickness for the lithium layer that process is simple and efficient but also is electroplated out is uniform and very thin, can meet strict demand of the complex lithium band to thickness.

Description

Complex lithium band process units
Technical field
The utility model is related to complex lithium band process units.
Background technology
Lithium-sulfur cell is one of direction of following battery development, and lithium-sulfur cell generally use lithium metal is as negative material. The theoretical specific capacity of lithium is up to 3860mAh/g, and usual a thin layer lithium metal (less than 100 μm) can meet capacity requirement, therefore Ultrathin metal lithium strip has potential market demand.It is limited to the physical characteristic of itself, metal lithium bands tensile strength is poor, easy pleat Wrinkle, fracture, and thickness is smaller, and it is bigger fold, the chance of fracture occur.Therefore it is typically chosen a kind of larger foil of tensile strength (such as copper foil) makees complex lithium ribbon matrix, covers one layer of lithium band on it, forms complex lithium band.Made using the big copper foil of tensile strength The matrix relied on for lithium layer so that complex lithium band has relatively large tensile strength, is conducive to retractable volume operation, convenient for industry Change application.But there is no a kind of complex lithium bands simple and effective, lithium layer thickness is small and each point thickness error is small currently on the market Process units, if lithium layer is in uneven thickness or lithium layer thickness cannot mostly meet very much the requirement of complex lithium band.
Utility model content
Small and small each point thickness error the purpose of this utility model is to provide a kind of simple and effective, lithium layer thickness is compound Lithium band process units.
To achieve the above object, the complex lithium band process units of the utility model adopts the following technical scheme that:
Technical solution 1:Complex lithium band process units includes being respectively used to band-like lithium source, solid electrolyte and complex lithium band Lithium source retractable volume mechanism, electrolyte retractable volume mechanism and the complex lithium band retractable volume mechanism that matrix is wound and unreeled, also It is used to band-like lithium source, solid electrolyte and complex lithium ribbon matrix being bonded between unreeling structure and rolling-up mechanism including being arranged on Doubling roller, during fitting, band-like solid electrolyte is between band-like lithium source and band-like complex lithium ribbon matrix, the production of complex lithium band The cathode power supply part that device further includes the anode power supply part being electrically connected with band-like lithium source and is electrically connected with complex lithium ribbon matrix.This Utility model provides a kind of new technology of complex lithium band production, is realized by the method for electrochemistry and is electroplated in complex lithium ribbon matrix Lithium layer, not only the thickness for the lithium layer that process is simple and efficient but also is electroplated out is uniform and very thin, can meet complex lithium band to thickness It is strict with.
Technical solution 2:On the basis of technical solution 1, the doubling roller has two sets, is passed respectively positioned at three unreeling structures The downstream in path and the upstream of three rolling-up mechanism drive paths are moved, more transition rollers, a part are equipped between two sets of doubling rollers Transition roller be connected with positive pole form anode power supply part, another part is connected with power cathode and forms the cathode power supply Part.Band-like lithium source, band-like solid electrolyte and band-like complex lithium ribbon matrix realize fitting on doubling roller and transition roller, due to mistake It crosses roller with power supply to be connected, when each band-like material on doubling roller and transition roller when being bonded, electrolysis circuit is formed.
Technical solution 3:On the basis of technical solution 2, the transition roller being capable of rotation.
Technical solution 4:On the basis of technical solution 2 or 3, transition roller has a two rows, each transition roller on a row with it is another Each transition roller on one row is staggeredly arranged on the length direction of transition roll row.Save space ensures band in transition roller again Between wind when cornerite it is sufficiently large.
Technical solution 5:On the basis of technical solution 4, the diameter of row's transition roller in two rows of transition rollers is more than another The diameter of the transition roller of row.Wrap angle of the band on transition roller can be increased.
Technical solution 6:On the basis of technical solution 4, the quantity of two rows of transition rollers it is equal or difference one.
Technical solution 7:On the basis of technical solution 1-3 any one, lithium source retractable volume mechanism, electrolyte retractable volume machine Structure and pole piece retractable volume mechanism include:Scroll and unreeling shaft for retractable volume, for the deflector roll of guiding and for being tensioned Floating roller.
Description of the drawings
Fig. 1 is the structure diagram of the embodiment 1 of the complex lithium with process units of the utility model;
Fig. 2 is the connection diagram of power supply and triple layer shape material in Fig. 1;
Fig. 3 is the schematic diagram of Fig. 2;
Fig. 4 is the structure diagram of the band-like lithium source in embodiment 6;
In figure:The band-like lithium sources of 1-, 2- solid electrolytes, 3- complex lithium ribbon matrix, 4- unreeling shafts, 5- deflector rolls, 6- floating rollers, 7- Doubling roller, 8- positive conductive rollers, 9- negative conductive rollers, 10- Scrolls, 11- DC constant current power supplies, 20- lithium coating, 21- Copper substrates, A- is unreeled, B- electrolysis, C- windings.
Specific embodiment
The embodiment of the utility model is described further below in conjunction with the accompanying drawings.
Embodiment 1 of the complex lithium of the utility model with process units:As shown in Figure 1, one kind that the application provides is compound Lithium band process units in addition to control system, further includes unreeling structure, electrolysis mechanism and rolling-up mechanism.Control system overall control Device is run.Unreeling structure and rolling-up mechanism draw band-like lithium source 1,2 and of solid electrolyte for placement and with appropriate tension Complex lithium ribbon matrix 3.Unreeling structure includes band-like lithium source unreeling structure, solid electrolyte unreeling structure and complex lithium ribbon matrix Three sets of mechanisms such as unreeling structure, unreeling structure are at least made of components such as unreeling shaft 4, deflector roll 5, floating rollers 6;Rolling-up mechanism includes Three sets of mechanisms, the rolling-up mechanisms such as band-like lithium source rolling-up mechanism, solid electrolyte rolling-up mechanism, complex lithium band rolling-up mechanism are at least It is made of components such as deflector roll 5, floating roller 6, Scrolls 10.Mechanism is electrolysed by positive conductive roller 8, negative conductive roller 9, direct current Constant Electric Current Compositions, wherein the positive conductive roller 8 such as source 11 and electrolysis circuit are connected with the anode of DC constant current power supply, negative conductive roller 9 and direct current The cathode of constant-current source is connected.
Band-like lithium source 1, solid electrolyte 2, complex lithium ribbon matrix 3 come together in doubling roller 7 by respective unreeling structure, so After pass sequentially through first negative conductive roller, 9, first positive conductive rollers, 8, second negative conductive rollers 9 ..., n-th of anode Conductive rollers 8, m-th of negative conductive roller 9, then go out electrolysis zone, are respectively wound into rolling-up mechanism.
By it is appropriate unreel with threading mode, when in negative conductive 9 surface wrap of roller, complex lithium ribbon matrix 3 is most Internal layer is in direct contact with negative conductive roller 9, is solid electrolyte 2, band-like lithium source 1 successively outward;When in 8 table of positive conductive roller When face is wound, band-like lithium source 1 is in direct contact in innermost layer, with positive conductive roller 8, is solid electrolyte 2, complex lithium successively outward Ribbon matrix 3.
Under appropriate retractable volume tension, band-like lithium source 1, solid electrolyte 2, complex lithium ribbon matrix 3 can be pasted closely It closes on the surface of positive conductive roller 8 and negative conductive roller 9.When band-like lithium source 1, solid electrolyte 2, complex lithium ribbon matrix 3 are just When pole conductive rollers 8 and 9 surface of negative conductive roller fit closely, electronics is provided simultaneously between band-like lithium source 1 and complex lithium ribbon matrix 3 Channel and lithium ion tunnel connect electrolysis circuit on this condition, and under electric field action, electronics passes through dispatch from foreign news agency from band-like lithium source 1 Road flows to complex lithium ribbon matrix 3, and lithium ion is deviate from from band-like lithium source 1, across solid electrolyte 2, is obtained in complex lithium ribbon matrix 3 Electron reduction, generation lithium metal, so as to which complex lithium band be made.
A positive conductive rollers 8 of n (n is positive integer), m (m is positive integer) a negative conductive roller 9 are set, it is preferred that m=n+ 1st, n or n-1, positive conductive roller 8 are connect with the anode of DC constant current power supply 11, the cathode of negative conductive roller 9 and DC constant current power supply 11 Connection.Positive conductive roller 8 and negative conductive roller 9 are conductive rolls, its electron resistivity is less than 10 under room temperature-3Ω·m.Just The roller diameter of pole conductive rollers 8 can be identical with the roller diameter of negative conductive roller 9, can not also be identical.Positive conductive roller 8 and negative conductive Roller 9 can be with rotation, in favor of band-like lithium source 1, solid electrolyte 2,3 retractable volume of complex lithium ribbon matrix.Setting can transmit lithium from The solid electrolyte 2 of son is to separate (or connection) band-like lithium source 1 and complex lithium ribbon matrix 3, under 2 room temperature of solid electrolyte Conductivity is more than 10-7S/cm, it is preferred that the conductivity of solid electrolyte 2 is more than 10-4S/cm.Band-like lithium source 1 be metal lithium bands, Complex lithium band either lithium ion cell positive.Lithium source 1, solid electrolyte 2, complex lithium ribbon matrix 3 are all ribbons, can Carry out retractable volume operation.Complex lithium ribbon matrix 3 is copper foil or other materials.
In the present embodiment:(1) 138 negative conductive rollers 9 and 137 positive conductive rollers 8, each negative conductive roller 9 are set A diameter of 100mm, 9 axle center spacing 200mm of two neighboring negative conductive roller;Each 8 a diameter of 150mm of positive conductive roller, anode The distance of 8 axle center of conductive rollers to two 9 axial connecting lines of negative conductive roller adjacent thereto is 175mm.By this set, entirely It is about 60m that length is effectively electrolysed in electrolysis zone;
(2) complex lithium ribbon matrix 3 is the copper foil of wide 84mm, thickness 0.010mm;
(3) solid electrolyte film selects Li1.4Al0.4Ti1.6(PO4)3LISICON types inorganic solid electrolyte 2, the lithium of material Ionic conductivity is 1.12 × 10-3S/cm, thickness 0.030mm, width 110mm;
(4) band-like lithium source 1 is the metal lithium bands of width 100mm, thickness 0.150mm;
(5) DC constant current power supply setting electric current value 1500A, band-like lithium source 1, solid electrolyte 2 and complex lithium ribbon matrix 3 are walked Tape speed is 10m/min.
Embodiment 2:The difference lies in DC constant current power supply setting electric current value 1500A, band-like lithium source is consolidated with embodiment 1 The tape running speed of body electrolyte and complex lithium ribbon matrix is 20m/min.
Embodiment 3:The difference lies in DC constant current power supply setting electric current value 1500A, band-like lithium source is consolidated with embodiment 1 The tape running speed of body electrolyte and complex lithium ribbon matrix is 30m/min.
Embodiment 4:The difference lies in DC constant current power supply setting electric current value 3000A, band-like lithium source is consolidated with embodiment 1 The tape running speed of body electrolyte and complex lithium ribbon matrix is 20m/min.
Embodiment 5:The difference lies in DC constant current power supply setting electric current value 4500A, band-like lithium source is consolidated with embodiment 1 The tape running speed of body electrolyte and complex lithium ribbon matrix is 30m/min.
Embodiment 6:The difference lies in band-like lithium source is width 100mm, the complex lithium of total thickness 0.150mm with embodiment 1 Band, complex lithium band be the copper foil using 0.010mm thickness as matrix, i.e. Copper substrate 21 adheres to the lithium of one layer of 0.140mm thickness on copper foil Layer, i.e. lithium coating 20, structure is as shown in Figure 4.
Embodiment 7:The difference lies in band-like lithium source is wide 100mm, one side coating amount is 17mg/ with embodiment 1 cm2Lithium cobaltate cathode.
Embodiment 8:The difference lies in band-like lithium source is wide 100mm, one side coating amount is 15mg/ with embodiment 1 cm2Lithium manganate cathode.
Embodiment 9:The difference lies in band-like lithium source is wide 100mm, one side coating amount is 15mg/ with embodiment 1 cm2Iron phosphate lithium positive pole.
Embodiment 10:The difference lies in band-like lithium source is wide 100mm, one side coating amount is 17mg/ with embodiment 1 cm2Lithium nickel cobalt manganese oxide (ternary) anode.
Embodiment 11:With embodiment 1 the difference lies in, solid electrolyte film select width 110mm, 50 μm of thickness, Ionic conductivity is 7.5 × 10 at 30 DEG C-4The modified PE O based polyalcohol solid electrolytes of S/cm.
Embodiment 12:The difference lies in set 70 negative conductive rollers 9 and 69 positive conductive rollers with embodiment 1 8, each negative conductive roller diameter is 100mm, 9 axle center spacing 200mm of two neighboring negative conductive roller;Each positive conductive roller 8 A diameter of 150mm, the distance in 8 axle center of positive conductive roller to two 9 axial connecting lines of negative conductive roller adjacent thereto is 175mm. It is about 30m to be effectively electrolysed length by this set, in entire electrolysis zone.DC constant current power supply 11 setting electric current value 750A, it is band-like Lithium source 1, solid electrolyte 2 and 3 tape running speed of complex lithium ribbon matrix are 5m/min.
For the complex lithium band that each embodiment obtains, a sample is taken every 1 meter, takes 50 samples altogether, each embodiment is measured and obtains The sampling quality and thickness of the complex lithium band obtained, and the deviation of statistical sample sampling quality and thickness.Comparative example is as compound The copper foil (thickness 0.010mm, width 84mm) of lithium ribbon matrix.Statistical result is as follows:
Note:1) sampling quality of each embodiment and sampling thickness are the average value of 50 samplings;2) lithium layer surface density= (sampling quality-copper foil substrate quality) ÷ Sampling Areas;3) sampling quality deviation and thickness deviation are the observed values of 50 samplings With the maximum deviation of its mean value.
The experimental results showed that the device can effectively implement plating lithium on copper foil, and by adjusting size of current, walking Tape speed can quantify control plating lithium amount.
Complex lithium band production method:Entirety includes the following steps:The first step, by band-like lithium source, solid electrolyte, complex lithium Ribbon matrix forms all solid state electrolytic cell of an open type;Second step controls current electroanalysis to all solid state electrolytic cell.
The specific steps are:Band-like lithium source, solid electrolyte and complex lithium ribbon matrix are respectively fitted over first corresponding On unreeling shaft, while three is carried out to unreel operation, lap wound realizes three to three on doubling roller simultaneously after deflector roll, floating roller The fitting of person, subsequently into electrolysis, mechanism carries out electrolysis procedure, and band-like lithium source with positive conductive roller by contact and reality during electrolysis It is now electrically connected with positive pole, band-like complex lithium ribbon matrix is by contacting with negative conductive roller the electricity to realize with power cathode Connection, then powers on, by the electrochemical reaction between positive and negative electrode, make lithium source lithium ion pass through solid electrolyte to Complex lithium ribbon matrix surface is mobile, electron reduction is obtained in complex lithium ribbon matrix, lithium metal is produced, so as to fulfill lasting plating Then lithium carries out winding behaviour by rolling-up mechanism to band-like lithium source, solid electrolyte and the electroplated complex lithium band for crossing lithium layer Make, simultaneously wound three by the corresponding Scroll of three.

Claims (7)

1. complex lithium band process units, it is characterized in that, including being respectively used to band-like lithium source, solid electrolyte and complex lithium tape base Lithium source retractable volume mechanism, electrolyte retractable volume mechanism and the complex lithium band retractable volume mechanism that body is wound and unreeled, are also wrapped It includes to be arranged between unreeling structure and rolling-up mechanism and is used for be bonded band-like lithium source, solid electrolyte and complex lithium ribbon matrix Doubling roller, during fitting, band-like solid electrolyte is mended lithium device and is further included between band-like lithium source and band-like complex lithium ribbon matrix For the anode power supply part being electrically connected with band-like lithium source and the cathode power supply part being electrically connected with complex lithium ribbon matrix.
2. complex lithium band process units according to claim 1, it is characterized in that, the doubling roller has two sets, is located at respectively The downstream of three unreeling structure drive paths and the upstream of three rolling-up mechanism drive paths are equipped with more between two sets of doubling rollers Transition roller, a part of transition roller is connected with positive pole forms the anode power supply part, another part transition roller and power cathode It is connected and forms the cathode power supply part.
3. complex lithium band process units according to claim 2, it is characterized in that, the transition roller being capable of rotation.
4. the complex lithium band process units according to Claims 2 or 3, it is characterized in that, transition roller has a two rows, every on a row A transition roller is staggeredly arranged with each transition roller on another row on the length direction of transition roll row.
5. complex lithium according to claim 4 band process units, it is characterized in that, row's transition roller in two rows of transition rollers Diameter is more than the diameter of another row's transition roller.
6. complex lithium band process units according to claim 4, it is characterized in that, the quantity of two rows of transition rollers is equal or differs One.
7. the complex lithium band process units according to claim 1-3 any one, it is characterized in that, lithium source retractable volume mechanism, Electrolyte retractable volume mechanism and complex lithium band retractable volume mechanism include:Scroll and unreeling shaft for retractable volume, for leading To deflector roll and the floating roller for tensioning.
CN201721217123.6U 2017-09-21 2017-09-21 Complex lithium band process units Withdrawn - After Issue CN207542317U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107644973A (en) * 2017-09-21 2018-01-30 中航锂电技术研究院有限公司 A kind of complex lithium band process units and production method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107644973A (en) * 2017-09-21 2018-01-30 中航锂电技术研究院有限公司 A kind of complex lithium band process units and production method
CN107644973B (en) * 2017-09-21 2023-12-15 中创新航技术研究院(江苏)有限公司 Composite lithium belt production device and production method

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Patentee after: AVIC Innovation Technology Research Institute (Jiangsu) Co.,Ltd.

Patentee after: CHINA AVIATION LITHIUM BATTERY Co.,Ltd.

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Patentee before: CHINA AVIATION LITHIUM BATTERY Co.,Ltd.

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Address after: 166 Kejiao Road, Jintan District, Changzhou City, Jiangsu Province

Patentee after: Kaibo Energy Technology Co.,Ltd.

Patentee after: CHINA AVIATION LITHIUM BATTERY Co.,Ltd.

Address before: No.88 Jintan Avenue, Jintan District, Changzhou City, Jiangsu Province 213299

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Address after: 166 Kejiao Road, Jintan District, Changzhou City, Jiangsu Province

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Address before: 166 Kejiao Road, Jintan District, Changzhou City, Jiangsu Province

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