CN207537295U - A kind of high-salt wastewater treatment process system - Google Patents

A kind of high-salt wastewater treatment process system Download PDF

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Publication number
CN207537295U
CN207537295U CN201720770524.8U CN201720770524U CN207537295U CN 207537295 U CN207537295 U CN 207537295U CN 201720770524 U CN201720770524 U CN 201720770524U CN 207537295 U CN207537295 U CN 207537295U
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water
bed
process system
super
weak acid
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陈�峰
李京红
王正江
周小龙
李雨蔓
代静
曲艳春
樊永旺
肖世全
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Guoneng Water Environmental Protection Co.,Ltd.
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Beijing Lucency Enviro Tech Co Ltd
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Abstract

The utility model discloses a kind of high-salt wastewater treatment process system, including desulfurization process system, raw water regulating reservoir, super softening sedimentation basin, super ozone equipment, clear water reserviors, more medium filter, weak acid cation bed, sodium bed, ultraviolet device, tubular membrane, cartridge filter, SCRO, special separation film, high pressure be reverse osmosis, flue evaporative crystallization drier, wastewater disposal basin, reuse pool;To ensure the operation steady in a long-term of this process system, further include related mating cleaning device, chemicals dosing plant, electrical system and instrument control, there is few dosing, recycling, save effluent part investment and operation processing cost, solve the problems, such as that current zero discharge of industrial waste water encounters.

Description

A kind of high-salt wastewater treatment process system
Technical field
The utility model is related to Industrial Wastewater Treatment environmental technology fields, and in particular to a kind of high-salt wastewater treatment process system System.
Background technology
China's rapid economic development at present, the huge consumption of the simultaneous energy, environmental problem also getting worse.In order to Current environment situation is made to be improved, country is also increasingly tighter to the management of the three wastes, and zero discharge of industrial waste water is numerous enterprises Received with professional occurrences in human life, while gradual beginning is implemented in industrial circle.And water is essential as industrial circle Resource, the discharge of the strong brine environmental protection index important as one after concentration.The zero-emission that China industrial wastewater field is implemented, Especially in thermal power plant, critical issue is that desulfurization wastewater operating cost and cost of investment are too high, and lacks stable operation warp It tests, is now exploring how to test and finding more stable processing method and operating cost compared with low technical.
The utility model patent application integrally considers a kind of high-salt wastewater treatment process system, and high-salt wastewater and power plant are taken off Sulphur system integrally considers that by the waste water that desulphurization system generates after the softening of super softening sedimentation basin, sludge reenters desulfurization system System and SO2Carry out reaction generation gypsum;The regeneration of sodium bed simultaneously using the reverse osmosis concentrated water of high pressure, regenerative wastewater part directly into Enter desulphurization system and SO2Carry out reaction generation gypsum;Other water, into membranous system, are carried out after softening by special separation film Divide salt, the concentrated water of generation directly returns to desulphurization system, with SO2React generation gypsum on absorption tower, and it is anti-that production water enters high pressure After osmosis concentration, into after flue evaporative crystallization drier, water is taken away by flue gas, carries out condensation recycling in desulfurization offer, is left Salt directly by flue gas drying, reach Nacl primary standard.It realizes complete zero-emission, while there is the other product of technical grade to be able to It utilizes.
It is that embrane method+evaporative crystallization and fume afterheat evaporate two kinds that the country common at present, which was explored with the experimental stage, Embrane method has that positive infiltration and high pressure are reverse osmosis, and flue residue heat evaporation is divided into before deduster to be sprayed after spray and deduster.Fume afterheat It is carnallite to steam generation, and possible next stage can be influenced by environmental protection policy, and embrane method+evaporative crystallization, softens reagent cost It is excessively high, it runs and overhauls and is more demanding.
Invention content
The utility model overcomes the deficiencies in the prior art, provides a kind of high-salt wastewater treatment process system.
In view of the above problem of the prior art, one side according to the present utility model, the technology to solve above-mentioned is asked Topic, the utility model use a kind of high-salt wastewater treatment process system, this system include desulfurization process system, raw water regulating reservoir, Super softening sedimentation basin, super ozone equipment, clear water reserviors, more medium filter, weak acid cation bed, sodium bed, ultraviolet device, tubular type Film, cartridge filter, SCRO, special separation film, high pressure are reverse osmosis, flue evaporative crystallization drier, wastewater disposal basin, reuse pool; To ensure the operation steady in a long-term of this process system, related mating cleaning device, chemicals dosing plant, electrical system and instrument are further included Table controls, it is characterised in that:
The sludge that super softening sedimentation basin generates is CaCO3、Mg(OH)2Desulfurization process system is sent into, makes itself and SO2It is inhaling Tower is received to react;
Super ozone equipment carries out catalysis oxidation to waste water COD and bacterium in the process of running, by COD be reduced to 10mg/L with Under;
Weak acid cation bed and sodium bed are removed the hardness in water again, ensure that rear end hardness is reduced to 0.1mmol/L;
A part of Direct Regeneration weak acid cation bed of concentrated water and sodium bed of the reverse osmosis generation of high pressure;Regenerated liquid and flushing water Separately processing, flushing water to more medium filter, regenerative wastewater enter desulphurization system, make itself and SO2It reacts on absorption tower;
The concentrated water that special separation film generates directly returns to desulphurization system, reacts generation with the absorption tower in desulphurization system Gypsum, SO4 2-、Ca2+、Mg2+, it is more than 95% to ensure removal rate;
SCRO uses two sections of level-one, and intersegmental using supercharging pump reflux, the rate of recovery is 40 ~ 75%;Special separation film uses one Two sections of grade, intersegmental using supercharging pump reflux, the rate of recovery is 60 ~ 75%, and the reverse osmosis rate of recovery of high pressure is 70%;It is reverse osmosis through high pressure Concentrated water enter flue evaporative crystallization drier, water is taken away by flue gas, desulfurization offer carry out condensation recycling, remaining salt is direct By flue gas drying, reach Nacl primary standard.It realizes complete zero-emission, while there is the other product of technical grade to be utilized.
In order to which the utility model is better achieved, further technical solution is:
Preferably, the industrial wastewater COD with high salt is 5 ~ 300mg/L, SO4 2-For 500 ~ 40000mg/L, Ca2+For 50 ~ 50000mg/L、Mg2+For 10 ~ 30000mg/L.
Preferably, flocculant described in accordance with the claim 1 is carboxymethyl cellulose.
Compared with prior art, the utility model is advantageous in that:
(1)For waste water after the softening of super softening sedimentation basin, sludge reenters desulphurization system and SO2Carry out reaction generation life Into gypsum, the lime stone of desulphurization system is saved;
(2)The concentrated water that special separation film generates directly is back to desulphurization system, directly and SO2Gypsum is generated, saves desulfurization system The lime stone of system;
(3)Sodium bed regeneration high pressure reverse osmosis concentrated water saves medicament and saves effluent part investment and operation processing simultaneously Cost;
(4)Directly after flue is evaporated crystallizing and drying device, water is taken away by flue gas, and remaining salt is directly done by flue gas It is dry, reach Nacl primary standard;
(5)Each unit can independent operating, regulating power is stronger;
(6)Technological process is relatively short, reduces investment outlay and operating cost;
(7)Cleaning frequency is relatively low, this is because under high ph conditions, bacterium is difficult to breed, is not likely to produce potential Pollution;
(8)Bating effect is preferable, and a point salt is carried out using fume afterheat after finally having concentrated, and reaches relatively good operation effect Fruit.
Description of the drawings
Illustrate present specification embodiment or technical solution of the prior art in order to clearer, it below will be to embodiment Or attached drawing is briefly described needed in the description of the prior art, it should be apparent that, the accompanying drawings in the following description is only It is the reference to some embodiments in present specification, for those skilled in the art, what is do not made the creative labor In the case of, other attached drawings can also be obtained according to these attached drawings, are used after being also adjusted to certain part therein.
Fig. 1 shows the structure diagram of the high-salt wastewater treatment process system according to the utility model one embodiment. In figure, (100) desulfurization process system, (101) raw water regulating reservoir, (102) super softening sedimentation basin, (103) clear water reserviors, (104) Super ozone equipment, (105) more medium filter, (106) weak acid cation bed, (107) sodium bed, (108) ultraviolet device, (109) pipe Formula film, (110) cartridge filter, (111) SCRO, (112) special separation film, (113) high pressure are reverse osmosis, the evaporation of (114) flue Crystallizing and drying device, (115) wastewater disposal basin, (116) reuse pool.
Specific embodiment
The utility model is described in further detail with reference to embodiment, but the embodiment of the utility model is not It is limited to this.
Fig. 1 shows the high-salt wastewater treatment process system according to the utility model one embodiment, including
(100) desulfurization process system, (101) raw water regulating reservoir, (102) super softening sedimentation basin, (103) clear water reserviors, (104) super ozone equipment, (105) more medium filter, (106) weak acid cation bed, (107) sodium bed, (108) ultraviolet device, (109) tubular membrane, (110) cartridge filter, (111) SCRO, (112) special separation film, (113) high pressure be reverse osmosis, (114) cigarette Road evaporative crystallization drier, (115) wastewater disposal basin, (116) reuse pool.
In order to realize zero discharge of industrial waste water with high salt, this system couples each device by pipeline with pump, high salt worker Industry waste water collects in raw water regulating reservoir (101), and super softening sedimentation basin is squeezed by pump(102), in super softening sedimentation basin (102) caustic soda, lime, carboxyethyl cellulose, soda ash and flocculation aid are added in different zones, the pH value of water is made to be maintained at 11, Go out the water hardness and be reduced to 0.5mmol/L, the sludge that super softening sedimentation basin (102) generates is CaCO3、Mg(OH)2It is sent into desulphurization system (100), make itself and SO2Following react occurs in absorption tower:
CaCO3+SO2+1/2H2O─→CaSO3•1/2H2O+CO2
2CaSO3•1/2H2O+O2+3H2O─→2CaSO4•2H2O
Mg(OH)2+SO2+5H2O─→MgSO3•6H2O
Water after super softening sedimentation basin (102) clarification softening enters clear water reserviors (103), then enters multimedium by pump Filter (105) carries out catalysis oxygen by the super ozone that (104) super ozone equipment generates in more medium filter (105) to waste water Change, COD is reduced to below 10mg/L;It produces water and enters weak acid cation bed (106) afterwards into sodium bed (107) filtering, in waste water Hardness is removed again, ensures that rear end hardness is reduced to 0.1mmol/L;
After sodium bed (107) produces water by ultraviolet device (108) disinfection, softened again into tubular membrane (109), softened Enter cartridge filter (110) and SCRO (111) afterwards, after desalination, production water is recycled, and concentrated water enters special separation Film (112), the concentrated water that special separation film (112) generates directly return to desulphurization system (100), and react generation stone on absorption tower Cream, SO4 2-、Ca2+、Mg2+, it is more than 95% to ensure removal rate;
SCRO (111) is using two sections of level-one, and intersegmental using supercharging pump reflux, the rate of recovery is 40 ~ 75%;Special separation film (112) using two sections of level-one, intersegmental using supercharging pump reflux, the rate of recovery is 60 ~ 75%;
Reverse osmosis (113), the rate of recovery 70% that special separation film (112) production water enters high pressure, high pressure are reverse osmosis (113) Production water is recycled, and produces a part of concentrated water Direct Regeneration weak acid cation bed (106) of water and sodium bed (107), other parts Concentrated water enters flue evaporative crystallization drier (114), and concentrated water is after flue evaporative crystallization drier (114) is evaporated by flue gas It takes away, the absorption tower in desulphurization system (100) carries out condensation recycling, and remaining salt directly by flue gas drying, reaches Nacl Primary standard.
Weak acid cation bed (106) and sodium bed (107) regeneration liquid are separately handled with flushing water, flushing water to reuse pool (116), more medium filter (105) flushing water is also connected to reuse pool (116), then passes through pump to clear water reserviors (103) reuse; Weak acid cation bed (106) and sodium bed (107) regenerative wastewater are connected to wastewater disposal basin (115), subsequently into desulphurization system (100), make its with SO2Following react occurs in absorption tower:
CaCO3+SO2+1/2H2O─→CaSO3•1/2H2O+CO2
2CaSO3•1/2H2O+O2+3H2O─→2CaSO4•2H2O
Mg(OH)2+SO2+5H2O─→MgSO3•6H2O
To ensure the operation steady in a long-term of this process system, realize complete zero-emission, while product is utilized, further include Related mating cleaning device, chemicals dosing plant, electrical system and instrument control participate in a kind of this high-salt wastewater treatment process system Operation.
" one embodiment " and " embodiment " for being spoken of in the present specification etc. refers to combining embodiment description Specific features, structure or feature are included at least one embodiment of the application generality description.It is multiple in the description It is not centainly to refer to same embodiment that statement of the same race, which occurs, in place.Furthermore, it is understood that describe one with reference to any embodiment Specific features, structure either feature when to be advocated is that this feature, structure or feature are realized with reference to other embodiment Also it falls in the scope of the utility model.
Although reference be made herein to the utility model is described in multiple explanatory embodiments of the utility model, still, It should be understood that those skilled in the art can be designed that a lot of other modifications and embodiment, these modifications and embodiment It will fall within spirit disclosed in the present application and spirit.More specifically, it discloses in the application, drawings and claims In the range of, a variety of variations and modifications can be carried out to the building block and/or layout of theme combination layout.In addition to building block And/or outside the variations and modifications of layout progress, to those skilled in the art, other purposes also will be apparent.

Claims (1)

1. a kind of high-salt wastewater treatment process system, this system includes desulfurization process system, raw water regulating reservoir, super softening precipitation Pond, super ozone equipment, clear water reserviors, more medium filter, weak acid cation bed, sodium bed, ultraviolet device, tubular membrane, cartridge filter, SCRO, special separation film, high pressure are reverse osmosis, flue evaporative crystallization drier, wastewater disposal basin, reuse pool;To ensure this technique system The operation steady in a long-term of system further includes related mating cleaning device, chemicals dosing plant, electrical system and instrument control, feature It is:
The sludge that super softening sedimentation basin generates is CaCO3、Mg(OH)2It is sent into desulfurization process system;
A part of Direct Regeneration weak acid cation bed of concentrated water and sodium bed of the reverse osmosis generation of high pressure;Weak acid cation bed and sodium bed regeneration liquid with Flushing water is separately handled, and flushing water to reuse pool, more medium filter flushing water is also connected to reuse pool, then by pumping extremely Clear water reserviors reuse;Weak acid cation bed and sodium bed regenerative wastewater are connected to wastewater disposal basin, subsequently into desulphurization system;
The concentrated water that special separation film generates directly returns to desulphurization system, and the absorption tower in desulphurization system, which reacts, generates stone Cream;
SCRO uses two sections of level-one, intersegmental using supercharging pump reflux;Special separation film uses two sections of level-one, intersegmental to use booster pump Reflux;Enter flue evaporative crystallization drier through the reverse osmosis concentrated water of high pressure, water is taken away by flue gas, is condensed in desulfurization offer Recycling, remaining salt is directly by flue gas drying.
CN201720770524.8U 2017-06-29 2017-06-29 A kind of high-salt wastewater treatment process system Active CN207537295U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111001445A (en) * 2019-12-26 2020-04-14 华电电力科学研究院有限公司 System and method for recycling weak acid cation bed regeneration wastewater of thermal power plant according to quality

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111001445A (en) * 2019-12-26 2020-04-14 华电电力科学研究院有限公司 System and method for recycling weak acid cation bed regeneration wastewater of thermal power plant according to quality

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Address after: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee after: Guoneng Lang Xinming Environmental Protection Technology Co.,Ltd.

Address before: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee before: BEIJING LUCENCY ENVIRO-TECH Co.,Ltd.

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Address before: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee before: Guoneng Lang Xinming Environmental Protection Technology Co.,Ltd.

Country or region before: China