CN207488658U - It is a kind of to have both photochromic and electrochromism function glass devices - Google Patents
It is a kind of to have both photochromic and electrochromism function glass devices Download PDFInfo
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- CN207488658U CN207488658U CN201721735392.1U CN201721735392U CN207488658U CN 207488658 U CN207488658 U CN 207488658U CN 201721735392 U CN201721735392 U CN 201721735392U CN 207488658 U CN207488658 U CN 207488658U
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Abstract
Photochromic and electrochromism function glass devices are had both the utility model discloses a kind of; by the first basal layer connected in sequence, the first conductive membrane layer, working electrode, electrolyte layer, electrode, the second conductive membrane layer, the second basal layer, photochromatic layer and protective layer are formed, working electrode is connect with to electrode by electrolyte layer.The glass devices had not only included photochromic function layer but also including electrochromism functional layers, when device works, photochromic function layer can generate color change with the variation of ambient, electrochromism functional layer then can be more dim in environment or be started when having specific demand, control glass discoloration, electrochromism part can be deactivated under normal illumination, save electric energy, extend the service life of glass devices, it is a kind of intelligent and energy-efficient photo chromic glass device, in addition the glass devices also have the function of good isolation infrared ray and ultraviolet light, further improve the comfort level of user.
Description
Technical field
The utility model belongs to photo chromic glass technical field, relates in particular to one kind and has both photochromic and electrochromism
The glass devices of function.
Background technology
With the continuous improvement of people's levels of substance, the requirement to standard of living is also increasing increasingly, such as in outdoor glass
Technical field, traditional windowpane can not gradually be met the needs of users since function is single, at present the most common glass of application
Glass window generally comprises water white transparency, colored transparent and its limitation is individually present in types, these windowpanes such as stamp is opaque：It is high
The glass of transmitance can generate the phenomenon that dazzling due to the direct projection of sunlight in the weather of sunlight strong and indoor temperature is made significantly to rise
Height without heat-insulated function, causes the wasting of resources；And the good glass of light-proofness then can make indoor light in gloomy weather
It is bad, visibility is low；The glass of stamp causes the visual field not open enough.Therefore traditional glass window advantage cannot be complementary, influences user
Satisfaction.
Demand of the people to intelligent glass was more and more urgent in recent years, and summer, it is desirable to as far as possible keep off sunlight in room
Outside, make indoor holding refrigerant, winter then wishes that sunlight is got in, and increases comfort level and reduces heating cost, is needed based on these
It asks, the various dimming glass that production is made using new technology and new process are continued to bring out, and mainly include photochromic glass and electricity
Photo chromic glass is caused, wherein, photochromic glass can make glass colour generate variation with the variation of ambient, to interior
The adjusting of light has certain effect, but its interception effect to infrared ray and ultraviolet light is bad, and in dark weather,
Regulating effect is bad, and most importantly photochromic is passive adjusting, it is impossible to it goes to change by the subjective demand of people,
There is larger limitation in application process.Electrochomeric glass is using laminated glass manufacturing method, and light modulation film is bonded in
Between simple glass, so as to fulfill intelligent dimming, it can pass through people's by changing the big minor adjustment light transmittance of electric current
Subjective idea realizes the effect that light is adjusted, but light conversion is required for electric drive, controls every time, and there are certain energy
Waste problem, and as usage time increases, the increase of number of transitions can also influence service life and the performance of electrochomeric glass.
Utility model content
For this purpose, the technical problem to be solved by the utility model is to be adjusted light glass be individually present its shortcoming and
Application limitation, so as to propose it is a kind of can intelligently be adjusted with environmental change and user demand translucency have both it is photochromic with it is electric
The glass devices of inducing off-coloring function.
In order to solve the above technical problems, the technical solution of the utility model is：
The utility model offer is a kind of to have both photochromic and electrochromism function glass devices, by connected in sequence
First basal layer, the first conductive membrane layer, working electrode, electrolyte layer, to electrode, the second conductive membrane layer, the second basal layer,
Photochromatic layer and protective layer composition.
Preferably, first conductive membrane layer is connected to one end of power supply, second conductive membrane layer is connected to
The other end of power supply.
Preferably, the electrolyte layer surrounding is provided with sealant layer.
Preferably, first basal layer, the second basal layer are transparent base layer, the transparent base layer is transparent glass
Glass, PC or pet layer.
Preferably, first conductive membrane layer, the second conductive membrane layer are transparent ITO conductive layer.
Preferably, the working electrode oxidation tungsten electrode, pyroles electrode or thiophene-based electrode.
Preferably, described is nickel oxide electrode, pyroles electrode or thiophene-based electrode to electrode.
Preferably, the photochromatic layer is made of at least one P-type semiconductor and at least one N-type semiconductor.
Preferably, the protective layer is niobium oxide layer.
Preferably, the electrolyte layer is the quasi-solid electrolyte layer of ultra-violet curing.
The above-mentioned technical proposal of the utility model has the following advantages compared with prior art：
It is described in the utility model to have both photochromic and electrochromism function glass devices, by connected in sequence first
Basal layer, the first conductive membrane layer, working electrode, electrolyte layer, to electrode, the second conductive membrane layer, the second basal layer, photic
Photochromic layer and protective layer composition, the working electrode are connect electrode by electrolyte layer with described.The glass devices both include light
Inducing off-coloring function layer includes electrochromism functional layer again, and when device works, photochromic function layer can be with the variation of ambient
And color change is generated, start when electrochromism functional layer then can be more dim in environment or has specific demand, control glass discoloration,
Electrochromism part can be deactivated under normal illumination, saves electric energy, the service life for extending glass devices, be it is a kind of intelligence and
Energy-efficient photo chromic glass device, in addition the glass devices also there is good isolation infrared ray and ultraviolet light, further
Improve the comfort level of user.
Description of the drawings
In order to which the content for making the utility model is more likely to be clearly understood, below according to the specific implementation of the utility model
Example and with reference to attached drawing, is described in further detail the utility model, wherein
Fig. 1 is the structure diagram of the electrochromic device described in the utility model embodiment；
Reference numeral is expressed as in figure：The first basal layers of 1-；The first conductive membrane layers of 2-；3- working electrodes；4- is to electrode；
The second conductive membrane layers of 5-；The second basal layers of 6-；7- photochromatic layers；8- protective layers；9- electrolyte layers；10- power supplys；11- is sealed
Frame glue layer.
The utility model can be implemented with many different forms, should not be construed as limited to embodiment set forth herein,
On the contrary, provide these embodiments so that the disclosure is thorough and complete, and the design of the utility model is fully conveyed to this
Field technology personnel, the utility model will be defined by the claims.In the accompanying drawings, for clarity, each device can be exaggerated
Size and relative size.Term " first ", " second " in the utility model specification and claims and attached drawing etc. are
For distinguishing similar object, specific sequence or precedence are described without being used for.It should be appreciated that the data used in this way
It can be interchanged in the appropriate case.In addition, term " comprising ", " having " and their any deformation, it is intended that covering is not
Exclusive includes.
Specific embodiment
Embodiment
Photochromic and electrochromism function glass devices are had both the present embodiment provides a kind of, can be used as glass curtain
Wall, building glass window etc., can with environment and people demand free switching is photochromic and electrochromism function, the vierics
The structure of part as shown in Figure 1, its by the first basal layer 1 connected in sequence, the first conductive membrane layer 2, working electrode 3, electrolyte
Layer 9 forms electrode 4, the second conductive membrane layer 5, the second basal layer 6, photochromatic layer 7 and protective layer 8, the working electrode
3 are connect electrode 4 by electrolyte layer 9 with described.
Wherein photochromatic layer 7 is that the part of photochromic action is played in device, the first conductive membrane layer 2, work electricity
Pole 3, electrolyte layer 9 form electrochromism part to electrode 4, the second conductive membrane layer 5, and first conductive membrane layer 2 connects
In one end of power supply 10, the second conductive membrane layer 5 is connected to the other end of power supply 10, so as to make working electrode 3 and electrode 4 is divided
It is not connected to the both ends of power supply, forms a current loop, coloring or colour fading is realized by changing power positive cathode, such as works as
Working electrode 3 is connected to the cathode of power supply 10, and the anode of power supply 10 is connected to electrode 4, realizes coloring；On the contrary, work as work
Electrode 3 is connected to 10 anode of power supply, and 10 cathode of power supply is connected to electrode 4, realizes and fades, by adjusting 10 voltage value of power supply
Size realizes the adjusting to fading extent.
The glass devices have photochromic and electrochromic function simultaneously, can change and apply with ambient light and is different
Voltage glass transmission rate is made to change, meet the needs of people intelligently adjust glass transmission rate, at the same have it is energy saving, make
With the advantage of long lifespan.
In photo chromic glass device, 1 and second basal layer 6 of the first basal layer be transparent base layer, optional self-induced transparency glass
One kind in glass, transparent PC (makrolon) layers and transparent PET (polyethylene terephthalate) layer.
First conductive membrane layer 2, the second conductive membrane layer 5 are transparent ITO conductive layer, with good electric conductivity
And the transparency, as transparent conducting glass, harmful electron radiation and ultraviolet, infrared ray can be reduced.
The working electrode 3 is the one kind aoxidized in tungsten electrode, pyroles organic electrode, thiophene-based organic electrode；It is described
It is one kind in nickel oxide electrode, pyroles organic electrode or thiophene organic electrode to electrode 4, wherein, the nickel oxide electricity
Doped at least one of vanadium, silicon, aluminium, magnesium, titanium, tungsten in extremely.
The electrolyte layer 9 is set to working electrode 3 and between electrode 4, plays the role of connecting the two, also,
As shown in the figure, the surrounding of the electrolyte layer 9 is additionally provided with sealant layer 11.In the present embodiment, the electrolyte layer 9 is can be purple
Outer cured quasi-solid electrolyte.
The photochromatic layer 7 is prepared by P-type semiconductor and N-type semiconductor material by PVD method plated films, is formed
One P-N hetero-junctions, wherein P-type semiconductor can be NiO, WO3、VO2Grade holes are positively charged to material, and N-type semiconductor is
TiO2、P2O5、Ta2O5Deng the material that an electron is negatively charged.The protective layer 8 is niobium oxide layer.
The photochromic preparation process with the glass devices of electrochromism function that has both described in the present embodiment is：First
One layer of working electrode 3 is plated in the top surface of conductive membrane layer 2, by magnetron sputtering or electron beam evaporation process in the second conductive membrane layer
5 bottom surfaces are electroplated one layer and plate photochromatic layer 7 to electrode 4, on 6 surface of the second basal layer at 5 top of the second conductive membrane layer,
One layer of niobium oxide protective layer 8 is deposited on 7 surface of photochromatic layer again, by working electrode 3 with being pasted to electrode 4 by electrolyte layer 9
Merge ultra-violet curing, the first conductive film 2, the second conductive film 5 are connect respectively by power cord with power supply 10, then the
One conductive membrane layer, 2 non-electrical surfacing connects the first basal layer 1, then carries out the processing of envelope frame with frame adhesive to get light-induced variable is had both
Color and the glass devices of electrochromism function.
Obviously, the above embodiments are merely examples for clarifying the description, and is not intended to limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And the obvious variation thus extended out or
Among the protection domain that variation is created still in the utility model.
Claims (10)
1. a kind of have both photochromic and electrochromism function glass devices, which is characterized in that by the first base connected in sequence
Bottom, the first conductive membrane layer, working electrode, electrolyte layer, to electrode, the second conductive membrane layer, the second basal layer, light-induced variable
Chromatograph and protective layer composition.
2. according to claim 1 have both photochromic and electrochromism function glass devices, which is characterized in that described
First conductive membrane layer is connected to one end of power supply, and second conductive membrane layer is connected to the other end of power supply.
3. according to claim 2 have both photochromic and electrochromism function glass devices, which is characterized in that described
Electrolyte layer surrounding is provided with sealant layer.
4. according to claim 3 have both photochromic and electrochromism function glass devices, which is characterized in that described
First basal layer, the second basal layer are transparent base layer, and the transparent base layer is transparent glass, PC or pet layer.
5. according to claim 4 have both photochromic and electrochromism function glass devices, which is characterized in that described
First conductive membrane layer, the second conductive membrane layer are transparent ITO conductive layer.
6. according to claim 5 have both photochromic and electrochromism function glass devices, which is characterized in that described
Working electrode oxidation tungsten electrode, pyroles electrode or thiophene-based electrode.
7. according to claim 6 have both photochromic and electrochromism function glass devices, which is characterized in that described
It is nickel oxide electrode, pyroles electrode or thiophene-based electrode to electrode.
8. according to claim 7 have both photochromic and electrochromism function glass devices, which is characterized in that described
Photochromatic layer is made of at least one P-type semiconductor and at least one N-type semiconductor.
9. according to claim 8 have both photochromic and electrochromism function glass devices, which is characterized in that described
Protective layer is niobium oxide layer.
10. according to claim 9 have both photochromic and electrochromism function glass devices, which is characterized in that institute
State the quasi-solid electrolyte layer that electrolyte layer is ultra-violet curing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721735392.1U CN207488658U (en) | 2017-12-13 | 2017-12-13 | It is a kind of to have both photochromic and electrochromism function glass devices |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721735392.1U CN207488658U (en) | 2017-12-13 | 2017-12-13 | It is a kind of to have both photochromic and electrochromism function glass devices |
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| CN207488658U true CN207488658U (en) | 2018-06-12 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108945386A (en) * | 2018-07-26 | 2018-12-07 | 中国商用飞机有限责任公司 | The control method of main cabin porthole, intelligent side of a ship window system and main cabin porthole |
| CN109683416A (en) * | 2019-01-28 | 2019-04-26 | 青岛九维华盾科技研究院有限公司 | A kind of double-colored adjustable electrochromism thin-film device |
| WO2024000449A1 (en) * | 2022-06-30 | 2024-01-04 | 京东方科技集团股份有限公司 | Dimming structure and dimming device |
-
2017
- 2017-12-13 CN CN201721735392.1U patent/CN207488658U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108945386A (en) * | 2018-07-26 | 2018-12-07 | 中国商用飞机有限责任公司 | The control method of main cabin porthole, intelligent side of a ship window system and main cabin porthole |
| CN109683416A (en) * | 2019-01-28 | 2019-04-26 | 青岛九维华盾科技研究院有限公司 | A kind of double-colored adjustable electrochromism thin-film device |
| WO2024000449A1 (en) * | 2022-06-30 | 2024-01-04 | 京东方科技集团股份有限公司 | Dimming structure and dimming device |
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| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220802 Address after: 200131 floors 1 and 3, building 5, No. 99 and 111 Boyi Road, Lingang New Area, China (Shanghai) pilot Free Trade Zone, Pudong New Area, Shanghai Patentee after: Shanghai Centaur Enterprise Development Group Co.,Ltd. Address before: 518000 101, 201, first floor and second floor, building 1, No. 9, xiaweiyuan Industrial Zone, Gushu community, Xixiang street, Bao'an District, Shenzhen, Guangdong Province Patentee before: JISHENG PHOTOELECTRIC (SHENZHEN) Co.,Ltd. |