CN207391353U - Remove the device of phenolic comp ' ds pollution in oil product - Google Patents
Remove the device of phenolic comp ' ds pollution in oil product Download PDFInfo
- Publication number
- CN207391353U CN207391353U CN201721042563.2U CN201721042563U CN207391353U CN 207391353 U CN207391353 U CN 207391353U CN 201721042563 U CN201721042563 U CN 201721042563U CN 207391353 U CN207391353 U CN 207391353U
- Authority
- CN
- China
- Prior art keywords
- container
- oil
- water
- pollution
- bottom wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Water Treatment By Sorption (AREA)
Abstract
The utility model provides a kind of device for removing phenolic comp ' ds pollution in oil product.The device includes：The first container and agitating element, the first container include the cavity that side wall, bottom wall and side wall are formed with bottom wall, and bottom wall is oleophobic hydrophilic film；Agitating element is arranged in the cavity of the first container.Remove the device of phenolic comp ' ds pollution in oil product, the oil product (such as coal derived oil) in the first container with water is mixed using agitating element, grease is made to be layered after uniformly mixing, in delaminating process, aldehydes matter is extracted by water when its hydrophily is stronger, is transferred to from oil in water；Then the water containing phenol can penetrate oleophobic hydrophilic film due to gravity, and oil is trapped because can not penetrate the oleophobic hydrophilic film due to, so as to fulfill efficiently separating for water containing phenol and dephenolize oil.
Description
Technical field
The utility model is related to coal liquifaction field, in particular to a kind of device for removing phenolic comp ' ds pollution in oil product.
Background technology
Mainly there are phenol, cresols, ammonia containing more phenolic comp ' ds pollution, phenolic comp ' ds pollution in the product and waste of coal chemical industry
It is arranged in base phenol, naphthols etc., such as coal base diesel oil outside the volatilization of phenol or untreated phenol wastewater, phenol will be volatized into air
Or permeate the ground, pollution air, underground water and crops.Phenol and its compound are that one kind has moderately toxic substance, phenol, first
The phenol compounds such as phenol they can enter human body through number of ways such as skin, mucous membrane, respiratory tract and oral cavities.
Utility model content
The main purpose of the utility model is that a kind of device for removing phenolic comp ' ds pollution in oil product is provided, to remove coal system
Phenolic comp ' ds pollution in oil product.
To achieve these goals, the utility model provides a kind of device for removing phenolic comp ' ds pollution in oil product, the dress
Put including：The first container and agitating element, the first container include the cavity that side wall, bottom wall and side wall are formed with bottom wall, bottom
Wall is oleophobic hydrophilic film；Agitating element is arranged in the cavity of the first container.
Further, oleophobic hydrophilic film is to construct Cu (OH) in red copper net surface2With PDDA-PFO/SiO2Micro-nano knot
Structure film.
Further, device further includes second container, and at least part the first container is located in the accommodating chamber of second container.
Further, whole the first containers are located in the accommodating chamber of second container.
Further, device further includes phenol wastewater recovery unit, for being returned to the phenol wastewater in second container
Receipts processing.
Further, the first container is open cylinder body, and the bottom wall of cylinder body is oleophobic hydrophilic film.
Further, agitating element is blender.
Further, blender includes stirring rod and agitating paddle, and agitating paddle is located at one end of stirring rod, and agitating paddle is more
A, multiple agitating paddles are set by axial symmetry of stirring rod.
Further, second container is open cylinder body.
Using the technical solution of the utility model, the device of phenolic comp ' ds pollution in oil product is removed, using agitating element by the
Oil product (such as coal derived oil) in one container is mixed with water, and grease is made to be layered after uniformly mixing, in delaminating process, phenol
Class substance is extracted by water when its hydrophily is stronger, is transferred to from oil in water；Then the water containing phenol can penetrate due to gravity
Oleophobic hydrophilic film, and oil is trapped because can not penetrate the oleophobic hydrophilic film due to, so as to fulfill the effective of water containing phenol and dephenolize oil
Separation.
Description of the drawings
The accompanying drawings which form a part of this application are used to provide a further understanding of the present invention, this practicality
New schematic description and description does not form the improper restriction to the utility model for explaining the utility model.
In the accompanying drawings：
Fig. 1 shows the dress of phenolic comp ' ds pollution in the removing oil product in a kind of preferred embodiment according to the present utility model
The structure diagram put.
Wherein, above-mentioned attached drawing is marked including the following drawings：
10th, the first container；
20th, agitating element；
30th, second container；
11st, side wall；12nd, bottom wall；13rd, cavity.
Specific embodiment
It should be noted that in the case where there is no conflict, the feature in embodiment and embodiment in the application can phase
Mutually combination.The utility model will be described in detail below with reference to the accompanying drawings and embodiments.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root
According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singulative
Be also intended to include plural form, additionally, it should be understood that, when in the present specification using belong to "comprising" and/or " bag
Include " when, indicate existing characteristics, step, operation, device, component and/or combination thereof.
For ease of description, spatially relative term can be used herein, as " ... on ", " ... top ",
" ... upper surface ", " above " etc., for describing such as a device shown in the figure or feature and other devices or spy
The spatial relation of sign.It should be appreciated that spatially relative term is intended to comprising the orientation except device described in figure
Outside different azimuth in use or operation.For example, if the device in attached drawing is squeezed, it is described as " in other knots
Structure or construction top " will be positioned as " on other structures or construction " " below other structures or construction " or " at it
Under his structure or construction ".Thus, exemplary term " ... top " can include " ... top " and " ... under
Two kinds of side " orientation.The device can also other different modes positioning (being rotated by 90 ° or in other orientation), and to institute here
Respective explanations are made in the opposite description in space used.
In the description of the utility model, it is to be understood that the noun of locality such as " forward and backward, upper and lower, left and right ", " horizontal,
Vertically, vertically, it is horizontal " and " pushing up, bottom " etc. indicated by orientation or position relationship be normally based on orientation or position shown in the drawings
Relation is put, be for only for ease of description the utility model and simplifies description, in the case where not making explanation on the contrary, these nouns of locality
It does not indicate that and implies signified device or element must have specific orientation or with specific azimuth configuration and operation, because
This is it is not intended that limitation to scope of protection of the utility model；The noun of locality " inside and outside " refers to the wheel compared with each component in itself
Wide is inside and outside.
As background technology is previously mentioned, coal chemical industry, especially in coal liquifaction product, phenolic comp ' ds pollution is usually contained, no
Only have an impact to the performance of product, and phenolic comp ' ds pollution is readily volatilized and pollutes environment, thus, in order to remove in such oil product
Phenolic comp ' ds pollution, in a kind of typical embodiment of the application, provide it is a kind of remove oil product in phenolic comp ' ds pollution dress
Put, as shown in Figure 1, the device include the first container 10 and agitating element 20, the first container 10 include bottom wall 12, side wall 11 and
The cavity 13 that bottom wall 12 and side wall 11 are formed, bottom wall 12 are oleophobic hydrophilic film；Agitating element 20 is arranged on the chamber of the first container 10
In body 13.
The device of phenolic comp ' ds pollution in above-mentioned removing oil product, using agitating element 20 by the oil product in the first container 10 (such as
Coal derived oil) it is mixed with water, grease is made to be layered after uniformly mixing, in delaminating process, aldehydes matter is because of its hydrophily
It is stronger and extracted by water, it is transferred to from oil in water；Then the water containing phenol can penetrate oleophobic hydrophilic film due to gravity, and oily
It is trapped because can not penetrate the oleophobic hydrophilic film due to, so as to fulfill efficiently separating for water containing phenol and dephenolize oil.
In above-mentioned removing oil product in the device of phenolic comp ' ds pollution, the method for specific removing phenolic comp ' ds pollution is as follows：It will contain
The oil product of phenolic comp ' ds pollution is first put into above-mentioned the first container 10, oily since the bottom wall 12 of the first container 10 is oleophobic hydrophilic film
Product are difficult to penetrate, and it (is 4~5 usually according to mass volume ratio that water is then added in into oil product:1 ratio adds water) and stirred
It mixes, it is heavier since the density of water is big after oil mixing with water is uniform, it can move down, so as to grease layering occur, upper strata is oil, under
Layer is water.Oleophobic hydrophilic film has hydrophily to the water of lower floor, it is thus possible to lower water be allowed to pass through and then the phenol that will be dissolved in water
Class substance removes together, it is achieved thereby that oil is efficiently separated with phenolic comp ' ds pollution.
In above-described embodiment, the effect of oleophobic hydrophilic film is exactly selectively to remove hydrophilic aldehydes matter, so as to
Itself and oil are efficiently separated.Therefore, the hydrophily of oleophobic hydrophilic film is stronger, and dehydration rate is higher, and de-oiling rate is lower.A kind of preferred
In embodiment, oleophobic hydrophilic film is to construct Cu (OH) in red copper net surface2With PDDA-PFO/SiO2Micro nano structure film, it is this
The water-oil separating of oleophobic hydrophilic film is efficient, can refer to existing preparation method and is prepared.
In order to effectively collect separated phenol wastewater, in an advantageous embodiment, as shown in Figure 1, above device also wraps
Second container 30 is included, the first container 10 is located in second container 30.Phenol wastewater after being separated so from oil product is collected into the
In two containers 30, it is convenient for focusing on.
In order to reduce pollution of the phenol wastewater to environment, in an advantageous embodiment, above device is further included to give up containing phenol
Water recovery unit, for being recycled to the phenol wastewater in second container 30.
In above device, the shape and concrete structure of the first container 10 have no particular/special requirement, if can accommodate oil product and
For the agitating element 20 of stirring.In an advantageous embodiment, the first container 10 is open cylinder body, the bottom wall of cylinder body
For oleophobic hydrophilic film.Open cylinder body is more convenient the addition or stirring of oil product for the smaller container of opening.
In above device, agitating element 20 uses existing agitation means.In an advantageous embodiment, stirring member
Part 20 is blender.In the utility model, concrete structure to blender is simultaneously not particularly limited, any to realize that mixing is equal
Even blender is suitable for the application.
In an advantageous embodiment, as shown in Figure 1, above-mentioned blender includes stirring rod and agitating paddle, agitating paddle is located at
One end of stirring rod, agitating paddle are multiple, and multiple agitating paddles are set by axial symmetry of stirring rod.Stirring with multiple agitating paddles
It is more preferable that device stirs and evenly mixs effect.In concrete application, in 300r/min or so, mixing time is the speed control of blender
10-30min.Design parameter can be adjusted according to actual requirement.
In above device, for second container 30 structure also without particular/special requirement.In an advantageous embodiment, second holds
Device 30 is open cylinder body.
The diameter of outer shell and interior thick stick in above device is changeable, and specific material is also not particularly limited, and can be glass
Material.For the diameter of usual outer shell in 30-60cm, high 30-50cm is more suitable.Specific size can be adjusted according to actual requirement.
It should be noted that term " first " in the description and claims of this application and above-mentioned attached drawing, "
Two " etc. be the object for distinguishing similar, without being used to describe specific order or precedence.It should be appreciated that it so uses
Data can exchange in the appropriate case, so that presently filed embodiment described herein can be with except illustrating herein
Or the order beyond those of description is implemented.
In a kind of preferred embodiment, as shown in Figure 1, in the device of phenolic comp ' ds pollution includes in the removing oil product
Cylinder, outer shell and blender, inner casing are located in outer shell, and blender is located in inner casing, and the bottom wall of inner casing is constructed for red copper net surface
Cu(OH)2With PDDA-PFO/SiO2Micro nano structure film formed oleophobic hydrophilic film.Specific oil water separation process is as follows：
Coal derived oil containing phenol with water in inner casing is mixed, is stood after stirring 5min, waits to be layered, coal system in delaminating process
Aldehydes matter in diesel oil is extracted by water when its hydrophily is stronger, is transferred to from oil in water；Then the water containing phenol can be because of weight
Power enters outer shell through the super hydrophilic film of high oleophobic, and the oil in inner casing is trapped because can not penetrate film due to, so as to fulfill containing phenol
The separation of water and dephenolize oil.
Phenol wastewater is finally recycled, recycles waste water, you can completes coal derived oil dephenolize.
The illustrative embodiments according to the application are described in more detail below.However, these illustrative embodiments
It can be implemented by many different forms, and should not be construed to be limited solely to embodiments set forth herein.It should
These embodiments that are to provide understood are in order to enable disclosure herein is thoroughly and complete, and by these exemplary realities
The design for applying mode is fully conveyed to those of ordinary skill in the art.
In order to further illustrate the advantageous effect of the application, using the device of the application in the laboratory of certain coal liquifaction enterprise
It is interior, small-scale experiment is carried out to the coal liquifaction sample of three groups of different batches, the structure of device such as Fig. 1 used in the small-scale experiment
It is shown, using a diameter of 60cm, highly for 50cm glass material outer shell, a diameter of 25cm, highly the glass material for 50cm
The inner casing of matter, wherein, the bottom wall of interior thick stick constructs Cu (OH) for red copper net surface2With PDDA-PFO/SiO2Micro nano structure film shape
Into oleophobic hydrophilic film.Three parts of different oil products 1,2 and 3 containing phenolic comp ' ds pollution are subjected to following oil water separation process such as successively
Under：
Oil product containing phenolic comp ' ds pollution is first put into inner casing, since inner casing bottom wall is oleophobic hydrophilic film, oil product is difficult to
It crosses, is then 5 according to mass volume ratio into oil product:1 ratio adds in water and is stirred, and the speed of stirring is 300r/
Min, mixing time 30min.During stirring, oil mixing with water is heavier since the density of water is big, can move down, from
And there is grease layering, upper strata is oil, and lower floor is water.Oleophobic hydrophilic film has hydrophily to the water of lower floor, it is thus possible to allow
Lower water by, and then the aldehydes matter dissolved in water is removed together, it is achieved thereby that oil and phenolic comp ' ds pollution effectively point
From.Result of the test see the table below 1：
Table 1：
It can be seen from the above description that the above embodiments of the present invention achieve the following technical effects：This is de-
Except the device of phenolic comp ' ds pollution in oil product, by using agitating element by the oil product (such as coal derived oil) in the first container and water into
Row is mixed, and grease is made to be layered after uniformly mixing, and in delaminating process, aldehydes matter is extracted by water when its hydrophily is stronger,
It is transferred to from oil in water；Then the water containing phenol can penetrate oleophobic hydrophilic film due to gravity, and oil through this because can not dredge
Oily hydrophilic film and be trapped, so as to fulfill water containing phenol and dephenolize oil efficiently separate.Specifically have the following advantages that：
(1) dephenolize efficiency is higher, while can realize water-oil separating, and original moisture in coal derived oil is spun off,
Obtain environmental-protecting performance more preferably oil product.
(2) it is easy to operate using the device of the application when removing phenolic comp ' ds pollution, into relatively low.
The above is only the preferred embodiment of the utility model only, is not intended to limit the utility model, for this
For the technical staff in field, various modifications and changes may be made to the present invention.It is all in the spirit and principles of the utility model
Within, any modifications, equivalent replacements and improvements are made should be included within the scope of protection of this utility model.
Claims (9)
1. a kind of device for removing phenolic comp ' ds pollution in oil product, which is characterized in that described device includes：
The first container (10), the chamber formed including side wall (11), bottom wall (12) and the side wall (11) and the bottom wall (12)
Body (13), the bottom wall (12) are oleophobic hydrophilic film；
Agitating element (20), the agitating element (20) are arranged in the cavity (13) of the first container (10).
2. the apparatus according to claim 1, which is characterized in that the oleophobic hydrophilic film is to construct Cu in red copper net surface
(OH)2With PDDA-PFO/SiO2Micro nano structure film.
3. device according to claim 1 or 2, which is characterized in that described device further includes second container (30), at least portion
The first container (10) is divided to be located in the accommodating chamber of the second container (30).
4. device according to claim 3, which is characterized in that all the first container (10) is located at the second container
(30) in accommodating chamber.
5. device according to claim 4, which is characterized in that described device further includes phenol wastewater recovery unit, is used for
Phenol wastewater in the second container (30) is recycled.
6. the apparatus according to claim 1, which is characterized in that the first container (10) is open cylinder body, the cylinder
The bottom wall (12) of body is the oleophobic hydrophilic film.
7. the apparatus according to claim 1, which is characterized in that the agitating element (20) is blender.
8. device according to claim 7, which is characterized in that the blender includes stirring rod and agitating paddle, described to stir
One end that paddle is located at the stirring rod is mixed, the agitating paddle is multiple, and multiple agitating paddles are using the stirring rod as axial symmetry
It sets.
9. device according to claim 3, which is characterized in that the second container (30) is open cylinder body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721042563.2U CN207391353U (en) | 2017-08-18 | 2017-08-18 | Remove the device of phenolic comp ' ds pollution in oil product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721042563.2U CN207391353U (en) | 2017-08-18 | 2017-08-18 | Remove the device of phenolic comp ' ds pollution in oil product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN207391353U true CN207391353U (en) | 2018-05-22 |
Family
ID=62418330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201721042563.2U Active CN207391353U (en) | 2017-08-18 | 2017-08-18 | Remove the device of phenolic comp ' ds pollution in oil product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN207391353U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112678975A (en) * | 2019-10-18 | 2021-04-20 | 中国石油化工股份有限公司 | Method and device for removing nitrification inhibitor in oily sewage |
| CN113244661A (en) * | 2021-05-24 | 2021-08-13 | 西安石油大学 | Dehydration purification device and dehydration purification method |
-
2017
- 2017-08-18 CN CN201721042563.2U patent/CN207391353U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112678975A (en) * | 2019-10-18 | 2021-04-20 | 中国石油化工股份有限公司 | Method and device for removing nitrification inhibitor in oily sewage |
| CN112678975B (en) * | 2019-10-18 | 2022-08-16 | 中国石油化工股份有限公司 | Method and device for removing nitrification inhibitor in oily sewage |
| CN113244661A (en) * | 2021-05-24 | 2021-08-13 | 西安石油大学 | Dehydration purification device and dehydration purification method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN207391353U (en) | Remove the device of phenolic comp ' ds pollution in oil product | |
| CN206285830U (en) | A kind of forage for turkey processes agitating device | |
| CN205774724U (en) | A kind of rare earth processing stirring linkage extraction equipment | |
| CN112845570B (en) | Soil is administered and is added medicine mixing arrangement with soil breakage | |
| CN111744230A (en) | Extraction element of circulated extraction plant active ingredient | |
| CN107158970A (en) | A kind of preparation method and its usage of super hydrophilic gel compound membrane | |
| CN102580350B (en) | Airlift air stirring multi-sublayer circulating extraction device and method | |
| CN107129438A (en) | A kind of method of glyoxaline ion liquid double-aqueous phase system multitple extraction tetracycline | |
| CN109967232A (en) | A kind of waste lithium cell powder deferrization device | |
| CN103736418A (en) | Composite stirring device | |
| CN107537361A (en) | A kind of bitumen recovery special agitating apparatus | |
| CN206529507U (en) | A kind of rare earth feed liquid extraction equipment | |
| CN115487070B (en) | Chinese herbal medicine extraction element | |
| CN104138723A (en) | Efficient pesticide mixing and stirring machine | |
| CN208389454U (en) | A kind of device for effectively separating for bio-pharmaceuticals | |
| CN208234955U (en) | A kind of rare earth processing stirring linkage extraction equipment | |
| CN105268410B (en) | A kind of preparation method and application method of antibiotic adsorbed film | |
| JP2015501294A (en) | Liquid-liquid extraction process and equipment | |
| CN209205325U (en) | A kind of beaker with stirring tool | |
| CN104525039B (en) | Sludge conditioning agitating paddle and the mixer including the agitating paddle | |
| CN207655141U (en) | A kind of Double shaft stirring reaction unit for pesticide producing | |
| CN208940726U (en) | A kind of storage device keeping entomopathogenic nematode suspended state | |
| CN208959794U (en) | A kind of automatic pathological tissue dehydrating machine rabbling mechanism | |
| CN209378496U (en) | A kind of automatic extraction instrument | |
| CN205340719U (en) | Sub - extractor of magnetic stirring |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant |