CN207254061U - A kind of plasma waste gas pollution control and treatment system - Google Patents

A kind of plasma waste gas pollution control and treatment system Download PDF

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Publication number
CN207254061U
CN207254061U CN201721212339.3U CN201721212339U CN207254061U CN 207254061 U CN207254061 U CN 207254061U CN 201721212339 U CN201721212339 U CN 201721212339U CN 207254061 U CN207254061 U CN 207254061U
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China
Prior art keywords
spark arrester
gas
plasma
waste gas
pollution control
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CN201721212339.3U
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Inventor
彭辉
周建军
黄文莉
龚华
肖会民
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China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
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BEIJING PUHUI SHIHUA SCIENCE AND TECHNOLOGY Co Ltd
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Abstract

A kind of plasma waste gas pollution control and treatment system, system are passed sequentially through pipeline and are composed in series by the first spark arrester, first gas filter, dehumidifier, the second spark arrester, plasma reactor, the 3rd spark arrester, second gas filter, ozone decomposed tank, adsorption tanks, the 4th spark arrester.The utility model plasma waste gas pollution control and treatment system, which is opened, stops, and VOCs exhaust gas concentrations is fluctuated adaptable.

Description

A kind of plasma waste gas pollution control and treatment system
Technical field
A kind of plasma waste gas pollution control and treatment system is the utility model is related to, belongs to exhaust gas draining technology field.
Background technology
In PETROLEUM PROCESSING and petrochemical production process, a certain amount of organic exhaust gas, such as ethene are inevitably discharged The oil separator and neutralization pond in workshop, in process treatment process, loss goes out the exhaust gas containing components such as benzene homologues, alkane, alkene. If do not recycled such exhaust gas effectively, on the one hand environment is caused seriously to pollute, is on the other hand threatened to health.
Administering the method that volatile organic compounds uses both at home and abroad at present mainly has absorption method, absorption process, catalysis burning Method etc..These methods were faced using the problems such as equipment is more, experiment is complicated, energy consumption is big.
CN200610047790.4 propositions purify sulfide and hydro carbons in exhaust gas using liquefied ammonia and high boiling organic solvent, This method treatment effect is obvious, but the ammonia to volatilize easily causes secondary pollution.
CN200710012210.2 is taken off using desulfurization-absorbing process purification storage-tank waste gas pollutant, this method using lye Sulphide removal, then adsorbs hydro carbons using combine adsorption bed, can purify the pollutant well, but there are saturated hydrocarbons gas The problem of recovery process is longer.
CN01100559.9 carries out hydro carbons recycling using traditional condensation method, after which uses precooling-deep cooling condensed in two stages, Condensation temperature reaches -70 DEG C, then, is discharged after activated carbon adsorption.This method can make discharge gas hydro carbons concentration up to standard.The party The shortcomings that method is that condensation energy consumption is big, acticarbon replacement frequency, and operating cost is high.
On the one hand waste gas pollution control and treatment will consider treatment cost, on the other hand to consider the problem up to standard of emission, existing side Although method has certain technique effect in some aspects, overall target need to further improve.Particularly contain in processing loss When having the exhaust gas of complex component, tend not to preferably be purified.
Utility model content
In view of the shortcomings of the prior art, the utility model aims to provide a kind of gas recovery system of economical and efficient.
In order to achieve the above object, the technical solution adopted in the utility model is:A kind of plasma waste gas pollution control and treatment system, system By the first spark arrester, first gas filter, dehumidifier, the second spark arrester, plasma reactor, the 3rd spark arrester, second Pneumatic filter, ozone decomposed tank, adsorption tanks, the 4th spark arrester pass sequentially through pipeline and are composed in series.
The plasma reactor is composed in parallel by multigroup low temperature plasma, and low-temperature plasma degradation is used for handling VOCs and H2S in organic exhaust gas;The adsorption tanks use the adsorption tanks of this area routine, and suitable absorption is set in adsorption tanks Agent, adsorbent can use sorbing material commonly used in the art, such as activated carbon, zeolite particle, can go out to give up in adsorption process Remaining VOCs components in gas.
Industrial waste gas enters low-temperature plasma generator, low temperature plasma hair after first passing around filtering, homogeneous, dehumidifying Raw device degrades pollutant, then is discharged into adsorption tanks after ozone decomposed tank removes the ozone produced, is most inhaled afterwards through adsorption tanks It is attached it is up to standard after be discharged into exhaust tube.
During work, industrial waste gas enters dehumidifier through the first spark arrester, first gas filter first, is controlled after dehumidifier Between gas humidity 40%~90% processed, gas enters plasma reactor, plasma reactor via the second spark arrester By the degradation of organic substances that discharges, subsequent gas enters ozone decomposed tank, subsequent gas via the 3rd spark arrester, second gas filter Body enters adsorption tanks, and last gas is discharged by the 4th spark arrester.
The exhaust gas can produce ozone in plasma reactor discharges degradation process, and ozone decomposed tank disappears ozone Remove, adsorption tanks further remove organic matter in industrial waste gas.
In the utility model plasma waste gas pollution control and treatment system, using plasma is by exhaust gas decomposition.Plasma chemistry In reaction process, electronics obtains energy from electric field first, is transferred energy into by exciting or ionizing in molecule or atom, obtains The molecule or atom of energy are excited, while have moieties to be ionized, so as to become active group, these active groups afterwards Stable product and heat are generated after mutually being collided between molecule or atom, active group and active group.In addition, high energy electron By the stronger materials capture of the electron affinities such as halogen and oxygen, become anion.This kind of anion has chemical living well Property, play an important role in chemical reaction.In the utility model plasma waste gas pollution control and treatment system, plasma discharging precursor reactant There are substantial amounts of electronics and living radical, dissociation atom, excited state molecule isoreactivity ion in device space, they have stronger Reactivity, some chemical reactions being difficult to realize with other means is carried out in plasma reactor.Medium hinders The electron energy that gear electric discharge produces be 2-20eV, and maximum Energy distribution probability VOCs molecule syntheses and divides between 2-12eV Required energy is solved in the region of free electron Energy distribution maximum probability.When energy possessed by electronics and VOCs points Sub internal a certain chemical bond energy is identical or bigger, and the collision of electronics and VOCs molecules will be inelastic collision, electronics by itself Energy wholly or largely passes to VOCs molecules, these energy are converted into the interior energy of VOCs, therefore contaminant molecule will occur Ionization, dissociation and excitation.The method can effectively destroy contaminant molecule, and after electronics destroys VOCs structures, VOCs is original Stability destroyed, the VOCs fragment molecules after ionizing or dissociating are easy to and positive plasma present in gas occurs Reaction, once, will go on quickly, until end-product formation.
The utility model plasma waste gas pollution control and treatment system, which is opened, stops, and VOCs exhaust gas concentrations is fluctuated adaptable. Stable it can realize that petrochemical enterprise organic exhaust gas floss hole benzene concentration is less than 4mg/Nm3, operating cost is low, the degree of automation Height, is realized unattended.A variety of VOCs pollutants such as benzene homologues, alkane, straight-chain hydrocarbons, alkene, phenol, ketone, base can effectively be removed This realization is degraded, and to the removal efficiency of hydrogen sulfide and ammonia up to more than 99%, non-secondary pollution.
Brief description of the drawings
Fig. 1 is a kind of structure diagram for plasma waste gas pollution control and treatment system that the utility model embodiment provides.
Reference numeral:
1st, exhaust gas 2-1, the first spark arrester 2-2, the second spark arrester 2-3, the 3rd spark arrester
2-4, the 4th spark arrester 3-1, first gas filter 3-2, second gas filter
4th, dehumidifier 5, plasma reactor 6, ozone decomposed tank 7, adsorption tanks
8th, gas up to standard
Embodiment
Technical solutions of the utility model are described in detail with specific embodiment below in conjunction with the accompanying drawings.
As shown in Figure 1, a kind of plasma waste gas pollution control and treatment system by the first spark arrester 2-1, first gas filter 3-1, Dehumidifier 4, the second spark arrester 2-2, plasma reactor 5, the 3rd spark arrester 2-3, second gas filter 3-2, ozone point Solution tank 6, adsorption tanks 7, the 4th spark arrester 2-4 pass sequentially through pipeline and are composed in series.
During work, industrial waste gas 1 enters dehumidifier 4 through the first spark arrester 2-1, first gas filter 3-1 first, through except Between controlling gas humidity 40%~90% after wet machine 4, gas enters plasma reactor 5 via the second spark arrester 2-2, etc. Plasma reactor 5 by the degradation of organic substances that discharges, subsequent gas via the 3rd spark arrester 2-3, second gas filter 3-2 into Enter ozone decomposed tank 6, subsequent gas enters adsorption tanks 7, and last gas is discharged by the 4th spark arrester 2-4.
The exhaust gas 1 can produce ozone in plasma reactor 5 discharges degradation process, and ozone decomposed tank 6 is by ozone Eliminate, adsorption tanks 7 further remove organic matter in industrial waste gas.

Claims (1)

1. a kind of plasma waste gas pollution control and treatment system, system is by the first spark arrester, first gas filter, dehumidifier, the second resistance Firearm, plasma reactor, the 3rd spark arrester, second gas filter, ozone decomposed tank, adsorption tanks, the 4th spark arrester according to It is secondary to be composed in series by pipeline;The plasma reactor is composed in parallel by multigroup low temperature plasma;In the adsorption tanks It is provided with adsorbent;The preferred activated carbon of the adsorbent, zeolite.
CN201721212339.3U 2017-09-20 2017-09-20 A kind of plasma waste gas pollution control and treatment system Active CN207254061U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201721212339.3U CN207254061U (en) 2017-09-20 2017-09-20 A kind of plasma waste gas pollution control and treatment system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201721212339.3U CN207254061U (en) 2017-09-20 2017-09-20 A kind of plasma waste gas pollution control and treatment system

Publications (1)

Publication Number Publication Date
CN207254061U true CN207254061U (en) 2018-04-20

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CN201721212339.3U Active CN207254061U (en) 2017-09-20 2017-09-20 A kind of plasma waste gas pollution control and treatment system

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CN (1) CN207254061U (en)

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Effective date of registration: 20180823

Address after: 100027 Chaoyangmen North Street, Chaoyang District, Chaoyang District, Beijing

Co-patentee after: Qingdao Safety Engineering Research Institute of Sinopec Co., Ltd.

Patentee after: Sinopec Corp.

Address before: 100096 five floor, 2 East Road, building materials City, Haidian District, Beijing.

Patentee before: Beijing Puhui Shihua Science and Technology Co., Ltd.