CN207250627U - A kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane - Google Patents

A kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane Download PDF

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Publication number
CN207250627U
CN207250627U CN201721043774.8U CN201721043774U CN207250627U CN 207250627 U CN207250627 U CN 207250627U CN 201721043774 U CN201721043774 U CN 201721043774U CN 207250627 U CN207250627 U CN 207250627U
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membrane
high molecular
ultra high
molecular polyethylene
layer
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陈博裕
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Jiujiang Lixin New Material Co Ltd
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Jiujiang Lixin New Material Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The utility model discloses a kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane, micropore is provided with ultra high molecular polyethylene membrane, ultra high molecular polyethylene membrane upper and lower surface is provided with polypropylene layer, polypropylene layer surface is provided with inorganic ceramic anticorrosive paint layer, the surface of inorganic ceramic anticorrosive paint layer is provided with water wetted material coating layer, the cracking resistance that the polypropylene coat that the utility model uses can effectively improve membrane improves its mechanical performance, inorganic ceramic anticorrosive paint layer can improve the corrosion-resistant of membrane, resistance to elevated temperatures, wear-resisting property, chemical stability and stability, water wetted material coating layer, improve the hydrophily of membrane surface.When this composite diaphragm works in the electrolytic corrosion environment of battery, the stability of good heat-resisting quantity can be kept, and due to increasing every film strength, so as to extend the service life of battery, improves battery performance.

Description

A kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane
Technical field
Technical field of lithium batteries is the utility model is related to, it particularly relates to which a kind of High Temperature Lithium Cell is gathered with supra polymer Ethene multilayer composite membrane.
Background technology
Polyethylene is that current production rate is maximum, one of most widely used plastics variety, accounts for world's plastics total output 30%, wherein, LDPE, HDPE and it is referred to as LLDPE of third generation polyethylene etc. and belongs to thermoplasticity general-purpose plastics, only There is the UHMWPE that molecular weight is up to more than 1,500,000, engineering plastics application is used as because physical and mechanical property is excellent.UHMWPE High molecular weight (molecular weight of HDPE usually only 2~300,000) assigns its excellent performance, and belongs to In moderate, function admirable thermoplastic engineering plastic, the advantages of it has almost concentrated various plastics, there is common polythene Wear-resisting, impact resistance unrivaled with other engineering plastics, self-lubricating, it is corrosion-resistant, absorb impact energy, it is low temperature resistant, health it is nontoxic, It is not easy to adhere to, the comprehensive performance such as not hygroscopic, density is smaller.In fact, there is presently no a kind of simple high molecular material is simultaneous There are so numerous excellent properties.Ultra-high molecular weight polyethylene has had been applied to numerous areas at present, but is not yet applied to lithium On battery diaphragm, in addition to hydrophily is bad, every characteristic of ultra-high molecular weight polyethylene is suitable for lithium battery diaphragm.Membrane Main function is to completely cut off the problems such as positive and negative anodes are to prevent battery self discharging and short-circuit the two poles of the earth, lithium-ion electric in battery material Pond diaphragm material can be divided into:It is several to weave film, nowoven membrane (non-woven fabrics), microporous barrier, composite membrane, diaphragm paper, laminate etc. Class, but due to being filled with the corrosion of electrolyte and the change of temperature in the working environment of battery, so in long-time service, on State that the stability in use of various lithium battery diaphragms is poor, be unfavorable for the use steady in a long-term of battery.
The problem of in correlation technique, not yet propose effective solution at present.
Utility model content
For the above-mentioned technical problem in correlation technique, the utility model proposes a kind of High Temperature Lithium Cell supra polymer to gather Ethene multilayer composite membrane, aluminium oxide and inorganic ceramic anticorrosive paint are evenly applied on membrane, and control coating thickness In favor of the application of heavy-duty battery, high-performance lithium battery high temperature resistant ultra high molecular polyethylene composite diaphragm is made.
To realize above-mentioned technical purpose, what the technical solution of the utility model was realized in:
High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane, including ultra high molecular polyethylene membrane are described super Micropore is provided with high molecular polythene membrane, the ultra high molecular polyethylene membrane upper and lower surface is provided with polypropylene layer, institute State polypropylene layer surface and be provided with inorganic ceramic anticorrosive paint layer, the surface of the inorganic ceramic anticorrosive paint layer is provided with hydrophilic Material coating layer.
Further, the micropore size uses 0.026-0.038 μm.
Further, the polyethylene diagrams thickness uses 12-38 μm.
The beneficial effects of the utility model:The polypropylene coat that the utility model uses can effectively improve the cracking resistance of membrane Performance improves its mechanical performance, inorganic ceramic anticorrosive paint layer can improve the corrosion-resistant of membrane, resistance to elevated temperatures, wear-resisting property, Chemical stability and stability, water wetted material coating layer, improves the hydrophily of membrane surface.Electricity of this composite diaphragm in battery When working in solution corrosion environment, the stability of good heat-resisting quantity can be kept, and due to increasing every film strength, from And the service life of battery is extended, improve battery performance.
Brief description of the drawings
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Needed in attached drawing be briefly described, it should be apparent that, drawings in the following description are only the utility model Some embodiments, for those of ordinary skill in the art, without creative efforts, can also be according to this A little attached drawings obtain other attached drawings.
Fig. 1 is the High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane according to the utility model embodiment Cross section structure schematic diagram.
In figure:1. ultra high molecular polyethylene membrane;2. polypropylene layer;3. inorganic ceramic anticorrosive paint layer;4. water wetted material Coating layer;5. micropore.
Embodiment
The following is a combination of the drawings in the embodiments of the present utility model, and the technical scheme in the embodiment of the utility model is carried out Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole Embodiment.Based on the embodiment in the utility model, those of ordinary skill in the art's all other embodiments obtained, all belong to In the scope of the utility model protection.
As shown in Figure 1, the High Temperature Lithium Cell according to the utility model embodiment is answered with ultra high molecular polyethylene multilayer Membrane, including ultra high molecular polyethylene membrane 1 are closed, micropore 5, the supra polymer are provided with ultra high molecular polyethylene membrane 1 1 upper and lower surface of polyethylene diagrams is provided with polypropylene layer 2, and 2 surface of polypropylene layer is provided with inorganic ceramic anticorrosive paint layer 3, the surface of the inorganic ceramic anticorrosive paint layer 3 is provided with water wetted material coating layer 4.
The micropore size uses 0.026-0.038 μm.
The polyethylene diagrams thickness uses 12-38 μm.
When specifically used, according to High Temperature Lithium Cell described in the utility model with ultra high molecular polyethylene MULTILAYER COMPOSITE every Film, is provided with some micropores 5 on ultra high molecular polyethylene membrane 1, and 1 upper and lower surface of ultra high molecular polyethylene membrane is set respectively There is polypropylene layer 2, be the first polypropylene layer and the second polypropylene layer respectively, two 2 surfaces of polypropylene layer are respectively arranged with inorganic Ceramic anticorrosive paint layer 3, is the first inorganic ceramic anticorrosive paint layer and the second inorganic ceramic anticorrosive paint layer respectively, first poly- third The outer surface of alkene layer is provided with the first inorganic ceramic anticorrosive paint layer, and the outer surface of the second polypropylene layer is provided with the second inorganic pottery Porcelain anticorrosive paint layer, the surface of two inorganic ceramic anticorrosive paint layers 3 are respectively arranged with water wetted material coating layer 4;Polypropylene layer 2 The cracking resistance that membrane can be effectively improved improves its mechanical performance, inorganic ceramic anticorrosive paint layer 3, and powder ceramics are added in coating The ceramic components such as oxide, ceramic hollow microballon, improve coating heatproof, wear-resisting, crosslinking and thermal insulation, and ceramic component and altogether Poly- lotion produces chemistry and the cohesive force and adhesive force of mechanical bond, improves tensile strength and adhesion strength, inorganic ceramic without Machine coating forms the tough and tensile durable elastic film inorganic layer of high intensity coated in 2 surface of polypropylene layer, is a kind of after curing of coatings The flexibility of existing high molecular material, but the heat safe inorganic coating of organic and/or inorganic materials durability, water wetted material coating layer 4 improve The hydrophily of membrane surface.
In conclusion by means of the above-mentioned technical proposal of the utility model, by using polypropylene coat can be effective The cracking resistance for improving membrane improves its mechanical performance, and inorganic ceramic anticorrosive paint layer can improve corrosion-resistant, the high temperature resistant of membrane Performance, wear-resisting property, chemical stability and stability, water wetted material coating layer, improves the hydrophily of membrane surface.This is compound When membrane works in the electrolytic corrosion environment of battery, the stability of good heat-resisting quantity can be kept, and due to every Film strength increase, so as to extend the service life of battery, improves battery performance.
The above is only the preferred embodiment of the utility model only, is not intended to limit the utility model, all at this Within the spirit and principle of utility model, any modification, equivalent replacement, improvement and so on, should be included in the utility model Protection domain within.

Claims (3)

1. High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane, it is characterised in that including ultra high molecular polyethylene every Film(1), the ultra high molecular polyethylene membrane(1)On be provided with micropore(5), the ultra high molecular polyethylene membrane(1)Up and down Surface is provided with polypropylene layer(2), the polypropylene layer(2)Surface is provided with inorganic ceramic anticorrosive paint layer(3), it is described inorganic Ceramic anticorrosive paint layer(3)Surface be provided with water wetted material coating layer(4).
A kind of 2. High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane according to claim 1, it is characterised in that The micropore size uses 0.026-0.038 μm.
A kind of 3. High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane according to claim 1, it is characterised in that The polyethylene diagrams thickness uses 12-38 μm.
CN201721043774.8U 2017-08-21 2017-08-21 A kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane Active CN207250627U (en)

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CN201721043774.8U CN207250627U (en) 2017-08-21 2017-08-21 A kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane

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Application Number Priority Date Filing Date Title
CN201721043774.8U CN207250627U (en) 2017-08-21 2017-08-21 A kind of High Temperature Lithium Cell ultra high molecular polyethylene multilayer composite membrane

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CN207250627U true CN207250627U (en) 2018-04-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112467308A (en) * 2020-10-27 2021-03-09 惠州锂威新能源科技有限公司 Diaphragm, preparation method thereof and lithium ion battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112467308A (en) * 2020-10-27 2021-03-09 惠州锂威新能源科技有限公司 Diaphragm, preparation method thereof and lithium ion battery
CN112467308B (en) * 2020-10-27 2023-09-05 惠州锂威新能源科技有限公司 Diaphragm, preparation method thereof and lithium ion battery

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Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: Ultra-high molecular-weight polyethylene multi-layer composite diaphragm for high-temperature lithium-ion batteries

Effective date of registration: 20190620

Granted publication date: 20180417

Pledgee: Bank of Communications Limited Jiujiang Branch

Pledgor: Jiujiang Lixin New Material Co., Ltd.

Registration number: 2019990000590