CN207248851U - A kind of dystopy multichannel Mercury in Soil flux rapid measurement device - Google Patents

A kind of dystopy multichannel Mercury in Soil flux rapid measurement device Download PDF

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Publication number
CN207248851U
CN207248851U CN201721302416.4U CN201721302416U CN207248851U CN 207248851 U CN207248851 U CN 207248851U CN 201721302416 U CN201721302416 U CN 201721302416U CN 207248851 U CN207248851 U CN 207248851U
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China
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mercury
soil
flux
channel
measurement device
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Expired - Fee Related
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CN201721302416.4U
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Chinese (zh)
Inventor
张华�
朱宗强
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Institute of Geochemistry of CAS
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Institute of Geochemistry of CAS
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Abstract

The utility model discloses a kind of dystopy multichannel Mercury in Soil flux rapid measurement device, including mercury vapour analyzer and multi-channel sampling device, the channel outlet of multi-channel sampling device is connected by the port input of out sample tube and mercury vapour analyzer, the channel entrance of the multi-channel sampling device is connected by sample feeding pipe with the high borosilicate flux bottle top for holding soil to be measured, high borosilicate flux bottle lower part is provided with air inlet, aspiration pump is provided with sample feeding pipe;Compared with prior art, the utility model successively can measure multigroup Mercury in Soil flux, it is possible to increase the measurement efficiency of Mercury in Soil;In addition, this measurement method can exclude influence of the external environment to measurement result, there is measurement result is accurate, needs sample amount few etc., easy to the analysis contrast to multigroup measurement result at the same time.

Description

A kind of dystopy multichannel Mercury in Soil flux rapid measurement device
Technical field
A kind of dystopy multichannel Mercury in Soil flux rapid measurement device is the utility model is related to, belongs to the measurement skill of Mercury in Soil Art field.
Background technology
Soil is the basis of agricultural production, however as the fast development of China's economy, the pollutant containing heavy metal, especially It is that mercury metal enters soil by all means, has gradually formed heavy metal pollution of soil, heavy metal pollution of soil is polluted because of it Concealment, chronicity and irreversibility and by World Focusing, its not only degenerated soil fertility, reduce crop product and product Matter, and pollution of agricultural products and water resource pollution can be triggered, and the life and health of the mankind is endangered by food chain.
Reparation for Soil Mercury Pollution has become the hot spot in current environment scientific and engineering field, dirty to Mercury in Soil Before dye is administered, measurement soil mercury content is generally required, but existing measurement method mainly measures at the scene, or by soil Independent measurement after earth collection, measurement error big the problems such as low there are measurement efficiency.
Mercury is one of most strong heavy metal contamination thing of bio-toxicity, and it is big that its murder by poisoning to human body is mainly manifested in damage Brain.In past more than 100 years, air mercury content adds 3 times.Soil, deposit, lake and the river of global large area, by Produce in the unreasonable mode of the mankind, use and store mercury and be subject to serious mercury pollution.China is that the discharge of global mercury is big State, while be also one of mercury pollution country the most serious.The research of mining soil mercury flux monitoring, to mercury contaminated soil reparation Research and development and the soil pollution integrated control of mercury ore area of technology etc. have great importance.
Due to long-term exploitation and smelting, mercury content is up to 29.6-793mg/kg in Guizhou wanshan mercury area agricultural land soil, Decades of times beyond national Soil standard is to thousands of times.According to incompletely statistics, the area of Guizhou Mercury Mine's area's mercury contaminated soil has surpassed Cross 69000 hectares.Mercury content is 120-1150ug/kg in mercury ore area crops, and 115 are up to beyond national food hygienic standard Times.Correlative study shows that the mercury in vegetables is mainly derived from air.Existing mercury ore exploitation and smelting have stopped, and high Mercury In The Air contains Amount is volatilized essentially from serious mercury contaminated soil.Previously there is scholar to study the flux for finding that mercury mining soil discharges mercury into air Average value ranges are 162-8385ng/ (m2H), it is higher by 1-3 order of magnitude of background area.It can be seen that this area suffers from serious air Mercury pollution.Therefore, while being administered to Soil Mercury Pollution, mercury should be avoided to be volatized into air from soil, causes two Secondary pollution.At this time, it may be necessary to observe the volatilization flux of Mercury in Soil.But existing measurement method mainly field survey at the scene, and This measurement method needs to transport complicated instrument and its supporting equipment;Environmental condition at the same time(Wind speed, temperature and illumination etc.) Real-time change, easily influences Mercury in Soil volatilization, and multigroup Mercury in Soil flux can not be measured at the same time.
In summary:A kind of efficient, quick, accurate and multichannel Mercury in Soil flux measuring device is established, it is dirty to following mercury The research and development and the soil pollution integrated control of mercury ore area of dye soil restoring technology, which all have, to be of great significance.
Utility model content
The technical problems to be solved in the utility model is:A kind of dystopy multichannel Mercury in Soil flux is provided and quickly measures dress Put, have simple in structure, easy to operate, measurement efficiency is high, the advantages that sample amount is few, result is accurate is needed, to overcome the prior art Deficiency.
The technical solution of the utility model:A kind of dystopy multichannel Mercury in Soil flux rapid measurement device, including mercury vapour Analyzer and multi-channel sampling device, the channel outlet of multi-channel sampling device pass through out sample tube and the port input of mercury vapour analyzer Connection, the channel entrance of the multi-channel sampling device pass through sample feeding pipe and the high borosilicate flux bottle top for holding soil to be measured Connection, in sample feeding pipe(Sample introduction pipe end)On be provided with aspiration pump.
Flowmeter is provided with the sample feeding pipe.
The flowmeter is arranged between aspiration pump and high borosilicate flux bottle.
The multiple sample feeding pipes being wherein arranged side by side are connected by Teflon threeway with aspiration pump, can so pass through same pumping Air pump realizes the pumping of multiple sample feeding pipes, and realization measures at the same time.
The internal diameter 15cm, height 20cm of the high borosilicate flux bottle;Away from bottom 3cm be inserted into respectively two it is symmetrical a length of 2cm, internal diameter is 0.5cm tubules, as air inlet;The lid of flux bottle is frosted mouth, and cap top inserts a tubule and is used as Gas port.
The beneficial effects of the utility model are:Compared with prior art, the utility model can be successively(At the same time)To multigroup soil Earth mercury flux is quickly measured, it is possible to increase the measurement efficiency of Mercury in Soil.In addition, this measurement method can exclude external ring Influence of the border to measurement result, has the characteristics that measurement result is accurate, needs sample amount few etc., easy at the same time to multigroup measurement result Analysis contrast.
Brief description of the drawings
Fig. 1 is the structure diagram of the utility model;
In attached drawing:1st, mercury vapour analyzer, 2, multi-channel sampling device, 3, Teflon threeway, 4, spinner flowmeter, 5, sample introduction Pipe, 6, gas outlet, 7, high borosilicate flux bottle, 8, air inlet, 9, aspiration pump.
Embodiment
It is new to this practicality below in conjunction with attached drawing to make the purpose of this utility model, technical solution and advantage clearer Type is described in further detail.
With reference to figure 1, a kind of dystopy multichannel Mercury in Soil flux rapid measurement device of the utility model, including mercury vapour analysis Instrument 1, multi-channel sampling device 2, Teflon threeway 3, out sample tube, sample feeding pipe 5, high borosilicate flux bottle 7, aspiration pump 9 and flowmeter, High 7 lower part of borosilicate flux bottle is equipped with(Symmetrical two)Air inlet 8, passes through sample introduction equipped with gas outlet 6, gas outlet 6 at an upper portion thereof Channel entrance of the pipe 5 successively with flowmeter, aspiration pump 9 and multi-channel sampling device 2 is connected, the channel outlet of multi-channel sampling device 2 Connected by the port input of out sample tube and mercury vapour analyzer.
The internal diameter 15cm, height 20cm of the high borosilicate flux bottle 7;It is inserted into respectively away from bottom 3cm two symmetrical long For 2cm, internal diameter is 0.5cm tubules, as air inlet 8;The lid of flux bottle is frosted mouth(With anti-gas-leak), cap top inserts one Root tubule is as gas outlet 6.
The mercury vapour analyzer 1 produces for Tekran companies of Canada, model:2537X.
The multi-channel sampling device 2 produces for Tekran companies, model:1110.
The sample feeding pipe 5 is Teflon material, and internal diameter size is 1/4 inch.
The operation principle of the utility model is:The soil to be measured of collection is contained in high borosilicate flux bottle, opens pumping The mercury flux that the passage inlet and outlet of pump 9, mercury vapour analyzer 1 and corresponding multi-channel sampling device 2 can be achieved to treat survey soil is surveyed Amount.When needing to measure contrast to a variety of soil, each air flow rate can be made identical, you can successively by adjusting flowmeter Mercury flux measurement is carried out to soil to be measured.
When the utility model is used:By 50 grams of the different mercury contaminated soils of collection(On a small quantity)It is contained in high borosilicate flux bottle 7 Interior, frosted lid is tightened in rotation, to prevent its gas leakage.Each several part gas circuit is connected with sample feeding pipe 5 according to shown in Fig. 1, and will Each flowmeter is disposed as the flow velocity of 1 L/min(It is consistent with mercury analyzer flow velocity).At this time, aspiration pump 9, mercury vapour point are opened The channel inlet mouth 8 of analyzer 1 and corresponding multi-channel sampling device 2 is that can be achieved to treat to survey the multigroup of Mercury in Soil flux while measure.
Tested through inventor:Using this multichannel measuring apparatus, the flux of four groups of wanshan mercury area Mercury in Soil is determined(Soil Earth mercury content is respectively 12.0,16.8,26.9,40.9 mg/kg)Respectively 42.5,65.3,104.1,180.5 ng/ (m2· h);Its collimation relative standard deviation is respectively smaller than 2.05%, 1.58%, 1.02%, 1.27%(n=20).
Above content is that a further detailed description of the present invention in conjunction with specific preferred embodiments, it is impossible to is assert The specific implementation of the present invention is confined to these explanations.For general technical staff of the technical field of the invention, On the premise of not departing from present inventive concept, some simple deduction or replace can also be made, should all be considered as belonging to the present invention's Protection domain.

Claims (5)

1. a kind of dystopy multichannel Mercury in Soil flux rapid measurement device, including mercury vapour analyzer(1)With multi-channel sampling device (2), multi-channel sampling device(2)Channel outlet connected by the port input of out sample tube and mercury vapour analyzer, its feature exists In:The multi-channel sampling device(2)Channel entrance pass through sample feeding pipe(5)With the high borosilicate flux bottle for holding soil to be measured (7)Top connects, in high borosilicate flux bottle(7)Lower part is provided with air inlet(8), in sample feeding pipe(5)On be provided with aspiration pump (9).
2. multichannel Mercury in Soil flux rapid measurement device according to claim 1, it is characterised in that:In the sample feeding pipe (5)On be provided with spinner flowmeter(4).
3. multichannel Mercury in Soil flux rapid measurement device according to claim 2, it is characterised in that:The flowmeter is set Put in aspiration pump(9)With high borosilicate flux bottle(7)Between.
4. multichannel Mercury in Soil flux rapid measurement device according to claim 1, it is characterised in that:Wherein it is arranged side by side Sample feeding pipe(5)Pass through Teflon threeway(3)With aspiration pump(9)Connection.
5. multichannel Mercury in Soil flux rapid measurement device according to claim 1, it is characterised in that:The high borosilicate Flux bottle(7)Internal diameter 15cm, height 20cm;Two symmetrical a length of 2cm are inserted into respectively away from bottom 3cm, and internal diameter is small for 0.5cm Pipe, as air inlet(8);The lid of flux bottle is frosted mouth, and cap top inserts a tubule as gas outlet(6).
CN201721302416.4U 2017-09-30 2017-09-30 A kind of dystopy multichannel Mercury in Soil flux rapid measurement device Expired - Fee Related CN207248851U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201721302416.4U CN207248851U (en) 2017-09-30 2017-09-30 A kind of dystopy multichannel Mercury in Soil flux rapid measurement device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201721302416.4U CN207248851U (en) 2017-09-30 2017-09-30 A kind of dystopy multichannel Mercury in Soil flux rapid measurement device

Publications (1)

Publication Number Publication Date
CN207248851U true CN207248851U (en) 2018-04-17

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CN201721302416.4U Expired - Fee Related CN207248851U (en) 2017-09-30 2017-09-30 A kind of dystopy multichannel Mercury in Soil flux rapid measurement device

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180417

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