Flyash desulfurizer
Technical field
It the utility model is related to a kind of flue gas desulfurization device, and in particular to the flyash in a kind of pulverized-coal fired boiler corollary equipment
Desulfurizer.
Background technology
At present, greenhouse effects, air quality acute exacerbation, water pollution and extensive acid deposition contamination phenomenon are increasingly apparent.
Carry out global climate and environmental protection, it is the dedusting of smoke gas treatment, desulfurization integrated, evil, comprehensive utilization, comprehensive exploitation are controlled with useless,
It is one of major measure, and reduces the most effective approach of scrubbing CO_2 cost.It has been investigated that the raw coal warp of thermal power plant
The flyash discharged after boiler combustion originally belongs to solid waste, useless, is harmful to, and amount is big, and more, and its acid-base value is typically in 8.5-
13 or so.And flyash is a kind of porous mass and specific surface area is larger, itself contains about 16-20% calcium oxide component and one
A little uncombusted charcoals, so flyash has certain active group, to SO2There is certain adsorption capacity.Secondly, in flyash
The alkaline matter such as calcium oxide be dissolved in water after, its solution alkaline, SO soluble in water can be absorbed2.Utilize flyash generation
Alkaline slurry carries out desulfurization, and one kind effectively in calcium-based desulfurizing agent.If its alkalescence is applied into desulfurization, according to medium inclined
Lower principle calculates the sweetening substance in pulverized fuel ash slurry, is in the case of coal-fired sulfur content 3% more than 4 times, it is seen that be enough to be used in taking off
Sulphur.
For the traditional such as electrostatic precipitation in domestic and international coal-burning power plant -- desulfurization of gypsum dedusting, sulfur removal technology, its flow are deposited
It is cumbersome, complicated, involve great expense, operating cost is high, treatment effeciency is low, there are the various problems such as secondary pollution,
This is also one of balky basic reason of smoke gas treatment.It is dust so reducing dedusting, the cost and operating cost of desulfurization
With sulphur, nitrogen, oxycarbide pollution control basic place.According to the constituent, physical property and chemical property of flyash, lead to
After wet method is crossed to its modification, its hiding activity internally can be excited, improves desulfurization degree.Choosing is prepared using flyash
The SO that selecting property is good, adsorption capacity is big, adsorption efficiency is high2Adsorbent, removing coal combustion exhaust SO2, evil, and desulfurization technology are controlled with useless
Development trend.
Utility model content
The utility model can not be accomplished to reduce the cost of desulfurization and the deficiency of operating cost for existing desulfurizer, there is provided
A kind of energy-efficient, safety and environmental protection flyash desulfurizer.The technical problems to be solved in the utility model passes through following technology
Scheme is realized.
A kind of flyash desulfurizer, including the conveying of cigarette wind devices, slurries Preparation equipment, slurries and recycle unit, desulfurization
Equipment and control device;
Described cigarette wind devices include flue, fresh-air duct road, compensator, flue by-passing valve and flue gas motorized adjustment
Valve, flue by-passing valve is closed during work, and sulfur-bearing caused by the boiler combustion after sack cleaner dedusting gives up
The gas approach that flue gas is tilted down through flue by air-introduced machine by desulfurizing tower enters in desulfurizing tower, by net gas after desulfurization
Pipeline enters in chimney, subsequent discharges into air;
Described slurries Preparation equipment includes electric cinder valve, pulping tank and stirring motor, the fine coal being stored in ash silo
Ash is delivered in pulping tank by electric cinder valve, carries out plus water mixes;
Described slurries conveying and recycle unit include pump for mortar transmission, circulating pump, Pulp pump, vacuum filter and matched
Valve and flowmeter;
Described desulphurization plant includes desulfurizing tower, circulating tank, loop slurry spray piping and demister;Described desulfurizing tower
Including housing, bottom plate, inlet and outlet flue, external reinforcement rib and internal unit supporting construction;Described circulating tank includes tank body and stirred
Mix motor;Totally four layers of described loop slurry spray piping, is divided into two groups;Described demister includes two layers demister piece, four
Layer demister backwashing water pipeline;
Described control device include be located at each pipeline in multiple sensors, multiple PLCs, data/address bus, on
Position machine, control cabinet and PLC rack, each sensor control the data information transfer collected to host computer, PC control PLC
Device, PLC control the open and close of each pump, valve;
By compressed air by the ash transfer in boiler tail storehouse pump and sack cleaner to ash silo, by under ash silo
The flyash in portion, which is collected into pulping tank, is made pulverized fuel ash slurry, and pulverized fuel ash slurry is delivered to following for desulfurization tower bottom by pump for mortar transmission
Stored in ring tank, circulating pump pulverized fuel ash slurry is delivered in the loop slurry spray piping in the middle part of desulfurizing tower and from nozzle with
Under the spray of water smoke form;Meanwhile flue by-passing valve is closed, the sulfur-bearing flue gas after sack cleaner dedusting is by drawing
The gas approach that blower fan flows through the flue where flue gas electric control valve and tilted down from desulfurization tower bottom pours in desulfurization
In tower, column plate guiding in the presence of rotation rise and with mist-like pulverized fuel ash slurry counter current contacting, so as to absorb in flue gas
Sulfide;Flue gas after absorption is entered in demister and drawn after progress dewater treatment by desulfurizing tower top, after chimney
It is discharged into air;Desulfurization product is discharged and is delivered in vacuum filter by Pulp pump with pulverized fuel ash slurry, then by automatic loading and unloading
Car transports filtrate;Slurries after vacuum filter filters are flowed into sedimentation basin, and slurrying is delivered to by reflux pump after precipitation
In tank and circulating tank.
Further, described desulfurizing tower is using ordinary carbon steel and glass inner-lining scale paint, outside acid washing phosphorization and two bottoms
The mode of two finish paints is made, and its pipeline is laid according to the 0.002-0.003 gradient, and external heating and insulation construction.In this way,
On the premise of increasing the service life, it can be achieved to reduce cost, solve the problems, such as preventing freeze in winter, take into account attractive in appearance and practicality.
Further, described pump for mortar transmission, circulating pump and Pulp pump use wear resistant corrosion resistant pump, when it selects pony pump
When, its shaft seal uses K-type dynamic seal, and when it selects mammoth pump, its shaft seal is using the sealing or double of Z-type self-balancing
End face integrated mechanical sealing.
Further, two are set into the flue of desulfurizing tower, one is provided with regulating valve, another small work(of conduct
Flue when rate is run is not provided with regulating valve;Described slurries conveying is corresponding with recycle unit, loop slurry spray piping
Set two sets.In this way, individually but also can not only co-operate, and switching undisturbed can be realized, greatly improve operating efficiency.
Further, the tank body of the pulping tank is made using the stainless steel of wear resistant corrosion resistant, and portion in the inner
It is provided with pH monitors and tank gage.
Further, described nozzle is made of the carborundum of wear resistant corrosion resistant, and each layer nozzle top-bottom cross staggers
Arranged.So so that each spray region has identical spray flux density, so as to which fully reaction occur with flue gas
Further, described demister upper and lower ends are respectively provided with backwashing water pipeline, and backwashing water pipeline is through recoil
Wash pump with water tank to be connected, water tank access tap water pipe network.
Further, described fresh-air duct road afterbody carries out preservative treatment, and sets water fender in its minimum point and put
The mouth of a river.So as to prevent the flue-gas temperature of fresh-air duct road afterbody too low and caused by boiler flue corrosion.
Further, in addition to lime tank, described lime tank are connected through pipeline and valve with pulping tank.
Pulverized fuel ash slurry contacts in desulfurizing tower with sulfur-containing smoke gas occurs absorbing reaction, and the afwillite of generation can promote
Gas, solid diffusion and increase specific surface area, also with high water retention property, keep desulfurizing agent surface wettability in mortar, strengthen between gas-liquid
The sour gas such as reaction, sulfur dioxide, sulfur trioxide in flue gas just absorbed in the process.
Compared with prior art, the unique structure of flyash desulfurizer is novel, and complete equipment is easily installed, Load Regulation
Scope is wide, and fault rate is low, and is easy to safeguard, service life length;Abundant, efficient exhaust gas dust absorption can be handled,
And the waste product flyash discharged in industrial processes can be changed into absorbent and be made full use of, safety and environmental protection, energy-saving and emission-reduction.
By supporting programme-control, whole system can realize stabilization, accurate automatic operating, substantially increase operating efficiency,
And reduce artificial input.The utility model can control evil, comprehensive utilization, comprehensive exploitation with useless, substantially reduce cost and running cost
With treatment effeciency is high, and simple to operate, non-secondary pollution reaches the requirement of energy-conserving and environment-protective, and can be widely used in smoke gas treatment neck
Domain.
Brief description of the drawings
Fig. 1 is overall structure diagram of the present utility model;
Fig. 2 is the structural representation of desulfurizing tower of the present utility model;
Reference in accompanying drawing is followed successively by:1st, boiler, 2, storehouse pump, 3, sack cleaner, 4, ash silo, 5, lime tank, 6,
Pulping tank, 7, pump for mortar transmission, 8, circulating tank, 9, circulating pump, 10, desulfurizing tower, 11, air-introduced machine, 12, flue by-passing valve, 13, flue gas electricity
Dynamic regulating valve, 14, Pulp pump, 15, vacuum filter, 16, lift truck, 17, sedimentation basin, 18, reflux pump, 19, running water
Pipe network, 20, water tank, 21, anti-cleaning pump.
Embodiment
Design feature of the present utility model is expanded on further with specific embodiment below in conjunction with the accompanying drawings.
Embodiment 1:
Reference picture 1,2, a kind of flyash desulfurizer, including the conveying of cigarette wind devices, slurries Preparation equipment, slurries and circulation
Equipment, desulphurization plant and control device;
Described cigarette wind devices include flue, fresh-air duct road, compensator, flue by-passing valve 12 and flue gas motorized adjustment
Valve 13, flue by-passing valve 12 is closed during work, caused by the boiler 1 after the dedusting of sack cleaner 3 burns
The gas approach that sulfur-bearing flue gas is tilted down through flue by air-introduced machine 11 by desulfurizing tower 10 enters in desulfurizing tower 10, warp
Entered after desulfurization by fresh-air duct road in chimney, subsequent discharged into air;
Described slurries Preparation equipment includes electric cinder valve, pulping tank 6 and stirring motor, the powder being stored in ash silo 4
Coal ash is delivered in pulping tank 6 by electric cinder valve, carries out plus water mixes;
Described slurries conveying and recycle unit include pump for mortar transmission 7, circulating pump 9, Pulp pump 14, vacuum filter 15 and
The valve and flowmeter to match;
Described desulphurization plant includes desulfurizing tower 10, circulating tank 8, loop slurry spray piping and demister;Described is de-
Sulphur tower 10 includes housing, bottom plate, inlet and outlet flue, external reinforcement rib and internal unit supporting construction;Described circulating tank 8 includes tank
Body and stirring motor;Totally four layers of described loop slurry spray piping, is divided into two groups;Described demister includes two layers of demister
Piece, four layers of demister backwashing water pipeline;
Described control device include be located at each pipeline in multiple sensors, multiple PLCs, data/address bus, on
Position machine, control cabinet and PLC rack, each sensor control the data information transfer collected to host computer, PC control PLC
Device, PLC control the open and close of each pump, valve;
By compressed air by ash transfer to the ash silo 4 in the afterbody storehouse pump 2 of boiler 1 and sack cleaner 3, by ash
The flyash of the bottom of storehouse 4, which is collected into pulping tank 6, is made pulverized fuel ash slurry, and pulverized fuel ash slurry is delivered to desulfurizing tower by pump for mortar transmission 7
Stored in the circulating tank 8 of 10 bottoms, pulverized fuel ash slurry is delivered to the loop slurry spray piping at the middle part of desulfurizing tower 10 by circulating pump 9
It is interior and from nozzle in the form of water smoke spray under;Meanwhile flue by-passing valve 12 is closed, after the dedusting of sack cleaner 3
Sulfur-bearing flue gas flowed through by air-introduced machine 11 flue where flue gas electric control valve 13 and from the bottom of desulfurizing tower 10 to
Under inclined gas approach pour in desulfurizing tower 10, column plate guiding in the presence of rotation rise and with mist-like pulverized fuel ash slurry
Counter current contacting, so as to absorb the sulfide in flue gas;Flue gas after absorption is entered in demister after progress dewater treatment
Drawn by the top of desulfurizing tower 10, be discharged into after chimney in air;Desulfurization product is discharged and defeated with pulverized fuel ash slurry by Pulp pump 14
Deliver in vacuum filter 15, then transported filtrate by lift truck 16;Slurry stream after the filtering of vacuum filter 15
Enter in sedimentation basin 17, be delivered to after precipitation by reflux pump 18 in pulping tank 6 and circulating tank 8.
Embodiment 2:
On the basis of embodiment 1, described desulfurizing tower 10 uses ordinary carbon steel and glass inner-lining scale paint, outside pickling
Phosphatization and the mode of the finish paint of two bottom two are made, and its pipeline is laid according to the 0.002-0.003 gradient, and external heating and insulation knot
Structure.
Embodiment 3:
On the basis of embodiment 2, described pump for mortar transmission 7, circulating pump 9 and Pulp pump 14 use wear resistant corrosion resistant pump,
When it selects pony pump, its shaft seal uses K-type dynamic seal, and when it selects mammoth pump, its shaft seal uses Z-type
Self-balancing seals or Double End integrated mechanical sealing.
Embodiment 4:
On the basis of embodiment 3, the flue into desulfurizing tower 10 sets two, and one is provided with regulating valve, separately
One flue when being run as small-power is not provided with regulating valve;Described slurries conveying and recycle unit, loop slurry
Two sets of spray piping relative set.
Embodiment 5:
On the basis of embodiment 4, the tank body of the pulping tank 6 is made using the stainless steel of wear resistant corrosion resistant, and
Portion is provided with pH monitors and tank gage in the inner.
Embodiment 6:
On the basis of embodiment 5, described nozzle is made of the carborundum of wear resistant corrosion resistant, and each layer nozzle is handed over up and down
Pitch staggered arrangement;Described demister upper and lower ends are respectively provided with backwashing water pipeline, and backwashing water pipeline is through backwashing pump
21 are connected with water tank 20, and water tank 20 accesses tap water pipe network 19;Described fresh-air duct road afterbody carries out preservative treatment, and in it most
Low spot sets water fender and dewatering outlet;Also include lime tank 5, described lime tank 5 is connected through pipeline and valve with pulping tank 6
Connect.
The chemical reaction mechanism of the utility model flyash desulfurization is:
Ca(OH)2+SiO2+H2O→(CaO)x(SiO2)y(H2O)z (1)
Ca(OH)2+Al2O3+H2O→(CaO)x(Al2O3)y(H2O)z (2)
Ca(OH)2+SiO2+Al2O3+H2O→
(CaO)x(Al2O3)y(SiO2)z(H2O)w (3)
Ca(OH)2+Al2O3+SO2+H2O→
(CaO)x(Al2O3)y(CaSO3)z(H2O)w (4)
The afwillite of generation can promote gas, solid diffusion and increase specific surface area, also with high water retention property, keep slurry
Desulfurizing agent surface wettability in liquid, strengthen the reaction between gas-liquid, be finally reached qualified fume emission index:Sulfur dioxide SO2≤
20mg/Nm3, soot dust granule thing≤10mg/Nm3。
Embodiment described above only expresses a kind of embodiment of the present utility model, but can not therefore be interpreted as
Limitation to the scope of the utility model.It should be pointed out that for the person of ordinary skill of the art, it is new not departing from this practicality
On the premise of type is conceived, various modifications and improvements can be made.These belong to the scope of protection of the utility model.