CN206970213U - A kind of argon gas EGR in monocrystalline silicon production - Google Patents

A kind of argon gas EGR in monocrystalline silicon production Download PDF

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Publication number
CN206970213U
CN206970213U CN201720927760.6U CN201720927760U CN206970213U CN 206970213 U CN206970213 U CN 206970213U CN 201720927760 U CN201720927760 U CN 201720927760U CN 206970213 U CN206970213 U CN 206970213U
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pipeline
argon gas
valve
pass
single crystal
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崔永祥
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Kaide Electronic Engineering Design Co.,Ltd.
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China Construction Kide Engineering Corp
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Abstract

The utility model discloses the argon gas EGR in a kind of monocrystalline silicon production, including argon gas storage tank, vaporizer, single crystal growing furnace, vavuum pump, solidfied material processor, cupric oxide reactor, limewash reaction unit, drier and rectifying device;Enter solidfied material processor using vacuum pumped from the high-concentration waste argon gas that single crystal growing furnace ejects and carry out electrostatic precipitation, the solidfied materials such as oil therein, silicon class are filtered out by Electrostatic Absorption;The useless argon gas of early stage 5% drains into air after filtering, later stage 95% give up argon gas by scorching hot cupric oxide reactor make the hydrocarbons such as carbon monoxide, hydrogen, methane high temperature action issue it is biochemical reaction generation carbon dioxide, water, copper, enter back into that the device equipped with limewash is cooled down and chemical reaction removes carbon dioxide therein, moisture is got rid of by drying device, argon gas and nitrogen are fractionated into rectifier unit, the pure argon being fractionated, which is entered back into single crystal growing furnace, to be recycled;Realization rationally utilizes resource, does not pollute air.

Description

A kind of argon gas EGR in monocrystalline silicon production
Technical field
It the utility model is related to a kind of system for applying to monocrystalline silicon production, the argon gas in especially a kind of monocrystalline silicon production EGR.
Background technology
Show that the whole world there are 10,000 or so single crystal growing furnaces there are more than 8,000 platforms in China at present according to investigations, to the year two thousand twenty, single crystal growing furnace will Reach 20,000, and a single crystal growing furnace takes around using 5.76 × 10 for average 1 year5L - 8.64×105L argon gas.Market at present The cost of upper argon gas retracting device is significantly larger than the purchase cost of argon gas, and in face of the cost of great number, many producer more options will Caused useless argon gas, which is directly thrown into air, during monocrystalline silicon production is not recycled.But result of which will The continuous waste of our only earth resources is caused, the huge resource for wasting not only let us is fewer and fewer will also to cause me Environment harm.
Application No. 201210078306.X, argon gas can say the method and apparatus of purifying in entitled monocrystalline silicon production The method of middle use is:Thick oil removing first is carried out to the argon gas reclaimed from single crystal growing furnace, then high-precision oil removing removes after compressed cooling Dirt;Then the hydro carbons such as methane and carbon monoxide is made to generate water and carbon dioxide, catalysis with oxygen reaction by high-temperature catalytic reaction Ensure that oxygen is excessive in reaction;Again by making under catalyst action excessive oxygen react generation with the hydrogen added again after cooling Water, the argon gas after catalytic reaction twice pass through normal temperature absorbing unit to adsorb water and carbon dioxide;By above-mentioned argon gas Low-temperature fractionating tower is sent into after cooling, argon gas is produced rectifying with nitrogen and hydrogen and separates, obtain pure liquid argon, then obtained after re-heat Straight argon product.The invention system is complicated, and equipment price is high, and is constantly consuming oxygen, hydrogen while argon gas is reclaimed, Increase cost.
Application No. 201580006723.5, the argon gas of entitled manufacturing device of single crystal silicon reclaim exquisite method and argon Gas reclaims delicate instruments, and this method, which has to import from manufacturing device of single crystal silicon to useless argon gas storage tank, contains nitrogen, oxygen and an oxygen Change the process of the useless argon gas of carbon, remove the work of the solid content with the pre-processing device for removing the solid content in the useless argon gas Sequence, the oxygen is converted into respectively by water by catalytic reaction, carbon monoxide will be narrated the process of carbon dioxide is converted into and goes Except the process that the water, the carbon dioxide and the nitrogen are recycled gas, by the way that catalyst is configured at into twin-stage pressure In contracting machine, the catalytic reaction only is carried out to obtain in the process of the gas recovery with the heat of compression, is gone in advance with drying machine After the water, the nitrogen, the carbon dioxide are removed with normal temperature adsorption tower, obtains required argon gas product.The method equipment Cost is high, in constantly consumption oxygen, hydrogen while argon gas is reclaimed, increases cost.
Utility model content
Therefore, in order to overcome above-mentioned deficiency, the utility model provides a kind of reasonable in design, simple in construction, user herein Just, caused useless argon gas be recovered by filtration recycling during in a manner of low cost to monocrystalline silicon production, so as to reduce Argon gas loses, and saves production cost.
The utility model is achieved in that the argon gas EGR constructed in a kind of monocrystalline silicon production, including argon gas are deposited Storage tank, vaporizer, single crystal growing furnace, vavuum pump, solidfied material processor, cupric oxide reactor, limewash reaction unit, drier, with And rectifying device;
The argon gas storage tank is connected by pipeline with vaporizer;
The vaporizer is connected with single crystal growing furnace by pipeline and is respectively arranged with valve on the connecting pipe;
The single crystal growing furnace is connected by pipeline with vavuum pump and rectifying device again, while is provided with valve on the pipeline;
The vavuum pump is connected with cupric oxide reactor and limewash reaction unit respectively by pipeline, and respectively in the pipe Valve is provided with road, while the vavuum pump is also connected by pipeline with solidfied material processor, and threeway is set on the pipeline Pipeline, and it is provided with valve;
The solidfied material processor is connected by pipeline with cupric oxide reactor, and is provided with valve on the pipeline;
The cupric oxide reactor is connected by pipeline with limewash reaction unit, and is provided with valve on the pipeline;
The limewash reaction unit is connected by pipeline with drier again, and valve is set on the pipeline;
The drier is connected by pipeline with rectifying device again.
Preferably, in addition to hydrolysis device, the hydrolysis device are connected by pipeline with cupric oxide reactor, and in the pipeline On be provided with valve.
Preferably, the solidfied material processor is electrostatic precipitation oil expeller, and collection storage device is provided with bottom.
The utility model application method is as follows:
The useless argon gas come out from single crystal growing furnace removes through vacuum pumping to solidfied material processor, the solidfied material processor for electric precipitation Oily device is removed oil, silicon class solidfied material using the principle of Electrostatic Absorption;The useless argon gas of early stage 5% is drained into air, later stage 95% again Useless argon gas makes the hydrocarbons such as hydrogen in waste gas, carbon monoxide, methane occur with scorching hot cupric oxide by scorching hot cupric oxide Chemical reaction generation carbon dioxide, water, copper;Then useless argon gas is removed into carbon dioxide therein by limewash reaction unit, After being dried into drier, then nitrogen is removed in rectifying, and the pure argon after most handling at last, which is sent back in single crystal growing furnace, to be recycled.
The utility model has the advantages that:
The utility model is designed reasonably, it is simple in construction, it is easy to use, can be reasonably in a manner of low cost to monocrystalline silicon Caused useless argon gas be recovered by filtration recycling in production process, so as to reduce argon gas loss, saves production cost;
By reasonably designing solidfied material processor, the processor uses electrostatic precipitation oil expeller, the oil of attachment and solidification Thing is voluntarily fallen into storage tank according to Gravitative Loads, belongs to recycling plant, and filter will be regularly replaced by being different from other filters Core increases cost.
By reasonably designing cupric oxide reactor, in the reactor, cupric oxide and carbon monoxide, hydrogen, methane etc. The product copper of chemical reaction generation occurs for hydrocarbons, and oxygen is added under normal temperature condition can make copper continue oxidation generation cupric oxide Reach the purpose of recycling, unnecessary oxygen is discharged into air.
Simultaneously by reasonably designing hydrolysis device, the source of oxygen is realized, the source of oxygen is then produced using water electrolysis Oxygen, without removing the oxygen of buy product, the method that oxygen is directly just produced by water electrolysis provides required oxygen, section The about energy, reduce cost.
And by reasonably designing limewash reaction unit, in the apparatus, using limewash generation calcium carbonate and Calcium bicarbonate makes it be decomposed into calcium oxide, carbon dioxide by heating, and calcium oxide meets water generation calcium hydroxide and realizes reuse, Carbon dioxide is discharged into air.
The utility model is in argon gas refines removal process, and the rate of recovery of argon gas reaches more than 90 percent, utilization rate For 85 percent, recovery precision can reach 99.99%, and cost recovery is 1,000 yuan per ton of price.
Brief description of the drawings
Fig. 1 is Tthe utility model system module diagram;
In figure:101st, argon gas storage tank;102nd, vaporizer;103rd, single crystal growing furnace;104th, vavuum pump;105th, solidfied material is handled Device;107th, cupric oxide reactor;108th, limewash reaction unit;109th, drier;110th, rectifying device;1、2、3、4、5、6、7、 8th, 9,10,11,12,13, valve.
Embodiment
The utility model is described in detail below in conjunction with accompanying drawing 1, to the technical side in the utility model embodiment Case is clearly and completely described, it is clear that and described embodiment is only the utility model part of the embodiment, rather than Whole embodiments.Based on the embodiment in the utility model, those of ordinary skill in the art are not making creative work Under the premise of the every other embodiment that is obtained, belong to the scope of the utility model protection.
As shown in figure 1, single crystal growing furnace 103 closes all valves after starting in addition to valve 1,3,6,7, vavuum pump 104 is utilized It will be vacuumized in stove, most of air in single crystal growing furnace 103 and small part argon gas drained into air, this process needs 4 hours;When When vacuum reaches 10 support in stove, valve 7 is closed, while opens valve 2,8,11,13, is filled with the argon gas from recovery circulation, Insufficient section comes out the argon gas after normal temperature vaporization to supply using liquid argon storage tank, and this process needs 2 hours;When vacuum in stove Reach 15 supports, silicon material is heated, melted, this process is time-consuming 8 hours;Then crystal pulling 4 hours, cool down 6 ~ 8 hours, argon gas from Into single crystal growing furnace to 24 ~ 26 hours or so the time left, finally close stove and shut down the time without argon gas as 6 hours.Whole blow-on During argon gas ceaselessly refining recovery, recycle, close above-mentioned all valves after blowing out, open valve 4,5,9, 10th, material carries out secondary chemical reaction in 12 pairs of cupric oxide reactors and lime water reactor, is returned to original state.
In said process, the useless argon gas that argon concentration is up to 90 percent drains into solidfied material processor by vavuum pump Electrostatic precipitation oil removing is carried out, removes the solidfied materials such as oil in useless argon gas, silicon class.Adsorb oil, solidfied material in electrostatic precipitator Bottom storage tank is fallen into by deadweight, periodically carries out cleaning dedusting oil removing when not in use.
Useless argon gas after solidfied material has been handled is chemically reacted into the reactor equipped with scorching hot cupric oxide, CuO+ H2 → Cu + H2O, CuO + CO → Cu + CO2, 4CuO + CH4→ 4Cu + CO2↑+ 2H2O, the mistake of this chemical reaction Journey disposably removes the foreign gases such as the hydrogen in useless argon gas, carbon monoxide, methane, and the copper for being reduced out is at normal temperatures Add oxygen and can and be oxidized to cupric oxide, reused, process was not only simple but also environmentally friendly.
Gas from said process out includes:Carbon dioxide, water, nitrogen, argon gas, this mixed gas is passed through into lime Water reactor removes carbon dioxide therein, and the chemical reaction of generation is:Ca(OH)2 + CO2→ CaCO3↓ +H2O, CaCO3 + CO2 +H2O →Ca(HCO3)2, it is dried into drying device, eventually enters into rectifier unit and remove nitrogen, be fractionated Be we extract the pure argon of recycling.The pure argon of recovery endlessly enters single crystal growing furnace and repeats to make With when yield deficiency, Open valve 1 supplements the argon gas required in single crystal growing furnace.
Above-mentioned all valves are closed after blowing out, open valve 4,5,9,10,12.Using apparatus for electrolyzing by oxygen and hydrogen Gas carries out separation electrolysis equation:2H2O → 2H2↑ + O2↑, the oxygen separated is sent into the device equipped with cupric oxide, Sufficient oxygen is chemically reacted at normal temperatures with copper: 2Cu + O2→ 2CuO, unnecessary oxygen passes through after the completion of reaction Vavuum pump drains into air.
Limewash removes the calcium carbonate of carbon dioxide production simultaneously and calcium bicarbonate is decomposed life in the state of heating Into calcium oxide and water, calcium oxide meets water and becomes calcium hydroxide again, becomes the product of our needs again, and chemical equation is:Ca (HCO3)2→ CaCO3↓ + CO2↑ + H2O, CaCO3→CaO + CO2↑, CaO+H2O →Ca(OH)2, it is raw after the completion of reaction Into carbon dioxide drained into by vavuum pump in air.Check function is respectively provided between valve, is closed after the completion of gas emptying Close and state valve, whole argon recovery systems are in original state again, wait for quietly recycling useless argon gas next time.
The foregoing description of the disclosed embodiments, professional and technical personnel in the field are enable to realize or new using this practicality Type.A variety of modifications to these embodiments will be apparent for those skilled in the art, determine herein The General Principle of justice can be realized in other embodiments in the case where not departing from spirit or scope of the present utility model.Cause This, the utility model is not intended to be limited to the embodiments shown herein, and is to fit to and principles disclosed herein The most wide scope consistent with features of novelty.

Claims (3)

  1. A kind of 1. argon gas EGR in monocrystalline silicon production, it is characterised in that:Including argon gas storage tank(101), vaporizer (102), single crystal growing furnace(103), vavuum pump(104), solidfied material processor(105), cupric oxide reactor(107), limewash reaction Device(108), drier(109)And rectifying device(110);
    The argon gas storage tank(101)Pass through pipeline and vaporizer(102)Connection;
    The vaporizer(102)Pass through pipeline and single crystal growing furnace(103)Connect and be provided with valve on the connecting pipe;
    The single crystal growing furnace(103)Pass through pipeline and vavuum pump respectively(104)And rectifying device(110)Connection, while in the pipeline On be provided with valve;
    The vavuum pump(104)By pipeline respectively with cupric oxide reactor(107)With limewash reaction unit(108)Connection, And valve is provided with the pipeline respectively, while the vavuum pump(104)Also pass through pipeline and solidfied material processor(105)Even Connect, triplate line is set on the pipeline, and is provided with valve;
    The solidfied material processor(105)Pass through pipeline and cupric oxide reactor(107)Connection, four-way pipe is set on the pipeline Road, and it is provided with valve on the pipeline;
    The cupric oxide reactor(107)Pass through pipeline and limewash reaction unit(108)Connection, and be provided with the pipeline Valve;
    The limewash reaction unit(108)Pass through pipeline and drier again(109)Connection, valve is set on the pipeline;
    The drier(109)Pass through pipeline and rectifying device again(110)Connection.
  2. A kind of 2. argon gas EGR in monocrystalline silicon production according to claim 1, it is characterised in that:Also include hydrolysis dress Put(106), the hydrolysis device(106)Pass through pipeline and cupric oxide reactor(107)Connection, and it is provided with valve on the pipeline Door.
  3. A kind of 3. argon gas EGR in monocrystalline silicon production according to claim 1, it is characterised in that:At the solidfied material Manage device(105)For electrostatic precipitation oil expeller, and collection storage device is provided with bottom.
CN201720927760.6U 2017-07-28 2017-07-28 A kind of argon gas EGR in monocrystalline silicon production Active CN206970213U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109078442A (en) * 2018-09-18 2018-12-25 湖北和远气体股份有限公司 A kind of crystal pulling furnace richness argon tail gas oil removing system
CN110608367A (en) * 2019-09-30 2019-12-24 苏州苏净保护气氛有限公司 Argon recycling system and method
CN111403784A (en) * 2020-03-23 2020-07-10 中铁轨道交通装备有限公司 Apparatus for removing carbon monoxide, hydrogen fuel cell having the same, and vehicle
CN112320164A (en) * 2020-12-09 2021-02-05 浙江佳乐科仪股份有限公司 Garbage classification collection transfer vehicle

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109078442A (en) * 2018-09-18 2018-12-25 湖北和远气体股份有限公司 A kind of crystal pulling furnace richness argon tail gas oil removing system
CN110608367A (en) * 2019-09-30 2019-12-24 苏州苏净保护气氛有限公司 Argon recycling system and method
CN111403784A (en) * 2020-03-23 2020-07-10 中铁轨道交通装备有限公司 Apparatus for removing carbon monoxide, hydrogen fuel cell having the same, and vehicle
CN112320164A (en) * 2020-12-09 2021-02-05 浙江佳乐科仪股份有限公司 Garbage classification collection transfer vehicle

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Address after: No. 14, Floor 19, Unit 1, Building 18, No. 360, Tianhui Road, High-tech Zone, Chengdu, Sichuan, 610000

Patentee after: Kaide Electronic Engineering Design Co.,Ltd.

Address before: 610041 Tianhui Road, Chengdu High-tech Zone, Sichuan Province, No. 360, 18 Blocks 1, Unit 19, Layer 14

Patentee before: CHINA CONSTRUCTION KIDE ENGINEERING CORPORATION CO.,LTD.