A kind of device for Detection electrode active material softening degree
Technical field
Lead accumulator technical field of quality detection is the utility model is related to, is used for Detection electrode activity more particularly to one kind
The device of material softening degree.
Background technology
The history in lead-acid accumulator modern existing more than 150 years, and application field is very extensive.In recent years, electric car with its compared with
Good performance of riding instead of walk, relatively low storage space requirement and outstanding price advantage has benefited from this, battery in China's fast development
Industry has also obtained rapid development.
Lead-acid accumulator is a kind of device that chemical energy is converted into electric energy, belongs to secondary cell.Charging process is by electric energy
Chemical energy is converted into be stored in active material;During electric discharge, the chemical energy being stored in active material is converted into electric energy.Electric discharge
When, positive pole PbO2It is converted into PbSO4, active material volumetric expansion, although being converted into the bigger PbSO of volume4, due to negative electrode active
Material is softer, it is easier to compresses, negative pole does not have the tendency expanded.Positive plate PbO2Relatively difficult compression, after repeated charge,
Positive plate between continuously expansion causes active material repeatedly adhesion die down, until breaking releasing, form isolated island particle.
Actual use process, battery softening degree is different, and very thin one layer of some polar board surfaces softens, and what is had is soft
Change degree is deeper, and overall activity material all softens.During failure cause is carried out to battery and searches analysis, the boundary of softening degree
Surely the process improving measure of actual production is influenced whether.In addition, softening degree be also judge battery quality quality one it is important
Factor.Therefore, the detection of pole plate softening degree is significant.
Publication No. CN105140578A Chinese invention patent discloses a kind of detection lead acid battery positive electrode active matter
The method of matter softening degree, comprises the following steps:(1) battery is dissected, takes out the positive plate for needing to test;(2) positive plate is done
After dry, weigh, record weight is M1;(3) dried positive plate is immersed in distilled water, sonic oscillation processing a period of time;
(4) positive plate is taken out, dries, weigh, record weight is M2;(5) the softness number X, X=of positive active material is calculated
(M1-M2)/M1.This method in ultrasonic vibration processing and then the quality proportion to drop by positive plate by characterizing positive plate
Softening degree, the inside lead plaster of concussion process positive plate are shaken as the lead plaster on surface so that concussion process drops
Some is probably due to the loosening between active material caused by detection process to quality, rather than lead accumulator actually uses
During cause pole plate to soften, loosened so as to combine between active material.
Utility model content
The utility model characterizes asking for plate active material softening degree for no good means in the prior art
A kind of topic, there is provided device for Detection electrode active material softening degree.
A kind of device for Detection electrode active material softening degree, including:
Universl tester, have base and can vertical lifting central sill, the central sill is provided with upper fixture joint, on base
Provided with lower clamp joint;
For fixing the horizontally disposed test platform of support polar plate;
The sliding block being overlying on during test on the pole plate, the surface of face pole plate are provided with least three stitch;
Sliding block is pulled to connect the upper fixture with respect to the drawstring that pole plate slides, one end connection sliding block, the other end around pulley
Joint.
Support bar and support base, the support base and lower clamp joint grafting are provided with below the test platform, and is passed through
Latch is fixed.
The support base includes upper support seat and lower support base, upper support seat are fixedly connected with test platform one end, lower branch
Seat and lower clamp joint grafting are supportted, the upper support seat is connected with lower support base by universal joint.
The locking nut coordinated with lower clamp joint is arranged with the lower support base.
The support bar is coated with fixing nut with being threadedly coupled in the middle part of test platform.
Supporting plate is provided with below the support bar, supporting plate is fixedly connected by bolt with base.
The one end of the test platform away from universl tester is provided with limited block, and the limited block is fixed on survey by latch
Try on platform.In addition to pole plate, for the sample of some other detection, some can be hung on limited block by one end and carried out
It is fixed.
The test platform is provided with the pressing plate coordinated with pole plate both side edges.
A kind of method using described device Detection electrode softening degree, including:
Pole plate is fixed on test platform, sliding block is pressed on pole plate, is started universl tester, is at the uniform velocity pulled sliding block, is remembered
Pulling force is recorded, calculates friction coefficient μ (the friction system i.e. between the pole plate of remains stationary and the sliding block of motion between pole plate and stitch
Number), with the softening degree of 1/ μ sign pole plates.Coefficient of friction refers to frictional force between two surfaces and acted in surface thereof
The ratio of vertical force.When object uniform motion in the horizontal direction, friction coefficient μ=F/ (mg), then 1/ μ=mg/F, wherein, F
The pulling force F, m being subject to for sliding block horizontal direction are the quality of sliding block (if increasing counterweight on sliding block, for sliding block and counterbalance mass
Sum), g is acceleration of gravity, usual value 9.8m/s2。
The utility model device is in use, by the way that pole plate is fixed on horizontally disposed test platform, then sliding block
In stitch insertion plate active material, sliding block is pulled to be calculated to pulling force kept stable by universl tester constant level
Friction coefficient μ, the softening degree of pole plate is characterized with 1/ μ, value is bigger, and softening degree is higher, can be fast using utility model device
Speed, the bond strength for accurately characterizing plate active material softening degree, green plate or ripe plate active material.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model device.
Fig. 2 is the structural representation that the utility model device is free of universl tester.
Fig. 3 is the overlooking the structure diagram that the utility model device is free of universl tester.
Embodiment
Embodiment 1
As shown in Figures 1 to 3, a kind of device for Detection electrode active material softening degree, including:Universl tester 1,
Test platform 2, sliding block 3, drawstring 4.Universl tester 1 have base 11 and can vertical lifting central sill 12, central sill 12 is provided with
Upper fixture joint 13, base 11 are provided with lower clamp joint 14.
Test platform 2 is horizontally disposed, below provided with support bar 6 and support base 7.Support base 7 totally one is flat positioned at test
On the axis of platform 2.Support base 7 includes upper support seat 71 and lower support base 72, and upper support seat 71 is fixed with the one end of test platform 2 to be connected
Connect.Lower support base 72 and the grafting of lower clamp joint 14, the lower part of the insertion lower clamp of support base 72 joint 14 has wears for latch 16
The pin hole 75 crossed, both are fixed by latch 16.When being fixed due to relying solely on latch 16, lower support base 72 and lower folder
Be likely present loosenings between tool joint 14, locking nut with the cooperation of lower clamp joint 14 is arranged with following support base 72
74, locking nut 74 be screwed down make its with lower clamp joint 14 tightly against, make lower support base 72 by the power being lifted up,
So that lower support base 72 is completely fixed with lower clamp joint 14, will not loosen.Upper support seat 71 is logical with lower support base 72
Universal joint 73 is crossed to connect.
Support bar 6 is threadedly coupled with the middle part of test platform 2, and fixed spiral shell is also coated with the thread segment 62 on the top of support bar 6
Mother 61, support bar 6 and test platform 2 are completely fixed by fixing nut 61, avoid to loosen between the two.Support bar 6
Two are shared, both sides are arranged on along the axisymmetrical of test platform 2.The lower section of support bar 6 is provided with supporting plate 15, and supporting plate 15 passes through spiral shell
Bolt is fixedly connected with base 11, and the bottom of support bar 6 is round end 63, and round end 63 is larger with aspect own vol, and heavier-weight is another
Aspect and the relative contact of supporting plate 15 product are smaller, support bar 6 is kept vertical state as far as possible, so as to which test platform 2 keeps water
Level state.
The one end of test platform 2 away from universl tester 1 is provided with limited block 9, and limited block 9 is fixed on test by latch 91
On platform 2.In addition to pole plate, for the sample of some other detection, some can be hung on limited block 9 by one end and carried out
It is fixed.Pressing plate 8 is provided with test platform 2 at limited block 9, pressing plate 8 is two pieces of test platform two, by bolt with surveying
Examination platform 2 is fixed.Two block pressur plates 8, which are used to coordinate with pole plate both side edges, is fixed pole plate.Test platform 2 is close to omnipotent test
One end of instrument 1 has pulley 5, and pulley 5 is arranged on test platform 2 by pulley mounting seat 51.
During detection, first pole plate to be detected is pushed down with two block pressur plates 8, fixed pressing plate 8 by bolt, so as to by pole plate
It is pressed abd fixed on test platform 2.Sliding block 3 is pressed on pole plate, and the surface of its face pole plate is provided with least three stitch 31, pin
Pin 31 is provided with scale, make stitch 31 insert pole plate active material certain depth, one end connection sliding block 3 of drawstring 4, the other end around
Cross pulley 5 and connect upper fixture joint 13.Test platform 2 is solid by the support base 7 of one end and two support bars 6 support at middle part
It is fixed, and keep level state, connected between the upper support seat 71 of support base 7 and lower support base 72 by universal joint 73, so only
Test need to be put down by adjusting the height (length for making to stretch into test platform by rotating support bar 6 changes) of support bar 6
The keep level of platform 2.Then universal tester 1 is started, central sill 12 rises, and at the uniform velocity pulls sliding block 3 to run certain distance, to pulling force base
This holding is stable, ensures that the depth that stitch 31 is inserted in plate active material keeps being basically unchanged in the motion process of sliding block 3, necessary
When, the counterweight or weight of certain mass can be placed on sliding block 3, increases pressure, occurs gently in test platform 2 so as to reduce
During low dip, air acts the influence of power in motion process.Calculate the friction system between acquisition pole plate and test platform 2
Number μ (coefficient of friction i.e. between the pole plate of remains stationary and the sliding block of motion), the softening degree of pole plate is characterized with 1/ μ, for
The pole plate of same type, its 1/ μ value is bigger to represent that softening degree is higher.
Embodiment 2
(1) the 12Ah batteries of 300 cycle charge-discharges are dissected, take out positive plate A;
(2) positive plate is positioned on test platform, fixed with pressing plate;
(3) counterweight (weight 500g) of certain mass is placed on sliding block (weight 100g), makes the stitch below sliding block deep
Enter active material about 1mm depth;
(4) universal testing machine is started, constant level pulls sliding block to run 500mm, to pulling force F kept stables (35N);
(5) coefficient of friction is calculated, friction coefficient μ=F/ (mg), wherein g is acceleration of gravity (value 9.8m/s2), so
1/ μ=mg/F=(100+500) × 9.8 ÷ 35=168.
It is same use the above method, another piece of measurement circulate after, the pole plate B without washing and drying.It is computed, the pole plate 1/
μ is 82, then assert that pole plate A softening degree is higher.
Embodiment 3
(1) the positive plate A after the solidification of certain company is taken;
(2) positive plate is positioned on test platform, fixed with pressing plate;
(3) counterweight (weight 1000g) of certain mass is placed on sliding block (weight 95g), makes the stitch below sliding block deep
Enter active material about 1mm depth;
(4) universal testing machine is started, constant level pulls sliding block to run 500mm, to pulling force F kept stables
(122N);
(5) coefficient of friction is calculated, friction coefficient μ=F/ (mg), wherein g is acceleration of gravity (value 9.8m/s2), so
1/ μ=mg/F=(95+1000) × 9.8 ÷ 122=87.9.
It is same to use the above method, measure the pole plate B after another piece of solidification.It is computed, the pole plate 1/ μ is 95.6, then recognizes
The bond strength of fixed plate A active materials is higher, and pole plate B softening degree is higher.