CN206768044U - A kind of fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater - Google Patents

A kind of fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater Download PDF

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Publication number
CN206768044U
CN206768044U CN201720585663.3U CN201720585663U CN206768044U CN 206768044 U CN206768044 U CN 206768044U CN 201720585663 U CN201720585663 U CN 201720585663U CN 206768044 U CN206768044 U CN 206768044U
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fine coal
sleeve
organic wastewater
passage
oxygen
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郭保方
张海军
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Luxi Chemical Group Co Ltd
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Luxi Chemical Group Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Abstract

Mixed the utility model discloses a kind of fine coal and burn the compound gasification combustor of high concentrated organic wastewater,By to the independent peripheral hardware of combustor firing gun,Burner fine coal, which feeds to mix to burn with waste water, is arranged to respective independent passage,Igniting,The periodic off-gases that go into operation are same passage,Organic wastewater oxygen and the oxygen that goes into operation are same passage,And fine coal passage is arranged on the improvement of the gasification furnace structures such as burner outer ring and realizes that the organic wastewater in coal gasification mixes firing technique,Appropriate organic wastewater is burnt by mixing,Fine coal can individually spray can also be with waste water while mixing burning spray combustion,The operation of original coal gasification burning is not influenceed,Solve burner it is single injection fine coal the drawbacks of,Reduce the steam usage amount of coal gasification process,Burner is that can be mixed to burn a certain proportion of waste water according to operating load in injection fine coal,Save the fine coal energy,Steam caused by the steam that is formed under the high temperature conditions of high concentrated organic wastewater and combustion reaction simultaneously,Carbon dioxide further participates in gasification reaction generation synthesis gas,Organic wastewater sedimentation is realized to recycle.

Description

A kind of fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater
Technical field
A kind of novel energy-conserving coal gasification production technique device is the utility model is related to, it is highly concentrated that more particularly to a kind of fine coal mixes burning Spend the compound gasification combustor of organic wastewater.
Background technology
In recent years, developing rapidly with petroleum chemical industry, produced while various product is produced substantial amounts of organic Waste water, not only organic concentration is high, and poisonous and harmful substance is also contained in part, and intractability is big.With new environment Protection Code Implementation, how efficient process organic wastewater turns into the important topic that faces of enterprise.Organic wastewater generally use is biochemical or burns Mode handled.Poisonous and harmful substance easily causes biochemical bacteria inactivation in organic wastewater in biochemical treatment mode, needs supporting build If physics and Chemical Pretreatment device can ensure biochemical treatment efficiency, and be only applicable to handle low-concentration organic waste water.Burn Burning processing refers in the combustion chamber of incinerator, is chemically reacted by controllable high-temperature and destroys the molecule of various harmful substances in waste water Structure, by the oxidation operation in waste water into CO, H2The innocuous substances such as O, suitable for handling high concentrated organic wastewater.Such as acyl in oneself The organic liquid wastes such as amine, double ethylbenzene amine directly outer can not be arranged, handling process typically using will organic liquid waste spray to burning on fine coal Burn in the combustion chamber of stove and burn.Waster water incinerator is typically using clean fuels such as low-sulfur diesel-oils as igniting combustion supporting agent, caused tail Gas main component is steam, flue dust, SO2、NO2Deng to ensure tail gas qualified discharge, needing auxiliary construction chilling, desulphurization and denitration etc. Auxiliary equipment, investment is big, operating cost height is the principal element for restricting the application of burning disposal organic wastewater Technique Popularizing.Production at present Raw organic wastewater, the mode of conventional sewage processing, can not meet needs;Waste water is difficult to handle, and has been to restrict chemical enterprise The bottleneck problem of development, how to handle, it is extremely urgent.
Coal gasification is an important directions of coal utilization technology, and it is coal to be converted fuel gas or the change for ease of burning Work raw material, its main component are the gaseous mixture of carbon monoxide and hydrogen.The fine coal gas making burner such as shell that the country uses at present The burner that board stove, GSP stoves, space flight stove etc. use only has the function of single injection pulverized coal friring.
For the Environmental Protection Situation of current rigorous, study compound gasification installation and mix and burn high concentrated organic wastewater device and technique Technology, on the one hand can thoroughly solve the reluctant problem of high concentrated organic wastewater, on the other hand can be that coal chemical industry enterprises are handled High concentrated organic wastewater opens up a new approach, realizes the synthesis chemical enterprise high concentrated organic wastewater based on coal chemical industry Recycling, improve the level of clean production of enterprise, provided safeguard for Resources for construction economizing type, environment-friendly enterprise, be Environmental Protection in China field waste water incineration technological development is promoted to provide technical support.
Utility model content
In order to solve the shortcomings that prior art is present, the purpose of this utility model, which is to provide a kind of fine coal, which mixes burning high concentration, has The compound gasification combustor of machine waste water, the burner can use special burner structure to design, it is single to solve conventional burners The drawbacks of spraying fine coal, burner are that can be mixed to burn a certain proportion of waste water according to operating load in injection fine coal, simple structure, Strong adaptability, environmental protection and energy saving, turn waste into wealth.
To achieve the above object, the utility model uses following technical scheme:
A kind of fine coal mix burn the compound gasification combustor of high concentrated organic wastewater, including burning torch, waste water tunnel, igniting/ Go into operation periodic off-gases passage, oxygen channel of lighting a fire/go into operation, cooling water jecket passage, the main oxygen/steam channel of fine coal, fine coal passage group Water-cooling wall is set with into, burner bottom, and the cavity in water-cooling wall forms vaporizer, and described combustor firing gun is individually outer If fine coal passage and waste water tunnel are arranged to each independent passage, light a fire, the periodic off-gases that go into operation are same passage, organic wastewater Oxygen and the oxygen that goes into operation are same passage, and described fine coal passage is to be arranged on burner outer ring, ecto-entad by fine coal passage Setting the main oxygen of fine coal/steam channel, lighting a fire/respectively, go into operation oxygen channel, and light a fire/go into operation periodic off-gases passage, waste water tunnel are described Waste water tunnel is located at burner centre.
It is of the present utility model mix burn waste water gasification combustor, the independent peripheral hardware of combustor firing gun, burner fine coal charging with Waste water, which is mixed to burn, is arranged to respective independent passage, lights a fire, the periodic off-gases that go into operation are same passage, organic wastewater oxygen and the oxygen that goes into operation For same passage, and fine coal passage is arranged on burner outer ring.On the one hand, fine coal charging is mixed burning with waste water and is arranged to each solely Vertical passage, which ensure that fine coal can individually spray, not to influence original coal gasification with waste water while mixing burning spray combustion The operation of burning.Another aspect waste water tunnel is located at burner centre, fine coal passage is located at the peripheral reasonable Arrangement of vaporizer, really Protect waste water and can realize farthest to contact with the thermal-flame of pulverized coal friring in burner hearth and gasification, and combustion occurs, prevent waste water gas Gas expansion caused by change influences the operation of the original coal gasification burning in periphery, produces the gasification gas of quality dissatisfaction;Mix simultaneously Burning a certain proportion of waste water makes waste water atomization reach optimum efficiency, it is ensured that the burn rate and burning degree of waste water, and meanwhile it is highly concentrated Steam, carbon dioxide further participate in gasified reverse caused by the steam that is formed under the high temperature conditions of degree organic wastewater and combustion reaction Synthesis gas should be generated, organic wastewater sedimentation is realized and recycle, device structure is novel, technique is simple, efficiency high, saving into This, stabilization safe for operation.
Fine coal guide flight can realize that fine coal farthest disperses, and improve powder coal gasification and efficiency of combustion, Save the energy.
Preferably, described burner include be set in together successively from inside to outside the first sleeve, second sleeve, the 3rd Sleeve, 4th sleeve and vaporizer, and, it is not connected. between each sleeve, vaporizer independently of each other;And from top to bottom successively One sleeve is higher than 4th sleeve higher than second sleeve, second sleeve higher than 3rd sleeve, 3rd sleeve, and 4th sleeve is higher than gasification Room, and be bolted each other;Waste liquid import is provided with the top of the first described sleeve;In described second sleeve Side wall be provided with and light a fire/go into operation periodic off-gases import, be provided with oxygen inlet of lighting a fire/go into operation, cold in the side wall of described 3rd sleeve But water out, cooling water inlet;Fine coal import, fine coal main oxygen/steam inlet, gasification are provided with described 4th sleeve side wall Room side wall is provided with coil pipe cooling water inlet, coil pipe coolant outlet;The bottom corresponding with each sleeve is respectively equipped with waste water and gone out Mouthful, periodic off-gases of lighting a fire/go into operation outlet, oxygen outlet of lighting a fire/go into operation, fine coal outlet, fine coal oxygen/steam (vapor) outlet.
Preferably, described water-cooling wall is integral type coil wall, if it includes Heavenly Stems and Earthly Branches heat exchanger tube, the heat exchange pipe dish The welded seal between arrangement one cavity of formation, adjacent heat exchange tubes, the cavity inner wall is according to the different coverings of the smooth temperature that works The refractory masses of different-thickness, the refractory masses are fixed with fixing glue, and the fixing glue is uniform along cavity inner wall Staggeredly it is distributed in radiant type;The bottom of described water-cooling wall is by several seat supports, and the bearing is circumferentially symmetrically Distribution.
Preferably, the inner side of described water-cooling wall is coated with refractory material in stepped, and refractory material passes through fixing glue It is fixed on water-cooling wall coil pipe.
Preferably, the first described sleeve and second sleeve, second sleeve and 3rd sleeve, 3rd sleeve with the 4th set Cylinder, 4th sleeve are connected with vaporizer by sealing flange.
Preferably, fine coal and organic wastewater feed compound burner structure, burner injector fine coal charging with it is organic Wastewater feed is arranged to each independent passage, and fine coal can individually spray can also be with waste water while mixing burning spray combustion gas Change.
Preferably, the main oxygen of described fine coal/steam channel, lighting a fire/goes into operation periodic off-gases passage, oxygen channel of lighting a fire/go into operation Set tolerance to match instrument and meter for automation, control gas flow.
The process of described device is as follows:
Preferably, fine coal mixes the mass ratio 15 of burning with organic wastewater:2.
Control fine coal and organic wastewater mixed-fuel burning proportion particularly significant, organic wastewater mixes the big influence original gasification of fine coal of burning amount Reaction, the gas co and H of coal gasification2The ratio of active ingredient declines, the increase of pernicious gas yield, corrosion pipeline, after increase Continuous intractability;Organic wastewater mixed-fuel burning proportion is smaller, it is impossible to realizes the recycling of organic wastewater to greatest extent.
The beneficial effects of the utility model are:
(1) the utility model utility model, which is mixed, burns waste water gasification combustor, the independent peripheral hardware of combustor firing gun, burner powder Coal, which feeds to mix to burn with waste water, is arranged to each independent passage, lights a fire, the periodic off-gases that go into operation be same passage, organic wastewater oxygen and The oxygen that goes into operation is same passage, and fine coal passage is arranged on into burner outer ring, and waste water tunnel is located at burner centre structure and entered Row reasonable Arrangement, waste water can be realized farthest to contact in burner hearth with the thermal-flame of pulverized coal friring occurs gasification, and combustion, Prevent gas expansion caused by waste water gasification from influenceing the operation of the original coal gasification burning in periphery, produce the gasification of quality dissatisfaction Gas.
(2) charging of burner fine coal mixes to burn with waste water is arranged to respective independent passage, and fine coal, which can individually spray, also may be used To mix burning spray combustion simultaneously with waste water, the operation of original coal gasification burning is not influenceed, solves the single injection fine coal of burner The drawbacks of, reduce the steam usage amount of coal gasification process, burner is that burning can be mixed according to operating load in injection fine coal A certain proportion of waste water, save the fine coal energy.
(3) for the utility model on the premise of process unit demand is met, mixing a certain proportion of waste water of burning is atomized waste water Reach optimum efficiency, it is ensured that the burn rate and burning degree of waste water, while high concentrated organic wastewater is formed under the high temperature conditions Steam and combustion reaction caused by steam, carbon dioxide further participate in gasification reaction generation synthesis gas, realize organic waste Water sedimentation recycles, and device structure is novel, technique is simple, efficiency high, cost-effective, stabilization safe for operation.
Brief description of the drawings
The concrete structure diagram of Fig. 1 burners;
Fig. 2 is the sectional view of figure part A;
In figure:1st, waste water inlet, 2, periodic off-gases import of lighting a fire/go into operation, 3, oxygen inlet of lighting a fire/go into operation, 4, cooling water enters Mouthful, 5, coolant outlet, 6, fine coal import, 7, fine coal oxygen/steam inlet, 8, coil pipe cooling water inlet, 9, coil pipe cooling water Outlet, 10, wastewater outlet, 11, periodic off-gases of lighting a fire/go into operation outlet, 12, oxygen outlet of lighting a fire/go into operation, 13, fine coal outlet, 14, Fine coal oxygen/steam (vapor) outlet, 15 fine coal guide flights, the 16, first sleeve, 17 second sleeves, 18 3rd sleeves, 19 the 4th sets Cylinder, 20, vaporizer.
Embodiment
This practical utility model is further elaborated below in conjunction with the accompanying drawings, it should which explanation, the description below is only It is to explain this practical utility model, its content is not defined.
Embodiment 1
Fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, including burning torch, waste water tunnel, igniting/go into operation Periodic off-gases passage, oxygen channel of lighting a fire/go into operation, cooling water jecket passage, the main oxygen/steam channel of fine coal, fine coal passage composition, combustion Burner bottom is set with water-cooling wall, and the cavity in water-cooling wall forms vaporizer 20, the independent peripheral hardware of described combustor firing gun, powder Coal channel and waste water tunnel are arranged to each independent passage, light a fire, the periodic off-gases that go into operation be same passage, organic wastewater oxygen and The oxygen that goes into operation is same passage, and to be arranged on burner outer ring, fine coal passage side ecto-entad is set described fine coal passage respectively Go into operation the main oxygen of fine coal/steam channel, lighting a fire/oxygen channel, and light a fire/go into operation periodic off-gases passage, waste water tunnel, described waste water lead to Road is located at burner centre, is additionally provided with fine coal guide flight 15 in described fine coal passage, described burner include by It is interior to outer the first sleeve 16, second sleeve 17,3rd sleeve 18,4th sleeve 19 and the vaporizer 20 being set in together successively, And, it is not connected. between each sleeve, vaporizer independently of each other;And the first sleeve 16 is higher than second sleeve successively from top to bottom 17th, second sleeve 17 is higher than 4th sleeve 19 higher than 3rd sleeve 18,3rd sleeve 18, and 4th sleeve 19 is higher than vaporizer 20, First sleeve and second sleeve, second sleeve and 3rd sleeve, 3rd sleeve and 4th sleeve, 4th sleeve pass through with vaporizer Sealing flange connects;Waste liquid import 1 is provided with the top of the first described sleeve 16;It is provided with the side wall of described second sleeve Light a fire/go into operation periodic off-gases import 2, light a fire/go into operation oxygen inlet 3, coolant outlet are provided with the side wall of described 3rd sleeve 4th, cooling water inlet 5;Fine coal import 6, fine coal main oxygen/steam inlet 7, vaporizer side are provided with described 4th sleeve side wall Wall is provided with coil pipe cooling water inlet 8, coil pipe coolant outlet 9;The bottom corresponding with each sleeve is respectively equipped with wastewater outlet 10, periodic off-gases of lighting a fire/go into operation outlet 11, oxygen outlet 12 of lighting a fire/go into operation, fine coal outlet 13, fine coal oxygen/steam (vapor) outlet 14, Described water-cooling wall is integral type coil wall, if it includes Heavenly Stems and Earthly Branches heat exchanger tube, the heat exchanger tube coiling arrangement forms a chamber Body, welded seal between adjacent heat exchange tubes, the inner side of water-cooling wall passes through solid in the stepped refractory material that is coated with, refractory material Fixed nail is fixed on water-cooling wall coil pipe, and the fixing glue is uniformly staggeredly distributed along cavity inner wall in radiant type;Described water-cooling wall Bottom is circumferentially uniformly and symmetrically distributed by several seat supports, the bearing.
The compound burner structure of fine coal and organic wastewater feed, the charging of burner injector fine coal are fed with organic wastewater It is arranged to each independent passage, fine coal can individually spray can also be with waste water while mixing and burning spray combustion and gasify.Fine coal master Oxygen/steam channel, lighting a fire/go into operation periodic off-gases passage, oxygen channel of lighting a fire/go into operation set tolerance match instrument and meter for automation, control Gas flow.
Embodiment 2
After fine coal mixes the burning compound gasification test plant running of high concentrated organic wastewater, according to Process Design Package value to experiment Device has carried out 72h Performance Assessments, and waste water mixes the indices such as burning amount, synthesis gas available gas composition and entirely reached expected mesh Mark.
Applicant adjusts high-concentration waste water according to actual conditions and mixes burning amount in real time, wherein mixing the run time that burning amount is 5t/h Reach 635h, compound gasification installation is stable, synthesis gas available gas (CO+H2) average out to yield is 91.63%, it is annual It is co-doped with burning waste water 22870t, steam saving 10710t, has reached target.The project system overall operation, energy utilization, Safety and environmental protection etc. has all reached domestically leading level, creates preferable economic benefit and environmental benefit, has wide Development prospect.
The preferred embodiment of the application is the foregoing is only, is not limited to the application, for the skill of this area For art personnel, the application can have various modifications and variations.It is all within spirit herein and principle, made any repair Change, equivalent substitution, improvement etc., should be included within the protection domain of the application.

Claims (9)

1. a kind of fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that leads to including burning torch, waste water Road, light a fire the main oxygen/steam channel of/the periodic off-gases passage that goes into operation, lighting a fire/oxygen channel that goes into operation, cooling water jecket passage, fine coal, powder Coal channel forms, and burner bottom is set with water-cooling wall, and the cavity in water-cooling wall forms vaporizer, described combustor firing gun Independent peripheral hardware, fine coal passage and waste water tunnel are arranged to each independent passage, light a fire, the periodic off-gases that go into operation are same passage, have Machine waste water oxygen and the oxygen that goes into operation be same passage, and described fine coal passage is to be arranged on burner outer ring, by fine coal passage by Setting the main oxygen of fine coal/steam channel, lighting a fire/respectively outside to inside, go into operation oxygen channel, light a fire/go into operation periodic off-gases passage, waste water tunnel, Described waste water tunnel is located at burner centre.
2. fine coal as claimed in claim 1, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that in institute Fine coal guide flight is additionally provided with the fine coal passage stated.
3. fine coal as claimed in claim 1, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that described Burner include being set in together successively from inside to outside the first sleeve (16), second sleeve (17), 3rd sleeve (18), the Four sleeves (19) and vaporizer (20), and, it is not connected. between each sleeve, vaporizer independently of each other;And from top to bottom successively First sleeve (16) is higher than second sleeve (17), second sleeve (17) higher than 3rd sleeve (18), 3rd sleeve (18) higher than the Four sleeves (19), 4th sleeve (19) is higher than vaporizer (20), and is bolted each other;In the first described sleeve (16) top is provided with waste liquid import (1);Periodic off-gases import (2) of lighting a fire/go into operation is provided with the side wall of described second sleeve, The side wall of described 3rd sleeve is provided with light a fire/go into operation oxygen inlet (3), coolant outlet (4), cooling water inlet (5);Institute The 4th sleeve side wall stated is provided with fine coal import (6), fine coal main oxygen/steam inlet (7), and vaporizer side wall cools down provided with coil pipe Water inlet (8), coil pipe coolant outlet (9);The bottom corresponding with each sleeve is respectively equipped with wastewater outlet (10), light a fire/ The periodic off-gases that go into operation export (11), oxygen outlet (12) of lighting a fire/go into operation, fine coal outlet (13), fine coal oxygen/steam (vapor) outlet (14).
4. fine coal as claimed in claim 3, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that described The first sleeve and second sleeve, second sleeve and 3rd sleeve, 3rd sleeve and 4th sleeve, 4th sleeve lead to vaporizer Cross sealing flange connection.
5. fine coal as claimed in claim 3, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that described The main oxygen of fine coal/steam channel, lighting a fire/go into operation periodic off-gases passage, oxygen channel of lighting a fire/go into operation set tolerance match automation instrument Table, control gas flow.
6. fine coal as claimed in claim 1, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that described Water-cooling wall be integral type coil wall, if it includes Heavenly Stems and Earthly Branches heat exchanger tube, the heat exchanger tube coiling arrangement forms a cavity, phase Welded seal between adjacent heat exchanger tube, the cavity inner wall is according to the different refractory materials for covering different-thickness of the smooth temperature that works Layer, the refractory masses are fixed with fixing glue, and the fixing glue is uniformly staggeredly distributed along cavity inner wall in radiant type;Institute The bottom for the water-cooling wall stated circumferentially is uniformly and symmetrically distributed by several seat supports, the bearing.
7. fine coal as claimed in claim 4, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, it is characterised in that described The inner side of water-cooling wall be coated with refractory material in stepped, refractory material is fixed on water-cooling wall coil pipe by fixing glue.
8. the fine coal as described in claim 1-7 is any, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, its feature exists In the compound burner structure of fine coal and organic wastewater feed, burner injector fine coal charging is set with organic wastewater charging For each independent passage, fine coal can individually spray can also be with waste water while mixing and burning spray combustion and gasify.
9. the fine coal as described in claim 1-7 is any, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater, its feature exists In fine coal mixes the mass ratio 15 of burning with organic wastewater:2.
CN201720585663.3U 2017-05-24 2017-05-24 A kind of fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater Active CN206768044U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189820A (en) * 2017-05-24 2017-09-22 鲁西化工集团股份有限公司 A kind of fine coal mixes the burning compound gasification combustor of high concentrated organic wastewater and process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189820A (en) * 2017-05-24 2017-09-22 鲁西化工集团股份有限公司 A kind of fine coal mixes the burning compound gasification combustor of high concentrated organic wastewater and process
CN107189820B (en) * 2017-05-24 2018-07-31 鲁西化工集团股份有限公司 A kind of fine coal, which is mixed, burns the compound gasification combustor of high concentrated organic wastewater and process

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