CN206762897U - A kind of bale packing catalyst of methanol oxidation and combinations thereof structure - Google Patents
A kind of bale packing catalyst of methanol oxidation and combinations thereof structure Download PDFInfo
- Publication number
- CN206762897U CN206762897U CN201720485329.0U CN201720485329U CN206762897U CN 206762897 U CN206762897 U CN 206762897U CN 201720485329 U CN201720485329 U CN 201720485329U CN 206762897 U CN206762897 U CN 206762897U
- Authority
- CN
- China
- Prior art keywords
- catalyst
- bale packing
- active
- methanol oxidation
- active catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 88
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 238000012856 packing Methods 0.000 title claims abstract description 51
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 22
- 230000003647 oxidation Effects 0.000 title claims abstract description 21
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 12
- 239000010935 stainless steel Substances 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 6
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000012535 impurity Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical group COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- -1 poly- methyl dimethoxy ether Chemical compound 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
A kind of bale packing catalyst of methanol oxidation, including stainless steel ripple silk net, active catalyst, flat screen, described active catalyst is evenly distributed on described flat screen, described stainless steel ripple silk net tiles with it be superimposed the active catalyst that clad residence is stated after, by border seal, bale packing catalyst is rolled into by axle center of one end, change the physical arrangement of catalyst, significantly improve the distributional pattern and the type of flow of reaction mass, improve product quality, reduce impurity, it reduce further energy consumption, material consumption, industrial-scale exploitation is aoxidized for methanol and solid foundation has been laid in production.
Description
Technical field
The utility model is related to a kind of bale packing catalyst of methanol oxidation, for methanol oxidation produce formaldehyde equipment and
In method, belong to coal chemical industry, field of chemical technology.
Background technology
With the development of coal chemical technology, large-scale poly- methyl dimethoxy ether (DMMn) process unit will be born.But mesh
Before, there is great drawback, outstanding behaviours are single thick in the physical arrangement of oxidation catalyst for the country, in the world methanol oxidation technology
Put, common application is hollow cylinder, so cause the back-mixing of oxidation reaction material, vortex, turbulent phenomenon serious, into
For the bottleneck of methanol oxidation technology development.Therefore it is imperative to break through these technology drawbacks,
The content of the invention
The utility model discloses a kind of bale packing catalyst of methanol oxidation, the physical arrangement of catalyst, pole are changed
The earth improves the distributional pattern and the type of flow of reaction mass, improves reacted product quality, reduces impurity, enters one
Step reduces energy consumption, material consumption, aoxidizes industrial-scale exploitation for methanol and solid foundation has been laid in production.
The technical solution of the utility model is as follows：
A kind of bale packing catalyst of methanol oxidation, including stainless steel ripple silk net (4), active catalyst (3), plane silk
Net (1), described active catalyst (3) are evenly distributed on described flat screen (1), described stainless steel ripple silk net with
It is tiled after the active catalyst (3) that superposition clad residence is stated, and by border seal, bale packing catalysis is rolled into by axle center of one end
Agent.
Described active catalyst (3) is graininess, and its diameter or peripheral minimum dimension are more than described stainless steel ripple
The mesh diameter of silk screen (4) and flat screen (1).
Described active catalyst (3) is spherical, bar shaped, cube shaped or cylindrical particle.
The bale packing catalyst (2) is rolled into solid cylindrical shape, and its is a diameter of >=50 ㎜, its height is >=100 ㎜.
The bale packing catalyst（2）Active catalyst on cross section is uniformly distributed.
A kind of combining structure of the bale packing catalyst of described methanol oxidation, including tubulation, described tubulation internal diameter with
The diameter of the bale packing catalyst (2) is consistent, and N number of bale packing catalyst is loaded from top to bottom in described row inner axial tube
(2)。
Active catalyst (3) sendout in the tubulation is incremented by with the bale packing catalyst (2) for unit from top to bottom,
Increased amplitude follows following rule：
K=(an+1-an)/an
an+1For anThe amount of the active catalyst of one layer of bale packing below；
anFor the amount of the active catalyst of N layers bale packing；
N=1,2,3,4,5,6......n natural positive integer；
Wherein k：0 ＜ k ＜ 1,
As k=1, active catalyst is to be uniformly distributed in as whole tubulation；As 0 ＜ k ＜ 1 then along tubulation axial direction
Active catalyst is gradually increased in units of each bale packing, i.e., more arrives the bottom of reactor tubulation, each upper active catalytic of bale packing
Amount contained by agent is more, and is uniformly increased.
Effect of the present utility model is as follows：
The utility model packs catalyst by stainless steel ripple silk net and the flat screen phase for being uniformly distributed active catalyst
Superposition, which rolls, to be formed, the grain structure such as active catalyst design globulate, contained by tubulation axially each bale packing catalyst
Active catalytic dosage is gradually increased, changes the physical arrangement of catalyst, significantly improves the distribution shape of reaction mass
State and the type of flow, improve product quality, reduce impurity, reduce further energy consumption, material consumption, big for methanol oxidation industry
Solid foundation has been laid in scale development and production.
Brief description of the drawings
Fig. 1 is the hollow cylinder catalyst of prior art；
Fig. 2 is bale packing catalyst structure schematic diagram of the present utility model；
Fig. 3 is the schematic top plan view of Fig. 2 bale packing catalyst structure；
Fig. 4 is the bale packing non-volume state schematic diagram of catalyst structure of the present utility model；
Label in figure：
1- flat screens 2- packs catalyst 3- active catalyst 4- stainless steel ripple silk nets
Embodiment
Following examples are only to illustrate the utility model example to be clear, and not to reality of the present utility model
Apply the restriction of mode.For those of ordinary skill in the field, other can also be made on the basis of the following description
Various forms of changes or variation, and these belong to the obvious changes or variations that the utility model spirit is drawn and still located
Among the scope of protection of the utility model.
As shown in Fig. 2 the utility model is a kind of bale packing catalyst 2 of methanol oxidation, it includes stainless steel corrugation
Net 4, active catalyst 3, flat screen 1, described active catalyst 3 is evenly distributed on described flat screen 1, described
Stainless steel ripple silk net 4 is tiled with it after active catalyst 3 for being superimposed and stating in clad residence, by border seal, using one end as axle center
Roll into bale packing catalyst 2；Described active catalyst 3 is graininess, its diameter or peripheral minimum dimension be more than it is described not
The mesh diameter of rust steel ripple silk net 4 and flat screen 1, to prevent spilling；Described active catalyst 3 be spherical, bar shaped, cube
The bodily form or cylindrical particle multiple choices；The bale packing catalyst 2 is shown in Fig. 2 to be rolled into solid cylindrical shape, its is a diameter of >=
50 ㎜, it is highly >=100 ㎜；It is preferred that diameter >=80 ㎜, the ㎜ of height >=200；The further preferably ㎜ of diameter >=100, the ㎜ of height >=300；
3 doses of active catalytic on bale packing catalyst 2 cross section is uniformly distributed；The percentage by weight composition of the active catalyst 3
For： MOO3:60-78%, Fe2O3：20-39%, remaining composition are such as one of IIIA, IV A and VIII in the periodic table of elements
Kind or two oxides：0.1-2.0%；The proportioning of described two oxides is 0.1-1:1, preferably Al2O3；
A kind of combining structure of the bale packing catalyst of methanol oxidation, including tubulation, described tubulation internal diameter and the bundle
The diameter of bag catalyst 2 is consistent, and N number of bale packing catalyst 2 is loaded from top to bottom in described row inner axial tube.By described
Tubulation combination loading uses the bale packing catalyst 2.
The sendout of active catalyst 3 in the tubulation is incremented by units of the bale packing catalyst 2 from top to bottom, is increased
The amplitude added follows following rule：
K=(an+1-an)/an
an+1For anThe amount of the active catalyst of one layer of bale packing below；
anFor the amount of the active catalyst of N layers bale packing；
N=1,2,3,4,5,6......n natural positive integer；
Wherein k：0 ＜ k ＜ 1,
As k=1, active catalyst is to be uniformly distributed in as whole tubulation；As 0 ＜ k ＜ 1 then in the tubulation
The sendout of active catalyst 3 is incremented by units of the bale packing catalyst 2 from top to bottom, i.e., more arrives the bottom of reactor tubulation,
Amount contained by the active catalyst of the bale packing catalyst 2 is more, and is uniformly increased.
In use, oxidized reaction mass is methanol or is dimethyl ether, or it is dimethoxym ethane, or is two kinds therein or two
The reaction mass of the mixing of the kind above, by described bale packing catalyst 2, is aoxidized jointly.
Claims (7)
1. a kind of bale packing catalyst of methanol oxidation, including stainless steel ripple silk net (4), active catalyst (3), flat screen
(1), it is characterised in that described active catalyst (3) is evenly distributed on described flat screen (1), described stainless steel wave
Line silk screen is tiled with it after active catalyst (3) for being superimposed and stating in clad residence, and border seal rolls bundled using one end as axle center
Bag catalyst.
A kind of 2. bale packing catalyst of methanol oxidation according to claim 1, it is characterised in that described active catalytic
Agent (3) is graininess, and its diameter or peripheral minimum dimension are more than described stainless steel ripple silk net (4) and flat screen (1)
Mesh diameter.
A kind of 3. bale packing catalyst of methanol oxidation according to claim 2, it is characterised in that described active catalytic
Agent (3) is spherical, bar shaped, cube shaped or cylindrical particle.
A kind of 4. bale packing catalyst of methanol oxidation according to claim 1, it is characterised in that：The bale packing catalyst
(2) solid cylindrical shape is rolled into, its is a diameter of >=50 ㎜, its height is >=100 ㎜.
A kind of 5. bale packing catalyst of methanol oxidation according to claim 1, it is characterised in that：The bale packing catalyst
（2）Active catalyst on cross section is uniformly distributed.
A kind of 6. combining structure of the bale packing catalyst of methanol oxidation described in claim 1, it is characterised in that：Including row
Pipe, described tubulation internal diameter is consistent with the diameter of the bale packing catalyst (2), is loaded from top to bottom in described row inner axial tube
N number of bale packing catalyst (2).
A kind of 7. combining structure of the bale packing catalyst of methanol oxidation described in claim 6, it is characterised in that：The tubulation
In active catalyst (3) sendout from top to bottom with
The bale packing catalyst (2) is incremented by for unit, and increased amplitude follows following rule：K=(an+1-an)/an
an+1For anThe amount of the active catalyst of one layer of bale packing below；
anFor the amount of the active catalyst of N layers bale packing；
N=1,2,3,4,5,6......n natural positive integer；
Wherein k：0 ＜ k ＜ 1,
As k=1, active catalyst is to be uniformly distributed in as whole tubulation；It is then axially active along tubulation as 0 ＜ k ＜ 1
Catalyst is gradually increased in units of each bale packing, i.e., more arrives the bottom of reactor tubulation, each upper active catalyst institute of bale packing
The amount contained is more, and is uniformly increased.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720485329.0U CN206762897U (en) | 2017-05-04 | 2017-05-04 | A kind of bale packing catalyst of methanol oxidation and combinations thereof structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720485329.0U CN206762897U (en) | 2017-05-04 | 2017-05-04 | A kind of bale packing catalyst of methanol oxidation and combinations thereof structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206762897U true CN206762897U (en) | 2017-12-19 |
Family
ID=60649190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201720485329.0U Active CN206762897U (en) | 2017-05-04 | 2017-05-04 | A kind of bale packing catalyst of methanol oxidation and combinations thereof structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206762897U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108499493A (en) * | 2018-05-02 | 2018-09-07 | 西安纳瑞工控科技有限公司 | A kind of gas-liquid counter current reaction unit |
| WO2021223289A1 (en) * | 2020-05-08 | 2021-11-11 | 山东爱亿普环保科技股份有限公司 | Cylindrical porous carrier and method for preparing same, and catalyst and application thereof |
-
2017
- 2017-05-04 CN CN201720485329.0U patent/CN206762897U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108499493A (en) * | 2018-05-02 | 2018-09-07 | 西安纳瑞工控科技有限公司 | A kind of gas-liquid counter current reaction unit |
| CN108499493B (en) * | 2018-05-02 | 2024-05-14 | 西安纳瑞工控科技有限公司 | Gas-liquid countercurrent reaction device |
| WO2021223289A1 (en) * | 2020-05-08 | 2021-11-11 | 山东爱亿普环保科技股份有限公司 | Cylindrical porous carrier and method for preparing same, and catalyst and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN206762897U (en) | A kind of bale packing catalyst of methanol oxidation and combinations thereof structure | |
| CN102824890B (en) | Catalytic distillation filler with alternative flow structure | |
| CN103752253B (en) | Catalytic rectification filler with radial distribution capability | |
| CN103691387A (en) | Circularly-arranged catalytic distillation packing | |
| CN102862961A (en) | Novel extraction technology in process of preparing hydrogen peroxide by anthraquinone process | |
| CN106938195A (en) | A kind of bale packing catalyst of methanol oxidation and combinations thereof structure | |
| CN100431687C (en) | Regular packing of helical cylindrical net | |
| CN104587908A (en) | Catalyst filling structure applicable to large-tower-diameter catalytic rectifying column and usage thereof | |
| CN207041947U (en) | A kind of catalytic distillation module | |
| CN103894117A (en) | Method for structurally filing contact tubes of a bank of contact tubes | |
| CN104587946A (en) | Regular catalyst packing for reactive distillation column | |
| CN101306256B (en) | Catalyst distillation column internals for high effective mass transfer | |
| CN202446855U (en) | Efficient liquid-liquid extraction tower containing combined stuffing unit | |
| CN206868232U (en) | A kind of equipment of methanol oxidation | |
| CN105561911B (en) | Catalyst capsule filler and preparation method thereof in a kind of efficient catalytic rectifying tower | |
| CN105732281B (en) | Pre-depropanization pre-hydrogenation method for carbon-dioxide fraction | |
| CN205235942U (en) | Gas -liquid reaction device | |
| CN213049457U (en) | Loose-packed catalytic filler fixing structure of looped netowrk frame | |
| CN210314073U (en) | Device for preparing trioxymethylene by oxidizing methylal | |
| CN201894861U (en) | Catalyst distillation tower suitable for production of MTBE (methyl tertiary butyl ether) | |
| CN203990657U (en) | A kind of flow guiding type filler | |
| Weng et al. | Performance characteristics of a new spherical metal mesh packing | |
| CN109678120A (en) | A kind of hydrogenation reactor and method for hydrogenation of hydrogen dioxide solution production by anthraquinone process | |
| CN201030302Y (en) | Combined type plate-net filler | |
| CN211677767U (en) | Novel garland filler |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant |