CN206751663U - Lime slaking prepares the residual heat using device of calcium hydroxide refining - Google Patents

Lime slaking prepares the residual heat using device of calcium hydroxide refining Download PDF

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CN206751663U
CN206751663U CN201720585187.5U CN201720585187U CN206751663U CN 206751663 U CN206751663 U CN 206751663U CN 201720585187 U CN201720585187 U CN 201720585187U CN 206751663 U CN206751663 U CN 206751663U
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heat exchanger
lime
pulp
calcium hydroxide
tank
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邹林富
刘亚雄
雷水根
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Fujian Xihong Nanotechnology Co ltd
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FUJIAN HONGFENG NANO TECHNOLOGY Co Ltd
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    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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Abstract

The utility model discloses the residual heat using device that a kind of lime slaking prepares calcium hydroxide refining, including digestion machine, raw slurry aging tank, the lime bin on digestion machine, in addition to hot water cistern, buffer pool, pump for mortar transmission, heat exchanger, cyclone hydraulic separators, vibratory sieve, refining storage tank, normal temperature pond, high-pressure water-flushing device, back water pump.Reaction heat caused by lime slaking can be recycled using the device, effectively Resource Recycling Utilization, reduces energy consumption and production costs, and the impurity in calcium hydroxide refining can also be effectively removed, suitable for the production of nano-calcium carbonate.

Description

石灰消化制备氢氧化钙精浆的余热利用装置Waste heat utilization device for preparing calcium hydroxide fine pulp from lime digestion

技术领域technical field

本实用新型涉及纳米碳酸钙生产技术领域,具体涉及石灰消化制备氢氧化钙精浆的余热利用装置。The utility model relates to the technical field of nano-calcium carbonate production, in particular to a waste heat utilization device for preparing calcium hydroxide fine pulp by digesting lime.

背景技术Background technique

纳米碳酸钙目前国内采用的方法通常采用石灰石煅烧得到石灰,石灰用水消化,精制过筛后,再用窑气碳化的方法得到纳米碳酸钙。碳化法制备纳米碳酸钙的工艺中,石灰的消化反应用水的温度对后续生产有很大的影响,采用高温消化石灰石,得到的石灰乳产率高,且石灰乳较为细腻、分散性好。在碳化工艺相同的条件下,高温消化得到的石灰乳经碳化制备的碳酸钙产品比表面积较高,二次团聚后的粒径小,并且吸油值较低。一般石灰消化用水的温度在45~65℃为最好,石灰消化时的温度越高,可以快速将石灰胀开,得到粒度细、分散性好的石灰乳,并能提高石灰乳的产率,石灰乳的粒子较为细腻,工业化生产允许消化反应在小于100℃下进行。目前,石灰消化制备氢氧化钙精浆所用热水主要采用锅炉或者蒸汽加热冷水得到,不足之处在于:锅炉和蒸汽加热设备投资和能耗较大,生产成本高。同时石灰中含有许多杂质,一类是粒度较大的生烧石灰石,未消化的过烧石灰和煤渣等,另一类是密度较大的SiO2、AL2O3、Fe2O3等,这些杂质如果不除去,将会影响产量质量。Nano-calcium carbonate is currently used domestically to obtain lime by calcination of limestone, digested with water, refined and sieved, and then carbonized with kiln gas to obtain nano-calcium carbonate. In the process of preparing nano-calcium carbonate by carbonization, the temperature of the water used for the digestion of lime has a great influence on the subsequent production. Using high-temperature digestion of limestone, the yield of milk of lime is high, and the milk of lime is relatively fine and dispersible. Under the same conditions of the carbonization process, the calcium carbonate product prepared by carbonization of milk of lime obtained by high-temperature digestion has a higher specific surface area, a smaller particle size after secondary agglomeration, and a lower oil absorption value. Generally, the temperature of water for lime digestion is best at 45-65°C. The higher the temperature of lime digestion, the faster the lime can be expanded, and the lime milk with fine particle size and good dispersibility can be obtained, and the yield of lime milk can be increased. The particles of lime milk are relatively fine, and industrial production allows the digestion reaction to be carried out at less than 100°C. At present, the hot water used for lime digestion to prepare calcium hydroxide concentrate is mainly obtained by heating cold water with boilers or steam. The disadvantages are: the investment and energy consumption of boilers and steam heating equipment are large, and the production cost is high. At the same time, lime contains many impurities, one is raw burnt limestone with larger particle size, undigested burnt lime and cinder, etc., and the other is SiO 2 , Al 2 O 3 , Fe 2 O 3 with high density, etc. If these impurities are not removed, it will affect the yield quality.

实用新型内容Utility model content

本实用新型所解决的技术问题是针对上述不足,提供一种石灰消化制备氢氧化钙精浆的余热利用装置,应用该装置能将石灰消化产生的反应热进行回收利用,有效地循环利用资源,降低能耗和生产成本,还可以有效去除氢氧化钙精浆中的杂质,适用于纳米碳酸钙的生产。The technical problem solved by the utility model is to provide a kind of waste heat utilization device for lime digestion to prepare calcium hydroxide fine pulp, which can recycle the reaction heat generated by lime digestion and effectively recycle resources. It reduces energy consumption and production cost, and can effectively remove impurities in calcium hydroxide fine pulp, and is suitable for the production of nanometer calcium carbonate.

本实用新型所采用的技术方案是:石灰消化制备氢氧化钙精浆的余热利用装置,包括消化机、生浆陈化罐、设于消化机上的石灰料斗,还包括热水蓄水池、缓冲池、输浆泵、换热器、旋液分离器、振动筛、精浆存放罐、常温水池、高压冲水装置、回水泵;热水蓄水池与消化机的进料端相连接,消化机的出料端与缓冲池相连接,缓冲池还与生浆陈化罐相连接,生浆陈化罐通过输浆泵、进浆管与换热器相连接,换热器的出浆口通过管道与旋液分离器相连接,旋液分离器通过管道与振动筛连接,振动筛的出料口通过管道与精浆存放罐相连接;所述高压冲水装置与换热器的进浆管相连接;所述常温水池通过管道与换热器的进水口相连接,换热器的出水口通过回水泵、管道与热水蓄水池相连接。The technical scheme adopted by the utility model is: a waste heat utilization device for preparing calcium hydroxide fine pulp by digesting lime, including a digester, a raw pulp aging tank, a lime hopper installed on the digester, and a hot water storage tank, a buffer Pool, slurry pump, heat exchanger, hydrocyclone, vibrating screen, fine pulp storage tank, normal temperature pool, high-pressure flushing device, return pump; the hot water reservoir is connected to the feed end of the digester, The discharge end of the machine is connected with the buffer tank, and the buffer tank is also connected with the raw pulp aging tank, and the raw pulp aging tank is connected with the heat exchanger through the slurry pump and the slurry inlet pipe, and the slurry outlet of the heat exchanger The hydrocyclone is connected with the hydrocyclone through the pipeline, the hydrocyclone is connected with the vibrating screen through the pipeline, and the outlet of the vibrating screen is connected with the fine pulp storage tank through the pipeline; The pipes are connected; the normal temperature water pool is connected with the water inlet of the heat exchanger through the pipe, and the water outlet of the heat exchanger is connected with the hot water storage tank through the return pump and the pipe.

所述换热器为板式换热器。The heat exchanger is a plate heat exchanger.

所述振动筛为二级旋振筛,第一级筛网目数为150~250目,第二级筛网目数为300~350目。The vibrating sieve is a secondary rotary vibrating sieve, the mesh number of the first stage is 150-250 mesh, and the mesh number of the second stage is 300-350 mesh.

本实用新型的有益效果是:1、本实用新型通过设置热水蓄水池、缓冲池、换热器、旋液分离器、振动筛、常温水池等机构,石灰消化得到的浆料经缓冲池后进入生浆陈化罐,然后用输浆泵将陈化后约50~70℃的生浆输入换热器中与常温水进行换热后可降到18~28℃,经振动筛过筛后可直接用于碳化生成纳米碳酸钙,不需要用冷水机组进行冷却,节省了电能;同时,常温水池的常温水通过在换热器中与温度较高的热浆进行热交换,可得到45~65℃的热水,再流到热水蓄水池中可用于消化石灰,可以省去对热水蓄水池中水的加热,降低能耗和生产成本;2、本实用新型中换热器的进浆管连接有高压冲水装置,换热器每次热交换后,可用高压冲水装置冲洗换热器和连接管道,使其不易结垢,延长换热器和连接管道的使用寿命;3、本实用新型通过设置二级旋振筛,第一级筛网目数为150~250目,第二级筛网目数为300~350目,可以有效去除氢氧化钙浆料中的杂质,得到细度合格的氢氧化钙精浆。The beneficial effects of the utility model are: 1. The utility model is provided with mechanisms such as a hot water storage tank, a buffer tank, a heat exchanger, a hydrocyclone, a vibrating screen, and a normal temperature pool, and the slurry obtained by lime digestion passes through the buffer tank. Then enter the raw pulp aging tank, and then use the slurry pump to transfer the aged pulp at about 50-70°C into the heat exchanger to exchange heat with normal temperature water and then reduce it to 18-28°C, and pass through the vibrating sieve. Afterwards, it can be directly used for carbonization to generate nano-calcium carbonate, which does not need to be cooled by a chiller, which saves electric energy; at the same time, the normal-temperature water in the normal-temperature pool is exchanged with the hot slurry with a higher temperature in the heat exchanger to obtain 45 The hot water at ~65°C flows into the hot water storage tank and can be used to digest lime, which can save the heating of the water in the hot water storage tank and reduce energy consumption and production costs; 2. Heat exchange in the utility model The slurry inlet pipe of the machine is connected with a high-pressure flushing device. After each heat exchange of the heat exchanger, the high-pressure flushing device can be used to flush the heat exchanger and the connecting pipes so that it is not easy to scale and prolong the service life of the heat exchanger and the connecting pipes 3. The utility model is provided with a secondary rotary vibrating screen, the mesh number of the first stage screen is 150-250 mesh, and the mesh number of the second stage screen is 300-350 mesh, which can effectively remove calcium hydroxide slurry. Impurities are removed to obtain calcium hydroxide fine pulp with qualified fineness.

附图说明Description of drawings

图1为石灰消化制备氢氧化钙精浆的余热利用装置的结构示意图。Fig. 1 is a schematic structural diagram of a waste heat utilization device for preparing calcium hydroxide fine slurry by digesting lime.

符号说明:1-石灰料斗;2-热水蓄水池;3-消化机;4-缓冲池;5-生浆陈化罐;6-换热器;7-旋液分离器;8-振动筛;9-精浆存放罐,10-常温水池;11-高压冲水装置;12-搅拌装置;13-进浆管;14-输浆泵;15-回水泵。Explanation of symbols: 1-lime hopper; 2-hot water storage tank; 3-digester; 4-buffer tank; 5-raw pulp aging tank; 6-heat exchanger; 7-hydrocyclone; 8-vibration Sieve; 9-fine pulp storage tank, 10-normal temperature pool; 11-high-pressure flushing device; 12-stirring device; 13-slurry inlet pipe; 14-slurry delivery pump;

具体实施方式detailed description

下面结合附图与具体实施对本实用新型做进一步的说明。Below in conjunction with accompanying drawing and concrete implementation the utility model is described further.

石灰消化制备氢氧化钙精浆的余热利用装置,如图1所示,包括消化机3、生浆陈化罐5、设于消化机3上的石灰料斗1、热水蓄水池2、缓冲池4、输浆泵14、换热器6、旋液分离器7、振动筛8、精浆存放罐9、常温水池10、高压冲水装置11、回水泵15等机构。热水蓄水池2与消化机3的进料端相连接,消化机3的出料端与缓冲池4相连接,缓冲池4还与生浆陈化罐5相连接,生浆陈化罐5通过输浆泵14、进浆管13与换热器6相连接,换热器6的出浆口通过管道与旋液分离器7相连接,旋液分离器7通过管道与振动筛8连接,振动筛8的出料口通过管道与精浆存放罐9相连接;所述高压冲水装置11与换热器6的进浆管13相连接;所述常温水池10通过管道与换热器6的进水口相连接,换热器6的出水口通过回水泵15、管道与热水蓄水池2相连接。所述换热器6为板式换热器。所述振动筛8为二级旋振筛,第一级筛网目数为150~250目,第二级筛网目数为300~350目。所述精浆存放罐9内设有搅拌装置12。The waste heat utilization device for lime digestion to prepare calcium hydroxide fine pulp, as shown in Figure 1, includes a digester 3, a raw pulp aging tank 5, a lime hopper 1 installed on the digester 3, a hot water storage tank 2, a buffer Pool 4, pulp delivery pump 14, heat exchanger 6, hydrocyclone 7, vibrating screen 8, fine pulp storage tank 9, normal temperature pool 10, high pressure flushing device 11, return water pump 15 and other mechanisms. The hot water reservoir 2 is connected to the feed end of the digester 3, the discharge end of the digester 3 is connected to the buffer pool 4, the buffer pool 4 is also connected to the raw pulp aging tank 5, and the raw pulp aging tank 5 Connect the heat exchanger 6 through the slurry pump 14 and the slurry inlet pipe 13, the slurry outlet of the heat exchanger 6 is connected with the hydrocyclone 7 through the pipeline, and the hydrocyclone 7 is connected with the vibrating screen 8 through the pipeline , the discharge port of the vibrating screen 8 is connected with the fine pulp storage tank 9 through a pipeline; the high-pressure flushing device 11 is connected with the slurry inlet pipe 13 of the heat exchanger 6; the normal temperature pool 10 is connected with the heat exchanger through a pipeline The water inlet of 6 is connected, and the water outlet of heat exchanger 6 is connected with hot water storage tank 2 through backwater pump 15, pipeline. The heat exchanger 6 is a plate heat exchanger. The vibrating sieve 8 is a two-stage rotary vibrating sieve, the mesh number of the first stage is 150-250 mesh, and the mesh number of the second stage is 300-350 mesh. The seminal pulp storage tank 9 is provided with a stirring device 12 .

本实用新型的工作原理如下:石灰在消化机3中消化得到的浆料经缓冲池4后进入生浆陈化罐5,然后用输浆泵14将陈化后约50~70℃的生浆输入换热器6中与常温水进行换热,生浆可降到18~28℃,再经振动筛8过筛后可直接用于碳化生成纳米碳酸钙;同时,常温水池10的常温水通过在换热器6中与温度较高的热浆进行热交换,可得到45~65℃的热水,再用回水泵15输到热水蓄水池2中可用于消化石灰,可以省去对热水蓄水池2中水的加热,降低能耗和生产成本。The working principle of the utility model is as follows: the slurry digested by the lime in the digester 3 enters the raw slurry aging tank 5 after passing through the buffer tank 4, and then the raw slurry of about 50-70 °C after aging is processed by the slurry pump 14. Enter the heat exchanger 6 to exchange heat with normal temperature water, the raw slurry can be reduced to 18-28 °C, and then sieved by the vibrating screen 8, it can be directly used for carbonization to generate nano-calcium carbonate; at the same time, the normal temperature water in the normal temperature pool 10 passes through In the heat exchanger 6, heat exchange is carried out with the hot slurry with a higher temperature to obtain hot water at 45-65°C, which is then transported to the hot water storage tank 2 by the return water pump 15 and can be used to digest lime, which can save the need for The heating of water in the hot water reservoir 2 reduces energy consumption and production costs.

上述实施例仅为本实用新型的具体实施方式,但本实用新型的设计构思并不局限于此,凡利用此构思对本实用新型进行非实质性的改动,均应属于本实用新型的保护范围。The above-mentioned embodiments are only specific implementations of the present utility model, but the design concept of the present utility model is not limited thereto, and any insubstantial changes made to the utility model by using this concept should belong to the protection scope of the present utility model.

Claims (3)

1.石灰消化制备氢氧化钙精浆的余热利用装置,其特征在于,包括消化机、生浆陈化罐、设于消化机上的石灰料斗,还包括热水蓄水池、缓冲池、输浆泵、换热器、旋液分离器、振动筛、精浆存放罐、常温水池、高压冲水装置、回水泵;热水蓄水池与消化机的进料端相连接,消化机的出料端与缓冲池相连接,缓冲池还与生浆陈化罐相连接,生浆陈化罐通过输浆泵、进浆管与换热器相连接,换热器的出浆口通过管道与旋液分离器相连接,旋液分离器通过管道与振动筛连接,振动筛的出料口通过管道与精浆存放罐相连接;所述高压冲水装置与换热器的进浆管相连接;所述常温水池通过管道与换热器的进水口相连接,换热器的出水口通过回水泵、管道与热水蓄水池相连接。1. The waste heat utilization device for lime digestion and preparation of calcium hydroxide fine pulp is characterized in that it includes a digester, a raw pulp aging tank, a lime hopper arranged on the digester, and also includes a hot water storage tank, a buffer tank, and a pulp delivery tank. Pumps, heat exchangers, hydrocyclones, vibrating screens, fine pulp storage tanks, normal temperature pools, high-pressure flushing devices, return pumps; hot water storage tanks are connected to the feed end of the digester, and the discharge of the digester The end is connected with the buffer pool, and the buffer pool is also connected with the raw pulp aging tank. The raw pulp aging tank is connected with the heat exchanger through the slurry pump and the slurry inlet pipe. The liquid separator is connected, the hydrocyclone is connected with the vibrating screen through a pipeline, and the outlet of the vibrating screen is connected with the fine pulp storage tank through a pipeline; the high-pressure flushing device is connected with the pulp inlet pipe of the heat exchanger; The normal temperature pool is connected to the water inlet of the heat exchanger through a pipeline, and the water outlet of the heat exchanger is connected to a hot water storage tank through a return pump and a pipeline. 2.根据权利要求1所述的石灰消化制备氢氧化钙精浆的余热利用装置,其特征在于:所述换热器为板式换热器。2. The waste heat utilization device for preparing calcium hydroxide fine slurry by digesting lime according to claim 1, characterized in that: the heat exchanger is a plate heat exchanger. 3.根据权利要求1所述的石灰消化制备氢氧化钙精浆的余热利用装置,其特征在于:所述振动筛为二级旋振筛,第一级筛网目数为150~250目,第二级筛网目数为300~350目。3. The waste heat utilization device for preparing calcium hydroxide fine pulp by lime digestion according to claim 1, characterized in that: the vibrating sieve is a secondary rotary vibrating sieve, the mesh number of the first stage is 150-250 mesh, The mesh number of the second stage screen is 300-350 mesh.
CN201720585187.5U 2017-05-24 2017-05-24 Lime slaking prepares the residual heat using device of calcium hydroxide refining Active CN206751663U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863113A (en) * 2017-05-15 2018-11-23 沈阳铝镁设计研究院有限公司 A method of improving lime milk concentration and quality
CN109539747A (en) * 2018-11-30 2019-03-29 吴祥初 A kind of technique that energy-saving tunnel-kiln type dries chamber system and its multiple dry code firing is utilized to make brick

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863113A (en) * 2017-05-15 2018-11-23 沈阳铝镁设计研究院有限公司 A method of improving lime milk concentration and quality
CN109539747A (en) * 2018-11-30 2019-03-29 吴祥初 A kind of technique that energy-saving tunnel-kiln type dries chamber system and its multiple dry code firing is utilized to make brick

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