CN206538195U - A kind of yellow phosphorus gasification combustion furnace - Google Patents

A kind of yellow phosphorus gasification combustion furnace Download PDF

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Publication number
CN206538195U
CN206538195U CN201720096830.8U CN201720096830U CN206538195U CN 206538195 U CN206538195 U CN 206538195U CN 201720096830 U CN201720096830 U CN 201720096830U CN 206538195 U CN206538195 U CN 206538195U
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CN
China
Prior art keywords
heat exchange
phosphorus
atomising head
exchange jacket
furnace
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Expired - Fee Related
Application number
CN201720096830.8U
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Chinese (zh)
Inventor
徐先海
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HUBEI YAOZHIHE CHEMICAL Co Ltd
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HUBEI YAOZHIHE CHEMICAL Co Ltd
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Priority to CN201720096830.8U priority Critical patent/CN206538195U/en
Application granted granted Critical
Publication of CN206538195U publication Critical patent/CN206538195U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

A kind of yellow phosphorus gasification combustion furnace, for the liquid phosphor burning in phosphorus-melting groove to be generated into phosphorous gas, it includes:It is internally formed in the body of heater of a combustion chamber, sidewall of the furnace body and is provided with flame retardant coating, the first heat exchange jacket is arranged with outside sidewall of the furnace body, the first heat exchange jacket has a water inlet and a delivery port, and sidewall of the furnace body top is provided with an escape pipe;It is arranged on the circular fixed seat on the base of body of heater;The annular turntable of fixed seat upper end can be arranged on circumferentially rotatablely;The atomising head at annular turntable upper end center is fixedly installed on, the spout direction of atomising head is tilted to be set upward, and the import of atomising head is connected by a feed tube with the outlet of a compression pump, and the import of compression pump passes through pipeline communication to phosphorus-melting groove;And it is uniform be arranged around around atomising head and multiple air nozzles that spout is set upward, air nozzle is fixed in fixed seat.It can increase operation rate and product quality, also by air-spray formation air curtain the sour glue to be formed can be prevented to be deposited on furnace bottom.

Description

A kind of yellow phosphorus gasification combustion furnace
Technical field
The utility model is related to phosphorous chemical industry field, and in particular to a kind of yellow phosphorus gasification combustion furnace.
Background technology
Phosphoric acid is the important component of chemical industry, is important basic chemical industry raw material.The production method of phosphoric acid is divided into Two kinds of thermal phosphoric acid and phosphoric acid by wet process.Thermal phosphoric acid refers to using rock phosphate in powder as raw material, is first processed into element phosphor, then added with element phosphor The phosphoric acid of work;Phosphoric acid by wet process refers to using rock phosphate in powder and inorganic acid as raw material, the phosphoric acid directly processed.Phosphoric acid by wet process is thick Product is impure more, mainly for the production of fertilizer;Thermal phosphoric acid but has the advantages that product design height, impurity are few, can be used for Manufacture food and PHOSPHORIC ACID TECH.GRADE product salt.The production method of thermal phosphoric acid has three kinds:Method one is directly fired with phosphorous furnace gas The complete combustion method of phosphoric acid processed is absorbed after burning with water;Method two is to mix phosphorous furnace gas with appropriate air, makes phosphorus steam and phosphorus Change hydrogen to be oxidized, then gas oxidation products phosphorus pentoxide is absorbed with phosphoric acid,diluted and phosphoric acid is made;Method three be by Phosphorus in phosphorous furnace gas is condensed into liquid phosphorus, and phosphorus pentoxide is generated with air burning, is then absorbed with water (or acid) and phosphorus is made The liquid phosphorus combustion method of acid.At present, it is many using liquid phosphorus combustion method production thermal phosphoric acid.It is existing in phosphorous acid production by BEP Phosphorus supply method is high-order phosphorus supply method.I.e. with high-pressure pump or compressed air by after the molten phosphorus that phosphorus-melting groove is melted is transported to head tank, Combustion furnace epimere, spraying and burning are flowed into high-pressure injection.The advantage of the method is:Molten phosphorus is through sprinkling, and burning is abundant;But its shortcoming It is:Because using dynamic power machine conveying, one is to increase the input of equipment funds;Two be to increase energy consumption;Three be delivery safety It can require high.In phosphorous acid production by BEP, the quality of combustion position of the yellow phosphorus in combustion furnace, to the quality and phosphorus of phosphoric acid product Yield important.Yellow phosphorus burning is insufficient, may cause the color of phosphoric acid product yellow, readily oxidizable substance partially it is exceeded, The problems such as chimney emits tobacco, the sour glue in combustion furnace bottom is excessive.
At present, in the prior art, it is many using liquid phosphorus combustion method production thermal phosphoric acid.Use high-pressure pump or compressed air By after the molten phosphorus that phosphorus-melting groove is melted is transported to head tank, combustion furnace burning is flowed into high-pressure injection.Though yellow phosphorus is with height in the method The mode of pressure injection enters combustion furnace, and dispersiveness preferably, but is in still droplet-like into the yellow phosphorus of combustion furnace, and it is difficult to reach with air To the state fully contacted, and then the combustion efficiency of yellow phosphorus is have impact on to a certain extent.
Utility model content
To solve the above problems, the utility model is directed to providing a kind of yellow phosphorus gasification combustion furnace, yellow phosphorus can be made More fully burn, to improve its utilization rate, and prevent the sour glue deposition of furnace bottom.
A kind of yellow phosphorus gasification combustion furnace that the utility model is provided, for the liquid phosphor burning generation in phosphorus-melting groove to be contained Phosphorus gas, it includes:It is internally formed in the body of heater of a combustion chamber, the sidewall of the furnace body and is provided with flame retardant coating, the sidewall of the furnace body Outer to be arranged with the first heat exchange jacket, first heat exchange jacket has a water inlet and a delivery port, the sidewall of the furnace body top It is provided with an escape pipe;It is arranged on the circular fixed seat on the base of body of heater;The fixed seat can be arranged on circumferentially rotatablely The annular turntable of upper end;It is fixedly installed on the atomising head at the annular turntable upper end center, the spout direction of the atomising head Inclination is set upward, and the import of the atomising head is connected by a feed tube with the outlet of a compression pump, the compression pump Import pass through pipeline communication to the phosphorus-melting groove;And be uniformly arranged around around the atomising head and spout is set upward Multiple air nozzles, the air nozzle is fixed in the fixed seat.
Preferably, be arranged with the second heat exchange jacket outside the phosphorus-melting groove, second heat exchange jacket have a water inlet and One delivery port, the delivery port of second heat exchange jacket is connected with the water inlet of first heat exchange jacket, and described first changes The delivery port of thermal jacket is connected with the water inlet of second heat exchange jacket.
Preferably, the spout direction of the atomising head and the angle of vertical direction are less than 25 degree.
Preferably, the spout direction of the atomising head and the angle of vertical direction are 10~25 degree.
Brief description of the drawings
Fig. 1 is the structural representation of the yellow phosphorus gasification combustion furnace of a preferred embodiments.
Embodiment
The technical solution of the utility model is clearly and completely described below in conjunction with accompanying drawing.In the utility model Description in, it is necessary to explanation, term " " center ", " on ", " under ", "left", "right", " vertical ", " level ", " interior ", " outer " Orientation or position relationship Deng instruction are, based on orientation shown in the drawings or position relationship, to be for only for ease of and describe this practicality newly Type and simplified description, rather than instruction or the signified device of hint or element must be with specific orientation, with specific orientation Construction and operation, therefore it is not intended that to limitation of the present utility model.In addition, term " first ", " second ", " the 3rd " are only used In description purpose, and it is not intended that instruction or hint face ground importance.
, it is necessary to which explanation, unless otherwise clearly defined and limited, term " are pacified in description of the present utility model Dress ", " connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integratedly Connection;Can be mechanical connection or electrical connection;Can be joined directly together, can also be indirectly connected to by intermediary, It can be the connection of two element internals.For the ordinary skill in the art, above-mentioned art can be understood with concrete condition Concrete meaning of the language in the utility model.
Refer to Fig. 1.
The preferred embodiment of the utility model one and yellow phosphorus gasification combustion furnace, it is used for the liquid phosphor burning in phosphorus-melting groove Generate phosphorous gas.It is specifically included:Be internally formed in the body of heater 11 of a combustion chamber (unmarked), the side wall of body of heater 11 be provided with it is resistance to The first heat exchange jacket 14 is arranged with outside fire bed 13, the side wall of body of heater 11, the first heat exchange jacket 14 has a water inlet 14a and a water outlet Mouth 14b, the side wall upper part of body of heater 11 is provided with an escape pipe 15;It is arranged on the circular fixed seat 16 on the base 12 of body of heater 11;Can The annular turntable 18 of the upper end of fixed seat 16 is arranged on circumferentially rotatablely;It is fixedly installed on the mist at the annular upper end center of turntable 18 Change first 19, the spout direction of atomising head 19 is tilted to be set upward, the import of atomising head 19 passes through a feed tube 190 and a compression The outlet of pump (not shown) is connected, and the import of compression pump is communicated to phosphorus-melting groove (not shown) by pipeline (not shown);And water Uniform in plane to be arranged around multiple air nozzles 17 that around atomising head 19 and spout is set upward, air, which sprays 17 mouths, to be fixed In fixed seat.
So, made from phosphorus-melting groove by atomising head and come liquid phosphorus be atomized into phosphorus mist, then be aided with multiple air of surrounding Nozzle, can make phosphorus be sufficiently mixed and burnt to increase operation rate and furnace gas quality with air;It can also pass through air simultaneously Fluidic vectoring thrust air curtain, prevents the sour glue to be formed to be deposited on furnace bottom.
In some other embodiments, it is preferable that the second heat exchange jacket (not shown) is arranged with outside phosphorus-melting groove, second changes Thermal jacket has a water inlet (not shown) and a delivery port (not shown), and the delivery port of the second heat exchange jacket and the first heat exchange are pressed from both sides The water inlet of set is connected, and the delivery port of the first heat exchange jacket is connected with the water inlet of the second heat exchange jacket.So, Ke Yitong Cross in the second heat exchange jacket from combustion process draw heat and be allowed to fusing for yellow phosphorus, therefore, it is possible to relative reduction energy Consumption.
In some other embodiments, it is preferable that the spout direction of atomising head 19 and the angle of vertical direction be less than 25 degree;It is highly preferred that the spout direction of atomising head and the angle of vertical direction are 10~25 degree.So, additionally it is possible to make phosphorus mist with Effect forms turbulent flow between air-spray, further improves both mixabilities.
The non-detailed portion of other in the utility model belongs to prior art, therefore will not be repeated here.
Finally it should be noted that:Various embodiments above is only limited to illustrate the technical solution of the utility model, rather than to it System;Although the utility model is described in detail with reference to foregoing embodiments, one of ordinary skill in the art should Understand:It can still modify to the technical scheme described in foregoing embodiments, or to which part or whole Technical characteristic carries out equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is departed from this practicality newly The scope of each embodiment technical scheme of type.

Claims (4)

1. a kind of yellow phosphorus gasification combustion furnace, for the liquid phosphor burning in phosphorus-melting groove to be generated into phosphorous gas, it is characterised in that Including:
It is internally formed in the body of heater of a combustion chamber, the sidewall of the furnace body and is provided with flame retardant coating, is arranged with outside the sidewall of the furnace body One heat exchange jacket, first heat exchange jacket has a water inlet and a delivery port, and the sidewall of the furnace body top is provided with one and gone out Tracheae;
It is arranged on the circular fixed seat on the base of body of heater;
The annular turntable of the fixed seat upper end can be arranged on circumferentially rotatablely;
The atomising head at the annular turntable upper end center is fixedly installed on, the spout direction of the atomising head is tilted to be set upward Put, the import of the atomising head is connected by a feed tube with the outlet of a compression pump, and the import of the compression pump passes through pipe Road is communicated to the phosphorus-melting groove;
And multiple air nozzles that around the atomising head and spout is set upward are uniformly arranged around, the air nozzle is consolidated It is scheduled in the fixed seat.
2. yellow phosphorus gasification combustion furnace as claimed in claim 1, it is characterised in that the second heat exchange folder is arranged with outside the phosphorus-melting groove Set, second heat exchange jacket has a water inlet and a delivery port, the delivery port of second heat exchange jacket and described first The water inlet of heat exchange jacket is connected, and the delivery port of first heat exchange jacket is connected with the water inlet of second heat exchange jacket It is logical.
3. yellow phosphorus gasification combustion furnace as claimed in claim 2, it is characterised in that the spout direction of the atomising head and vertical side To angle be less than 25 degree.
4. yellow phosphorus gasification combustion furnace as claimed in claim 3, it is characterised in that the spout direction of the atomising head and vertical side To angle be 10~25 degree.
CN201720096830.8U 2017-01-22 2017-01-22 A kind of yellow phosphorus gasification combustion furnace Expired - Fee Related CN206538195U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720096830.8U CN206538195U (en) 2017-01-22 2017-01-22 A kind of yellow phosphorus gasification combustion furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720096830.8U CN206538195U (en) 2017-01-22 2017-01-22 A kind of yellow phosphorus gasification combustion furnace

Publications (1)

Publication Number Publication Date
CN206538195U true CN206538195U (en) 2017-10-03

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Family Applications (1)

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CN201720096830.8U Expired - Fee Related CN206538195U (en) 2017-01-22 2017-01-22 A kind of yellow phosphorus gasification combustion furnace

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113942985A (en) * 2021-10-15 2022-01-18 马有苏夫 Yellow phosphorus gasification combustion furnace

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113942985A (en) * 2021-10-15 2022-01-18 马有苏夫 Yellow phosphorus gasification combustion furnace

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GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20171003

Termination date: 20180122