CN206529377U - A kind of high salt high-COD waste water processing and resource recovery device - Google Patents

A kind of high salt high-COD waste water processing and resource recovery device Download PDF

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Publication number
CN206529377U
CN206529377U CN201720180177.3U CN201720180177U CN206529377U CN 206529377 U CN206529377 U CN 206529377U CN 201720180177 U CN201720180177 U CN 201720180177U CN 206529377 U CN206529377 U CN 206529377U
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China
Prior art keywords
water
tank
pump
pole
elevator pump
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Expired - Fee Related
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CN201720180177.3U
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Chinese (zh)
Inventor
刘瑞聪
于德强
赵凤美
王云钟
柯爌琼
徐凯
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QINGDAO NORTH ENERGY AND ENVIRONMENT CO., LTD.
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Qingdao Bluevale Chemical Co Ltd
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Abstract

The utility model discloses a kind of processing of high salt high-COD waste water and recycling retracting device, including wastewater tank, the first elevator pump, cartridge filter, pole-reversing electroosmosis system, regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump, evaporated crystallization device, fresh water tanks, the 3rd elevator pump, MBR devices, clarified water pump and clear water water tank;Wastewater tank water side passes sequentially through the first elevator pump and cartridge filter and is connected with pole-reversing electroosmosis system water inlet end, pole-reversing electroosmosis system concentrated water water side passes sequentially through regulating reservoir and coagulative precipitation tank and is connected with concentrated water water tank, concentrated water water tank is connected by the second elevator pump with evaporated crystallization device, pole-reversing electroosmosis system fresh water outlet end passes sequentially through fresh water tanks and the 3rd elevator pump is connected with MBR device water inlet ends, and MBR devices water side is connected by clarified water pump with clear water water tank.Biochemical treatment process is placed on technique rear end, it is to avoid inhibitory action of the salt content to microorganism;Stable effluent quality, realizes the zero-emission of waste water.

Description

A kind of high salt high-COD waste water processing and resource recovery device
Technical field
The utility model belongs to technical field of sewage, and in particular to a kind of high-salt wastewater processing is filled with resource reclaim Put, be particularly suitable for the processing of high COD, high slat-containing wastewater.
Background technology
It is (dense when salt that the industries such as steel, coal chemical industry, weaving, papermaking and natural gas produce substantial amounts of high slat-containing wastewater every year Degree>When 1%, referred to as high slat-containing wastewater), contain substantial amounts of organic matter toward contact in these waste water, in order to remove in waste water Organic matter, reduction salinity, conventional processes mentality of designing is usually first organics removal desalination again.Biochemical process is conventional drop The method for solving organic matter, makes yet with the too high microbial activity easily to front end biochemical treatment process of the salt content in waste water Into influence;Hyperfiltration is one of conventional desalinating process, but reverse osmosis membrane easily goes out in processing salt content high waste water Existing calcium ions and magnesium ions fouling, counter-infiltration osmotic pressure height cause energy consumption to increase, while the problem of there is concentrated water discharge.
In recent years, electric drive membrane technology is led with being widely used in Industrial Wastewater Treatment, desalinization, medical waste water processing etc. Domain, the processing to brine waste achieves good effect.As every profession and trade is got over to the quality and horsepower requirements of product material Come higher, the superiority of homogeneous electric drive film is increasingly displayed.Homogeneous electric drive film disclosure satisfy that the processing of a variety of feed liquids It is required that, current efficiency high, energy consumption low, selective penetrated property good, the rate of recovery high the features such as small with membrane surface resistance.MBR techniques are one Plant the new water technology being combined by film separation unit with biological processing unit.The Process for Effluent water quality high-quality stable, is remained Remaining sludge quantity is few, and floor space is small, easy to operate.The production water of electric drive film can further be handled by MBR techniques, and water outlet can It is used as industrial water reuse.
The content of the invention
The purpose of this utility model is processing and the resource recovery device for providing a kind of high slat-containing wastewater, solves existing High-salt wastewater microorganism in processing procedure is easily suppressed, and bioactivity reduction, reverse osmosis unit front-end processing technique is answered It is miscellaneous.
In order to solve the above problems, the processing of high salt high-COD waste water and recycling retracting device that the utility model is related to, bag Include wastewater tank, the first elevator pump, cartridge filter, pole-reversing electroosmosis system, regulating reservoir, coagulative precipitation tank, concentrated water water tank, Second elevator pump, evaporated crystallization device, fresh water tanks, the 3rd elevator pump, MBR devices, clarified water pump and clear water water tank;Waste water water storage Case water side passes sequentially through the first elevator pump and cartridge filter and is connected with pole-reversing electroosmosis system water inlet end, pole-reversing electroosmosis system System concentrated water water side passes sequentially through regulating reservoir and coagulative precipitation tank and is connected with concentrated water water tank, concentrated water water tank by the second elevator pump and Evaporated crystallization device is connected, and pole-reversing electroosmosis system fresh water outlet end passes sequentially through fresh water tanks and the 3rd elevator pump and filled with MBR Water inlet end connection is put, MBR devices water side is connected by clarified water pump with clear water water tank.
Further, the pole-reversing electroosmosis system that the utility model is related to uses antipollution homogeneous ion-exchange membrane.
Further, the high salt high-COD waste water processing that the utility model is related to also includes anti-clear with recycling retracting device System is washed, back cleaning system includes cleaning pump, cleaning case and water pump, cleaning case water side and the connection of cleaning pump water inlet end, clearly Wash pump and circulation loop is constituted for membrane stack in MBR devices with MBR devices and frequently pole-reversing electroosmosis system by pipeline respectively Cleaned with membrane stack in frequently pole-reversing electroosmosis system, clear water water tank and cleaning case are connected to clear water water tank by water pump In water be pumped into cleaning case.
Compared with prior art, the utility model has advantages below:(1) frequently pole-reversing electroosmosis processing high-salt wastewater, Compared with reverse osmosis process, amberplex contamination resistance is stronger;(2) by the calcium in traditional handicraft in front-end processing during Magnesium ion, will be reprocessed, reducing needs water to be processed by electrodialysis system after the calcium ions and magnesium ions concentration in raw water, and then Reduce the use of medicament and the capital cost of regulating reservoir and coagulative precipitation tank;(3) biochemical treatment process is placed on work during Skill rear end, it is to avoid inhibitory action of the salt content to microorganism in waste water;(4) device stable effluent quality, whole process is realized The zero-emission of waste water;(5) purging system can be MBR devices and frequently pole-reversing electroosmosis cleaning systems simultaneously, save equipment Cost.
Brief description of the drawings:
Fig. 1 is the processing of high salt high-COD waste water and recycling retracting device structural representation that the utility model is related to.
Embodiment
The utility model is described further with reference to the accompanying drawings and detailed description:
Embodiment 1:
As shown in figure 1, the high salt high-COD waste water that the present embodiment is related to is handled and recycling retracting device, the high salt height COD waste water refers to the concentration of salt>1%, COD > 100mg/L waste water, including wastewater tank 1, the first elevator pump 2, ensured public security Filter 3, pole-reversing electroosmosis system 4, regulating reservoir 5, coagulative precipitation tank 6, concentrated water water tank 7, the second elevator pump 10, evaporated crystallization device 8th, fresh water tanks 9, the 3rd elevator pump 11, MBR devices 12, clarified water pump 16 and clear water water tank 17;The water side of wastewater tank 1 is successively It is connected by the first elevator pump 2 and cartridge filter 3 with the water inlet end of pole-reversing electroosmosis system 4, the concentrated water of pole-reversing electroosmosis system 4 goes out Water end (W.E.) passes sequentially through regulating reservoir 5 and coagulative precipitation tank 6 is connected with concentrated water water tank 7, and concentrated water water tank 7 is by the second elevator pump 10 with steaming Hair crystallization apparatus 8 is connected, and the fresh water outlet end of pole-reversing electroosmosis system 4 passes sequentially through the elevator pump 11 of fresh water tanks 9 and the 3rd and MBR The water inlet end of device 12 is connected, and the water side of MBR devices 12 is connected by clarified water pump 16 with clear water water tank 17.
Further, the pole-reversing electroosmosis system that the present embodiment is related to can auto switching polarity of electrode, it is and simultaneously automatic Change dense, light flow direction;Pole-reversing electroosmosis system uses antipollution homogeneous ion-exchange membrane, and the homogeneous ion of antipollution is handed over It is to cover the film layer with body membrane oppositely charged on homogeneous ion-exchange membrane surface to change film, utilizes electrostatic interaction and reduction film table Surface roughness, absorption of the contaminant restraining on film surface is deposited, and the waste water after cartridge filter is handled enters the electric osmose of falling pole The polarization layer for destroying amberplex surface after analysis system in the presence of polarity of electrode is frequently switched avoids precipitating fouling.
Further, the high salt high-COD waste water processing that the present embodiment is related to also includes anti-cleaning with recycling retracting device System, back cleaning system includes cleaning pump 13, cleaning case 14 and water pump 15, the water side of cleaning case 14 and the water inlet end of cleaning pump 13 Connection, cleaning pump 13 constitutes circulation loop (in figure not with MBR devices 12 and frequently pole-reversing electroosmosis system 4 respectively by pipeline Draw) it is used to clean membrane stack in membrane stack in MBR devices 12 and frequently pole-reversing electroosmosis system 4, go having for membrane removal surface Clear water water tank 17 and cleaning case 14 are connected to the water in clear water water tank 17 by machine thing, dirt and microorganism pollution, water pump 15 It is pumped into cleaning case 14.
The processing of high salt high-COD waste water and the specifically used process of recycling retracting device that the present embodiment is related to:
The waste water of high saliferous in wastewater tank 1, high COD is pumped into cartridge filter 3 and goes turbidity removal by (1) first elevator pump 2 The larger particulate of degree, is then delivered in pole-reversing electroosmosis system 4, the salt rejection rate of pole-reversing electroosmosis system 4 80-90% it Between, fresh-water recovery rate is between 70%-80%;
(2) enter after pole-reversing electroosmosis system 4, the ion in desalting chamber moves to adjacent concentration in the presence of electric field Salt content is reduced in room, desalting chamber's water, salt content increase in enriched chamber's water;
(3) it is 10-10.5 that enriched chamber's concentrated water water outlet, which enters pH in regulating reservoir 5, regulation regulating reservoir 5, in step (2), then will Water is transported to addition coagulant coagulating sedimentation in coagulative precipitation tank 6, the calcium ion and magnesium ion gone in water removal, it is to avoid it is to evaporation The influence of crystallization apparatus, the water outlet of coagulative precipitation tank 6 enters in concentrated water water tank 7;
(4) desalting chamber's fresh water outlet enters in fresh water tanks 9 in step (2), and the 3rd elevator pump 11 is by the reclaimed water of fresh water tanks 9 MBR devices 12 are pumped into, by the processing of biochemical and ultrafiltration membrance filter in MBR devices 12, the bacterium gone in water removal, virus, drop Organic matter is solved, water outlet is transported in clear water water tank 17;
(5) reclaimed water of step (3) concentrated water water tank 7 is pumped into the evaporative crystallization of evaporated crystallization device 8;
(6) needs are shut down periodically right when the processing for the high slat-containing wastewater that the present embodiment is related to is used with recycling retracting device Hyperfiltration membrane assembly and the membrane stack of frequently pole-reversing electroosmosis system 4 are cleaned in MBR devices 12,
Hyperfiltration membrane assembly cleaning process is in MBR devices 12:Respective valves are closed, by water pump 15 by clear water water tank 17 Reclaimed water is pumped into cleaning case 14, and hyperfiltration membrane assembly cleaning agent is added into cleaning case 14, realizes that rinse water exists by cleaning pump 13 Circulate, until completing cleaning, rinse water in cleaning water tank 14 is discharged between cleaning water tank 14 and MBR devices 12;
The membrane stack cleaning process of frequently pole-reversing electroosmosis system 4:Respective valves are closed, by water pump 15 by clear water water tank 17 Reclaimed water is pumped into cleaning case 14, and ion exchange cleaning agents of membrane is added into cleaning case 14, realizes that rinse water exists by cleaning pump 13 Circulated between cleaning water tank 14 and frequently pole-reversing electroosmosis system 4, until cleaning is completed, by rinse water in cleaning water tank 14 Discharge.

Claims (3)

1. a kind of high salt high-COD waste water processing and recycling retracting device, it is characterised in that carried including wastewater tank, first Rise pump, cartridge filter, pole-reversing electroosmosis system, regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump, evaporative crystallization Device, fresh water tanks, the 3rd elevator pump, MBR devices, clarified water pump and clear water water tank;Wastewater tank water side passes sequentially through One elevator pump and cartridge filter are connected with pole-reversing electroosmosis system water inlet end, and pole-reversing electroosmosis system concentrated water water side leads to successively Overregulate pond and coagulative precipitation tank to be connected with concentrated water water tank, concentrated water water tank is connected by the second elevator pump with evaporated crystallization device, Pole-reversing electroosmosis system fresh water outlet end passes sequentially through fresh water tanks and the 3rd elevator pump is connected with MBR device water inlet ends, MBR dresses Water side is put to be connected with clear water water tank by clarified water pump.
2. high salt high-COD waste water processing according to claim 1 and recycling retracting device, it is characterised in that extremely electric Electrodialysis system uses antipollution homogeneous ion-exchange membrane.
3. high salt high-COD waste water processing according to claim 2 and recycling retracting device, it is characterised in that high salt is high COD wastewater treatments also include back cleaning system with recycling retracting device, and back cleaning system includes cleaning pump, cleaning case and water intaking Pump, cleaning case water side and cleaning pump water inlet end connection, cleaning pump by pipeline respectively with MBR devices and frequently pole-reversing electroosmosis System, which constitutes circulation loop, to be used to clean membrane stack in membrane stack in MBR devices and frequently pole-reversing electroosmosis system, water pump Clear water water tank and cleaning case are connected to the water in clear water water tank is pumped into cleaning case.
CN201720180177.3U 2017-02-28 2017-02-28 A kind of high salt high-COD waste water processing and resource recovery device Expired - Fee Related CN206529377U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720180177.3U CN206529377U (en) 2017-02-28 2017-02-28 A kind of high salt high-COD waste water processing and resource recovery device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720180177.3U CN206529377U (en) 2017-02-28 2017-02-28 A kind of high salt high-COD waste water processing and resource recovery device

Publications (1)

Publication Number Publication Date
CN206529377U true CN206529377U (en) 2017-09-29

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Effective date of registration: 20191206

Address after: 266000 room 234, No.68, hailun Road, Sifang District, Qingdao, Shandong Province

Patentee after: QINGDAO NORTH ENERGY AND ENVIRONMENT CO., LTD.

Address before: 266200 Shandong Qingdao blue Silicon Valley core area Pioneer Center

Patentee before: Qingdao bluevale Chemical Co. Ltd.

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170929

Termination date: 20210228

CF01 Termination of patent right due to non-payment of annual fee