CN206474021U - A kind of high efficiency membrane component - Google Patents
A kind of high efficiency membrane component Download PDFInfo
- Publication number
- CN206474021U CN206474021U CN201621051901.4U CN201621051901U CN206474021U CN 206474021 U CN206474021 U CN 206474021U CN 201621051901 U CN201621051901 U CN 201621051901U CN 206474021 U CN206474021 U CN 206474021U
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- Prior art keywords
- membrane
- film head
- cavity
- film
- high efficiency
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- 239000012528 membrane Substances 0.000 title claims abstract description 91
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 238000001816 cooling Methods 0.000 claims abstract description 45
- 238000004821 distillation Methods 0.000 claims abstract description 18
- 108091006146 Channels Proteins 0.000 claims abstract description 16
- 108090000862 Ion Channels Proteins 0.000 claims abstract description 11
- 102000004310 Ion Channels Human genes 0.000 claims abstract description 11
- 230000008676 import Effects 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 27
- 238000007789 sealing Methods 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 14
- 238000010992 reflux Methods 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 9
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002379 silicone rubber Polymers 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 6
- 239000011162 core material Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 208000002925 dental caries Diseases 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- -1 polytetrafluoroethylene Polymers 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000003694 hair properties Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The utility model provides a kind of high efficiency membrane component, the film core is arranged inside the putamina, the film head includes the upper film head and lower film head for being packaged in the putamina two ends respectively, the film core is tubular membrane, the cooling tube that an internal diameter is more than the pipe external diameter is provided with the tubular membrane outside each pipe, a water vapor channel is formed between pipe outer wall in the cooling inside pipe wall and the tubular membrane, two individual cavities are equipped with the upper lower film head, and two individual cavities in the upper film head are connected by the tubular type membrane channels and water vapor channel with two individual cavities in lower film head respectively, and the side of the individual cavities is provided with import and export.Relative to prior art, high efficiency membrane component described in the utility model has the advantages that dimensionally stable, distillation efficiency are high, is readily cleaned, service life is long.
Description
Technical field
The utility model belongs to membrane distillation field, more particularly, to a kind of high efficiency membrane component, using above-mentioned efficient
The distillation device of rate membrane component.
Background technology
A kind of hot method desalting technology of membrane distillation (MD), using film both sides vapour pressure deficit as motive force, makes waving in the aqueous solution
The side that hair property component reaches film in steam (being usually water vapour) form through fenestra is condensed, so as to realize the mesh of feed liquid concentration
, and the opposite side of film then obstructs the aqueous solution by the hydrophobicity of film.MD has the advantages that low energy consumption, atmospheric operation, can use
It is currently the only the membrane process of crystallized product to be directly separated out from solution in the processing of high concentration salt solution.Wherein, GAP TYPE
Membrane distillation (AGMD) can be such that vapor is condensed in short distance, while the heat for condensing release can be used to heat material liquid, from
And the energy consumption of concentration process can be greatly reduced.AGMD processes can reach high water generation ratio, possess before industrialization well
Scape.However, AGMD technologies also rest on the experimental stage at present, and membrane module is generally used as core using doughnut and plastic catheter
Core material, poor dimensional stability at high temperature, the gap between film silk and cooling tube is unstable, can be produced between film and cooling tube
Heat transfer, therefore the efficiency of membrane module is unstable, high energy consumption and theoretical prediction have larger gap.On the other hand, due to cooling
Pipe usually used is plastic material, and thermal conductivity is poor, and cooling wall heat transmission resistance is big, therefore vapor cooling is insufficient, cold
Fluid heat supply is not enough, increases heating, the cooling load of external equipment, reduces efficiency.In addition, film distillation technology is generally used for
High salinity solution occasion, the fouling membrane (being usually that membrane crystallization causes hydrophobicity to decline) of hollow-fibre membrane can cause than more serious
Water generation ratio declines, and production water is not up to standard, therefore combines the dimensional stability and easy cleaned advantage of board-like film, while utilizing one
The high-termal conductivity of a little materials, research and development high efficiency, process stabilization, is easy to industrialized AGMD technologies and will have a wide range of applications valency
Value.
Utility model content
In view of this, the utility model is directed to a kind of high efficiency membrane component, and the membrane component includes film
Head, putamina and film core, the film core are arranged inside the putamina, and the film head includes being packaged in the putamina two ends respectively
Upper film head and lower film head, it is characterised in that:The film core is to be provided with an internal diameter outside each pipe in tubular membrane, the tubular membrane
More than the cooling tube of the pipe external diameter, a vapor is formed between the pipe outer wall in the cooling inside pipe wall and the tubular membrane and is led to
Two individual cavities in two individual cavities, and the upper film head are equipped with road, the upper lower film head respectively by described
Tubular type membrane channels and water vapor channel are connected with two individual cavities in lower film head, and the side of the individual cavities is set
There are import and export.
Further, the cooling tube is arranged concentrically with the pipe in the tubular membrane, and the cooling tube is highly less than institute
State tubular membrane height;Bore >=3mm of the tubular membrane.
Further, the upper film head is formed by the end cap in outside and the ponding plate stack combinations of inner side, in the end cap
Provided with the first cavity connected with the tubular type membrane channels, one end of first cavity is provided with import and export;In the ponding plate
Provided with the second cavity being connected with the water vapor channel, one end of second cavity also is provided with importing and exporting;The lower film
Head it is identical with the upper film header structure, be symmetrical arranged, wherein the first cavity of the upper film head by tubular type membrane channels with it is described
The first cavity connection of lower film head, the second cavity of the upper film head passes through water vapor channel and the second cavity of lower film head
It is connected.
Further, the film head is provided with sealing ring with the tubular membrane junction, and the sealing ring is externally provided with sealing ring
Lid.
Further, the film head, putamina and film core are installed together to form high efficiency membrane distillation by shell side sealing pouring adhesive
Material liquid entrance is offered on component, and the film shell side wall;The cooling tube is made up of high-termal conductivity material;The cooling tube
Material be quartz, ceramics, the plastics of stainless steel or high-termal conductivity, wherein the plastics of the high-termal conductivity preferably comprise graphite
Polytetrafluoro material.
Further, the ponding sheet material matter is silicon rubber or fluorubber, offer respectively on ponding plate with it is described cold
But pore footpath match through hole for connecting the second cavity and water vapor channel and with the tubular membrane inner tube external diameter phase
The sealing hole matched somebody with somebody, it is main to play connection end cover and putamina, while the through hole and sealing hole that are opened up on its plate body may be used also
Using the location-plate as cooling tube/tubular membrane, it is ensured that have rational gap between tubular membrane and cooling tube.
The utility model also provides a kind of high efficiency distillation device, including fluid reservoir, membrane component, pure water pipeline and
Pure water collection tank, the fluid reservoir passes through feed pipe and reflux line and the membrane component one circulatory system of formation, institute
The pure water outlet for stating membrane component is connected by pure water pipeline with the pure water collection tank, and the membrane component is high efficiency
Membrane component.
Further, the fluid reservoir is connected by the import of the first cavity on the feed pipe and the film head end cover
Logical, the outlet of first cavity passes through on reflux line and the inlet communication on the film shell side wall, the film shell side wall
Outlet is connected by feed pipe with the reservoir;The outlet of second cavity passes through pure water pipeline and the pure water collection
Tank is connected.
Further, the feed pipe is provided with heater, and the reflux line is provided with cooling fan.
Relative to prior art, high efficiency membrane component described in the utility model has the advantage that:Utilize tubular type
Dimensional stability, high porosity and the hydrophobic performance of film, are made porous pipe type film, and set cooling tube in the pipe of tubular membrane,
So that the vapor in feedstock solution enters film inner space in the presence of saturated vapor pressure difference through film outer wall, cooling is run into
Aqueous water is cooled to during tube outer surface, heat is released;Feed liquid after heat release simultaneously directly or after cooling enters back into cooling tube
Continue to cool down vapor, so move in circles, not only increase distillation efficiency and also a saving energy consumption;In addition, the component is also
Have the advantages that dimensionally stable, distillation efficiency are high, be readily cleaned, service life it is long.
The high efficiency distillation device is had the advantage that with above-mentioned high efficiency membrane component relative to prior art
It is identical, it will not be repeated here.
Brief description of the drawings
Constitute a part of accompanying drawing of the present utility model to be used for providing further understanding to of the present utility model, this practicality
New schematic description and description is used to explain the utility model, does not constitute to improper restriction of the present utility model.
In the accompanying drawings:
Fig. 1 is the structural representation of the high efficiency membrane component described in the utility model embodiment 1;
Fig. 2 be the utility model embodiment 1 described in high efficiency membrane component in end cap structural representation;
Fig. 3 be the utility model embodiment 1 described in high efficiency membrane component in ponding plate structural representation;
Fig. 4 is the schematic flow sheet of the high efficiency distillation device described in the utility model embodiment 2.
Description of reference numerals:
1- end caps;The cavitys of 11- first are imported and exported;The cavitys of 12- first;2- ponding plates;The cavitys of 21- second are imported and exported;22-
Two cavitys;23- sealing holes;3- putaminas;31- material liquid entrances;4- shell side sealing pouring adhesives;5- tubular membranes;6- cooling tubes;7- is sealed
Circle;8- seals ring cover.
Embodiment
It should be noted that in the case where not conflicting, the feature in embodiment and embodiment in the utility model can
To be mutually combined.
In description of the present utility model, it is to be understood that term " " center ", " longitudinal direction ", " transverse direction ", " on ", " under ",
The orientation or position relationship of the instruction such as "front", "rear", "left", "right", " vertical ", " level ", " top ", " bottom ", " interior ", " outer " are
Based on orientation shown in the drawings or position relationship, it is for only for ease of description the utility model and simplifies description, rather than indicate
Or imply that the device or element of meaning must have specific orientation, with specific azimuth configuration and operation, therefore be not understood that
For to limitation of the present utility model.In addition, term " first ", " second " etc. are only used for describing purpose, and it is not intended that indicating
Or imply relative importance or the implicit quantity for indicating indicated technical characteristic.Thus, " first ", " second " etc. are defined
Feature can express or implicitly include one or more this feature.In description of the present utility model, unless separately
It is described, " multiple " are meant that two or more.
, it is necessary to which explanation, unless otherwise clearly defined and limited, term " are pacified in description of the present utility model
Dress ", " connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integratedly
Connection;Can be mechanical connection or electrical connection;Can be joined directly together, can also be indirectly connected to by intermediary,
It can be the connection of two element internals.For the ordinary skill in the art, on being understood by concrete condition
State concrete meaning of the term in the utility model.
Describe the utility model in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
Embodiment 1
A kind of high efficiency membrane component, as shown in Figures 1 to 3, the membrane component include film head, putamina 3 and film core,
The film core is arranged inside the putamina, and the film head includes the upper film head and lower film for being packaged in the putamina two ends respectively
Head, the film core is to be provided with the cooling that an internal diameter is more than the pipe external diameter in tubular membrane 5, the tubular membrane 5 outside each pipe
Formed between pipe outer wall in pipe 6, the inwall of cooling tube 6 and the tubular membrane in a water vapor channel, the upper lower film head
Two individual cavities being equipped with two individual cavities, and the upper film head steam by the tubular type membrane channels and with water respectively
Gas passage is connected with two individual cavities in lower film head, and the side of the individual cavities is provided with import and export:
Specifically, upper film head described in the present embodiment by the end cap 1 in outside and the stack combinations of ponding plate 2 of inner side and
Provided with the first cavity 12 connect with the tubular type membrane channels in into, the end cap 1, one end of first cavity 12 is provided with the
One cavity imports and exports 11;Provided with the second cavity 22 being connected with the water vapor channel in the ponding plate 2, described second is empty
One end of chamber 22 also is provided with the second cavity and imports and exports 21;The lower film head is identical with the upper film header structure, is symmetrical arranged, wherein
First cavity 12 of the upper film head is connected by tubular type membrane channels with the first cavity 12 of lower film head, the upper film head
Second cavity 22 is connected by water vapor channel with the second cavity 22 of lower film head;
The height of cooling tube 6 is less than the height of tubular membrane 5, to ensure that the tubular membrane 5 can be placed through end cap
The ponding plate of inner side is extended at end cap 1 and connected with the first cavity 12 in end cap 1;And the bore of the tubular membrane 5 is
10mm, the internal diameter of cooling tube 6 is 15mm, and the tubular membrane 5 passes through the ponding plate 2 by ponding plate 2 sealing hole 23, then
Side bottom plate through the end cap is connected with the first cavity 12 in the end cap, and the upper end cover and the pipe of the film head
The junction of formula film 5 is provided with sealing ring 7, and the sealing ring 7 is externally provided with sealing ring cover 8, to ensure sealing effectiveness, prevents leakage.
The film head, putamina and film core are installed together to form high efficiency membrane component by shell side sealing pouring adhesive 4, and institute
State and material liquid entrance 31 is offered on film shell side wall.
In addition, tubular type membrane material described in embodiment can select polytetrafluoroethylene (PTFE) (PTFE), and polyethylene (PE) gathers inclined
PVF (PVDF), the hydrophobic material such as polypropylene (PP) can make stretching, Thermal inactive, the porous pipe type film of sintering generation,
Tubular membrane diameter is in more than 3mm;
The material of putamina 3 and section is the high temperature resistant nonmetallic materials such as ABS, PE, PP, PVDF, or metal material;
Ponding plate is to be offered respectively and the cooling tube on high temperature resistant elastomeric material, such as silicon rubber, fluorubber, ponding plate
Aperture match through hole for connecting the second cavity and water vapor channel and with the tubular membrane inner tube external diameter match it is close
Sealing of hole, mainly plays end cover and putamina, while being also used as the location-plate of cooling tube/tubular membrane, it is ensured that tubular type
There is rational gap between film and cooling tube.
The material of cooling tube can use stainless steel, quartz, ceramics or high-termal conductivity plastic material (to preferably comprise stone
The polytetrafluoro material of ink) it is made.
Embodiment 2
A kind of high efficiency distillation device, including fluid reservoir, membrane component, pure water pipeline and pure water collection tank, it is described
Fluid reservoir by feed pipe and reflux line and the membrane component one circulatory system of formation, the membrane component it is pure
Water out is connected by pure water pipeline with the pure water collection tank, and the membrane component is high efficiency membrane component.
Specifically, the fluid reservoir is connected by the import of the first cavity on the feed pipe and the film head end cover
Logical, the outlet of first cavity passes through on reflux line and the inlet communication on the film shell side wall, the film shell side wall
Outlet is connected by feed pipe with the reservoir;The outlet of second cavity passes through pure water pipeline and the pure water collection
Tank is connected;Simultaneously in order to ensure distilling effect, the feed pipe is provided with heater, and the reflux line is provided with cooling wind
Fan.
The course of work of above-mentioned high efficiency distillation device is:As shown in Fig. 4, after feed liquid in reservoir is heated by
The first cavity in upper film head end cover in tubular type air gap membrane module is imported and exported into the first cavity and then enters tubular type membrane channels
Inside, the water carried out in UF membrane, feed liquid is reached after certain temperature by heating, is flowed in tubular membrane inwall, now higher temperatures
The vapor of degree is preferential in the presence of saturated vapor pressure difference to enter film exterior space through film inwall, runs into cooling pipe internal surface
When be cooled to aqueous water, release heat;Due to the release of vapor, causing the temperature of this stock material liquid reduces, this stock material liquid
Enter after membrane separation the first cavity and by the first cavity import and export out after by reflux line enter back into membrane module, you can
To enter after the cooling fan of smaller power or the cooling of other cooling devices or without the feed liquid that cooling is directly on putamina
Outlet enters in membrane module internal cavities;When this stock material liquid flows in membrane module internal cavities, cooling tube pipe outer wall water is absorbed
The heat of steam release and temperature is raised, and feed pipe is flowed out to by the material liquid entrance on putamina, it is smaller by one
Heating amount just can reach higher temperature, reach to be re-circulated in tubular membrane component after reservoir and discharge steam, such as
This moves in circles;The vapor produced in the water vapor channel formed between the cooling tube and tubular membrane is then by entering film
Imported and exported in the second cavity in head ponding plate and by the second cavity and entered in pure water pipeline, and then collected to pure water collection tank
In it is standby.
Preferred embodiment of the present utility model is the foregoing is only, it is all at this not to limit the utility model
Within the spirit and principle of utility model, any modification, equivalent substitution and improvements made etc. should be included in the utility model
Protection domain within.
Claims (9)
1. a kind of high efficiency membrane component, the membrane component includes film head, putamina and film core, the film core is arranged at institute
State inside putamina, the film head includes the upper film head and lower film head for being packaged in the putamina two ends respectively, it is characterised in that:It is described
Film core is to be provided with the cooling tube that an internal diameter is more than the pipe external diameter outside each pipe in tubular membrane, the tubular membrane, described cold
But formed between the pipe outer wall in inside pipe wall and the tubular membrane in a water vapor channel, the upper lower film head and be equipped with two solely
Vertical cavity, and two individual cavities in the upper film head respectively by the tubular type membrane channels and water vapor channel with it is described under
Two individual cavities in film head are connected, and the side of the individual cavities is provided with import and export.
2. high efficiency membrane component according to claim 1, it is characterised in that:In the cooling tube and the tubular membrane
Pipe be arranged concentrically, and the cooling tube highly be less than the tubular membrane height;Bore >=3mm of the tubular membrane.
3. high efficiency membrane component according to claim 2, it is characterised in that:The upper film head by outside end cap and
The ponding plate stack combinations of inner side are formed, provided with the first cavity connected with the tubular type membrane channels in the end cap, and described the
One end of one cavity is provided with import and export;It is described provided with the second cavity being connected with the water vapor channel in the ponding plate
One end of second cavity also is provided with importing and exporting;The lower film head is identical with the upper film header structure, is symmetrical arranged, wherein on described
First cavity of film head is connected by tubular type membrane channels with the first cavity of lower film head, and the second cavity of the upper film head leads to
The second cavity that water vapor channel is crossed with lower film head is connected.
4. the high efficiency membrane component according to claim 1 or 2 or 3, it is characterised in that:The film head and the tubular type
Film junction is provided with sealing ring, and the sealing ring is externally provided with sealing ring cover.
5. high efficiency membrane component according to claim 1, it is characterised in that:The film head, putamina and film core pass through
Shell side sealing pouring adhesive is installed together to form high efficiency membrane component, and offers material liquid entrance on the film shell side wall;Institute
Cooling tube is stated to be made up of high-termal conductivity material;The material of the cooling tube is the modeling of quartz, ceramics, stainless steel or high-termal conductivity
Material, wherein the plastics of the high-termal conductivity preferably comprise the polytetrafluoro material of graphite.
6. high efficiency membrane component according to claim 3, it is characterised in that:The ponding sheet material matter be silicon rubber or
Offer and matched with the cooling tube aperture for connecting the second cavity and water vapor channel respectively on fluorubber, ponding plate
Through hole and the sealing hole that matches with the tubular membrane inner tube external diameter.
7. a kind of high efficiency distillation device, including fluid reservoir, membrane component, pure water pipeline and pure water collection tank, the storage
Flow container passes through feed pipe and reflux line and the membrane component one circulatory system of formation, the pure water of the membrane component
Outlet is connected by pure water pipeline with the pure water collection tank, it is characterised in that:The membrane component is high efficiency membrane distillation
Component.
8. high efficiency distillation device according to claim 7, it is characterised in that:The fluid reservoir passes through the feed pipe
The inlet communication in road and the first cavity on the film head end cover, the outlet of first cavity passes through reflux line and the film
Outlet on inlet communication on shell side wall, the film shell side wall is connected by feed pipe with the reservoir;Described second
The outlet of cavity is connected by pure water pipeline with the pure water collection tank.
9. high efficiency distillation device according to claim 7, it is characterised in that:The feed pipe is provided with heating
Device, the reflux line is provided with cooling fan.
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CN106422784A (en) * | 2016-09-12 | 2017-02-22 | 天津沃驰科技有限公司 | High-efficiency membrane distillation assembly and distillation method |
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CN106422784A (en) * | 2016-09-12 | 2017-02-22 | 天津沃驰科技有限公司 | High-efficiency membrane distillation assembly and distillation method |
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Effective date of registration: 20170911 Address after: Anxin County 071600 Hebei city of Baoding province Zhao Bei Kou Zhen Chuang-tzu Cun You Yi Lu Nan No. 7 season Patentee after: Sun Ziwei Address before: Room 3 building C3012 No. 6 building A, 300300 Tianjin District of Dongli City Huaming Industrial Park HuaFeng Road Patentee before: TIANJIN WOCHI TECHNOLOGY CO., LTD. |