CN206387761U - Quick-screening processing chip for detecting pesticide residues on vegetables and fruits - Google Patents

Quick-screening processing chip for detecting pesticide residues on vegetables and fruits Download PDF

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Publication number
CN206387761U
CN206387761U CN201621118066.1U CN201621118066U CN206387761U CN 206387761 U CN206387761 U CN 206387761U CN 201621118066 U CN201621118066 U CN 201621118066U CN 206387761 U CN206387761 U CN 206387761U
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China
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electrode
layer
vegetables
pesticides
circuit layer
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CN201621118066.1U
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Chinese (zh)
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王镜竣
陈肇和
王煜竑
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Individual
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Abstract

A fast screening processing chip for detecting pesticide residue on vegetables and fruits comprises a substrate layer, a circuit layer, a fluoride layer and a barrier layer. The circuit layer is disposed on the substrate layer and has a first electrode, a second electrode and a sensing pole, wherein the first electrode is connected to the sensing pole, and the second electrode is spaced from and not connected to the sensing pole. The fluorinated layer is a fluorinated polymeric derivative and covers the circuit layer. The barrier layer covers the fluoride layer, the circuit layer and the substrate layer, so that the first electrode and the second electrode of the circuit layer are exposed, and the barrier layer is provided with a detection hole corresponding to the sensing pole of the circuit layer.

Description

Detect the fast sieve process chip of vegetables and fruits residues of pesticides
Technical field
The utility model relates to a kind of test piece for detecting residues of pesticides, and detection vegetables and fruits are provided in particular to one kind In chlorobenzene content detection vegetables and fruits residues of pesticides fast sieve process chip.
Background technology
Food-safety problem emerges in an endless stream in recent years, and a series of food safety affair not only allows consumer to tighten god Morals through, food dealer are sincere lost, and under food peace health unit fails effectively to check on, consumer also can only everybody from Danger.Therefore, for agricultural product (vegetables and fruits) plantation process whether because of over administration, and cause vegetables and fruits residues of pesticides excessive The problem of, it is also one of focus that the common people are paid close attention to.
The method for being used for analyzing vegetables and fruits residues of pesticides concentration in the past, such as AAS, nuclear magnetic resonance spectroscopy, thin layer Analysis method, atomic absorption spectrography (AAS), gas chromatography, liquid chromatography, fluorescence method etc., wherein with gas chromatography and liquid phase layer Analysis method is more commonly used, and its grade has the advantages that good repeatability, sensitivity and can determine that pesticide variety and concentration.But, this Alanysis method is required to follow the detecting step flow of standard, and carries out sample via the laboratory personnel of tool professional knowledge Product pre-treatment and instrumentation are analyzed, and could obtain effective testing result, therefore the foregoing analysis method such as all, the problem of general just Work consuming and time-consuming, and can not quick and convenient apply to substantial amounts of Practice for Pesticide Residue in Agricultural Products amount detection, this understands being eager detailed For the consumer of feelings, probably slow action cannot save a critical situation.
The side of agricultural chemicals to detect ferment inhibitor type is had been developed using biochemical reaction and electrochemical techniques in recent years Method, such as United States Patent (USP) US 6,406,876, the immobilization ferment technology disclosed in it does not need the preparation of a large amount of test solutions, but such The shortcoming of immobilization ferment is that the complicated cost of fabrication schedule is high, and electrode preservation condition is quite rigorous, so, it is non-specialized-technical Personnel can not simultaneously be analyzed.
Secondly, TaiWan, China patent M376764 new patents and No. 101082599 inventions of Chinese Patent No. CN are special Sharp case, though propose that one fixes ferment in the relatively short-cut method on analytical equipment, to differentiate the concentration of residues of pesticides, its design side Formula is also complex, respectively must be stored in ferment in electrode and shuttle respectively to related chemical reaction substance, individually Two stage reaction is carried out, it may cause the error that analysis is tested.
And TaiWan, China patent I301541 patent of invention cases, it was also proposed that ferment is fixed on electrode, through agricultural chemicals pair The inhibition level of ferment is judged the pesticide concentration in water body, but its ferment fixed form is complex, in a large amount of manufactures There is it difficult and also only represented for the quantitative manner of residues of pesticides concentration with ferment inhibiting rate, it is impossible to be specific to allow device user Cognitive actual persticide residue.
In addition, general in the streets common ferment test piece, its main structure is that three electrodes are formed with test piece, one is work Make electrode, to measure main operating voltage, the second is auxiliary electrode, as the electrode of reduction reaction, the third is reference electrode, , no doubt can be by the 3rd electrode i.e. with reference to electricity using the detection mode of three electrodes as the electrode of detecting current correction Extremely carry out correction work electrode to be used, still, this enzymatic analysis method refers to a kind of acetylcholinesterase ferment method, mainly to agriculture Amidocarbonic acid salt and organic phosphate agent class are made to suppress reaction in medicine, i.e. the phenomenon reacted using ferment is as there is nonpersistent pesticide Qualitative screening method, therefore, enzymatic analysis method can only detect the residual quantity of organophosphor in vegetables and fruits at most, and can not be for true Just there is the chlorobenzene content seriously poisoned to detect to environment, human body.In addition, general ferment test piece is in order to prevent anodizing, One layer of carbon black layer would generally be coated in electrode outer surface, to prevent electrode by such environmental effects and Quick Oxidation, still, carbon black The impedance of layer is very high, relative to influence the degree of accuracy of detection, and this is also one of unevident main cause of Detection results of ferment test piece.
Furthermore, separately there is a kind of vegetables and fruits agricultural chemicals to measure method, be to be divided using carbon electrode come modified electrode current potential and redox Analysis, although carbon electrode, which measures method, has highly sensitive characteristic, simply, carbon electrode is measured outside not only repeatability is low, also easily Produce the passivation of electrode, it is often more important that, carbon electrode it is expensive, disposable measure uses, and not only takes the not corner of the eyes, more without Method is supplied to the common people generally to use, not very economical.
Utility model content
The purpose of this utility model is to provide a kind of fast sieve process chip for detecting vegetables and fruits residues of pesticides, by the fast sieve Fluorinated polymers derivative in its circuit layer of process chip is heavy using plasma-based chemistry to drip reagent when the circuit layer Accumulate Nafion and derivative to modify chip electrode, specialty analysis is carried out with the potential region of electrochemistry and redox, with energy The structure chlorobenzene of agricultural chemicals is detected, and judges the content number of the noxious material of chlorobenzene, to obtain high sensitivity detecting property With the using effect of splendid repeatability.
For up to above-mentioned purpose, solution of the present utility model is:
A kind of fast sieve process chip for detecting vegetables and fruits residues of pesticides, includes:
One basalis;
One circuit layer, is arranged on the basalis, and with a first electrode, a second electrode and a sensing limit, should First electrode is connected with the sensing limit, and the second electrode is separately not connected with the sensing limit;
One fluorinated layer, is fluorinated polymers derivative, is covered on the circuit layer;
One barrier layer, is covered on the fluorinated layer, the circuit layer and the basalis, allow its part of circuit layer first electricity Pole, second electrode are revealed in outer, detection hole of the barrier layer with a sensing limit for corresponding to the circuit layer.
Further, the circuit layer is silver, and it is silvery white that the wiring that process chip is sieved soon, which is revealed in outer part,.
Further, an anti oxidation layer is further included, the anti oxidation layer is covered on circuit layer, makes to be folded in the circuit layer and fluorine Between change layer.
Further, the anti oxidation layer is silica.
Further, the first electrode has first guiding access for being located at front end and stretched out simultaneously from first guiding access The first linkage section being connected with the sensing limit, the second electrode have one be located at front end the second guiding access and from this second The second linkage section that guiding access stretches out, it is remaining between the second linkage section of the second electrode and the sensing limit to have between one Gap, the detection hole of the barrier layer corresponds to the first linkage section of the first electrode part, the sensing limit, the second electrode portion Point the second linkage section and the gap so that the first partial linkage section, the sensing limit, the second linkage section of part and should between Gap is all revealed in outside.
Further, the basalis is made up of plastic cement material or paper wood.
Further, this sieves process chip soon is inserted on a Port of an action reading device, to detect that agricultural chemicals is residual The numerical value stayed.
Therefore, slow compared to complex operation, the detection speed of existing ferment test piece and impedance is high to cause detection inaccurate, And the expensive of carbon electrode, repeatability are low and are also easy to produce the use problem of electrode passivation.Fast sieve processing core of the present utility model Piece, chip electrode is modified using the fluorinated polymers derivative in circuit layer, is entered with the potential region and redox of electrochemistry Row specialty analysis, can carry out rapid detection to the structure chlorobenzene of agricultural chemicals, and judge the content number of the noxious material of chlorobenzene, with Obtain using effect of the high sensitivity detecting property with splendid repeatability.In addition, being covered in electrode using the anti oxidation layer of silver-colored material Outer surface, in addition to anti-oxidation, silver-colored electric conductivity is good, and impedance is low, so, the relative speed that can be improved in detection and Accuracy.
Brief description of the drawings
Fig. 1 is the exploded perspective of a preferred embodiment of the fast sieve process chip that the utility model detects vegetables and fruits residues of pesticides Figure;
Fig. 2 is the fast combination stereogram for sieving process chip;
Fig. 3 is the fast sectional view for sieving process chip;
Fig. 4 is the fast united application schematic diagram for sieving process chip.
【Symbol description】
The 100 fast sieve basalises of process chip 10
The first electrode of 20 circuit layer 21
The linkage section of 211 first guiding access 212 first
The guiding access of 22 second electrode 221 second
222 second linkage sections 23 sense limit
The anti oxidation layer of 24 gap 30
The barrier layer of 40 fluorinated layer 50
The reagent of 51 detection hole 60
The 70 action Ports of reading device 71
The running gear of 72 chip 80
90 national agriculture political affairs units.
Embodiment
In order to which the technical solution of the utility model is explained further, the utility model is entered below by specific embodiment Row is elaborated.
Shown in reference picture 1, Fig. 2 and Fig. 3, the one of the fast sieve process chip 100 of the utility model detection vegetables and fruits residues of pesticides Preferred embodiment, includes a basalis 10, a circuit layer 20, an anti oxidation layer 30, a fluorinated layer 40 and a barrier layer 50.
The basalis 10, is made up of plastic cement material or papery.
The circuit layer 20, is arranged on the basalis 10, and with a first electrode 21, a second electrode 22 and a sensing Limit 23, the first electrode 21 is connected with the sensing limit 23, and the second electrode 22 and the sensing limit 23 are separately and not Connection.In the present embodiment, the circuit layer 20 is silver, therefore, the portion that the wiring of the fast sieve process chip 100 appears in appearance Point for silvery white, non-conventional carbon black color.
The anti oxidation layer 30, is covered on the circuit layer 20.In the present embodiment, the anti oxidation layer 20 can be silica, To prevent the surface of circuit layer 20 from producing oxidation, reduce electrical conductivity.
The fluorinated layer 40, be fluorinated polymers derivative (for example:Nafion), and cover in the top of the anti oxidation layer 30.
The barrier layer 50, is covered on the fluorinated layer 40, the anti oxidation layer 30, the circuit layer 20 and the basalis 10, allows Outside first electrode 21, the second electrode 22 of its part of circuit layer 20 are revealed in, the barrier layer 50 has one to correspond to the circuit The detection hole 51 of the sensing limit 23 of layer 20.
Further, the first electrode 21 of the circuit layer 20 have one be located at front end the first guiding access 211 and from this first The first linkage section 212 that guiding access 211 stretches out and is connected with the sensing limit 23, the second electrode 22 has one to be located at Second guiding access 221 of front end and the second linkage section 222 stretched out from second guiding access 221, the second electrode 22 Remaining between second linkage section 222 and the sensing limit 23 to have a gap 24, the detection hole 51 of the barrier layer 50 corresponds to this First linkage section 212 of the part of first electrode 22, the sensing limit 23, the second linkage section 222 of the part of second electrode 22 and The gap 24, so that the first partial linkage section 212, the sensing limit 23, the second linkage section 222 of part and the gap 24 are all Outside is revealed in, as shown in Figure 1.
As for the occupation mode of the fast sieve process chip of the utility model detection vegetables and fruits residues of pesticides, should shown in ginseng Fig. 4 Fast sieve process chip 100 need to be connected to a Port 71 of an action reading device 70, and this action reading device 70 passes through Wi-Fi Or bluetooth (Bluetooth) system with wireless communication mode link to a running gear 80 (intelligent mobile phone, iPad, iPod or Mobile computer).When user drops to reagent 60 detection hole 51 of the fast sieve process chip 100, fall to put by reagent 60 In the sensing limit 23, the first electrode 21 and the mutual conduction of second electrode 22 are caused across the gap 24, makes the fast sieve processing After chip 100 is powered, the fast reaction on the fluorinated layer 40 for be dropped in Nafion of reagent 60, and gone out using plasma-based chemical analysis The concentration of the reagent 60, therefore, by means of current potential (Potential), electric current and the resistance (electrical conductivity) of measurement reagent 60, via the row The dynamic built-in chip 72 of reading device 70 goes out the levels of the Pesticide Residues of reagent 60 with sequencing calculation process, and changes out The data information of the levels of the residues of pesticides of reagent 60, transmit it is after 80s to this action device, through APP programs perform computing To handle the data information, user is allowed to learn whether the levels of the residues of pesticides of reagent 60 are exceeded in real time, accordingly, this Utility model is the application target that can reach Rapid Screening vegetables and fruits residues of pesticides through the fast sieve process chip 100.
In addition, the APP programs of this action device 80 are to be connected to a national agriculture political affairs unit 90 through wireless communication mode, with The vegetables and fruits pesticide standard data that the real-time update national agriculture political affairs unit 90 is issued, makes examination criteria more accurate.
In addition, this action reading device 70 in Fig. 4 also can be a kind of object wearing device or smart watch (i watch), All structures and function of foregoing action reading device 70 are had in smart watch, this no longer adds explanation.Therefore, will intelligence Type wrist-watch is worn in wrist, will be more easy when needing to make vegetables and fruits Pesticides Testing, and smart watch has basic hand concurrently Table function, when vegetables and fruits Pesticides Testing need not be made, function when general wrist-watch substantially aobvious can be also provided, and carrying above use Just.
It is mentioned above, compared to the existing enzymatic analysis method to differentiate residues of pesticides, its complex operation, detection speed Slow and impedance height causes detection inaccurate, and professional need to be coordinated to reach with professional equipment technology, and uses carbon The measurement of electrode analysis is with high costs and the problem of can not generally using.Due to detection vegetables and fruits residues of pesticides of the present utility model Fast sieve process chip, by the fluorinated polymers derivative in fast its fluorinated layer 40 of sieve process chip 100, to cause reagent 60 Drip when fluorinated layer 40, and promote circuit layer 20 conductive, chip is modified using plasma-based chemical deposition Nafion and derivative Electrode, specialty analysis is carried out with the potential region of electrochemistry and redox, can be detected to the structure chlorobenzene of agricultural chemicals, and The content number of the noxious material of chlorobenzene is judged, to obtain using effect of the high sensitivity detecting property with splendid repeatability.And And, the circuit layer of this in this case 20 is silver, outside the low characteristic of highly conductive, impedance, more by the antioxygen of silica material Change layer 40 and be covered in electrode outer surface, more can anti-oxidation, so, it is relative to improve the speed and accuracy in detection.
Therefore with upper, it is plugged in this action reading device 70 as long as process chip 100 will be sieved soon and is connected electrically, Again via the running gear 80 such as intelligent mobile phone, iPad, iPod or mobile computer, perform computing through APP programs and just may be used Learn whether the residues of pesticides content of vegetables and fruits has been above standard value soon, it is not only fast and convenient in operation, and need not particular professional people Member just can be used, and this is then a big Gospel for consumer or hygienic inspector, along with the almost human hand of society now The convenience that the Technology Times of one machine are brought, the APP programs through running gear 80 can quickly learn testing result, allow vegetable Fruit Detecting Pesticide can veritably realize Rapid Screening, and the function of detection mode more Simple convenient.
It is noted that because fast sieve process chip 100, this action reading device 70 and this action device 80 can be with Body is carried, and fast sieve process chip 100 can be deserted test piece, therefore is being drawn materials under easily, and consumer wants detection vegetables and fruits Residues of pesticides content, then can be easier to be quick, and performed through the APP programs of running gear 80, vegetables and fruits can be learnt in real time Residues of pesticides content it is whether exceeded so that more secure edible.
It is described above, a preferred embodiment only of the present utility model, when the utility model can not be limited with this The scope of implementation, i.e., the simple equivalence changes made generally according to present utility model application the scope of the claims and new description with Modification, all should still belong in the range of the utility model patent covers.

Claims (7)

1. a kind of fast sieve process chip for detecting vegetables and fruits residues of pesticides, it is characterised in that include:
One basalis;
One circuit layer, is arranged on the basalis, and with a first electrode, a second electrode and a sensing limit, this first Electrode is connected with the sensing limit, and the second electrode is separately not connected with the sensing limit;
One fluorinated layer, is fluorinated polymers derivative, is covered on the circuit layer;
One barrier layer, is covered on the fluorinated layer, the circuit layer and the basalis, allow its part of circuit layer first electrode, Second electrode is revealed in outer, detection hole of the barrier layer with a sensing limit for corresponding to the circuit layer.
2. the fast sieve process chip of vegetables and fruits residues of pesticides is detected as claimed in claim 1, it is characterised in that:The circuit layer is Silver, it is silvery white that the wiring that process chip is sieved soon, which is revealed in outer part,.
3. the fast sieve process chip of vegetables and fruits residues of pesticides is detected as claimed in claim 1, it is characterised in that:Further include an antioxygen Change layer, the anti oxidation layer is covered on circuit layer, is folded between the circuit layer and fluorinated layer.
4. the fast sieve process chip of vegetables and fruits residues of pesticides is detected as claimed in claim 3, it is characterised in that:The anti oxidation layer is Silica.
5. the fast sieve process chip of vegetables and fruits residues of pesticides is detected as claimed in claim 1, it is characterised in that:The first electrode has First for having first guiding access for being located at front end and stretching out from first guiding access and being connected with the sensing limit connects Section is connect, the second electrode has second guiding access for being located at front end and the second connection stretched out from second guiding access Section, remaining between the second linkage section of the second electrode and the sensing limit to have a gap, the detection hole of the barrier layer is correspondence The first linkage section, the sensing limit, the second linkage section of the second electrode part and the gap in the first electrode part, with The first linkage section, the sensing limit, the second linkage section of part and the gap of part is set all to be revealed in outside.
6. the fast sieve process chip of vegetables and fruits residues of pesticides is detected as claimed in claim 1, it is characterised in that:The basalis is modeling Glue material matter or paper wood are made.
7. the fast sieve process chip of vegetables and fruits residues of pesticides is detected as claimed in claim 1, it is characterised in that:The fast sieve processing core Piece is inserted on a Port of an action reading device, to detect the numerical value of residues of pesticides.
CN201621118066.1U 2016-02-25 2016-10-13 Quick-screening processing chip for detecting pesticide residues on vegetables and fruits Expired - Fee Related CN206387761U (en)

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TW105202648U TWM526071U (en) 2016-02-25 2016-02-25 Rapid screening processing chip for detecting pesticides residue of vegetables and fruits
TW105202648 2016-02-25

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI792161B (en) * 2021-01-26 2023-02-11 富蘭登科技股份有限公司 Apparatus and method for measuring physical state of matter by spectroscopy

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI707630B (en) * 2019-04-02 2020-10-21 劉茂誠 Residue detecting device, and method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI792161B (en) * 2021-01-26 2023-02-11 富蘭登科技股份有限公司 Apparatus and method for measuring physical state of matter by spectroscopy

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Granted publication date: 20170808

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