CN206378334U - A kind of sulfuric acid mist extracts sampling apparatus - Google Patents

A kind of sulfuric acid mist extracts sampling apparatus Download PDF

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Publication number
CN206378334U
CN206378334U CN201621448958.8U CN201621448958U CN206378334U CN 206378334 U CN206378334 U CN 206378334U CN 201621448958 U CN201621448958 U CN 201621448958U CN 206378334 U CN206378334 U CN 206378334U
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China
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impact type
type absorption
absorption bottle
sulfuric acid
connecting tube
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CN201621448958.8U
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Chinese (zh)
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徐玮
丁慧玲
李继军
杨芳芳
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SUZHOU HANNENG ENVIRONMENTAL PROTECTION MATERIAL TECHNOLOGY Co Ltd
Suzhou Chinese A Surname Detects Science And Technology Ltd
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SUZHOU HANNENG ENVIRONMENTAL PROTECTION MATERIAL TECHNOLOGY Co Ltd
Suzhou Chinese A Surname Detects Science And Technology Ltd
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Abstract

Sampling apparatus, including filter cylinder, two impact type absorption bottles, aspiration pumps of series connection are extracted the utility model discloses a kind of sulfuric acid mist;Filter membrane component is provided with close to outlet port in the filter cylinder, the filter membrane component includes filter membrane, and the outlet port of the filter cylinder is connected with the first connecting tube;Two impact type absorption bottles of the series connection include the first impact type absorption bottle, the second impact type absorption bottle, it is placed in ice-water bath, the first impact type absorption bottle is connected with the first connecting tube, the second impact type absorption bottle is connected by the second connecting tube with the first impact type absorption bottle, and hydrogenperoxide steam generator is placed with the second impact type absorption bottle.The utility model is directed to the environmental aspect of China, extraction sampling is carried out to soluble sulphate in the sulfuric acid droplets included in sulfuric acid mist, sulfur dioxide, sulfur trioxide and particle, ensure the accuracy of measurement result, in the case of high humility, extract sampling efficiency excellent.

Description

A kind of sulfuric acid mist extracts sampling apparatus
Technical field
The utility model is related to technical field of environmental detection, more particularly to a kind of sulfuric acid mist extracts sampling apparatus.
Background technology
The smog that sulfuric acid particles are formed that sulfuric acid mist also makes acid mist be often referred to largely float has fossil-fuel-fired or ore deposit The sulfur-containing oxide waste gas discharged during thing smelting, sulfuric acid generation etc. is caused, and is a kind of atmosphere pollution phenomenon.Three in smoke evacuation Sulfur oxide is combined generation sulfuric acid mist with water vapor in air, and sulfuric acid mist is easily adsorbed on particulate matter, particulate matter in China's environment Content is higher, and the sulfuric acid mist in waste gas is main to be existed with sulfuric acid, sulfur dioxide, sulfur trioxide and soluble sulphate.Its danger Evil effect is bigger than sulfur dioxide 10 times.Acid Rain Pollution scope constantly expands as caused by sulfur dioxide (SO2) emissions, by the beginning of the eighties Southwestern some areas, extend to southwest, Central China, the most area in south China and East China, at present average annual precipitation pH value be less than 5.6 Area accounted for 40% of national area or so.Acid rain and sulfur dioxide pollution harm residents ' health, corrode construction material, destruction The ecosystem, causes huge economic losses annual hundred million yuan up to more than 200, it has also become the key factor of restriction socio-economic development One of.
Through retrieval, Chinese patent Authorization Notice No. is the practicality that CN205593828U, authorized announcement date are 2016-07-06 New patent discloses a kind of sulfuric acid mist and extracts sampling apparatus, including generator, extractor and eliminator stack, the extractor Including tower body and Ta Kou, the tower mouth is arranged at the top of the tower body;Also include being arranged at the filter membrane on the inside of the tower body, institute State and fixed on the downside of filter membrane by filter membrane branch net, the filter membrane branch net is fixed on the inner side of the tower body and is close to the filter membrane;Institute Tower mouthful is stated by three-way pipe with the generator and the eliminator stack to be connected;Described eliminator stack one end is provided with air inlet Mouthful;Air inlet pipe is inserted with the generator.Effectively sulfate and sulfuric acid are separated.
Because sulfuric acid mist is easily adsorbed on particulate matter, China's atmosphere particle concentration is higher, and particulate form sulfuric acid mist, which is accounted for, always to be contained The 45% of amount, according to the special environmental aspect of China, the definition of sulfuric acid mist is sulfuric acid droplets, sulfur dioxide, sulfur trioxide and Soluble sulphate in grain, but the object determined in above-mentioned patent only sulfuric acid, extraction accuracy is not good, and sulfuric acid mist is determined As a result it is inaccurate, it is impossible to represent the true emission behaviour of stationary source, and the method sampled is extracted for traditional use filter cylinder, by High using enterprise's discharge waste gas water content in traditional sulfuric acid, sulfuric acid droplet and sulfur trioxide gas penetrate readily through filter cylinder, Simultaneously China's wet cleaning facility popularity rate it is higher, therefore can not single use filter cylinder sampled.
Utility model content
The utility model is intended at least solve one of technical problem in correlation technique to a certain extent.Therefore, this reality It is to propose that a kind of sulfuric acid mist extracts sampling apparatus with a new purpose, for the environmental aspect of China, in sulfuric acid mist Comprising sulfuric acid droplets, sulfur dioxide, soluble sulphate carries out extraction sampling in sulfur trioxide and particle, it is ensured that measurement result Accuracy, in the case of high humility, extract sampling efficiency it is excellent.
Sampling apparatus, including filter cylinder, two impacts of series connection are extracted according to a kind of sulfuric acid mist of the utility model embodiment Formula absorption bottle, aspiration pump;
Filter membrane component is provided with close to outlet port in the filter cylinder, the filter membrane component includes filter membrane, and the filter cylinder goes out Gas port end is connected with the first connecting tube;
Two impact type absorption bottles of the series connection include the first impact type absorption bottle, the second impact type absorption bottle, put In ice-water bath, the first impact type absorption bottle is connected with the first connecting tube, and the second impact type absorption bottle passes through second Connecting tube is connected with the first impact type absorption bottle, and hydrogenperoxide steam generator is placed with the second impact type absorption bottle;
The aspiration pump is connected by the 3rd connecting tube with the second impact type absorption bottle, is set successively in the 3rd connecting tube There are valve, gas flowmeter, flow control valve and active carbon filter.
In some embodiments of the present utility model, the filter cylinder is glass fiber filter cylinder or quartz fibre filter cylinder.
In some embodiments of the present utility model, the filter membrane is 0.45 μm of ultra-fine fibre glass filter membrane or 0.45 μm of stone English fibrous filter membrane.
In some embodiments of the present utility model, the bottom of first connecting tube is located in the first impact type absorption bottle Bottom, the bottom of second connecting tube is located at the bottom in the second impact type absorption bottle.
In other embodiments of the present utility model, the first impact type absorption bottle and the second connecting tube, the second punching Formula absorption bottle is hit with the 3rd connecting tube by snap joint to be connected.
In the utility model, aerosol sample can extract by filter cylinder, wherein filter membrane can extract particle in uncontrollable discharge Thing sample, sulfuric acid mist, including sulfuric acid droplets, sulfur dioxide, three oxidations can be filtered by two impact type absorption bottles collection of series connection Sulphur, for the environmental aspect of China, to solvable in the sulfuric acid droplets included in sulfuric acid mist, sulfur dioxide, sulfur trioxide and particle Property sulfate carry out extraction sampling, it is ensured that the accuracy of measurement result, in the case of high humility, extract sampling efficiency it is excellent.
Brief description of the drawings
Accompanying drawing is used for providing further understanding to of the present utility model, and constitutes a part for specification, with this practicality New embodiment is used to explain the utility model together, does not constitute to limitation of the present utility model.In the accompanying drawings:
Fig. 1 be the utility model proposes a kind of sulfuric acid mist extract sampling apparatus structural representation.
In figure:1 filter cylinder, 2 filter membrane components, 3 first connecting tubes, 4 first impact type absorption bottles, 5 second impact type absorption bottles, 6 ice-water baths, 7 second connecting tubes, 8 the 3rd connecting tubes, 9 aspiration pumps, 10 valves, 11 gas flowmeters, 12 flow control valves, 13 are lived Property carbon filter.
Embodiment
Below in conjunction with the accompanying drawing in the utility model embodiment, the technical scheme in the utility model embodiment is carried out Clearly and completely describe, it is clear that described embodiment is only a part of embodiment of the utility model, rather than whole Embodiment.
The example of the embodiment is shown in the drawings, wherein same or similar label represents identical or class from beginning to end As element or the element with same or like function.The embodiments described below with reference to the accompanying drawings are exemplary, purport For explaining the utility model, and it is not intended that to limitation of the present utility model.
In description of the present utility model, it is to be understood that term " " center ", " longitudinal direction ", " transverse direction ", " length ", " width Degree ", " thickness ", " on ", " under ", "front", "rear", "left", "right", " vertical ", " level ", " top ", " bottom " " interior ", " outer ", " suitable The orientation or position relationship of the instruction such as hour hands ", " counterclockwise ", " axial direction ", " radial direction ", " circumference " are based on orientation shown in the drawings Or position relationship, be for only for ease of description the utility model and simplify and describe, rather than indicate or imply signified device or Element must have specific orientation, with specific azimuth configuration and operation, therefore it is not intended that to limit of the present utility model System.
In addition, term " first ", " second " are only used for describing purpose, and it is not intended that indicating or implying relative importance Or the implicit quantity for indicating indicated technical characteristic.Thus, define " first ", the feature of " second " can express or Implicitly include one or more this feature.In description of the present utility model, " multiple " are meant that two or two More than, unless otherwise specifically defined.
In the utility model, unless otherwise clearly defined and limited, term " installation ", " connected ", " connection ", " Gu It is fixed " etc. term should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integrally;Can be Mechanically connect or electrically connect;Can be joined directly together, can also be indirectly connected to by intermediary, can be two The connection of element internal or the interaction relationship of two elements.For the ordinary skill in the art, can basis Concrete condition understands concrete meaning of the above-mentioned term in the utility model.
A kind of reference picture 1, sulfuric acid mist extracts sampling apparatus, including filter cylinder 1, two impact type absorption bottles of series connection, pumping Pump;Filter membrane component 2 is provided with close to outlet port in filter cylinder 1, filter membrane component includes filter membrane and filter holder, and filter holder passes through spiral shell The mode of line is removably attached in filter cylinder 1, and the outlet port of filter cylinder 1 is connected with the first connecting tube 3;Two impacts of series connection Formula absorption bottle includes the first impact type absorption bottle 4, the second impact type absorption bottle 5, is placed in ice-water bath 6, and the first impact type is inhaled Receive bottle 4 with the first connecting tube 3 to be connected, the second impact type absorption bottle 5 passes through the second connecting tube 7 and the first impact type absorption bottle phase Even, 30mmol/L hydrogenperoxide steam generators are placed with the second impact type absorption bottle 5;Aspiration pump 9 passes through the 3rd connecting tube 8 and second Impact type absorption bottle 5 is connected, and valve 10, gas flowmeter 11, flow control valve 12 and activity are sequentially provided with the 3rd connecting tube 8 Carbon filter 13, wherein, the model LZJ-25F glass rotameters of gas flowmeter 11, the model of flow control valve 12 For SG-ZZ-2, the model VAK5008 minipumps of aspiration pump 9, the pollution that active carbon filter 13 is used in adsorbed gas Thing.
In some embodiments of the present utility model, filter cylinder 1 is glass fiber filter cylinder, in collection in a organized way discharge Grain thing sample.
In some embodiments of the present utility model, filter membrane is 0.45 μm of ultra-fine fibre glass filter membrane, for gathering no group Knit aerosol sample in discharge.
In some embodiments of the present utility model, the bottom of the first connecting tube 3 is located in the first impact type absorption bottle 4 Bottom, the bottom of the second connecting tube 7 is located at the bottom in the second impact type absorption bottle 5, is easy to sulfuric acid droplets, sulfur dioxide, three The absorption of sulfur oxide.
In other embodiments of the present utility model, the first impact type absorption bottle 4 and the second connecting tube 7, second are impacted Formula absorption bottle 5 is connected with the 3rd connecting tube 8 by snap joint, and each connecting portion is sealed will not gas leakage.
Waste sample for moisture content is low, more than Particulate Inclusion thing, the absorptivity of filter cylinder 1 contains up to 92.6%-98.4% The high waste gas sample of moisture, sulfuric acid droplets, sulfur dioxide gas, sulfur trioxide gas easily penetrate filter cylinder 1, filtered with glass fibre Cylinder, filter membrane carry out isokinetic sampling, with water extraction, after decationizing, in weakly acidic solution, the sulfuric acid in alkali piece sample solution Radical ion and barium chromate suspension reaction generation barium sulfate.In ammonia-ethanol solution, the chromic acid of barium sulfate and excess is separated off Barium, the yellow chromate ion of reaction release is directly proportional to sulfate concentration, according to shade, with spectrophotometry, Plus sulfuric acid droplets in the first impact type absorption bottle 4, the second impact type absorption bottle 5, sulfur dioxide, sulfur trioxide detection knot Really, it is the measurement result of whole sulfuric acid mists, it is more representative, in the case of high humility, extract sampling efficiency excellent.
In the utility model, unless otherwise clearly defined and limited, fisrt feature is "above" or "below" second feature Can be that the first and second features are directly contacted, or the first and second features pass through intermediary mediate contact.Moreover, first is special Levy second feature " on ", " top " and " above " but fisrt feature directly over second feature or oblique upper, or only Represent that fisrt feature level height is higher than second feature.Fisrt feature second feature " under ", " lower section " and " below " can be with Be fisrt feature immediately below second feature or obliquely downward, or be merely representative of fisrt feature level height less than second feature.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means to combine specific features, structure, material or the spy that the embodiment or example are described Point is contained at least one embodiment of the present utility model or example.In this manual, to the schematic table of above-mentioned term State and be not necessarily referring to identical embodiment or example.Moreover, specific features, structure, material or the feature of description can be Combined in an appropriate manner in any one or more embodiments or example.
It is described above, only the utility model preferably embodiment, but protection domain of the present utility model is not This is confined to, any one skilled in the art is in the technical scope that the utility model is disclosed, according to this practicality New technical scheme and its utility model design are subject to equivalent substitution or change, should all cover in protection model of the present utility model Within enclosing.

Claims (5)

1. a kind of sulfuric acid mist extracts sampling apparatus, it is characterised in that:Including filter cylinder, two impact type absorption bottles of series connection, pumping Pump;
Filter membrane component is provided with close to outlet port in the filter cylinder, the filter membrane component includes filter membrane, the gas outlet of the filter cylinder End is connected with the first connecting tube;
Two impact type absorption bottles of the series connection include the first impact type absorption bottle, the second impact type absorption bottle, are placed in ice In water-bath, the first impact type absorption bottle is connected with the first connecting tube, and the second impact type absorption bottle passes through the second connection Pipe is connected with the first impact type absorption bottle, and hydrogenperoxide steam generator is placed with the second impact type absorption bottle;
The aspiration pump is connected by the 3rd connecting tube with the second impact type absorption bottle, and valve is sequentially provided with the 3rd connecting tube Door, gas flowmeter, flow control valve and active carbon filter.
2. a kind of sulfuric acid mist according to claim 1 extracts sampling apparatus, it is characterised in that:The filter cylinder is glass fibre Filter cylinder or quartz fibre filter cylinder.
3. a kind of sulfuric acid mist according to claim 1 extracts sampling apparatus, it is characterised in that:The filter membrane is 0.45 μm and surpassed Thin glass fiber filter membrane or 0.45 μm of quartz fibre filter membrane.
4. a kind of sulfuric acid mist according to claim 1 extracts sampling apparatus, it is characterised in that:The bottom of first connecting tube End is located at the bottom in the first impact type absorption bottle, and the bottom of second connecting tube is located at the bottom in the second impact type absorption bottle Portion.
5. a kind of sulfuric acid mist according to claim 1 extracts sampling apparatus, it is characterised in that:First impact type absorbs Bottle is connected with the second connecting tube, the second impact type absorption bottle with the 3rd connecting tube by snap joint.
CN201621448958.8U 2016-12-27 2016-12-27 A kind of sulfuric acid mist extracts sampling apparatus Active CN206378334U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107894491A (en) * 2017-10-27 2018-04-10 东南大学 Test the device and method of water soluble ion concentration in wet desulphurization neat stress
CN108871877A (en) * 2018-04-03 2018-11-23 南京师范大学 A kind of multistage temperature control acquisition condensable particulate matter device
CN109077044A (en) * 2018-08-31 2018-12-25 岳西县惠友生态农业有限公司 A kind of agricultural irrigating cart
CN110220755A (en) * 2019-07-24 2019-09-10 福建省锅炉压力容器检验研究院 A kind of stationary source sulfureous in flue gas acid mist sample devices

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107894491A (en) * 2017-10-27 2018-04-10 东南大学 Test the device and method of water soluble ion concentration in wet desulphurization neat stress
CN108871877A (en) * 2018-04-03 2018-11-23 南京师范大学 A kind of multistage temperature control acquisition condensable particulate matter device
CN108871877B (en) * 2018-04-03 2021-08-10 南京师范大学 Device for collecting condensable particles through multistage temperature control
CN109077044A (en) * 2018-08-31 2018-12-25 岳西县惠友生态农业有限公司 A kind of agricultural irrigating cart
CN110220755A (en) * 2019-07-24 2019-09-10 福建省锅炉压力容器检验研究院 A kind of stationary source sulfureous in flue gas acid mist sample devices

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