Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol
Technical field
The utility model belongs to Coal Chemical Industry, petrochemical industry and field of fine chemical, and being related to a kind of volatility containing polyalcohol has
Equipment of the purification of alcohols with reclaiming in machine waste gas, the equipment is mainly used in organic containing polyalcohol (C1~C10 alcohols) volatility
Alcohols purification and recovery, particularly polyalcohol (C1~C10 alcohols) volatile organic waste gas for long boiling range in waste gas (VOC)
(VOC) or long boiling range polyalcohol (C1~C10 alcohols) volatile organic waste gas (VOC) and polarity organic waste or not acid reaction
Alcohols purification is with reclaiming in the mix waste gas of gas (aldehyde, ketone etc.) composition.
Background technology
In recent years, with the development of domestic economy, the demand of various chemical products is growing, increasing chemical industry enterprise
Industry is set up therewith.With the increasingly raising that the foundation of new spectra, the development of long-established enterprise and people are required life, enterprise
The environmental issue of industry becomes outstanding day by day.
The processing method of current traditional volatile organic exhaust gas (VOC) mainly has:Heat damage method, traditional burning at present or
Catalytic combustion technology is gradually replaced by heat storage type combustion (RTO) and heat accumulating type catalytic combustion (RCO) technology.But it is dense by waste gas
The influence of impurity in degree and waste gas, the application of direct combustion method is restricted, the regenerative combustion technology come into vogue in recent years
(RTO) and heat accumulating type catalytic combustion technology (RCO), operating temperature is high, and the once investment of equipment is larger, and cost is higher, works as processing
Equipment needs increase during high flux gas, can increase equipment investment.Absorption method, when having micelle or other impurities to be in waste gas, is adsorbed
Agent is easily poisoned, and absorption method is mainly used in low concentration, high-throughout VOC processing.Absorption process, pollutant is handled according to absorbent
Method is divided into chemical absorbing and Physical Absorption, and the advantage of absorption process is that absorbent can be reused, and pollutant can obtain comprehensive profit
With.Several processing methods except more than, with technology development in recent years, lower temperature plasma technology, biologic treating technique is not
Disconnected development, is constantly widened using scope.
With coal gas, the development of coal liquifaction at home in recent years, there is intermediate products first in gas processed and oil-producing technique
Side reaction is had in the synthesis technique of alcohol, synthesising gas systeming carbinol technical process to occur to produce a large amount of accessory substances, is being produced and is being refined
During can produce the substantial amounts of organic exhaust gas containing polyalcohol (C1~C10 alcohols), traditional handicraft is mostly direct by this waste gas
Emptying enters the burning of torch pipe network, and directly emptying can cause the pollution of air, and enter dropping a hint for torch pipe network, compare
Easily reach explosion limit and produce explosion danger.Meanwhile, it is vented and burns the waste for causing large-tonnage product.In fine chemistry industry
Also alcohols, aldehydes or ketone often are used as solvent, above-mentioned solvent, which is evaporate into air, easily causes volatile organic waste gas (VOC)
Pollution.At present, the purification of traditional organic exhaust gas (VOC) mainly uses thermal accumulating incinerator (RTO) or absorbing process, though
Right RTO stoves can effectively handle the organic exhaust gas (VOC) in waste gas, but equipment investment cost is higher, and in order to
Ensure the waste gas that the stable accumulation of heat of ceramic heat-storing physical efficiency then needs upstream to have steady and continuous.Waste gas is noted also before burning simultaneously
The explosion limit of interior each material, if having material in waste gas in the range of explosion limit, it is necessary to dilute waste gas using large quantity of air,
The explosion limit of waste gas is reduced, undoubtedly this will increase waste gas treatment equipment size, add the cost of exhaust-gas treatment.It is simultaneously a large amount of
Utility is burned to cause the wasting of resources.And use absorbing process to produce substantial amounts of solid waste per annual meeting, cause at waste gas
The secondary pollution of reason.
Utility model content
The purpose of this utility model is to provide the purification and recovery of alcohols in a kind of volatile organic waste gas containing polyalcohol
Equipment, a kind of new processing method based on the equipment development, for containing polyalcohol (C1~C10 alcohols) volatility organic waste
Alcohols purification is with reclaiming in gas (VOC), and the equipment investment is small, energy consumption is low, pollution-free, low emission, many in waste gas by reclaiming
First alcohol improves the added value of whole technique, increases economic efficiency.
The purpose of this utility model is achieved through the following technical solutions:
Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol, including dealcoholysis tower 1, scrubbing tower
2nd, two-phase laminated flow tank 5, hydrolysis rectifying column 6, alcohol rectifying column 7, alcohol rectifying column reboiler 8;The described bottom of dealcoholysis tower 1 is entered provided with side
Exhaust gas inlet, the top of dealcoholysis tower 1 is provided with gas outlet, and the top of dealcoholysis tower 1 is provided with acid absorbent import, and the bottom of dealcoholysis tower 1 is provided with
Leakage fluid dram;Described dealcoholysis tower 1 is connected through top gas outlet with the air inlet of described scrubbing tower 2, and the top of scrubbing tower 2 is provided with row
Gas port, tail gas is directly discharged through exhaust outlet after being washed into scrubbing tower 2;The described bottom leakage fluid dram of dealcoholysis tower 1 is through drain line
It is connected with the inlet of described two-phase laminated flow tank 5, the heavy component outlet of two-phase laminated flow tank 5 and the acid absorbent of dealcoholysis tower 1 enter
Mouthful connection, the acid-containing solution of two phases were separated the lower floor of tank 5 return dealcoholysis tower 1 as acid absorbent again with raw material waste gas reaction,
The Light ends outlet of two-phase laminated flow tank 5 is connected with the inlet of hydrolysis rectifying column 6, and the ester on two phases were separated the upper strata of tank 5 sends into water
Solve rectifying column 6;Described hydrolysis rectifying column 6 bottom discharge mouthful is connected heavy constituent and two with the acid absorbent import of dealcoholysis tower 1
What phase separation pot 5 was discharged reuses containing return dealcoholysis tower 1 after sour phase materials mixing, hydrolysis rectifying column 6 top discharge mouthful and alcohol
Light component containing alcohol and water is sent into alcohol rectifying column 7 by the connection of the charging aperture of rectifying column 7, and described alcohol rectifying column 7 is provided with reboiler 8
Alcohol rectifying column 7 is sent back to after bottom of towe liquid portion is vaporized.
It is preferred that, 3A molecular sieve layers are provided with described dealcoholysis tower 1,3A molecular sieve layers use fluid bed or fixed bed
Form.
It is preferred that, dealcoholysis tower circulating pump 4 is provided with the described drain line of dealcoholysis tower 1.
It is preferred that, the described bottom drain road of dealcoholysis tower 1 makes the leakage fluid dram of dealcoholysis tower 1 be absorbed with top acid provided with branch road
Agent import is connected, and sour absorbing liquid is pumped into dealcoholysis tower 1 and recycled.
Described scrubbing tower 2 is water scrubber or caustic wash tower.
The described top of scrubbing tower 2 is used to input cleaning solution provided with inlet, and the bottom of scrubbing tower 2 is provided with liquid outlet, goes out liquid
Mouth is connected to discharge scrub raffinate with discharge of wastewater pipeline.Cleaning circulation pump 3 is provided with described discharge of wastewater pipeline.
It is preferred that, provided with branch road make the liquid outlet of scrubbing tower 2 and top feed liquor in the discharge of wastewater pipeline of described scrubbing tower 2
Mouth connection, is pumped into scrubbing tower 2 by cleaning solution and recycles.
Alcohols is net in (C1~C10 alcohols) volatile organic waste gas Han polyalcohol (VOC) based on the utility model equipment
Change and recovery method, if comprised only in waste gas polyalcohol (unitary such as C1~C10 alcohols, specially methanol, ethanol, ethylene glycol,
Binary and polyalcohol) and air (containing oxygen, nitrogen), step is as follows:
Step (1), absorption dealcoholysis, raw material waste gas is passed through dealcoholysis tower 1, at normal pressure, 80~150 DEG C of temperature, raw material waste gas
Bottom-up flowing, acid absorbent flow from up to down with raw material waste gas counter current contacting, in acid absorbent effective acid with alcohol in 3A
The lower reaction generation ester of molecular sieve catalyst effect, the reaction is a reversible reaction, by making raw material acid absorbent excessive, is made anti-
It should be moved to positive direction, improve alcohol reacting dose, one side acidic catalysis conditions esterification speed is fast, still further aspect molecular sieve
The water that can be generated with adsorption reaction so that balance forward direction, is accelerated absorbing reaction speed and yield, purification waste gas is reached with this
Purpose;Wherein, acid absorbent is sulfuric acid and one or two kinds of mixing in phosphoric acid or boric acid.
Step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 are passed through scrubbing tower 2, wash away the volatility remained in waste gas
Alcohol, tail gas can be discharged directly;
Step (3), from the bottom of towe of dealcoholysis tower 1 liquid containing ester and acid is discharged, ester is immiscible with acid, in two-phase laminated flow tank 5
Two-phase is separated after middle standing, and lower floor's heavy component is acid-containing solution, after treatment as acid absorbent return dealcoholysis tower 1 again with
Raw material waste gas reaction;Ester after two-phase laminated flow is upper strata light component, into hydrolysis rectifying column 6, in high temperature environments, hydrolysis generation
Alcohol, water and acid, alcohol and water low boiling point are light components, constantly rise in hydrolysis rectifying column 6, alcohol rectifying column is discharged into from tower top
7, tower reactor heavy component is higher boiling acids, and can return to dealcoholysis tower 1 through processing reuses as acid absorbent;
The light component that step (4), the hydrolysis top row of rectifying column 6 go out enters alcohol rectifying column 7, different according to the boiling point of alcohol, by alcohol
Separate.
If waste gas has for polyalcohol (C1~C10 alcohols) volatile organic waste gas (VOC) with the polarity or not acid reaction
The mix waste gas of machine waste gas (aldehyde, ketone, hydro carbons etc., specific such as formaldehyde, acetaldehyde, acetone) composition,
Step (1), step (3), step (5) are identical with the waste gas of air with comprising only polyalcohol.
Simply in step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 enters scrubbing tower 2, and aldehyde, ketone are absorbed with aqueous slkali,
The waste gas that processing is completed can safety dumping.
The above method based on principle:Unitary, binary and the polyalcohol contained in organic exhaust gas, in the catalyst concentrated sulfuric acid
Lower and phosphoric acid or/and acid reaction generation ester are acted on, because this is a reversible reaction, to ensure to remove tail gas to greatest extent
In alcohol, it is necessary to ensure excessive acid in absorbing reaction.And hydrolysis rectifying column 6 in ester hydrolysis, ester hydrolysis be esterification back reaction,
Need constantly to remove the alcohol that hydrolysis is come, it is ensured that reaction is constantly moved to the left, ester hydrolysis reaction enters in the hydrolysis tower reactor of rectifying column 6
OK, constantly volatilize and discharged from tower top as the alcohol and water of light component, reaction is constantly carried out by heating while hydrolysis.Hydrolysis
The tower top of rectifying column 6 discharge mixed alcohol obtains different alcohol from water through the rectifying of alcohol rectifying column 7.
Compared with prior art, the beneficial effects of the utility model:
The utility model equipment investment is small, energy consumption is low.Alcohol in volatile organic waste gas containing polyalcohol is realized using this equipment
In the mix waste gas that class purification is constituted with recovery or polyalcohol volatile organic waste gas and or not the polarity organic exhaust gas of acid reaction
Alcohols is purified with reclaiming, and flow is short, without high-temperature service, and purification efficiency is high, can serialization or semicontinuous processing, recovery waste gas
In polyalcohol, realize pollution-free, low emission, both solve pollution problem, while improve the added value of whole technique, improve warp
Ji benefit.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model equipment;
In Fig. 1,1-dealcoholysis tower;2-scrubbing tower;3-cleaning circulation pump;4-dealcoholysis tower circulating pump;5-two-phase laminated flow
Tank;6-hydrolysis rectifying column;7-alcohol rectifying column;8-reboiler.
Embodiment
The technical solution of the utility model is further described below by embodiment.
As shown in figure 1, equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol, including dealcoholysis
Tower 1, scrubbing tower 2, two-phase laminated flow tank 5, hydrolysis rectifying column 6, alcohol rectifying column 7, alcohol rectifying column reboiler 8;Under described dealcoholysis tower 1
The exhaust gas inlet that portion is entered provided with side, the top of dealcoholysis tower 1 is provided with gas outlet, and the top of dealcoholysis tower 1 is provided with acid absorbent import, dealcoholysis tower
1 bottom is provided with leakage fluid dram;The described top gas outlet of dealcoholysis tower 1 is connected with the air inlet of described scrubbing tower 2, and scrubbing tower 2 is pushed up
Portion is provided with exhaust outlet, and tail gas is directly discharged through exhaust outlet after being washed into scrubbing tower 2;The described bottom leakage fluid dram warp of dealcoholysis tower 1
Drain line is connected with the inlet of described two-phase laminated flow tank 5, and dealcoholysis tower circulating pump 4 is provided with the drain line of dealcoholysis tower 1,
The heavy component outlet of two-phase laminated flow tank 5 be connected with the acid absorbent import of dealcoholysis tower 1, the Light ends of two-phase laminated flow tank 5 export and
Hydrolyze the inlet connection of rectifying column 6;The acid absorbent import of described hydrolysis rectifying column 6 bottom discharge mouthful and dealcoholysis tower 1 connects
Connect return dealcoholysis tower 1 after the phase materials containing acid for discharging heavy constituent and two-phase laminated flow tank 5 are mixed to reuse, hydrolyze rectifying column 6
Top discharge mouth is connected with the charging aperture of alcohol rectifying column 7 by the light component feeding alcohol rectifying column 7 containing alcohol and water, described alcohol rectifying
Tower 7 is provided with reboiler 8, different according to the boiling point of alcohol, and alcohol is separated.
3A molecular sieve layers are provided with described dealcoholysis tower 1,3A molecular sieve layers use fluid bed or fixed bed form.
The described bottom drain road of dealcoholysis tower 1 makes the leakage fluid dram of dealcoholysis tower 1 and top acid absorbent import provided with branch road
Connection, is pumped into dealcoholysis tower 1 by sour absorbing liquid and recycles.
Described scrubbing tower 2 is water scrubber or caustic wash tower.
The described top of scrubbing tower 2 is used to input cleaning solution provided with inlet, and the bottom of scrubbing tower 2 is provided with liquid outlet, goes out liquid
Mouth is connected to discharge scrub raffinate with discharge of wastewater pipeline.Cleaning circulation pump 3 is provided with described wastewater discharge pipe.Institute
The discharge of wastewater pipeline for the scrubbing tower 2 stated makes the liquid outlet of scrubbing tower 2 be connected with top inlet provided with branch road, and cleaning solution is pumped into
Scrubbing tower 2 is recycled.
Alcohols purification and recovery method in volatile organic waste gas containing polyalcohol based on the present embodiment equipment, if waste gas
In comprise only polyalcohol (unitary such as C1~C10 alcohols, specially methanol, ethanol, ethylene glycol, binary and polyalcohol) and air
(containing oxygen, nitrogen), scrubbing tower 2 is water scrubber, and step is as follows:
Step (1), absorption dealcoholysis, raw material waste gas is passed through dealcoholysis tower 1, at normal pressure, 80~150 DEG C of temperature, raw material waste gas
Bottom-up flowing, acid absorbent flow from up to down with raw material waste gas counter current contacting, in acid absorbent effective acid with alcohol in 3A
The lower reaction generation ester of molecular sieve catalyst effect;Wherein, acid absorbent is one or two kinds of in sulfuric acid and phosphoric acid or boric acid
Mixing;
Step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 are passed through water scrubber 2, wash away the volatility remained in waste gas
Alcohol, tail gas can be discharged directly;
Step (3), from the bottom of towe of dealcoholysis tower 1 liquid containing ester and acid is discharged, ester is immiscible with acid, in two-phase laminated flow tank 5
Two-phase is separated after middle standing, acid solution after treatment as acid absorbent return dealcoholysis tower 1 again with raw material waste gas reaction;Two
Ester after phase separation enters hydrolysis rectifying column 6, in high temperature environments, hydrolysis generation alcohol, water and acid, and alcohol and water low boiling point is light group
Point, constantly rise in hydrolysis rectifying column 6, be discharged into alcohol rectifying column 7 from tower top, tower reactor heavy component is higher boiling acids, through processing
Dealcoholysis tower 1 is can return to reuse as acid absorbent;
The light component that step (4), the hydrolysis top row of rectifying column 6 go out enters alcohol rectifying column 7, different according to the boiling point of alcohol, by alcohol
Separate.
If waste gas is polyalcohol volatile organic waste gas and polarity organic exhaust gas (aldehyde, ketone, hydro carbons or not acid reaction
Deng specific such as formaldehyde, acetaldehyde, acetone) mix waste gas of composition, scrubbing tower 2 is caustic wash tower, and step is as follows:
Step (1), absorption dealcoholysis, raw material waste gas is passed through dealcoholysis tower 1, at normal pressure, 80~150 DEG C of temperature, raw material waste gas
Bottom-up flowing, acid absorbent flow from up to down with raw material waste gas counter current contacting, in acid absorbent effective acid with alcohol in 3A
The lower reaction generation ester of molecular sieve catalyst effect;Wherein, acid absorbent is one or two kinds of in sulfuric acid and phosphoric acid or boric acid
Mixing;
Step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 enters caustic wash tower 2, and aldehyde, ketone are absorbed with aqueous slkali, and processing is completed
Waste gas can safety dumping;
Step (3), from the bottom of towe of dealcoholysis tower 1 liquid containing ester and acid is discharged, ester is immiscible with acid, in two-phase laminated flow tank 5
Two-phase is separated after middle standing, acid solution after treatment as acid absorbent return dealcoholysis tower 1 again with raw material waste gas reaction;Two
Ester after phase separation enters hydrolysis rectifying column 6, in high temperature environments, hydrolysis generation alcohol, water and acid, and alcohol and water low boiling point is light group
Point, constantly rise in hydrolysis rectifying column 6, be discharged into alcohol rectifying column 7 from tower top, tower reactor heavy component is higher boiling acids, through processing
Dealcoholysis tower 1 is can return to reuse as acid absorbent;
The light component that step (4), the hydrolysis top row of rectifying column 6 go out enters alcohol rectifying column 7, different according to the boiling point of alcohol, by alcohol
Separate.