CN206315665U - Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol - Google Patents

Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol Download PDF

Info

Publication number
CN206315665U
CN206315665U CN201621425032.7U CN201621425032U CN206315665U CN 206315665 U CN206315665 U CN 206315665U CN 201621425032 U CN201621425032 U CN 201621425032U CN 206315665 U CN206315665 U CN 206315665U
Authority
CN
China
Prior art keywords
tower
rectifying column
waste gas
dealcoholysis
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201621425032.7U
Other languages
Chinese (zh)
Inventor
谢佳华
石杨夏艳
王健
高云山
钮跟跟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yan'an Jia'an Energy Technology Co., Ltd.
Original Assignee
Nanjing Insipai Engineering Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Insipai Engineering Technology Co Ltd filed Critical Nanjing Insipai Engineering Technology Co Ltd
Priority to CN201621425032.7U priority Critical patent/CN206315665U/en
Application granted granted Critical
Publication of CN206315665U publication Critical patent/CN206315665U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

Equipment the utility model discloses a kind of purification of alcohols in volatile organic waste gas containing polyalcohol with reclaiming, including dealcoholysis tower, scrubbing tower, two-phase laminated flow tank, hydrolysis rectifying column, alcohol rectifying column, reboiler;The exhaust gas inlet that dealcoholysis tower bottom is entered provided with side, top is provided with gas outlet, and top is provided with acid absorbent import, and bottom is provided with leakage fluid dram;Dealcoholysis tower gas outlet is connected with scrubbing tower air inlet, and exhaust outlet is provided with the top of scrubbing tower;Dealcoholysis tower bottom leakage fluid dram is connected through drain line with the inlet of two-phase laminated flow tank, and the heavy component outlet of two-phase laminated flow tank is connected with the acid absorbent import of dealcoholysis tower, and the Light ends outlet of two-phase laminated flow tank is connected with hydrolyzing the inlet of rectifying column;Hydrolysis rectifier bottoms discharging opening is connected with the acid absorbent import of dealcoholysis tower, and floss hole is connected with alcohol rectifying column charging aperture at the top of hydrolysis rectifying column.The utility model equipment investment is small, energy consumption is low, flow is short, the polyalcohol in exhaust gas recycling, and purification efficiency is high, realizes pollution-free, low emission.

Description

Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol
Technical field
The utility model belongs to Coal Chemical Industry, petrochemical industry and field of fine chemical, and being related to a kind of volatility containing polyalcohol has Equipment of the purification of alcohols with reclaiming in machine waste gas, the equipment is mainly used in organic containing polyalcohol (C1~C10 alcohols) volatility Alcohols purification and recovery, particularly polyalcohol (C1~C10 alcohols) volatile organic waste gas for long boiling range in waste gas (VOC) (VOC) or long boiling range polyalcohol (C1~C10 alcohols) volatile organic waste gas (VOC) and polarity organic waste or not acid reaction Alcohols purification is with reclaiming in the mix waste gas of gas (aldehyde, ketone etc.) composition.
Background technology
In recent years, with the development of domestic economy, the demand of various chemical products is growing, increasing chemical industry enterprise Industry is set up therewith.With the increasingly raising that the foundation of new spectra, the development of long-established enterprise and people are required life, enterprise The environmental issue of industry becomes outstanding day by day.
The processing method of current traditional volatile organic exhaust gas (VOC) mainly has:Heat damage method, traditional burning at present or Catalytic combustion technology is gradually replaced by heat storage type combustion (RTO) and heat accumulating type catalytic combustion (RCO) technology.But it is dense by waste gas The influence of impurity in degree and waste gas, the application of direct combustion method is restricted, the regenerative combustion technology come into vogue in recent years (RTO) and heat accumulating type catalytic combustion technology (RCO), operating temperature is high, and the once investment of equipment is larger, and cost is higher, works as processing Equipment needs increase during high flux gas, can increase equipment investment.Absorption method, when having micelle or other impurities to be in waste gas, is adsorbed Agent is easily poisoned, and absorption method is mainly used in low concentration, high-throughout VOC processing.Absorption process, pollutant is handled according to absorbent Method is divided into chemical absorbing and Physical Absorption, and the advantage of absorption process is that absorbent can be reused, and pollutant can obtain comprehensive profit With.Several processing methods except more than, with technology development in recent years, lower temperature plasma technology, biologic treating technique is not Disconnected development, is constantly widened using scope.
With coal gas, the development of coal liquifaction at home in recent years, there is intermediate products first in gas processed and oil-producing technique Side reaction is had in the synthesis technique of alcohol, synthesising gas systeming carbinol technical process to occur to produce a large amount of accessory substances, is being produced and is being refined During can produce the substantial amounts of organic exhaust gas containing polyalcohol (C1~C10 alcohols), traditional handicraft is mostly direct by this waste gas Emptying enters the burning of torch pipe network, and directly emptying can cause the pollution of air, and enter dropping a hint for torch pipe network, compare Easily reach explosion limit and produce explosion danger.Meanwhile, it is vented and burns the waste for causing large-tonnage product.In fine chemistry industry Also alcohols, aldehydes or ketone often are used as solvent, above-mentioned solvent, which is evaporate into air, easily causes volatile organic waste gas (VOC) Pollution.At present, the purification of traditional organic exhaust gas (VOC) mainly uses thermal accumulating incinerator (RTO) or absorbing process, though Right RTO stoves can effectively handle the organic exhaust gas (VOC) in waste gas, but equipment investment cost is higher, and in order to Ensure the waste gas that the stable accumulation of heat of ceramic heat-storing physical efficiency then needs upstream to have steady and continuous.Waste gas is noted also before burning simultaneously The explosion limit of interior each material, if having material in waste gas in the range of explosion limit, it is necessary to dilute waste gas using large quantity of air, The explosion limit of waste gas is reduced, undoubtedly this will increase waste gas treatment equipment size, add the cost of exhaust-gas treatment.It is simultaneously a large amount of Utility is burned to cause the wasting of resources.And use absorbing process to produce substantial amounts of solid waste per annual meeting, cause at waste gas The secondary pollution of reason.
Utility model content
The purpose of this utility model is to provide the purification and recovery of alcohols in a kind of volatile organic waste gas containing polyalcohol Equipment, a kind of new processing method based on the equipment development, for containing polyalcohol (C1~C10 alcohols) volatility organic waste Alcohols purification is with reclaiming in gas (VOC), and the equipment investment is small, energy consumption is low, pollution-free, low emission, many in waste gas by reclaiming First alcohol improves the added value of whole technique, increases economic efficiency.
The purpose of this utility model is achieved through the following technical solutions:
Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol, including dealcoholysis tower 1, scrubbing tower 2nd, two-phase laminated flow tank 5, hydrolysis rectifying column 6, alcohol rectifying column 7, alcohol rectifying column reboiler 8;The described bottom of dealcoholysis tower 1 is entered provided with side Exhaust gas inlet, the top of dealcoholysis tower 1 is provided with gas outlet, and the top of dealcoholysis tower 1 is provided with acid absorbent import, and the bottom of dealcoholysis tower 1 is provided with Leakage fluid dram;Described dealcoholysis tower 1 is connected through top gas outlet with the air inlet of described scrubbing tower 2, and the top of scrubbing tower 2 is provided with row Gas port, tail gas is directly discharged through exhaust outlet after being washed into scrubbing tower 2;The described bottom leakage fluid dram of dealcoholysis tower 1 is through drain line It is connected with the inlet of described two-phase laminated flow tank 5, the heavy component outlet of two-phase laminated flow tank 5 and the acid absorbent of dealcoholysis tower 1 enter Mouthful connection, the acid-containing solution of two phases were separated the lower floor of tank 5 return dealcoholysis tower 1 as acid absorbent again with raw material waste gas reaction, The Light ends outlet of two-phase laminated flow tank 5 is connected with the inlet of hydrolysis rectifying column 6, and the ester on two phases were separated the upper strata of tank 5 sends into water Solve rectifying column 6;Described hydrolysis rectifying column 6 bottom discharge mouthful is connected heavy constituent and two with the acid absorbent import of dealcoholysis tower 1 What phase separation pot 5 was discharged reuses containing return dealcoholysis tower 1 after sour phase materials mixing, hydrolysis rectifying column 6 top discharge mouthful and alcohol Light component containing alcohol and water is sent into alcohol rectifying column 7 by the connection of the charging aperture of rectifying column 7, and described alcohol rectifying column 7 is provided with reboiler 8 Alcohol rectifying column 7 is sent back to after bottom of towe liquid portion is vaporized.
It is preferred that, 3A molecular sieve layers are provided with described dealcoholysis tower 1,3A molecular sieve layers use fluid bed or fixed bed Form.
It is preferred that, dealcoholysis tower circulating pump 4 is provided with the described drain line of dealcoholysis tower 1.
It is preferred that, the described bottom drain road of dealcoholysis tower 1 makes the leakage fluid dram of dealcoholysis tower 1 be absorbed with top acid provided with branch road Agent import is connected, and sour absorbing liquid is pumped into dealcoholysis tower 1 and recycled.
Described scrubbing tower 2 is water scrubber or caustic wash tower.
The described top of scrubbing tower 2 is used to input cleaning solution provided with inlet, and the bottom of scrubbing tower 2 is provided with liquid outlet, goes out liquid Mouth is connected to discharge scrub raffinate with discharge of wastewater pipeline.Cleaning circulation pump 3 is provided with described discharge of wastewater pipeline.
It is preferred that, provided with branch road make the liquid outlet of scrubbing tower 2 and top feed liquor in the discharge of wastewater pipeline of described scrubbing tower 2 Mouth connection, is pumped into scrubbing tower 2 by cleaning solution and recycles.
Alcohols is net in (C1~C10 alcohols) volatile organic waste gas Han polyalcohol (VOC) based on the utility model equipment Change and recovery method, if comprised only in waste gas polyalcohol (unitary such as C1~C10 alcohols, specially methanol, ethanol, ethylene glycol, Binary and polyalcohol) and air (containing oxygen, nitrogen), step is as follows:
Step (1), absorption dealcoholysis, raw material waste gas is passed through dealcoholysis tower 1, at normal pressure, 80~150 DEG C of temperature, raw material waste gas Bottom-up flowing, acid absorbent flow from up to down with raw material waste gas counter current contacting, in acid absorbent effective acid with alcohol in 3A The lower reaction generation ester of molecular sieve catalyst effect, the reaction is a reversible reaction, by making raw material acid absorbent excessive, is made anti- It should be moved to positive direction, improve alcohol reacting dose, one side acidic catalysis conditions esterification speed is fast, still further aspect molecular sieve The water that can be generated with adsorption reaction so that balance forward direction, is accelerated absorbing reaction speed and yield, purification waste gas is reached with this Purpose;Wherein, acid absorbent is sulfuric acid and one or two kinds of mixing in phosphoric acid or boric acid.
Step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 are passed through scrubbing tower 2, wash away the volatility remained in waste gas Alcohol, tail gas can be discharged directly;
Step (3), from the bottom of towe of dealcoholysis tower 1 liquid containing ester and acid is discharged, ester is immiscible with acid, in two-phase laminated flow tank 5 Two-phase is separated after middle standing, and lower floor's heavy component is acid-containing solution, after treatment as acid absorbent return dealcoholysis tower 1 again with Raw material waste gas reaction;Ester after two-phase laminated flow is upper strata light component, into hydrolysis rectifying column 6, in high temperature environments, hydrolysis generation Alcohol, water and acid, alcohol and water low boiling point are light components, constantly rise in hydrolysis rectifying column 6, alcohol rectifying column is discharged into from tower top 7, tower reactor heavy component is higher boiling acids, and can return to dealcoholysis tower 1 through processing reuses as acid absorbent;
The light component that step (4), the hydrolysis top row of rectifying column 6 go out enters alcohol rectifying column 7, different according to the boiling point of alcohol, by alcohol Separate.
If waste gas has for polyalcohol (C1~C10 alcohols) volatile organic waste gas (VOC) with the polarity or not acid reaction The mix waste gas of machine waste gas (aldehyde, ketone, hydro carbons etc., specific such as formaldehyde, acetaldehyde, acetone) composition,
Step (1), step (3), step (5) are identical with the waste gas of air with comprising only polyalcohol.
Simply in step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 enters scrubbing tower 2, and aldehyde, ketone are absorbed with aqueous slkali, The waste gas that processing is completed can safety dumping.
The above method based on principle:Unitary, binary and the polyalcohol contained in organic exhaust gas, in the catalyst concentrated sulfuric acid Lower and phosphoric acid or/and acid reaction generation ester are acted on, because this is a reversible reaction, to ensure to remove tail gas to greatest extent In alcohol, it is necessary to ensure excessive acid in absorbing reaction.And hydrolysis rectifying column 6 in ester hydrolysis, ester hydrolysis be esterification back reaction, Need constantly to remove the alcohol that hydrolysis is come, it is ensured that reaction is constantly moved to the left, ester hydrolysis reaction enters in the hydrolysis tower reactor of rectifying column 6 OK, constantly volatilize and discharged from tower top as the alcohol and water of light component, reaction is constantly carried out by heating while hydrolysis.Hydrolysis The tower top of rectifying column 6 discharge mixed alcohol obtains different alcohol from water through the rectifying of alcohol rectifying column 7.
Compared with prior art, the beneficial effects of the utility model:
The utility model equipment investment is small, energy consumption is low.Alcohol in volatile organic waste gas containing polyalcohol is realized using this equipment In the mix waste gas that class purification is constituted with recovery or polyalcohol volatile organic waste gas and or not the polarity organic exhaust gas of acid reaction Alcohols is purified with reclaiming, and flow is short, without high-temperature service, and purification efficiency is high, can serialization or semicontinuous processing, recovery waste gas In polyalcohol, realize pollution-free, low emission, both solve pollution problem, while improve the added value of whole technique, improve warp Ji benefit.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model equipment;
In Fig. 1,1-dealcoholysis tower;2-scrubbing tower;3-cleaning circulation pump;4-dealcoholysis tower circulating pump;5-two-phase laminated flow Tank;6-hydrolysis rectifying column;7-alcohol rectifying column;8-reboiler.
Embodiment
The technical solution of the utility model is further described below by embodiment.
As shown in figure 1, equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol, including dealcoholysis Tower 1, scrubbing tower 2, two-phase laminated flow tank 5, hydrolysis rectifying column 6, alcohol rectifying column 7, alcohol rectifying column reboiler 8;Under described dealcoholysis tower 1 The exhaust gas inlet that portion is entered provided with side, the top of dealcoholysis tower 1 is provided with gas outlet, and the top of dealcoholysis tower 1 is provided with acid absorbent import, dealcoholysis tower 1 bottom is provided with leakage fluid dram;The described top gas outlet of dealcoholysis tower 1 is connected with the air inlet of described scrubbing tower 2, and scrubbing tower 2 is pushed up Portion is provided with exhaust outlet, and tail gas is directly discharged through exhaust outlet after being washed into scrubbing tower 2;The described bottom leakage fluid dram warp of dealcoholysis tower 1 Drain line is connected with the inlet of described two-phase laminated flow tank 5, and dealcoholysis tower circulating pump 4 is provided with the drain line of dealcoholysis tower 1, The heavy component outlet of two-phase laminated flow tank 5 be connected with the acid absorbent import of dealcoholysis tower 1, the Light ends of two-phase laminated flow tank 5 export and Hydrolyze the inlet connection of rectifying column 6;The acid absorbent import of described hydrolysis rectifying column 6 bottom discharge mouthful and dealcoholysis tower 1 connects Connect return dealcoholysis tower 1 after the phase materials containing acid for discharging heavy constituent and two-phase laminated flow tank 5 are mixed to reuse, hydrolyze rectifying column 6 Top discharge mouth is connected with the charging aperture of alcohol rectifying column 7 by the light component feeding alcohol rectifying column 7 containing alcohol and water, described alcohol rectifying Tower 7 is provided with reboiler 8, different according to the boiling point of alcohol, and alcohol is separated.
3A molecular sieve layers are provided with described dealcoholysis tower 1,3A molecular sieve layers use fluid bed or fixed bed form.
The described bottom drain road of dealcoholysis tower 1 makes the leakage fluid dram of dealcoholysis tower 1 and top acid absorbent import provided with branch road Connection, is pumped into dealcoholysis tower 1 by sour absorbing liquid and recycles.
Described scrubbing tower 2 is water scrubber or caustic wash tower.
The described top of scrubbing tower 2 is used to input cleaning solution provided with inlet, and the bottom of scrubbing tower 2 is provided with liquid outlet, goes out liquid Mouth is connected to discharge scrub raffinate with discharge of wastewater pipeline.Cleaning circulation pump 3 is provided with described wastewater discharge pipe.Institute The discharge of wastewater pipeline for the scrubbing tower 2 stated makes the liquid outlet of scrubbing tower 2 be connected with top inlet provided with branch road, and cleaning solution is pumped into Scrubbing tower 2 is recycled.
Alcohols purification and recovery method in volatile organic waste gas containing polyalcohol based on the present embodiment equipment, if waste gas In comprise only polyalcohol (unitary such as C1~C10 alcohols, specially methanol, ethanol, ethylene glycol, binary and polyalcohol) and air (containing oxygen, nitrogen), scrubbing tower 2 is water scrubber, and step is as follows:
Step (1), absorption dealcoholysis, raw material waste gas is passed through dealcoholysis tower 1, at normal pressure, 80~150 DEG C of temperature, raw material waste gas Bottom-up flowing, acid absorbent flow from up to down with raw material waste gas counter current contacting, in acid absorbent effective acid with alcohol in 3A The lower reaction generation ester of molecular sieve catalyst effect;Wherein, acid absorbent is one or two kinds of in sulfuric acid and phosphoric acid or boric acid Mixing;
Step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 are passed through water scrubber 2, wash away the volatility remained in waste gas Alcohol, tail gas can be discharged directly;
Step (3), from the bottom of towe of dealcoholysis tower 1 liquid containing ester and acid is discharged, ester is immiscible with acid, in two-phase laminated flow tank 5 Two-phase is separated after middle standing, acid solution after treatment as acid absorbent return dealcoholysis tower 1 again with raw material waste gas reaction;Two Ester after phase separation enters hydrolysis rectifying column 6, in high temperature environments, hydrolysis generation alcohol, water and acid, and alcohol and water low boiling point is light group Point, constantly rise in hydrolysis rectifying column 6, be discharged into alcohol rectifying column 7 from tower top, tower reactor heavy component is higher boiling acids, through processing Dealcoholysis tower 1 is can return to reuse as acid absorbent;
The light component that step (4), the hydrolysis top row of rectifying column 6 go out enters alcohol rectifying column 7, different according to the boiling point of alcohol, by alcohol Separate.
If waste gas is polyalcohol volatile organic waste gas and polarity organic exhaust gas (aldehyde, ketone, hydro carbons or not acid reaction Deng specific such as formaldehyde, acetaldehyde, acetone) mix waste gas of composition, scrubbing tower 2 is caustic wash tower, and step is as follows:
Step (1), absorption dealcoholysis, raw material waste gas is passed through dealcoholysis tower 1, at normal pressure, 80~150 DEG C of temperature, raw material waste gas Bottom-up flowing, acid absorbent flow from up to down with raw material waste gas counter current contacting, in acid absorbent effective acid with alcohol in 3A The lower reaction generation ester of molecular sieve catalyst effect;Wherein, acid absorbent is one or two kinds of in sulfuric acid and phosphoric acid or boric acid Mixing;
Step (2), the waste gas discharged from the tower top of dealcoholysis tower 1 enters caustic wash tower 2, and aldehyde, ketone are absorbed with aqueous slkali, and processing is completed Waste gas can safety dumping;
Step (3), from the bottom of towe of dealcoholysis tower 1 liquid containing ester and acid is discharged, ester is immiscible with acid, in two-phase laminated flow tank 5 Two-phase is separated after middle standing, acid solution after treatment as acid absorbent return dealcoholysis tower 1 again with raw material waste gas reaction;Two Ester after phase separation enters hydrolysis rectifying column 6, in high temperature environments, hydrolysis generation alcohol, water and acid, and alcohol and water low boiling point is light group Point, constantly rise in hydrolysis rectifying column 6, be discharged into alcohol rectifying column 7 from tower top, tower reactor heavy component is higher boiling acids, through processing Dealcoholysis tower 1 is can return to reuse as acid absorbent;
The light component that step (4), the hydrolysis top row of rectifying column 6 go out enters alcohol rectifying column 7, different according to the boiling point of alcohol, by alcohol Separate.

Claims (8)

1. equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol, it is characterised in that including dealcoholysis tower (1), scrubbing tower (2), two-phase laminated flow tank (5), hydrolysis rectifying column (6), alcohol rectifying column (7), reboiler (8);Described dealcoholysis tower (1) gas outlet is provided with the top of the exhaust gas inlet that bottom is entered provided with side, dealcoholysis tower (1), dealcoholysis tower (1) top is entered provided with acid absorbent Mouthful, dealcoholysis tower (1) bottom is provided with leakage fluid dram;Air inlet of the described dealcoholysis tower (1) through top gas outlet Yu described scrubbing tower (2) Exhaust outlet is provided with the top of mouth connection, scrubbing tower (2);Described dealcoholysis tower (1) bottom leakage fluid dram is through drain line and described two The inlet connection of phase separation pot (5), the heavy component outlet and the acid absorbent import of dealcoholysis tower (1) of two-phase laminated flow tank (5) connect Connect, the light fraction outlet of two-phase laminated flow tank (5) is connected with the inlet of hydrolysis rectifying column (6);Described hydrolysis rectifying column (6) bottom Portion's discharging opening is connected the aqueous-phase material containing acid for discharging heavy constituent and two-phase laminated flow tank (5) with the acid absorbent import of dealcoholysis tower (1) Dealcoholysis tower (1) is returned to after material mixing to reuse, hydrolysis rectifying column (6) top discharge mouthful is connected with alcohol rectifying column (7) charging aperture By the light component feeding alcohol rectifying column (7) containing alcohol and water, described alcohol rectifying column (7) is provided with reboiler (8) by bottom of towe liquid Part sends alcohol rectifying column (7) back to after vaporizing.
2. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 1, it is special Levy is that 3A molecular sieve layers are provided with described dealcoholysis tower (1).
3. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 1, it is special Levy is that dealcoholysis tower circulating pump (4) is provided with described dealcoholysis tower (1) drain line.
4. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 1, it is special Levy is that described dealcoholysis tower (1) bottom drain road makes dealcoholysis tower (1) leakage fluid dram enter with top acid absorbent provided with branch road Mouth connection.
5. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 1, it is special Levy is that described scrubbing tower (2) is water scrubber or caustic wash tower.
6. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 1, it is special It is that described scrubbing tower (2) top is used to input cleaning solution provided with inlet to levy, and scrubbing tower (2) bottom is provided with liquid outlet, gone out Liquid mouthful is connected to discharge scrub raffinate with discharge of wastewater pipeline.
7. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 6, it is special Levy is that cleaning circulation pump (3) is provided with described discharge of wastewater pipeline.
8. equipment of the purification of alcohols with reclaiming in volatile organic waste gas containing polyalcohol according to claim 1, it is special Levy is provided with branch road scrubbing tower (2) liquid outlet is connected with top inlet in the discharge of wastewater pipeline of described scrubbing tower (2) Connect.
CN201621425032.7U 2016-12-23 2016-12-23 Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol Active CN206315665U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621425032.7U CN206315665U (en) 2016-12-23 2016-12-23 Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201621425032.7U CN206315665U (en) 2016-12-23 2016-12-23 Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol

Publications (1)

Publication Number Publication Date
CN206315665U true CN206315665U (en) 2017-07-11

Family

ID=59258901

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201621425032.7U Active CN206315665U (en) 2016-12-23 2016-12-23 Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol

Country Status (1)

Country Link
CN (1) CN206315665U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115006967A (en) * 2022-08-04 2022-09-06 浙江晨阳新材料有限公司 Method and device for treating alcohol-containing waste gas in fuel cell production

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115006967A (en) * 2022-08-04 2022-09-06 浙江晨阳新材料有限公司 Method and device for treating alcohol-containing waste gas in fuel cell production
CN115006967B (en) * 2022-08-04 2022-11-18 浙江晨阳新材料有限公司 Method and device for treating alcohol-containing waste gas in fuel cell production

Similar Documents

Publication Publication Date Title
CN101735045B (en) Method for producing ethyl acetate by using entrainer
CN103803673B (en) Oilfield sewage and boiler flue gas mixed-bath two-way purification device
CN101108794B (en) Method for prolonging cycle of oparation of pimelinketone device and equipment thereof
CN103936569A (en) High-concentration dimethoxymethane production technology device and method
CN206315665U (en) Equipment of the purification of alcohols with reclaiming in a kind of volatile organic waste gas containing polyalcohol
CN102010760A (en) Coal gas washing, dedusting and purifying process
CN203754482U (en) Wet-type oxidation treatment device of waste water
CN203170211U (en) Ring-pipe rotational-flow wet-method flue gas desulfurization tower
CN113069893B (en) Treatment system and process suitable for Volatile Organic Compounds (VOCS) of tar storage tank
CN207203849U (en) A kind of industrial tail gas catalytic purification and heat utilization device
CN103877958B (en) For preparing the catalyst and preparation method of biodiesel and the preparation technology of biodiesel
CN203947049U (en) A kind of device of preparing formaldehyde
CN103265976B (en) Method and device for ordinary-pressure oxygen-enriched continuous gasification-gas-steam combined cycle power-generation heat supply
CN108554126A (en) A kind of continuous rectifying tower exhaust gas purification system
CN105777511B (en) A kind of energy-efficient acetylacetone,2,4-pentanedione synthesis technique
CN212282924U (en) THF (tetrahydrofuran) rectifying device for PBT (polybutylene terephthalate) production
CN204502800U (en) A kind of ammonia-soda process combined desulfurization and denitration device
CN203440262U (en) Device for producing trans-1, 2-dichloroethylene with acetylene by adopting catalytic chlorination method
CN207708838U (en) A kind of purification of PTA oxidized tail gas and bromine retracting device
CN201823331U (en) Solar rectification and purification device dedicated for crude pyroligneous acid
CN106861436A (en) One kind is using nano ceramics hyperfiltration treatment alkylation spent acid technique
CN110975316A (en) THF (tetrahydrofuran) rectifying device for PBT (polybutylene terephthalate) production
CN205965428U (en) Pyridine waste liquid and pyridine waste gas co-treatment device
CN207445909U (en) A kind of device of super solvent recycling treatment high concentration VOCs exhaust gas
CN206160777U (en) Heat recycling system of catalytic cracking catalyst spray drying tail gas

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20190530

Address after: 716000 Baota Office, Baota District, Yan'an City, Shaanxi Province Zhai Zeliang Shengyuan District, Building 6, Unit 3, Room 401

Patentee after: Yan'an Jia'an Energy Technology Co., Ltd.

Address before: 210009 Block B, Jinshan Building, 8 Shanxi Road, Gulou District, Nanjing City, Jiangsu Province

Patentee before: Nanjing insipai Engineering Technology Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190610

Address after: 716000 Baota Office, Baota District, Yan'an City, Shaanxi Province Zhai Zeliang Shengyuan District, Building 6, Unit 3, Room 401

Patentee after: Yan'an Jia'an Energy Technology Co., Ltd.

Address before: 210009 Block B, Jinshan Building, 8 Shanxi Road, Gulou District, Nanjing City, Jiangsu Province

Patentee before: Nanjing insipai Engineering Technology Co., Ltd.

TR01 Transfer of patent right