CN206229322U - A kind of processing system of catalyst for producing propylene with methanol - Google Patents

A kind of processing system of catalyst for producing propylene with methanol Download PDF

Info

Publication number
CN206229322U
CN206229322U CN201621321504.4U CN201621321504U CN206229322U CN 206229322 U CN206229322 U CN 206229322U CN 201621321504 U CN201621321504 U CN 201621321504U CN 206229322 U CN206229322 U CN 206229322U
Authority
CN
China
Prior art keywords
beds
heating furnace
processing system
mtp
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201621321504.4U
Other languages
Chinese (zh)
Inventor
王林
焦洪桥
雍晓静
罗春桃
袁炜
钱效南
齐静
关翀
李云
李云平
杜正平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenhua Group Corp Ltd
Shenhua Ningxia Coal Industry Group Co Ltd
Original Assignee
Shenhua Group Corp Ltd
Shenhua Ningxia Coal Industry Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenhua Group Corp Ltd, Shenhua Ningxia Coal Industry Group Co Ltd filed Critical Shenhua Group Corp Ltd
Priority to CN201621321504.4U priority Critical patent/CN206229322U/en
Application granted granted Critical
Publication of CN206229322U publication Critical patent/CN206229322U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A kind of processing system of catalyst for producing propylene with methanol, including:Process steam generation device, for providing the process steam produced by desalted water;First heating furnace, is provided with the first feeding line and the 3rd feeding line at charging aperture;Second heating furnace, charging aperture is provided with the second feeding line;MTP reactors, multiple beds are provided with it along longitudinal direction;Its top feed pipeline;Side entry feed pipeline;First gas distributor is provided with MTP reactors, first gas distributor is arranged between its top feed of MTP reactors mouthful and first beds.The processing system of catalyst for producing propylene with methanol of the present utility model, each beds are passed through by material from the top of MTP reactors and side line respectively, improve treatment effect;When carrying out steam treatment, it is to avoid using the process water of quenching column bottom of towe, and then avoid the influence of the methyl alcohol being mingled with the process water and dimethyl ether to steam treatment effect;When carrying out regeneration treatment, favorable regeneration effect.

Description

A kind of processing system of catalyst for producing propylene with methanol
Technical field
The utility model belongs to coal chemical technology, and in particular to a kind of processing system of catalyst for producing propylene with methanol.
Background technology
Catalyst as MTP technologies core, the quality of its performance is directly connected to the yield situation of target product, therefore Receive much concern.To improve catalyst performance, steam treatment of passing through need to be being entered to it before, on the one hand can dredge catalyst Duct;On the other hand catalyst surface can be adjusted acid, and then extends catalyst service life, optimized product distribution, made anti- Should be carried out to the direction for being more beneficial for generating propylene.
Preparing propylene from methanol (MTP) technique refers to coal base or the methyl alcohol of natural gas base synthesis as raw material, in the work of catalyst Under, the chemical process technology of propylene is obtained through the production of MTP reactors.In art production process, MTP reactor outlets product heat It is washed with chilled water in the quenching column for entering chilling train after changing, product temperatur is on the one hand further reduced, makes gas Liquid initial gross separation;On the other hand the pH value for adding alkali lye to adjust logistics is then needed, makes it be in neutral.From quenching column bottom of towe out Most of process water input methanol distillation column reclaims methyl alcohol therein and dimethyl ether, and remaining small part process water then enters technique Turret is distilled out of, it is possible to the beds of MTP reactors are directly returned to, during the course of the reaction as diluent and heat absorption Steam reduction reaction bed temperature, it is also possible to heated stove further heating after, to coming into operation before catalyst carry out vapor Treatment.That is, the technique of process steam when carrying out to catalyst steam treatment in original technique from quenching column bottom of towe Water, i.e. reactor outlet product can contain a small amount of methyl alcohol and diformazan through the process water after quenching column washing, this some processes water Ether, so as to also inevitably be mingled with methyl alcohol and dimethyl ether in the process steam that is distilled out of from process steam tower, and methyl alcohol and Used as reaction mass, (480 DEG C) can be reacted dimethyl ether with catalyst under the conditions of steam treatment, cause catalyst surface Part carbon distribution, it is impossible to reach expected steam treatment effect;In addition, during steam treatment, vapor is from reactor head Into, each beds are gradually penetrated, cause the steam treatment effect of each beds different, show as from upper Gradually weaken under.
With the carrying out of MTP techniques, carbon distribution gradually increases on catalyst, and the active sites on catalyst are eventually completely covered Point, the duct of blocking catalyst inactivates catalyst.Now need to regenerate catalyst, specifically use regeneration gas/nitrogen Carbon distribution on gas mixed combustion burning-off catalyst.In regenerative process, regeneration gas/nitrogen mixture enters from MTP reactor heads, Gradually penetrate each beds to be regenerated, when all air of regeneration gas for adding, all of bed inlet temperatures are 480 DEG C, and export there is no showing that regenerative process has been completed during temperature rise.The renovation process has that efficiency is low, the recovery time is long (about 150 hours), and each beds regeneration effect is difficult to that unified (catalyst of regeneration ending rear lower beds is carbon containing Amount is higher than top) the problems such as.
Utility model content
The purpose of this utility model is to provide a kind of processing system of catalyst for producing propylene with methanol, for improving catalyst Regeneration effect.
The technical solution of the utility model is as follows:
A kind of processing system of catalyst for producing propylene with methanol, including:
Process steam generation device, for providing the process steam produced by desalted water;
First heating furnace, is provided with the first feeding line and the 3rd feeding line at the charging aperture of first heating furnace, First feeding line is used to be input into nitrogen in first heating furnace to be heated;3rd feeding line is used for will Process steam from the process steam generation device is input into first heating furnace and is heated;
Second heating furnace, the charging aperture of second heating furnace is provided with the second feeding line, for regeneration gas to be input into Heated in second heating furnace;
In MTP reactors, the MTP reactors multiple beds are provided with along longitudinal direction;
Its top feed pipeline, for the material by part from first heating furnace and part from the described second heating The material of stove is delivered on first beds of the MTP reactors from top;
Side entry feed pipeline, for the material by part from first heating furnace and part from the described second heating The material of stove is delivered on the beds of the second to the most end of the MTP reactors;
First gas distributor is provided with the MTP reactors, it is anti-that the first gas distributor is arranged at the MTP Answer between its top feed mouthful of device and first beds, for the material being input into through its top feed pipeline to be uniformly distributed To first beds.
Preferably, multiple second gas distributors, the second gas distributor difference are provided with the MTP reactors Be arranged between each adjacent catalyst bed, for by the material being input into through side entry feed pipeline be respectively uniformly distributed to second to Most end beds.
Preferably, in each described beds, upper temperature sensor, middle portion temperature are disposed with from top to bottom Sensor and lower temperature sensor, the temperature of top, middle part and bottom for measuring each beds respectively.
Preferably, each described beds is in the plane where the upper temperature sensor, with plane The heart is radially provided with multiple face temperature sensors along radial direction for the center of circle, for measuring each catalyst respectively The temperature of diverse location in bed plane.
Preferably, the upper temperature sensor, middle portion temperature sensor, lower temperature sensor and plane TEMP Sleeve pipe is arranged with device.
Preferably, the bottom of the MTP reactors is provided with bottom outlet, is provided with the bottom outlet On-line detector, the content for detecting oxygen in discharging gas.
Preferably, the first valve and first flow are disposed with along Flow of Goods and Materials direction on the 3rd feeding line Meter, is controlled for the conveying to vapor and conveying capacity.
Preferably, set gradually respectively along Flow of Goods and Materials direction on its top feed pipeline and the side entry feed pipeline Have the second valve and second flowmeter, for respectively to the conveying of material that is input into from the MTP reactor heads and side line and Conveying capacity is controlled.
Preferably, the 3rd valve and the 3rd flow are disposed with along Flow of Goods and Materials direction on second feeding line Meter, for being controlled to nitrogen conveying and conveying capacity.
Preferably, the 4th valve and the 4th stream are disposed with respectively along Flow of Goods and Materials direction on the 3rd feeding line Gauge, is controlled for the conveying to regeneration gas and conveying capacity.
The beneficial effects of the utility model are:
The processing system of catalyst for producing propylene with methanol of the present utility model, by material respectively from the top of MTP reactors and Side line is passed through each beds, and the material intake of top and side line is controlled by corresponding valve and flowmeter, can Make its top feed of MTP reactors consistent with side entry feed as much as possible, and make various loci on each beds as far as possible Material it is uniform, improve treatment effect so that catalyst can keep more preferable state, be conducive to improving propylene in production process Yield;When regeneration treatment and steam treatment is carried out to catalyst, each bed treatment effect is consistent;Water-filling is being entered to catalyst During steam treated, it is to avoid using the process water of quenching column bottom of towe, and then avoid the methyl alcohol and diformazan being mingled with the process water Influence of the ether to steam treatment effect.
Brief description of the drawings
Fig. 1 is the processing system structural representation in one embodiment of catalyst for producing propylene with methanol of the present utility model Figure;
Fig. 2 is the longitudinal profile enlarged drawing of beds;
The horizontal section enlarged drawing of beds during Fig. 3.
Specific embodiment
The technical solution of the utility model and its effect are described further below by way of specific embodiment.Following reality The mode of applying is merely to illustrate content of the present utility model, is not limited to protection domain of the present utility model.Using this practicality The simple change that new design is carried out to the utility model is all in the scope that the utility model is claimed.
As Figure 1-3, the processing system of catalyst for producing propylene with methanol of the present utility model, including:
Process steam generation device 1, for providing the process steam produced by desalted water;
First heating furnace 31, is provided with the first feeding line 41 and the 3rd charging at the charging aperture of first heating furnace 31 Pipeline, first feeding line is used to be input into nitrogen in first heating furnace 31 to be heated;3rd feed pipe Line is heated for that will be input into first heating furnace 31 from the process steam of the process steam generation device 1;
Second heating furnace 32, the charging aperture of second heating furnace 32 is provided with the second feeding line 42, for that will regenerate Gas is input into second heating furnace 32 and is heated;
In MTP reactors 8, the MTP reactors multiple beds 9 are provided with along longitudinal direction;
Its top feed pipeline 7, described second is come from for the material by part from first heating furnace 31 and part The material of heating furnace 32 is delivered on first beds 9 of the MTP reactors 8 from top;
Side entry feed pipeline 10, described second is come from for the material by part from first heating furnace 31 and part The material of heating furnace 31 is delivered on the beds 9 of the second to the most end of the MTP reactors 8;
First gas distributor is provided with the MTP reactors 8, the first gas distributor is arranged at the MTP Between its top feed mouthful of reactor 8 and first beds 9, the material for will be input into through its top feed pipeline 7 is equal It is even to be distributed to first beds 99.
The processing system of catalyst for producing propylene with methanol of the present utility model, enters through top and side line respectively by by material Material, ensures that the charging of each bed is identical, it is ensured that the treatment effect of each bed as much as possible;By setting for first gas distributor Put, be more so that the charging of the first beds is uniform, the charging of each position is consistent with reaction, improves treatment effect.
The total amount that is passed through of regeneration gas is 30000-100000Nm3/ h, preferably 80000Nm3/h。
The process steam of the generation including low pressure steam pipe network, boiler or etc. synthesis drum of process steam generation device 1, produces The water source of raw process steam is non-chilled water.Due to being mingled with methyl alcohol, dimethyl ether etc. in chilled water, steam treatment is being carried out Catalyst surface carbon distribution can be caused as reaction raw materials and catalyst reaction when (480 DEG C).And low pressure steam pipe network, boiler Or it is not chilled water that synthesis drum etc. produces the water source of process steam, it is to avoid above mentioned problem so that after steam treatment, a side Surface catalysis agent duct is dredged, and another aspect catalyst surface is adjusted to acidity, and then is extended the service life of catalyst, improved and urge The catalytic performance of agent, optimized product distribution, make reaction be carried out to the direction for being more beneficial for generating propylene, are conducive to improving propylene Yield.Wherein, a special steam generator of " synthesis drum " this area, is natural circulation boiler and associated circulation boiler Important component, in a device its Main Function be reclaim high-quality heat energy, waste heat boiler is constituted together with synthesis reactor, So being also known as " synthesis drum ", thermal source is the heat release of methanol synthesis reactor catalyst, and water source is desalted water.Therefore from conjunction Methyl alcohol is not contained into the process steam of drum.
In one embodiment, multiple second gas distributors, second gas are provided with the MTP reactors 8 Body distributor is respectively arranged between each adjacent catalyst bed 9, for the material difference that will be input into through side entry feed pipeline 10 It is evenly distributed to the second to most end beds 9.So that the charging everywhere of each beds of the second to most end is uniform, carry High disposal effect.
In one embodiment, in each described beds 9, upper temp sensing is disposed with from top to bottom Device, middle portion temperature sensor and lower temperature sensor, top, middle part for measuring each beds 9 respectively And the temperature of bottom.By the top to each beds 9, middle part, temperature of lower measurement, judge corresponding catalyst bed Whether the regeneration treatment in layer 9 to catalyst is complete.Because regenerative process is exothermic reaction, and regeneration gas is to move from the top down , when regeneration treatment is not completed, the top of beds 9, middle part, the response situation difference of bottom, temperature are also different.When When the top of beds 9, middle part, temperature of lower all same, illustrate that the regeneration situation of its upper, middle and lower is consistent, regeneration is complete.
In one embodiment, each described beds 9 is in the plane where the upper temperature sensor, Multiple face temperature sensors are radially provided with as the center of circle along radial direction with the center of plane, for measuring each respectively The temperature of diverse location in the plane of the beds 9.By various location temperature in the plane to corresponding catalyst bed 9 The measurement of degree, judges the uniformity that regeneration gas is distributed thereon, the regeneration situation of each several part on Judge plane.If each several part temperature Unanimously, then explanation regeneration gas is evenly distributed, and the regeneration situation of each several part is consistent in plane.
In one embodiment, the upper temperature sensor, middle portion temperature sensor, lower temperature sensor peace Sleeve pipe is arranged with the temperature sensor of face.Sleeve pipe facilitates the installation and taking-up of said temperature sensor, and convenient being used is drawn Line is drawn, and it is connected with temperature indicating device, and measured temperature is shown to facilitate observation.
In one embodiment, the bottom of the MTP reactors 8 is provided with bottom outlet 15, and the bottom goes out On-line detector 16 is provided with expects pipe line 15, the content for detecting oxygen in discharging gas.By with on-line detector 16 The regeneration feelings of catalyst in the content of oxygen in the bottom discharge of detection MTP reactors 8, detection MTP reactors 8 this entirety Condition, when the content constant of oxygen is detected, the regeneration in MTP reactors to catalyst is completed, now oxygen in bottom discharge Content in 10wt% or so.
In one embodiment, it is disposed with the first valve along Flow of Goods and Materials direction on the 3rd feeding line 43 6 and first flowmeter 5, it is controlled for the conveying to vapor and conveying capacity.It is preferably right by the control to vapor Catalyst carries out steam treatment, improves the catalytic performance of catalyst.First valve 6 can be valve commonly used in the art, than Such as hand valve;First flowmeter 5 can be flowmeter commonly used in the art.
In one embodiment, along Flow of Goods and Materials side on its top feed pipeline 7 and the side entry feed pipeline 10 To the second valve and second flowmeter is disposed with respectively, for respectively to being input into from the top of the MTP reactors 8 and side line Material conveying and conveying capacity be controlled.
In one embodiment, it is disposed with the 3rd valve along Flow of Goods and Materials direction on second feeding line 41 With the 3rd flowmeter, for nitrogen conveying and conveying capacity be controlled.
In one embodiment, the 4th is disposed with respectively along Flow of Goods and Materials direction on the 3rd feeding line 42 Valve and the 4th flowmeter, are controlled for the conveying to regeneration gas and conveying capacity.
Second valve, the 3rd valve and the 4th valve can be valve commonly used in the art, such as hand valve;Second flow Meter, the 3rd flowmeter and the 4th flowmeter can be flowmeter commonly used in the art.
When steam treatment is carried out, the process steam from first heating furnace 31 enter MTP reactors 8 it Before, its temperature is 440-490 DEG C, such as 480 DEG C.
Its top feed amount of process steam is 1 with the mass ratio of each side entry feed amount summation:0.1-20, such as 1:9.
The processing system of catalyst for producing propylene with methanol of the present utility model as Figure 1-3 is when steam treatment is carried out Running be:
Process steam from process steam generation device 1 is input into the first heating furnace 31 and is heated, then according to matter Amount is than being 1:0.1-20 through purging 2-8h in its top feed pipeline 7 and the input MTP of side entry feed pipeline 10 reactors 8, is pushed up respectively The process steam in portion is through first beds 9 in the input MTP of its top feed pipeline 7 reactors 8, the process steam warp of side line The second to most end beds 9 in each input MTP of side entry feed pipeline 10 reactors 8, realize to the vapor of catalyst Reason.
When that need not regenerate, the effect of steam treatment compares:
The utility model:When carrying out steam treatment using above-mentioned processing system of the present utility model, with one 500,000 tons/ As a example by the MTP reactors in year, loaded catalyst is 50 tons;Steam treatment condition is:Vapor inlet amount be 25 tons/it is small When, treatment temperature is 480 DEG C, and process time is 48 hours.
Prior art:In other conditions just as in the case of, this practicality is replaced with the process steam in technique turret new Process steam in the process steam generation device 1 of type, carries out steam treatment.
Catalyst after processing in above-mentioned two situations is used for the production process of preparing propylene from methanol, the MTP reactions for obtaining The product distribution of device is shown in Table 1.
Table 1 carry out steam treatment with different vapor after MTP reactors product distribution
As shown in Table 1, steam treatment effect of the present utility model is more preferable, the catalytic performance of the catalyst obtained after treatment More preferably, the production process of preparing propylene from methanol is used it for, in the product of the MTP reactors for obtaining, propylene content improves a lot. Estimated 1 year can be with 3000 tons of propylene enhancing, according to 0.8 ten thousand yuan/ton of calculating, annual new output value is 24,000,000 yuan or so.
The processing system of catalyst for producing propylene with methanol of the present utility model carry out regeneration treatment when running be:
First, the process steam from process steam generation device 1 is input into the first heating furnace 31 and is heated, Ran Houfen In not through its top feed pipeline 7 and the input MTP of side entry feed pipeline 10 reactors 8, the process steam of input is first through first gas Distributor 81 and second gas distributor 82 carry out gas distribution, and each beds 9 are then blowed to again, after purging 2-8h, close Close the first valve 6;The 3rd valve and the 3rd flowmeter of the second feeding line 41 are opened, is entered to the input nitrogen of the first heating furnace 31 Row heating, the nitrogen after heating is input into MTP reactors 8 through its top feed pipeline 7 and side entry feed pipeline 10 respectively, input Nitrogen first carries out gas distribution through first gas distributor 81 and second gas distributor 82, and each beds are then blowed to again 9,2-8h is purged, then keep above-mentioned nitrogen to be passed through under state, open the 4th valve and the 4th on the second feeding line 42 Flowmeter, is heated to the input of the second heating furnace 32 regeneration gas, and the regeneration gas after heating is respectively through its top feed pipeline 7 and side Mix with nitrogen in the input MTP of line feeding line 10 reactors 8, and through first gas distributor 81 and second gas distributor 82 Gas distribution is carried out, each beds 9 are then blowed to again, the carbon distribution on catalyst is burnt, realize catalyst again It is raw.With the carrying out of regenerative process, regeneration gas replaces part nitrogen so that the gaseous mixture of nitrogen and regeneration gas (containing oxygen) In, oxygen content progressively increases to 5-20wt%, preferably 10wt%.When the inlet temperature stabilization of each beds 9, and export There is no during temperature rise, regenerative process is completed.Wherein, the total amount of regeneration gas is 30000-100000Nm3/ h, preferably 80000Nm3/h.
The effect for regenerating treatment compares:
The utility model:When carrying out regeneration treatment using above-mentioned processing system of the present utility model, with one 500,000 tons/year MTP reactors as a example by, loaded catalyst be 50 tons;Process steam, nitrogen and regeneration gas are respectively through its top feed pipeline 7 It is input into each beds 9 simultaneously with side entry feed pipeline 10;Process steam purge 4h, nitrogen purging 4h, regeneration gas it is total It is 80000Nm to measure3/ h, the amount from top input is 8000Nm3/ h, from side line input is always 72000Nm3/h;Regeneration gas is sky Gas, oxygen content is eventually increased to 10wt% in gaseous mixture, and bed temperature is maintained at 480 DEG C in regenerative process, and the recovery time is 72 hours.
Comparative example 1:In the case of other conditions identical, process steam, nitrogen and regeneration gas in each step are passed through Only it is input into MTP reactors through its top feed pipeline 7, each beds 9 is gradually regenerated, the total amount of regeneration gas is 80000Nm3/ h, the recovery time is 72 hours.
Comparative example 2:In other conditions just as in the case of, process steam, nitrogen and regeneration gas in each step are passed through Only it is input into MTP reactors through its top feed pipeline 7, each beds 9 is gradually regenerated, the total amount of regeneration gas is 80000Nm3/ h, the recovery time is 150 hours.
Each layer catalyst after being processed in the case of above-mentioned three kinds is sampled analysis, the carbon distribution content such as table 2 of catalyst.
The carbon distribution content of each layer catalyst after the regeneration treatment of the various process of table 2
As shown in Table 2, more preferably, the recovery time is short, and each catalyst bed after regeneration for regeneration treatment effect of the present utility model Carbon deposition quantity is more uniform on the catalyst of layer, and carbon deposition quantity is few.

Claims (10)

1. a kind of processing system of catalyst for producing propylene with methanol, it is characterised in that including:
Process steam generation device (1), for providing the process steam produced by desalted water;
First heating furnace (31), is provided with the first feeding line (41) and the 3rd and enters at the charging aperture of first heating furnace (31) Expects pipe line (43), first feeding line is used to be input into nitrogen in first heating furnace (31) to be heated;Described Three feeding lines (43) by the process steam from the process steam generation device (1) for being input into first heating furnace (31) heated in;
Second heating furnace (32), the charging aperture of second heating furnace (32) is provided with the second feeding line (42), for will again Heated in anger input second heating furnace (32);
In MTP reactors (8), the MTP reactors multiple beds (9) are provided with along longitudinal direction;
Its top feed pipeline (7), described second is come from for the material by part from first heating furnace (31) and part The material of heating furnace (32) is delivered on first beds (9) of the MTP reactors (8) from top;
Side entry feed pipeline (10), described second is come from for the material by part from first heating furnace (31) and part The material of heating furnace (31) is delivered on the beds (9) of the second to the most end of the MTP reactors (8);
First gas distributor is provided with the MTP reactors (8), it is anti-that the first gas distributor is arranged at the MTP Answer between its top feed mouthful of device (8) and first beds (9), for the thing that will be input into through its top feed pipeline (7) Material is evenly distributed to first beds (9).
2. processing system according to claim 1, it is characterised in that multiple second is provided with the MTP reactors (8) Gas distributor, the second gas distributor is respectively arranged between each adjacent catalyst bed (9), for that will enter through side line The material of expects pipe line (10) input is respectively uniformly distributed to the second to most end beds (9).
3. processing system according to claim 1 and 2, it is characterised in that in each described beds (9), by upper Upper temperature sensor, middle portion temperature sensor and lower temperature sensor are disposed with downwards, for measuring each respectively The temperature on the top, middle part and bottom of the beds (9).
4. processing system according to claim 3, it is characterised in that each described beds (9) is on the top In plane where temperature sensor, multiple face temperatures are radially provided with along radial direction by the center of circle of the center of plane Sensor, the temperature for measuring diverse location in each described beds (9) plane respectively.
5. processing system according to claim 4, it is characterised in that the upper temperature sensor, middle portion temperature sensing Sleeve pipe is arranged with device, lower temperature sensor and plane temperature sensor.
6. the processing system according to any one of claim 1,2,4 or 5, it is characterised in that the MTP reactors (8) Bottom be provided with bottom outlet (15), be provided with on-line detector (16) on the bottom outlet (15), be used for The content of oxygen in detection discharging gas.
7. processing system according to claim 6, it is characterised in that along Flow of Goods and Materials on the 3rd feeding line (43) Direction is disposed with the first valve (6) and first flowmeter (5), is controlled for the conveying to vapor and conveying capacity.
8. processing system according to claim 7, it is characterised in that its top feed pipeline (7) and the side line enter Expects pipe line is disposed with the second valve and second flowmeter respectively on (10) along Flow of Goods and Materials direction, for respectively to from described The conveying of the material of MTP reactors (8) top and side line input and conveying capacity are controlled.
9. processing system according to claim 8, it is characterised in that along Flow of Goods and Materials on second feeding line (41) Direction is disposed with the 3rd valve and the 3rd flowmeter, for being controlled to nitrogen conveying and conveying capacity.
10. the processing system according to any one of claim 1,2,4,5 or 7-9, it is characterised in that the 3rd charging Pipeline is disposed with the 4th valve and the 4th flowmeter respectively on (42) along Flow of Goods and Materials direction, for the conveying to regeneration gas It is controlled with conveying capacity.
CN201621321504.4U 2016-12-05 2016-12-05 A kind of processing system of catalyst for producing propylene with methanol Active CN206229322U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621321504.4U CN206229322U (en) 2016-12-05 2016-12-05 A kind of processing system of catalyst for producing propylene with methanol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201621321504.4U CN206229322U (en) 2016-12-05 2016-12-05 A kind of processing system of catalyst for producing propylene with methanol

Publications (1)

Publication Number Publication Date
CN206229322U true CN206229322U (en) 2017-06-09

Family

ID=58977993

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201621321504.4U Active CN206229322U (en) 2016-12-05 2016-12-05 A kind of processing system of catalyst for producing propylene with methanol

Country Status (1)

Country Link
CN (1) CN206229322U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110054539A (en) * 2019-05-10 2019-07-26 国家能源投资集团有限责任公司 A kind of preparing propylene from methanol device and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110054539A (en) * 2019-05-10 2019-07-26 国家能源投资集团有限责任公司 A kind of preparing propylene from methanol device and method
CN110054539B (en) * 2019-05-10 2022-05-20 国家能源投资集团有限责任公司 Device and method for preparing propylene from methanol

Similar Documents

Publication Publication Date Title
JP6102007B2 (en) Syngas cooling system and method of operation
CN104437274B (en) Fluidized bed reactor used for light olefin cracking and Methanol To Olefin (MTO)
CN107056582A (en) Coal-ethylene glycol carbonylation system reclaims the system and method for methyl nitrite
CN206229322U (en) A kind of processing system of catalyst for producing propylene with methanol
CN106582459A (en) Fluidized bed reactor, lower-carbon olefin preparation apparatus, and lower-carbon olefin preparation method
CN103571510B (en) Powder coal dry distillation method and device
CN102464523B (en) Method for producing light olefins
CN105861080A (en) Rapid catalytic pyrolysis system of biomass downward bed and biomass pyrolysis method
CN103341341A (en) Fluidized bed reactor for preparing butadiene
CN110346473A (en) A kind of device and method measuring catalytic reforming catalyst carbon deposition rate
CN101260014A (en) Method for producing low-carbon olefins from oxygen-containing compound
CN207722773U (en) The low change reactor for preventing drop from carrying secretly
CN211570499U (en) Isobutane production device
CN103073382B (en) The method of butylene isothermal oxidation Oxidative Dehydrogenation butadiene
CN102276393A (en) Method for getting regenerated catalyst back to reactor in regeneration system of reaction for preparing alkene from methanol
CN209197530U (en) A kind of cage heat exchanger in catalytic hydrogenation reaction device
CN101260015B (en) Method for preparing low-carbon olefins from oxygen-containing compound
CN210994350U (en) Reaction device for preparing methyl ethyl ketone by dehydrogenating sec-butyl alcohol
CN204973834U (en) Device of high concentration acetylene hydrogenation system ethylene
JP4183796B2 (en) Method for producing α, β-unsaturated nitrile
CN104610008B (en) System and method for preparing butadiene by butylene oxidation and dehydrogenation
CN208545336U (en) A kind of waste-heat recovery device in ethene hydroformylation reaction process
CN104437269B (en) The production method of shell and tube reactor and vinyl acetate for producing vinyl acetate
CN104140843B (en) A kind of fluid catalystic cracking testing apparatus
CN103464061B (en) A kind of by alkane fluidized bed plant preparing aromatic hydrocarbons and preparation method thereof

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant