CN206219330U - A kind of mining combined multi-stage filtering sewage treatment apparatus - Google Patents
A kind of mining combined multi-stage filtering sewage treatment apparatus Download PDFInfo
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- CN206219330U CN206219330U CN201621302263.9U CN201621302263U CN206219330U CN 206219330 U CN206219330 U CN 206219330U CN 201621302263 U CN201621302263 U CN 201621302263U CN 206219330 U CN206219330 U CN 206219330U
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- 238000001914 filtration Methods 0.000 title claims abstract description 92
- 239000010865 sewage Substances 0.000 title claims abstract description 63
- 238000005065 mining Methods 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 184
- 238000004140 cleaning Methods 0.000 claims abstract description 124
- 239000000919 ceramic Substances 0.000 claims abstract description 59
- 238000000746 purification Methods 0.000 claims abstract description 24
- 239000002351 wastewater Substances 0.000 claims description 47
- 239000012528 membrane Substances 0.000 claims description 26
- 239000010802 sludge Substances 0.000 claims description 20
- 230000001702 transmitter Effects 0.000 claims description 10
- 210000002356 Skeleton Anatomy 0.000 claims description 2
- 238000000034 method Methods 0.000 description 36
- 239000002245 particle Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000011068 load Methods 0.000 description 3
- 238000005374 membrane filtration Methods 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000001112 coagulant Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000007885 magnetic separation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 102000010637 Aquaporins Human genes 0.000 description 1
- 108010063290 Aquaporins Proteins 0.000 description 1
- 210000001138 Tears Anatomy 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 244000052616 bacterial pathogens Species 0.000 description 1
- 201000004569 blindness Diseases 0.000 description 1
- 230000000903 blocking Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000009295 crossflow filtration Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
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- 239000002244 precipitate Substances 0.000 description 1
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Abstract
The utility model discloses a kind of mining combined multi-stage filtering sewage treatment apparatus, including water pump, spiral-flow filter, suction type self-cleaning filter, ceramic inorganic film filter, mudpan, anti- washwater tank, air accumulator, filter press, the water pump and sump, spiral-flow filter is connected, spiral-flow filter is connected with suction type self-cleaning filter, suction type self-cleaning filter is connected with ceramic inorganic film filter, ceramic inorganic film filter is connected with anti-washwater tank, anti- washwater tank respectively with air accumulator, spiral-flow filter, mudpan is connected, mudpan respectively with suction type self-cleaning filter, ceramic inorganic film filter, sump, filter press is connected.The utility model uses three-stage filtration, has the advantages that simple structure, high degree of automation, reliable, purification efficiency are high.
Description
Technical field
The utility model is related to a kind of sewage-treatment plant, at more particularly to a kind of mining combined multi-stage filtering effluent sewage
Reason device.
Background technology
In mine(Colliery and metallic ore)Exploitation in, the technical process such as do mechanization operation and atomizing de-dusting will be produced greatly
The waste water of amount.Contain suspended contamination and the microorganisms such as a large amount of coal dusts, rock dust, and muddy stain in these waste water of mine.
If without treatment directly discharged, serious pollution can be caused to the environment near mining area, meanwhile, do mechanization operation and
The techniques such as atomizing de-dusting, require supplementation with a large amount of clean waters again.Therefore, it is necessary that waste water of mine is carried out to return after purified treatment
With.
The treatment of waste water of mine, there is various different handling process.At present, the technique taken both at home and abroad mainly has following several
Kind:
1st, flocculent precipitation.Flocculant is added in waste water of mine, a period of time is stood, makes coal dust, the Rock Powder of suspension
The impurity such as dirt flocculate into big aggregate, precipitate.Then, sediment unification is filtered.This method not only needs
Using substantial amounts of flocculant, and treatment effect is poor, and process cycle is more long, and floor space is big, if mismanagement contains can lead
Causing supernatant can not reach the standard of direct discharge, also need further reprocessing, and due to needing to add chemical agent, increase
Secondary pollution;
2nd, Bubble-floating Method.By to being input into certain gas in waste water of mine and combining flocculant, making the coal of suspension(Ore deposit)Powder
Big aggregate is flocculated into Deng impurity to be gathered in above bubble and be suspended on the water surface and be removed, this technique floor space
It is small, but water quality is unstable, and running cost is high;Equally exist the secondary pollution problem of chemical agent;
3rd, electromagnetic separation.On the basis of flocculation sediment, using the difference of pollutant magnetic susceptibility in waste water of mine, borrow
Help extraneous magnetic field carries out magnetization treatment so as to reach the technology of idetified separation by goods and materials.Contain magnetizable impurity in the technology water
More multiprocessing effect is better, small with efficiency high, equipment volume, can remove the advantage of bacterial pathogens and partial organic substances,
But technique is relative complex, operating cost is higher;
4th, membrane filter method.In the treatment of waste water, because filtering accuracy is high, the features such as flow is big, therefore, generally using being inorganic
Membrane filtration.But, during mine wastewater treatment, because water mineral content is larger, and particle is thick, is easily caused membrane element
Part is hit and weares and teares, and service life shortens.
Treatment using above-mentioned technique to waste water of mine, there is purified treatment and underground purified treatment two ways on ground.
On the ground treatment, it is necessary to the waste water that underground is produced by water pump lifting on ground, after being processed directly
Discharge returns again to underground for production technology by pipe special.In down-hole treatment, it is not required to waste water lifting to ground, directly
Direct reuse after being processed below the mine.Obviously, direct reuse after being processed under mine waste water of mine, can not only
Substantial amounts of lifting expense is reduced, furthermore, it is possible to reduce or save the conveyance conduit expense from ground to underground.
The need in order to adapt to waste water of mine down-hole treatment, patent ZL201510115939.7 provides a kind of without addition
Any chemical agent, it is pollution-free, have a safety feature, control unit is simple and high degree of automation, the ceramic nothing of high treating effect
The technique and device of machine membrane filtration technique treatment waste water of mine.The technology is using inorganic ceramic membrane as main filtration equipment;Adopt
With two-stage supply-water pump pattern, after the water of shaft sump is pumped into cyclone separator removing big particle by primary pump, nothing is directly entered
Machine film process equipment, concentration water outlet enters circulating line, treatment is circulated by two stage pump circulating pump, during circulation
Periodically the 5-10% of discharge primary pump inflow carries out sludge condensation to sludge concentration tank, supernatant be back to automatic filtering machine after
Continuous treatment.When the particulate matter of inoranic membrane surface accumulation reaches certain limit, by the use of compressed air as online backwash power, and
Online reverse cleaning is carried out to inoranic membrane processing equipment by the clean water in pressure water supply tank, inoranic membrane is recovered filtering work(
Energy.In order to solve the wastewater treatment demand of big flow, by multiple inoranic membrane serial or parallel connections together.In actually used process
In, the technology and technique come with some shortcomings part.Mainly in following several respects:
1st, circulating pump is used in technique, cross-flow filtration is carried out, it is necessary to discharge primary pump inflow in cyclic process
5-10% returns to sludge concentration tank, and power consumption is of a relatively high in operation;
2nd, Y-shaped filter is used in technical process, because its flow area is less, blocking is easily caused.It was cleaned
Journey needs manually to carry out offline, so, system can be influenceed continuously to run;
3rd, after waste water is through cyclone separator, inorganic membrane filter is directly entered, the load of inoranic membrane is larger, filtration resistance meeting
Sharply increase, water flux is greatly reduced, to ensure normal filtering, it is necessary to frequently clear up, so that, cause making for inoranic membrane
Use the lost of life;
4th, disposal ability is low.Main cause has two aspects:First, one-level water pump pumps into the waste water of inorganic film device, there is 10-
15% returns to Waste water concentrating equipment through circulating pump, and this just directly influences the disposal ability of system.Secondly as without good
Pre-filtering measure, processed using the inoranic membrane of fine filtering containing particulate matter waste water higher, filtration resistance rises too fast, frequency
Numerous backwash needs to reduce normal filtration time;
5th, when the filtration resistance value of film device does not have display device, selection filtering and cleaning state, with certain blindness
Property.
In sewage-treatment plant in above-mentioned technique, using cyclone separator except the big particle thing in decontaminated water.This
The cyclone separator of structure type is planted, by particle size, inlet velocity, the influence of many factors such as rotary barrel radius, effect
Rate is not high.In order to improve separative efficiency, patent ZL201420609263.8 employs a kind of by two kinds of mechanism of eddy flow and filtering
The device for combining.In use, separative efficiency increases, but, there is also many problems:
1st, flow deflector is designed in the outside of taper inner cylinder, the radius of turn of current is larger, and the current less for flow are very
Hardly possible forms cyclonic action, it is impossible to centrifugal force necessary to producing separation of solid and liquid, does not reach due effect;
If the 2, the flow and speed of water are sufficiently large, current can produce rotary motion, rotation along the flow deflector on the outside of inner cylinder
It is screen pack on the outside of circulation road, the silt particle of bulky grain is got rid of on screen pack because of centrifugal action with larger inertia, produces punching
Hit and rub, can make screen pack produce abrasion, also, in sewage the concentration of particulate matter and solid particulate matter size increase, rotation
The increase of rotary speed, abrasion plus evidence;
3rd, after sewage enters through cylinder top water inlet, space becomes suddenly big, and the silt particle of bulky grain can first in inlet water tank
It is interior to produce sedimentation, it is necessary to often cleaning.
The content of the invention
In order to solve the above-mentioned technical problem, the utility model provide a kind of simple structure, low production cost, it is reliable,
The mining combined multi-stage filtering sewage treatment apparatus of good filtration effect.
The technical scheme that the utility model solves the above problems is:A kind of mining combined multi-stage filtering treatment of sewage dress
Put, including water pump, spiral-flow filter, suction type self-cleaning filter, ceramic inorganic film filter, mudpan, anti-cleaning
Water pot, air accumulator, filter press, the first water inlet of the water pump are connected with sump, first delivery port and cyclone filter of water pump
The wastewater inlet of device is connected, and the pure water inlet of spiral-flow filter is connected with the second water inlet of suction type self-cleaning filter, inhales
Suck the second delivery port of formula self-cleaning filter to be connected with the 3rd water inlet of ceramic inorganic film filter, ceramic inorganic membrane filtration
3rd delivery port of device is connected with anti-washwater tank, anti-washwater tank respectively with air accumulator, spiral-flow filter, mudpan phase
Even, mudpan is connected with suction type self-cleaning filter, ceramic inorganic film filter, sump, filter press respectively.
In above-mentioned mining combined multi-stage filtering sewage treatment apparatus, the spiral-flow filter includes outer cylinder body, inner cylinder
Body, filtration barrel body, rotational flow generator, inner cylinder pallet, sludge hopper, the outer cylinder body, inner barrel, filtration barrel body coaxial package are one
Rise, and filtration barrel body is located at outer cylinder body, the centre of inner barrel, the inner barrel top is provided with wastewater inlet, is set at wastewater inlet
Have a rotational flow generator, inner barrel top periphery is provided with inner cylinder cover plate, the outer cylinder body top and inner barrel top it
Between be provided with outer barrel cover plate, outer barrel cover plate is located at inner cylinder cover plate top, and the outer cylinder body lower circumference inner side is provided with annular inner cylinder support
Disk, the filtration barrel body top is fixed on inner cylinder cover plate, and filtration barrel body bottom is fixed on inner cylinder pallet, on the outer cylinder body
The circumferencial direction any place in portion is provided with pure water inlet and cleaning water purification mouthful, and cleaning water purification mouthful is connected with anti-washwater tank, described outer
Cylinder lower section is provided with sludge hopper, and the filtration barrel body is made up of the screen pack with skeleton.
In above-mentioned mining combined multi-stage filtering sewage treatment apparatus, the sludge hopper top is cylinder, and bottom is
Inverted cone, cylinder top is fixed on outer cylinder body bottom, and cylinder bottom is fixedly connected with inverted cone top, the cylinder
Deflection cone is provided with being located in vivo immediately below inner barrel lower part outlet, deflection cone is spaced apart with inner barrel lower edge, described
Cylinder circumference any place is provided with the first cleaning sewage draining exit, and the first cleaning sewage draining exit is connected with sump, the inverted cone bottom
It is provided with slag-drip opening.
In above-mentioned mining combined multi-stage filtering sewage treatment apparatus, the suction type self-cleaning filter includes shell
Body, filter cylinder, dredge pump, rotating driving device, rotary shaft, blow-off pipe, suction nozzle, the housing bottom are provided with the second water inlet, shell
Body middle part of sliding channel is provided with the second delivery port, and housing upper is provided with dredge pump, and case top is provided with rotating driving device, in housing
Filter cylinder is provided with, filter cylinder bottom connects with the second water inlet, the blow-off pipe being vertically arranged, blow-off pipe top and blowdown are provided with filter cylinder
The 4th water inlet connection of pump, the 4th delivery port of dredge pump is connected with mudpan, if vertical interlaced arrangement on blow-off pipe
Dry suction nozzle, blow-off pipe top is connected with the rotary shaft of rotating driving device, driving lower band of the rotary shaft in rotating driving device
Dynamic blow-off pipe rotation.
In above-mentioned mining combined multi-stage filtering sewage treatment apparatus, the ceramic inorganic film filter include cylinder,
The some ceramic membrane elements of parallel arrangement in ceramic membrane element, cylinder, cylinder is provided with the 3rd delivery port, and cylinder is respectively arranged at two ends with
Water inlet end end socket and water side end socket, the axial direction on the outside of water inlet end end socket are provided with the 3rd water inlet, water inlet end end socket inner side
Be provided with water conservancy diversion buffer, be equipped with the second cleaning sewage draining exit on water inlet end end socket and water side end socket, the second cleaning sewage draining exit with
Mudpan is connected.
In above-mentioned mining combined multi-stage filtering sewage treatment apparatus, first water inlet, the first delivery port, second
Water inlet, the second delivery port, the 3rd water inlet, the 3rd delivery port, the 4th water inlet, the 4th delivery port, wastewater inlet, water purification go out
Valve is equipped with mouth, cleaning water inlet, the first cleaning sewage draining exit, the second cleaning sewage draining exit, the pipeline of slag-drip opening connection, it is described
Be equipped with pressure difference transmitter on spiral-flow filter, suction type self-cleaning filter, ceramic inorganic film filter, pressure difference transmitter with
The electric control gear of above-mentioned valve is controlled to electrically connect.
In above-mentioned mining combined multi-stage filtering sewage treatment apparatus, the water pump, spiral-flow filter, suctorial type are from clearly
Washed filter is arranged in parallel using two, and ceramic inorganic film filter is combined using multiple serial or parallel connections, each water pump
First water inlet is connected with sump, and the first delivery port of water pump is connected with the wastewater inlet of all spiral-flow filters, each eddy flow
The cleaning water purification of filter mouthful is connected with anti-washwater tank, the pure water inlet of each spiral-flow filter and all suctorial type self-cleanings
Second water inlet of filter is connected, and the first cleaning sewage draining exit of each spiral-flow filter is connected with sump, and each suctorial type is certainly
The 4th delivery port for cleaning the dredge pump of filter is connected with mudpan, and the second of each suction type self-cleaning filter goes out
The mouth of a river is connected with the 3rd water inlet of all ceramic inorganic film filters, the 3rd delivery port of each ceramic inorganic film filter with
Anti- washwater tank is connected, and the second cleaning sewage draining exit of each ceramic inorganic film filter is connected with mudpan.
The beneficial effects of the utility model are:
1st, technique is advanced, technically reliable.The utility model uses three-stage filtration, and first order filtering uses cyclone and filtering
The integral structure that device is organically combined, the filter core of second level filter uses sandwich construction, can remove the overwhelming majority in water
Grain thing, third level essence filtering uses inorganic ceramic membrane, and its filter opening is even less up to 1 nanometer, and purified water can reach drinking water quality
Standard.
2nd, disposal ability is big.Disposal ability of the present utility model depends on the treating capacity of third level essence filtering, due to first
Level and second level filter, to waste water in most particulate matters filtered, third level inorganic ceramic membrane filter water
In especially trickle particulate matter, small, the same film device of filtering load, disposal ability improves several times.Meanwhile, inorganic film device can
Combined in parallel and serial with by multiple, disposal ability increases with film device group number in parallel or series(Different filtering accuracies
Film device series connection, can not only improve filtering accuracy, filter capacity can also be improved.The film device of identical filtering accuracy is simultaneously
Connection, can improve filter capacity).First, second grade of filtering uses suctorial type self-cleaning or high pressure water backwashing, can be according to place
The need for reason ability, the equipment for selecting dimension, also, using " the using and the reserved " configuration, not only cleaning can be carried out offline,
And do not influence the disposal ability of system.
3rd, high degree of automation, saves manpower.The utility model is furnished with pressure difference transmitter on filters at different levels, not only may be used
Changed with display filter resistance in operation, furthermore, it is possible to pressure difference signal is sent into electric control gear, automatic or pass
Valve closing door, and open the anti-automatic cleaning of cleaning device realization.Filtered, it is necessary to close or open phase during the conversion of cleaning
The valve answered, and these valves are all to use electromagnetic actuator, it is not necessary to personnel participate in.The cleaning of filter medium, using pressure
Contracting air is loaded on pressure water supply tank as online backwash power, be allowed to be formed water under high pressure filter is carried out it is online clear
Wash.Not only cleaning performance is good, and simple and reliable.After having cleaned, the pressure difference signal again by filter two ends changes, automatically
Valve is closed or opened, cleaning is completed, recovers filtering.
4th, cost performance is high.The utility model is grading preceding two the particulate matter of the overwhelming majority in the form of multistage filtering
Row filtering is purged.Third level filter is served only for filtering quite trickle particle, and filtering load is at a fairly low, it is possible to reduce film
The quantity of equipment.First, secondary filter, because being that, using traditional filter medium, cost is relatively low.Increase this part of expense
With, far fewer than increase an expense for film device.Therefore, same disposal ability, same filtering accuracy, the property of this technology
Valency is than much higher.
5th, it is reliable, safeguard simple.First and second grade of filter, using the configuration mode of " master one is standby ", is not only convenient for
Realize on-line cleaning, and ensure that the continuation and reliability of operation, even if certain link occurs in that failure in system operation,
Can manually stop in emergency and be overhauled.The utility model eliminates the particulate matter of the overwhelming majority using first and second grade of filter,
Trickle particulate matter is difficult to produce damage to third level filter, and the water inlet of third level filter is also provided with buffer, subtracts
Impact of the current to ceramic membrane element is lacked, cleaning frequency is greatly reduced, so as to ensure that reliability of operation.
6th, compact conformation, floor space is few.First order filter of the present utility model is using eddy flow and filtering integral knot
Structure a, machine has two kinds of functions.Second level filter, is all disposed within together using rotation from formula cleaning way, filtering and cleaning is suck
On one body, inorganic film device in parallel or series, although also multiple independent equipment, however, it is possible to combine, so that
Make compact conformation, reduce floor space.This for carrying out wastewater treatment under mine after reuse, it is especially meaningful, it is possible to reduce
Tunnel is extended because equipment is installed and build large-scale underground building.
7th, strong adaptability.The utility model can be applied not only to mine wastewater treatment, and can be applied to other industrial and minerals enterprise
The sewage purification of industry.Particularly the spiral-flow filter of integral structure, can be applied to the purification of dusty gas.
8th, remarkable in economical benefits.Economic benefit of the present utility model, can be compared in terms of two.One is using not
Compare in the investment cost and operating cost of down-hole treatment simultaneously with technique and equipment.Two are distinguished using same equipment and technique
The investment cost and operating cost for the treatment of and down-hole treatment compare on well.
, different process and equipment compares in the investment cost that underground carries out water process:
By taking certain Mining Group as an example.The handling process taken is three kinds of " super magnetic separation method ", flocculent precipitation and Bubble-floating Method
Technique.So-called " super magnetic separation method " is:Sewage in production process, enters the preliminary sedimentation tank of system through water channel after collecting, sink naturally
Coal, the rock particulate matter of big particle diameter are removed behind shallow lake.Enter coagulating basin through flume again.By adding magnetic kind and coagulant(Mainly
Aluminium chloride), the suspension in sewage is formed " micro- floc sedimentation " with magnetic kind as core within a short period of time, consolidate into cotton-shaped in sewage
Body thing is swum on liquid level, and super magnetic separator is salvaged Solid separate and realizes separation of solid and liquid by magnetic.Nonmagnetic suspension
Grain is transported to special filter press carries out dehydration and drying, and the coal slime after dehydration and drying is transported on well or is filled in through belt feeder
Goaf.Clear water after filtration, purification, more than 70% is used for downhole production process, such as stope driving face spray for dust suppression.30%
The clear water of left and right is lifted onto ground and directly discharged.Design treatment ability is 7000 m3/ d, total investment is 40,000,000 yuan
(The price-level of 2009).
Using combined multi-stage filter, it is assumed that disposal ability is 5000 m3/ d, by present price-level, investment
Total value is 12,000,000 yuan.
Price bullish factor is picked out, disposal ability is 1000m3The investment of/d, the former is 5,710,000.The latter is 2,400,000.
Due to the complex process for using, operating cost is relatively high.Only by taking labour cost as an example.Guarantee system is normally transported
OK, the operating personnel of per tour at least 10 people, divide and work in three shifts.Cost of labor only monthly is accomplished by more than 10 ten thousand yuan.
Using Multistage filtering device, due to high degree of automation, same production scale, per tour operator 2-3 is just
Can be with.
, same technique and equipment compares in the investment cost of underground or down-hole treatment:
Processed on well:
The calculating of a, lifting expense
Lifting 1m3Water often lifts 1 meter about 0.0075 yuan(0.78 yuan of electricity price/degree, efficiency 57%), 1000 meters of meters are risen according to well
Calculate, 7.5 yuan/m of lifting expense3.With design treatment water as 5000m3/ d is calculated, then the annual lifting electricity charge are
5000x7.5x365=13687500 units.
B, delivered downhole Master Cost are calculated
Using ground to delivered downhole, using pipeline grade as well depth is pressurized, material requirement more and more higher is general to use
Reduced pressure treatment, through rough calculation, per yuan/meter of mitron road expense about 750.By the calculating of 1000 meters of well depth, pipeline valve it is disposable
Investment cost about needs 3,000,000 yuan.The maintenance cost of pipeline valve, it is annual to need 1,000,000 yuan.
C, water process expense
Using same process, on well or underground carries out water process, almost, expense remains basically stable equipment.
Down-hole treatment:
A, down-hole treatment mode is taken, it is also desirable to waste water of mine lifting to certain altitude, according to using water hydraulic demand, water
Pressure is not less than 1.6 MPas, is so not less than 200 meters in underground hoisting depth, and design considers lifting to 300 meters.Then
The lifting electricity charge are 2.25 yuan/m3.Equally with design treatment water as 5000m3/ d is calculated, then the annual lifting electricity charge are
5000x2.25x365=4106250 units.
B, equipment installation is carried out in underground, construction cost ratio in place is slightly higher on ground, it is necessary to increase by 500,000 yuan.
C, the one-time investment expense of pipeline valve reduce 2,000,000 yuan;The annual maintenance cost of pipeline valve reduces 2/3,
About 300,000 yuan.
Both compare:
Annual operation power charge decrement:13687500-4106250=9581250 units.Round is 9,600,000.
Build and maintenance cost decrement:(300-200)+ 50+ (100-30)=2,200,000 yuan.
By above-mentioned calculating and contrast, according to disposal ability 5000m3/ d is calculated, same handling process, in down-hole treatment
Than being processed on well, 15,000,000 yuan of system investments, period of recouping investments in equipment about 1 year half or so.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model embodiment one.
Fig. 2 is the structural representation of spiral-flow filter in Fig. 1.
Fig. 3 is the top view of Fig. 2.
Fig. 4 is the structural representation of suction type self-cleaning filter in Fig. 1.
Fig. 5 is the structural representation of ceramic inorganic film filter in Fig. 1.
Fig. 6 is the structural representation of the utility model embodiment two.
Specific embodiment
The utility model is further described with reference to the accompanying drawings and examples.
Embodiment one
As shown in figure 1, a kind of mining combined multi-stage filtering sewage treatment apparatus, including water pump 1, spiral-flow filter 2,
Suction type self-cleaning filter 4, ceramic inorganic film filter 5, mudpan 8, anti-washwater tank 6, air accumulator 8, filter press
9, the first water inlet of the water pump 1 is connected with sump 10, the first delivery port of water pump 1 and the wastewater inlet of spiral-flow filter 2
204 are connected, and the pure water inlet 202 of spiral-flow filter 2 is connected with the second water inlet 409 of suction type self-cleaning filter 4, sucks
Second delivery port 406 of formula self-cleaning filter 4 is connected with the 3rd water inlet 501 of ceramic inorganic film filter 5, ceramic inorganic
3rd delivery port 507 of film filter 5 is connected with anti-washwater tank 6, anti-washwater tank 6 respectively with air accumulator 8, spiral-flow filter
2nd, mudpan 8 be connected, mudpan 8 respectively with suction type self-cleaning filter 4, ceramic inorganic film filter 5, sump
10th, filter press 9 is connected.
The waste water of mine sump 10 is pumped into spiral-flow filter 2 by water pump 1, carries out first order purification, is removed thick
Enter in suction type self-cleaning filter 4 after silt particle particle, carry out second level filtering, remove the medium and small solid particle of the overwhelming majority
Thing;Water containing thin particulate matter less in a small amount, smart filtering is carried out into ceramic inorganic film filter 5, and the water after purification enters work
Process system reuse, meanwhile, in thering is a small part water purification to add to anti-washwater tank 6, exist by the compressed air after pressure regulation decompression
The inner storage of air accumulator 8, and be carried on anti-washwater tank 6, form anti-cleaning power;Sewage discharge after cleaning is to sludge settling
In pond 8, after standing a period of time, clear water returns to sump 10 through overfall, and the mud in sedimentation basin pumps into filter press 9 and enters terminal
Treatment.
As shown in Figure 2 and Figure 3, the spiral-flow filter 2 includes outer cylinder body 201, inner barrel 208, filtration barrel body 209, eddy flow
Generator 205, inner cylinder pallet 210, sludge hopper 213, the outer cylinder body 201, inner barrel 208, the coaxial package of filtration barrel body 209 exist
Together, and filtration barrel body 209 be located at outer cylinder body 201, the centre of inner barrel 208, the top of the inner barrel 208 is provided with wastewater inlet
204, rotational flow generator 205 is provided with wastewater inlet 204, the top periphery of the inner barrel 208 is provided with inner cylinder cover plate 206,
Outer barrel cover plate 203 is provided between the top of the outer cylinder body 201 and the top of inner barrel 208, outer barrel cover plate 203 is located at inner cylinder cover plate
206 tops, the lower circumference of the outer cylinder body 201 inner side is provided with annular inner cylinder pallet 210, and the top of the filtration barrel body 209 is fixed
On inner cylinder cover plate 206, the bottom of filtration barrel body 209 is fixed on inner cylinder pallet 210, the circumference side on the top of the outer cylinder body 201
Pure water inlet 202 and cleaning water purification mouthful 207 are provided with to any place, cleaning water purification mouthful 207 is connected with anti-washwater tank 6, described outer
The lower section of cylinder 201 is provided with sludge hopper 213, and the top of the sludge hopper 213 is cylinder, and bottom is inverted cone, cylinder top
The bottom of outer cylinder body 201 is fixed on, cylinder bottom is fixedly connected with inverted cone top, inner barrel is located in the cylinder
Deflection cone 212 is provided with immediately below 208 lower part outlets, deflection cone 212 is spaced apart with the lower edge of inner barrel 208, the circle
Cylinder circumference any place is provided with the first cleaning sewage draining exit 211, and the first cleaning sewage draining exit 211 is connected with sump 10, the inverted cone
Body bottom is provided with slag-drip opening 214, and slag-drip opening 214 is located at the top of sump 10.
As shown in figure 4, the suction type self-cleaning filter 4 includes that housing 401, filter cylinder 402, dredge pump 403, rotation are driven
Dynamic device 404, rotary shaft 405, blow-off pipe 407, suction nozzle 408, the bottom of the housing 401 is provided with the second water inlet 409, housing
401 middle part of sliding channel are provided with the second delivery port 406, and the top of housing 401 is provided with dredge pump 403, and the top of housing 401 is provided with rotation and drives
Dynamic device 404, filter cylinder 402 is provided with housing 401, and the bottom of filter cylinder 402 connects with the second water inlet 409, is provided with perpendicular in filter cylinder 402
The straight blow-off pipe 407 for setting, the top of blow-off pipe 407 connects with the 4th water inlet of dredge pump 403, and the 4th of dredge pump 403 goes out
The mouth of a river connects with mudpan 8, vertical several suction nozzles 408 of interlaced arrangement on blow-off pipe 407, with rotation at the top of blow-off pipe 407
The rotary shaft 405 of rotary driving device 404 is connected, and rotary shaft 405 drives blow-off pipe 407 under the driving of rotating driving device 404
Rotation.
As shown in figure 5, the ceramic inorganic film filter 5 includes cylinder 505, ceramic membrane element 506, the cylinder 505
The interior some ceramic membrane elements 506 of parallel arrangement, cylinder 505 is provided with the 3rd delivery port 507, and the two ends of cylinder 505 or so set respectively
The axial direction for having water inlet end end socket 502 and water side end socket 508, the outside of water inlet end end socket 502 is provided with the 3rd water inlet 501,
The inner side of water inlet end end socket 502 is provided with water conservancy diversion buffer 503, and it is clear to be equipped with second on water inlet end end socket 502 and water side end socket 508
Sewage draining exit 504 is washed, the second cleaning sewage draining exit 504 is connected with mudpan 8.
First water inlet, the first delivery port, the second water inlet 409, the second delivery port 406, the 3rd water inlet 501,
It is 3rd delivery port 507, the 4th water inlet, the 4th delivery port, wastewater inlet 204, pure water inlet 202, cleaning water inlet, first clear
Wash on the cleaning of sewage draining exit 211, second sewage draining exit 504, the pipeline of the connection of slag-drip opening 214 and be equipped with valve, the spiral-flow filter
2nd, pressure difference transmitter is equipped with suction type self-cleaning filter 4, ceramic inorganic film filter 5, on pressure difference transmitter and control
State the electric control gear electrical connection of valve.Pressure difference transmitter real-time monitors the change of resistance on filter, when reaching the upper of setting
During limit value, automatic cleaning device.
Operation principle is as follows:Water pump 1 will be useless in sump 10(It is dirty)Water, pump to spiral-flow filter 2, the side of wastewater inlet 204
To on the axial direction of rotational flow generator 205, after rotational flow generator 205, turning effort can be produced along inner tube wall, it is big
Particle is thrown toward inner tube wall because of centrifugal action, realizes separation of solid and liquid.Rotary water current continues downward, is stopped by deflection cone 212,
The sludge impacted in sludge hopper 213 is prevented, meanwhile, turned back through water conservancy diversion upwards, into leading between inner cylinder and filtration barrel body 209
Road, because the valve on the bottom slag-drip opening 214 of sludge hopper 213, cleaning water purification mouthful 207, cleaning sewage draining exit is all closed, waste water can pass through
Further purified after filtration barrel body 209, the passage between filtration barrel body 209 and shell, and entered through pure water inlet 202
Enter next stage filter.
After the dirt gathered on the filter screen of filtration barrel body 209 reaches certain thickness, i.e., resistance is increased to one on filter
During threshold value, the valve on wastewater inlet 204, pure water inlet 202 is simultaneously closed off, while opening cleaning water inlet and cleaning blowdown
Valve on mouth, the filter screen to filtration barrel body 209 carries out reverse cleaning.Waste water after cleaning returns to sump 10 or enters sludge and sinks
In shallow lake pond 8.After time delay certain hour, the valve closed on the cleaning water inlet and cleaning sewage draining exit of anti-cleaning, opening clean into
Valve on the mouth of a river and cleaning sewage draining exit, recovers filtration condition.
The waste water purified by spiral-flow filter 2, into suction type self-cleaning filter 4, waste water is from being arranged in housing 401
Second water inlet 409 of bottom, into filter cylinder 402, the water after filtering is arranged at second delivery port at the middle part of housing 401
406 discharges.After suction type self-cleaning filter 4 runs a period of time, the inwall dirt of filter cylinder 402 is constantly gathered, and resistance is raised
During to certain value, start dredge pump 403 and rotating driving device 404, rotating driving device 404 can be rotated axle 405, rotate
Axle 405 drives blow-off pipe 407 to rotate, and several suction nozzles 408, the connection dredge pump 403 of blow-off pipe 407, row are arranged on blow-off pipe 407
The powerful negative pressure that dirty pump 403 is produced, under the dirt of the inwall of filter cylinder 402 being inhaled by suction nozzle 408, is discharged by dredge pump 403
To mudpan 8.During removing contamination, filtering is carried out simultaneously.
The water of purification is sent to ceramic inorganic film filter 5, carries out three-stage filtration.When ceramic inorganic film filter 5 runs one
After fixing time, the inwall build up of dirt of ceramic membrane element 506 causes filtration resistance to raise, and when being increased to the higher limit of setting, closes
3rd water inlet 501 and the 3rd delivery port 507, open the second valve for cleaning sewage draining exit 504, while opening anti-washwater tank 6
Flowing water Valve and pressure breathing valve, compressed air makes the water in anti-washwater tank 6 inversely flow through ceramic inorganic film filter
5, rinse water is entered by the 3rd delivery port 507, reverse cleaning ceramic membrane element 506, and by the second cleaning row of sewage draining exit 504
It is put into mudpan 8.After cleaning, when the pressure difference of pressure difference transmitter returns to the value of setting, signal is provided to electric control gear,
Opposite sequence is closed or opens above-mentioned each valve, re-starts filtering.Water after purification sends underground process system back to.Meanwhile, have one
Fraction is flowed in pressure wash tank.
The first order and third level filter is anti-when being cleaned, will close corresponding entery and delivery port, realize offline fortune
OK, so, its method of operation is interval.
Embodiment two
As shown in fig. 6, embodiment two is with the difference of embodiment one, the water pump 1, spiral-flow filter 2, suctorial type are certainly
Cleaning filter 4 is arranged in parallel using two, and ceramic inorganic film filter 5 is using multiple serial or parallel connection combinations, each water
First water inlet of pump 1 is connected with sump 10, the first delivery port of water pump 1 and the phase of wastewater inlet 204 of all spiral-flow filters 2
Even, the cleaning water purification mouthful 207 of each spiral-flow filter 2 is connected with anti-washwater tank 6, the pure water inlet of each spiral-flow filter 2
202 are connected with the second water inlet 409 of all suction type self-cleaning filters 4, the first cleaning blowdown of each spiral-flow filter 2
Mouth 211 is connected with sump 10, the 4th delivery port and the mudpan 8 of the dredge pump 403 of each suction type self-cleaning filter 4
Connection, the second delivery port 406 of each suction type self-cleaning filter 4 and the 3rd water inlet of all ceramic inorganic film filters 5
Mouth 501 is connected, and the 3rd delivery port 507 of each ceramic inorganic film filter 5 is connected with anti-washwater tank 6, each ceramic inorganic
Second cleaning sewage draining exit 504 of film filter 5 is connected with mudpan 8.
Operation principle is as follows:Water pump 1 will be useless in sump 10(It is dirty)Water, pump to primary spiral-flow filter, wastewater inlet 204
Direction after rotational flow generator 205, can produce turning effort, greatly on the axial direction of rotational flow generator 205 along inner tube wall
Particle because of centrifugal action, be thrown toward inner tube wall, realize separation of solid and liquid.Rotary water current continues downward, is hindered by deflection cone 212
Gear, prevents the sludge impacted in sludge hopper 213, meanwhile, turned back through water conservancy diversion upwards, between inner cylinder and filtration barrel body 209
Passage, because the valve on the bottom slag-drip opening 214 of sludge hopper 213, cleaning water purification mouthfuls 207, cleaning sewage draining exit is all closed, waste water meeting
By further being purified after filtration barrel body 209, the passage between filtration barrel body 209 and shell, and through pure water inlet
202 enter next stage filter;After the dirt gathered on the filter screen of filtration barrel body 209 reaches certain thickness, standby rotation is opened
The wastewater inlet 204 and pure water inlet 202 of flow filter, filtration condition proceeds.Close the sewage of primary spiral-flow filter
Import 204 and pure water inlet 202, and cleaning water inlet and cleaning sewage draining exit are opened, into offline cleaning state.
The waste water purified by spiral-flow filter 2, into primary suction type self-cleaning filter in carry out cascade filtration.Inhale
It is also the standby configuration of a master one to suck formula self-cleaning filter 4, and waste water enters from the second water inlet 409 for being arranged in the bottom of housing 401
In filter cylinder 402, the water after filtering, the second delivery port 406 for being arranged at the middle part of housing 401 is discharged.When primary suctorial type is from clearly
After washing filter operation a period of time, the inwall dirt of filter cylinder 402 is constantly gathered, and when resistance is increased to certain value, opens standby suction
Second water inlet 409 and the second delivery port 406 of formula self-cleaning filter are suck, proceeds filtration condition.Close primary suction
Second water inlet 409 and the second delivery port 406 of formula self-cleaning filter are suck, is allowed in off-line state, meanwhile, start blowdown
Pump 403 and rotating driving device 404, rotating driving device 404 can be rotated axle 405, and rotary shaft 405 drives blow-off pipe 407
Rotation, the powerful negative pressure that dredge pump 403 is produced, under the dirt of the inwall of filter cylinder 402 being inhaled by suction nozzle 408, by dredge pump
403 are discharged into mudpan 8.
The water of purification is sent to ceramic inorganic film filter 5, carries out three-stage filtration.The ceramic inorganic film of multiple serial or parallel connections
Water after the purification of filter 5, is pooled to house steward and is sent to underground process system reuse.Meanwhile, there is sub-fraction to flow to pressure wash
In tank.After some ceramic inorganic film filter runs certain hour, the inwall build up of dirt of ceramic membrane element 506 caused
Filtration resistance power is raised, and when being increased to the higher limit of setting, closes the 3rd water inlet 501 and the 3rd delivery port 507, is opened second and is cleaned
The valve of sewage draining exit 504, while opening the flowing water Valve and pressure breathing valve of anti-washwater tank 6, compressed air makes anti-cleaning
Water in water pot 6 inversely flows through ceramic inorganic film filter, and rinse water is entered by the 3rd delivery port 507, reverse cleaning ceramics
Membrane component 506, and be discharged into mudpan 8 by the second cleaning sewage draining exit 504.After cleaning, the pressure difference of pressure difference transmitter
When returning to the value of setting, signal is provided to electric control gear, opposite sequence is closed or opens above-mentioned each valve, re-starts filtering.
The anti-cleaning of multiple ceramic inorganic film filters 5 is repeated by said process.Water after purification sends underground process system back to.Together
When, there is sub-fraction to flow in pressure wash tank.
When dirty pond accumulates to a certain amount of in mudpan 8, the bottom valve of mudpan 8 is opened, by filter press 9
Dewater treatment is carried out to sludge.
In technical process, first and second grade of filtering is all the standby configuration of a master one, third level filtering be it is multiple in parallel or series
Combination, when one of them carries out offline anti-cleaning, the filtering of other each inoranic membranes is normally carried out, so, the fortune of whole system
Row is continuous, is adapted to the sewage disposal of big flow.
Claims (7)
1. a kind of mining combined multi-stage filters sewage treatment apparatus, it is characterised in that:Including water pump, spiral-flow filter, suction
Suck formula self-cleaning filter, ceramic inorganic film filter, mudpan, anti-washwater tank, air accumulator, filter press, the water
First water inlet of pump is connected with sump, and the first delivery port of water pump is connected with the wastewater inlet of spiral-flow filter, cyclone filter
The pure water inlet of device is connected with the second water inlet of suction type self-cleaning filter, the second water outlet of suction type self-cleaning filter
Mouth is connected with the 3rd water inlet of ceramic inorganic film filter, the 3rd delivery port and the anti-washwater tank of ceramic inorganic film filter
Be connected, anti-washwater tank is connected with air accumulator, spiral-flow filter, mudpan respectively, mudpan respectively with suctorial type
Self-cleaning filter, ceramic inorganic film filter, sump, filter press are connected.
2. mining combined multi-stage according to claim 1 filters sewage treatment apparatus, it is characterised in that:The eddy flow
Filter includes outer cylinder body, inner barrel, filtration barrel body, rotational flow generator, inner cylinder pallet, sludge hopper, the outer cylinder body, inner cylinder
Body, filtration barrel body coaxial package together, and filtration barrel body be located at outer cylinder body, the centre of inner barrel, the inner barrel top sets
There is wastewater inlet, rotational flow generator is provided with wastewater inlet, inner barrel top periphery is provided with inner cylinder cover plate, described outer
Outer barrel cover plate is provided between cylinder top and inner barrel top, outer barrel cover plate is located at inner cylinder cover plate top, the outer cylinder body bottom
Inside circumference is provided with annular inner cylinder pallet, and the filtration barrel body top is fixed on inner cylinder cover plate, and filtration barrel body bottom is fixed on
On inner cylinder pallet, the circumferencial direction any place on the outer cylinder body top is provided with pure water inlet and cleaning water purification mouthful, cleaning water purification mouthful
It is connected with anti-washwater tank, the outer cylinder body lower section is provided with sludge hopper, and the filtration barrel body is made up of the screen pack with skeleton.
3. mining combined multi-stage according to claim 2 filters sewage treatment apparatus, it is characterised in that:The collection mud
Bucket top is cylinder, and bottom is inverted cone, and cylinder top is fixed on outer cylinder body bottom, cylinder bottom and inverted cone
Top is fixedly connected, and is located in the cylinder at inner barrel lower part outlet underface and is provided with deflection cone, deflection cone and inner barrel
Lower edge is spaced apart, and the cylinder circumference any place is provided with the first cleaning sewage draining exit, the first cleaning sewage draining exit and sump
Connection, the inverted cone bottom is provided with slag-drip opening.
4. mining combined multi-stage according to claim 3 filters sewage treatment apparatus, it is characterised in that:It is described to suck
Formula self-cleaning filter includes housing, filter cylinder, dredge pump, rotating driving device, rotary shaft, blow-off pipe, suction nozzle, the housing bottom
Portion is provided with the second water inlet, and housing central section side wall is provided with the second delivery port, and housing upper is provided with dredge pump, and case top is provided with
Rotating driving device, is provided with filter cylinder in housing, filter cylinder bottom is connected with the second water inlet, and the blowdown being vertically arranged is provided with filter cylinder
Pipe, blow-off pipe top is connected with the 4th water inlet of dredge pump, and the 4th delivery port of dredge pump is connected with mudpan, blowdown
Several suction nozzles of vertical interlaced arrangement on pipe, blow-off pipe top is connected with the rotary shaft of rotating driving device, and rotary shaft is in rotation
Drive blow-off pipe rotation under the driving of drive device.
5. mining combined multi-stage according to claim 4 filters sewage treatment apparatus, it is characterised in that:The ceramics
Inorganic membrane filter includes cylinder, ceramic membrane element, some ceramic membrane elements of parallel arrangement in the cylinder, and cylinder is provided with the
Three delivery ports, cylinder is respectively arranged at two ends with water inlet end end socket and water side end socket, and the axial direction on the outside of water inlet end end socket is provided with
3rd water inlet, water inlet end end socket inner side is provided with water conservancy diversion buffer, and it is clear to be equipped with second on water inlet end end socket and water side end socket
Sewage draining exit is washed, the second cleaning sewage draining exit is connected with mudpan.
6. mining combined multi-stage according to claim 5 filters sewage treatment apparatus, it is characterised in that:Described first
Water inlet, the first delivery port, the second water inlet, the second delivery port, the 3rd water inlet, the 3rd delivery port, the 4th water inlet, the 4th
Delivery port, wastewater inlet, pure water inlet, cleaning water inlet, the first cleaning sewage draining exit, the second cleaning sewage draining exit, slag-drip opening connection
Pipeline on be equipped with valve, be equipped with the spiral-flow filter, suction type self-cleaning filter, ceramic inorganic film filter
Pressure difference transmitter, pressure difference transmitter is electrically connected with the electric control gear of above-mentioned valve is controlled.
7. mining combined multi-stage according to claim 1 filters sewage treatment apparatus, it is characterised in that:The water
Pump, spiral-flow filter, suction type self-cleaning filter are arranged in parallel using two, and ceramic inorganic film filter is gone here and there using multiple
Connection or parallel combination, the first water inlet of each water pump are connected with sump, the first delivery port and all spiral-flow filters of water pump
Wastewater inlet be connected, the cleaning water purification of each spiral-flow filter mouthful is connected with anti-washwater tank, each spiral-flow filter it is net
Water out is connected with the second water inlet of all suction type self-cleaning filters, the first cleaning sewage draining exit of each spiral-flow filter
Connected with sump, the 4th delivery port of the dredge pump of each suction type self-cleaning filter is connected with mudpan, each suction
The second delivery port for sucking formula self-cleaning filter is connected with the 3rd water inlet of all ceramic inorganic film filters, each ceramic nothing
3rd delivery port of machine film filter is connected with anti-washwater tank, each ceramic inorganic film filter second cleaning sewage draining exit with
Mudpan is connected.
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CN201621302263.9U CN206219330U (en) | 2016-11-30 | 2016-11-30 | A kind of mining combined multi-stage filtering sewage treatment apparatus |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106396162A (en) * | 2016-11-30 | 2017-02-15 | 湖南科技大学 | Mining combined multi-stage filtration effluent sewage treatment device |
CN113354151A (en) * | 2021-06-29 | 2021-09-07 | 武汉市荣国环保科技有限公司 | Method for treating underground coal mine water |
-
2016
- 2016-11-30 CN CN201621302263.9U patent/CN206219330U/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106396162A (en) * | 2016-11-30 | 2017-02-15 | 湖南科技大学 | Mining combined multi-stage filtration effluent sewage treatment device |
CN113354151A (en) * | 2021-06-29 | 2021-09-07 | 武汉市荣国环保科技有限公司 | Method for treating underground coal mine water |
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