CN206184258U - Electrolytic aluminum flue gas liquid phase desulphurization unit - Google Patents

Electrolytic aluminum flue gas liquid phase desulphurization unit Download PDF

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Publication number
CN206184258U
CN206184258U CN201621215404.3U CN201621215404U CN206184258U CN 206184258 U CN206184258 U CN 206184258U CN 201621215404 U CN201621215404 U CN 201621215404U CN 206184258 U CN206184258 U CN 206184258U
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China
Prior art keywords
electrolytic aluminum
demister
aluminum smoke
air
introduced machine
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CN201621215404.3U
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Chinese (zh)
Inventor
王复生
班祥
库振环
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Jiaozuo Letter Metallurgical Science And Technology Co Ltd
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Jiaozuo Letter Metallurgical Science And Technology Co Ltd
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Abstract

The utility model provides an electrolytic aluminum flue gas liquid phase desulphurization unit, include the desulfurization flue that is used for with electrolytic aluminum gas cleaning headtotail, the desulfurization flue is connected with the draught fan, and the desulfurization flue is inside to be equipped with atomizing device, and the export of desulfurization flue is equipped with the defogging device, atomizing device is connected with the receiver, the defogging device is equipped with leakage fluid dram and exhaust port, and the leakage fluid dram is used for being connected with waste liquid treatment device, and the exhaust port is used for communicateing with outside. This device can direct and current electrolytic aluminum gas cleaning system be formed a complete set and is connected, and the investment is low with the running cost, influences for a short time to former electrolytic aluminum gas cleaning system, and the desulfurization is efficient.

Description

A kind of electrolytic aluminum smoke liquid desulfuration device
Technical field
The utility model is related to a kind of electrolytic aluminum smoke liquid desulfuration device, belongs to flue gas purifying equipment field.
Background technology
In aluminum electrolysis industry, aluminium electrolysis process is, with alumina melt as electrolyte, electricity to be carried out by electrode of carbon materials Solution, separates out the metallic aluminium of liquid on negative electrode, is produced with CO on anode2Based on anodic gas.Simultaneously because anode carbon block In contain S elements, therefore also contain SO in addition to containing with hydrogen fluoride, fluoride, dust in electrolytic aluminum smoke2.Former electrolytic aluminium Technique uses anode carbon block S constituent contents low, SO in electrolytic aluminum smoke2Concentration it is relatively low, so the electricity set up before Solution aluminium flue gas purification system is equipped without desulfurization.But sulfur content is increasingly in the anode carbon block that is used by electrolytic aluminium at present Height, causes SO in electrolytic aluminum smoke2Concentration also increase.According to SO in calculating current electrolysis aluminium flue gas2Concentration be generally 200-300mg/Nm3
According to《Aluminum i ndustry pollutant emission standard》(GB25465-2010)And promulgate for 2014《Aluminum i ndustry pollutant is arranged Put standard》Amendment, it is desirable in key area by SO2Concentration control in 100 mg/Nm3Below, it is therefore desirable to electrolytic aluminium cigarette Gas carries out desulfurization process.
Electrolytic aluminum smoke have exhaust gas volumn it is big, containing sulphur concentration it is relatively low the characteristics of, therefore use Gypsum Wet Desulphurization system floor space is big during sulfur removal technology, system operation whole efficiency is relatively low, operating cost is high.External electrolytic aluminium factory is general Build by the sea, therefore generally using the technique of sea water desulfuration.But domestic electrolytic aluminium factory is due to electricity price factor, typically will electrolysis Aluminium manufacturer is built in the relatively low inland of grid electricity fee cost, does not possess the condition of sea water desulfuration.Therefore need for China's aluminum electrolysis industry Actual conditions, develop new electrolytic aluminum smoke sulfur method and equipment.
Utility model content
In order to solve the above problems, the utility model provides a kind of electrolytic aluminum smoke liquid desulfuration device, particular technique Scheme is:
A kind of electrolytic aluminum smoke liquid desulfuration device, including the desulfurization cigarette for being connected with electrolytic aluminum smoke cleaning system Road, the desulfurization duct is connected with air-introduced machine, and atomising device is provided with inside desulfurization duct, and the outlet of desulfurization duct is provided with demisting dress Put;The atomising device is connected with receiver;The demister is provided with leakage fluid dram and exhaust opening, leakage fluid dram be used for at waste liquid Reason device connection, exhaust opening is used for and ft connection.
Further, it is provided with multigroup atomising device inside the desulfurization duct.
Further, before the atomising device is located at air-introduced machine, inside air-introduced machine, or after air-introduced machine.
Further, the atomising device is the makeup of reflux pump atomising device, compressed air atomising device or ultrasonic fog Put.
Further, the desulfurization duct rear portion is connected with multiple branch flues, and each branch flue is equipped with air-introduced machine, and often Individual branch flue is all connected to demister.
Further, the bottom of the air-introduced machine is provided with leakage fluid dram, and leakage fluid dram is used to be connected with liquid waste treating apparatus.
Further, the liquid waste treating apparatus include the neutralization pond, sedimentation basin and the Solid state fermentation device that are sequentially connected, institute State neutralization pond and be connected with lye tank (vat), the sedimentation basin is connected to receiver by circulation line.
Further, the demister is deentrainment tower, and demister is provided with deentrainment tower, and the exhaust opening is and deentrainment tower The smoke exhaust barrel of connection.
Further, the demister is chimney, and demister is provided with inside chimney.
Beneficial point of the present utility model is:The utility model is directed to the characteristics of domestic electrolytic aluminum smoke is purified and present situation, There is provided a kind of new electrolytic aluminum smoke desulfurizer, the device both can be applied to newly-built flue gas purification system desulfurization, also might be used It is applied to the desulfurizing fly ash of existing electrolytic aluminum smoke cleaning system.When existing electrolytic aluminum smoke desulphurization system transformation is applied to, Existing system capital equipment need not be modified and changed, directly can carried out with existing electrolytic aluminum smoke cleaning system supporting Connection, investment and operating cost are low, influence small to former electrolytic aluminum smoke cleaning system, and desulfuration efficiency is high.
The carrying out practically principle of this programme is to enter desulfurization duct through electrolytic aluminum smoke cleaning system sulfur-containing smoke gas out It is interior, while the atomizer that the water in being stored in receiver or the solution containing catalyst enter in desulfurization duct, produces spraying.Spraying with Sulfur-containing smoke gas mix in desulfurization duct, and by the high speed rotation reinforcing mixed effect of draught fan impeller, spray in flue gas After sulphur content is fully absorbed, preliminary aerosol separation is carried out using centrifugal force in air-introduced machine, finally carried out in demister Demisting.The sulphur-bearing waste solution isolated into being neutralized with alkaline reaction in neutralization pond, and into being settled out residue in sedimentation basin, Water or solution after precipitation are recycled in receiver and reuse, and waste residue can be recycled by after filtering and squeezing treatment.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing The accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, may be used also Other accompanying drawings are obtained with according to these accompanying drawings.
Fig. 1 is the structural representation of embodiment 1 in the utility model;
Fig. 2 is the structural representation of embodiment 2 in the utility model.
Specific embodiment
Below in conjunction with the accompanying drawing in the utility model embodiment, the technical scheme in the utility model embodiment is carried out Clearly and completely describe, it is clear that described embodiment is only a part of embodiment of the utility model, rather than whole Embodiment.Based on the embodiment in the utility model, those of ordinary skill in the art are not under the premise of creative work is made The every other embodiment for being obtained, any modification, equivalent substitution and improvements made etc., should be included in of the present utility model Within protection domain.
Embodiment 1:
A kind of electrolytic aluminum smoke liquid desulfuration device as shown in Figure 1, including for connecting with electrolytic aluminum smoke cleaning system 1 The desulfurization duct 2 for connecing, the desulfurization duct 2 is connected with air-introduced machine 6, and atomising device 3, desulfurization duct 2 are provided with inside desulfurization duct 2 Outlet be provided with demister 5;The atomising device 3 is connected with receiver 4;The demister 5 is provided with leakage fluid dram and smoke evacuation Mouthful, leakage fluid dram is used to be connected with liquid waste treating apparatus, and exhaust opening is used for and ft connection.
Multigroup atomising device 3 is provided with inside the desulfurization duct 2.
Before the atomising device 3 is located at air-introduced machine 6, inside air-introduced machine 6, or after air-introduced machine 6.
The atomising device 3 is reflux pump atomising device, compressed air atomising device or supersonic atomizer.
The rear portion of the desulfurization duct 2 is connected with multiple branch flues 13, and each branch flue 13 is equipped with air-introduced machine 6, and each Branch flue 13 is all connected to demister 5.
The bottom of the air-introduced machine 6 is provided with leakage fluid dram, and leakage fluid dram is used to be connected with liquid waste treating apparatus.
The liquid waste treating apparatus include the neutralization pond 8, sedimentation basin 9 and the Solid state fermentation device 10 that are sequentially connected, it is described in Lye tank (vat) 11 is connected with pond 8, the sedimentation basin 9 is connected to receiver 4 by circulation line 12.
The demister 5 is deentrainment tower, and demister 7 is provided with deentrainment tower, and the exhaust opening is to be connected with deentrainment tower Smoke exhaust barrel 14.
Embodiment 2:
As shown in Fig. 2 on the basis of embodiment 1, the demister 5 is chimney, and demister 7 is in chimney.

Claims (9)

1. a kind of electrolytic aluminum smoke liquid desulfuration device, including the desulfurization duct for being connected with electrolytic aluminum smoke cleaning system, It is characterized in that:The desulfurization duct is connected with air-introduced machine, and atomising device is provided with inside desulfurization duct, and the outlet of desulfurization duct sets There is demister;The atomising device is connected with receiver;The demister is provided with leakage fluid dram and exhaust opening, and leakage fluid dram is used for It is connected with liquid waste treating apparatus, exhaust opening is used for and ft connection.
2. electrolytic aluminum smoke liquid desulfuration device according to claim 1, it is characterised in that:Set inside the desulfurization duct There is multigroup atomising device.
3. electrolytic aluminum smoke liquid desulfuration device according to claim 2, it is characterised in that:The atomising device is located at and draws Before blower fan, inside air-introduced machine, or after air-introduced machine.
4. electrolytic aluminum smoke liquid desulfuration device according to claim 2, it is characterised in that:The atomising device is backflow Pump atomising device, compressed air atomising device or supersonic atomizer.
5. electrolytic aluminum smoke liquid desulfuration device according to claim 1, it is characterised in that:The desulfurization duct rear portion connects Multiple branch flues are connected to, each branch flue is equipped with air-introduced machine, and each branch flue is all connected to demister.
6. electrolytic aluminum smoke liquid desulfuration device according to claim 5, it is characterised in that:The bottom of the air-introduced machine sets There is leakage fluid dram, leakage fluid dram is used to be connected with liquid waste treating apparatus.
7. electrolytic aluminum smoke liquid desulfuration device according to claim 6, it is characterised in that:The liquid waste treating apparatus bag Neutralization pond, sedimentation basin and the Solid state fermentation device being sequentially connected are included, the neutralization pond is connected with lye tank (vat), and the sedimentation basin passes through Circulation line is connected to receiver.
8. electrolytic aluminum smoke liquid desulfuration device according to claim 1, it is characterised in that:The demister is demisting Tower, is provided with demister in deentrainment tower, the exhaust opening is the smoke exhaust barrel being connected with deentrainment tower.
9. electrolytic aluminum smoke liquid desulfuration device according to claim 1, it is characterised in that:The demister is cigarette Chimney, is provided with demister inside chimney.
CN201621215404.3U 2016-11-11 2016-11-11 Electrolytic aluminum flue gas liquid phase desulphurization unit Active CN206184258U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621215404.3U CN206184258U (en) 2016-11-11 2016-11-11 Electrolytic aluminum flue gas liquid phase desulphurization unit

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Application Number Priority Date Filing Date Title
CN201621215404.3U CN206184258U (en) 2016-11-11 2016-11-11 Electrolytic aluminum flue gas liquid phase desulphurization unit

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CN206184258U true CN206184258U (en) 2017-05-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106334442A (en) * 2016-11-11 2017-01-18 焦作和信冶金科技有限责任公司 Liquid-phase desulphurization device and method for electrolytic aluminum flue gas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106334442A (en) * 2016-11-11 2017-01-18 焦作和信冶金科技有限责任公司 Liquid-phase desulphurization device and method for electrolytic aluminum flue gas

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