CN206146875U - Can carry out normal position pond of electrochemistry spectrum experiment - Google Patents
Can carry out normal position pond of electrochemistry spectrum experiment Download PDFInfo
- Publication number
- CN206146875U CN206146875U CN201621170358.XU CN201621170358U CN206146875U CN 206146875 U CN206146875 U CN 206146875U CN 201621170358 U CN201621170358 U CN 201621170358U CN 206146875 U CN206146875 U CN 206146875U
- Authority
- CN
- China
- Prior art keywords
- situ
- main body
- normal position
- tank main
- pond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
The utility model discloses a can carry out normal position pond of electrochemistry spectrum experiment, including base and normal position pond main part, the inside cavity that be of normal position pond main part, main part upper portion open have with the cavity intercommunication to electrode slot, working electrode slot, reference electrode slot, feed liquor hole and go out the liquid hole, openly open flutedly in normal position pond main part, it has the light trap to open in the recess, the light trap both ends are the glutinous kapton sticky tape of going up all, just division is having an entrance pupil of an oblique stamp towards the recess lateral wall from normal position pond main part, is just personally submitting 45 with normal position pond main part. The utility model discloses a normal position pond is extremely acidproof, alkali, can carry out the normal position electrochemistry spectrum experiment of all kinds of catalyst in the acidic bath or in the alkaline electrolysis liquid, not only can be reacted the electrochemistry data in arbitrary stage and corresponding spectral data, can obtain electrochemistry data and spectral data under arbitrary voltage moreover.
Description
Technical field
This utility model belongs to electrochemical optical spectra in-situ characterization technical field, is related to a kind of catalyst electrification optical spectra in situ
The device and test system of sign, specifically a kind of pond in situ that can carry out electrochemistry spectrum experiment.
Background technology
X-ray absorption spectrum based on synchrotron due to breaching the energy limit of Traditional x-ray absorption spectrum, with
By means of can accurately frequency modulation the advantages of, become the exhausted of study mechanism in classical electrochemical issues together with electrochemical property test
Good means.Under the conditions of the certain electrical potential in actual electrochemical reaction process is existed only in due to real avtive spot, based on same
The X-ray technology of step accelerator combines the introducing of electrochemical in-situ technology, can really analyze the boundary in reaction real-time process
Face phenomenon.
In general, X-ray absorption spectrum includes two parts：X-ray absorption near side (ns) composes (XANES) and extension x-ray
Absorption Fine Structure spectrogram (EXAFS).Wherein XANES can provide the chemical state information of metallic element, including oxidation state information,
Sometimes also have local geometry information, EXAFS can provide absorb atom to adjacent to atom distance adjacent to atom kind
Class sum purpose quantitative information, both combinations can obtain the more comprehensive Local Structure information of nanoparticle.
Utility model content
In order to obtain the electrochemical in-situ data and spectroscopic data of catalyst, the interface preferably studied in catalytic process is existing
As and reaction mechanism, this utility model provides a kind of pond in situ that can carry out electrochemistry spectrum experiment of highly versatile.
The pond in situ that electrochemistry spectrum experiment can be carried out of the present utility model, including base and the original being installed on base
Position tank main body, is cavity inside described tank main body in situ, and tank main body top is provided with connect with cavity slotting to electrode in the original location
Groove, working electrode slot, reference electrode slots, in the original location tank main body both sides have the inlet opening that connects with cavity and go out liquid
Hole, described inlet opening and liquid outlet connect the two ends of circulation pump, and the another two ends of circulation pump form electricity in being immersed in electrolytic solution
Solution liquid closed circuit；Tank main body front is provided with groove in the original location, is provided with a loophole, loophole in groove on tank main body in situ
Two ends affix kapton adhesive tapes, are just provided with an entrance pupil for tiltedly stabbing towards recess sidewall from tank main body in situ, with original position
Tank main body front is in 45 °.
In above-mentioned technical proposal, described tank main body in situ can be 3D printing politef cell body.
It is described to electrode slot for diameter 1.5cm circular socket, the circle of described reference electrode slots for diameter 1cm
Shape slot, described working electrode slot are the rectangle slot of 1cm × 0.3cm.
Described adopt to the electrode good carbon-point of electric conductivity, reference electrode adopts calomel electrode, and working electrode is to scribble
The carbon cloth and carbon paper of catalyst.
Described loophole is located at a diameter of 0.5cm, a diameter of 1.5cm of opposite side of tank main body face side in situ.Printing opacity
Hole two ends are sealed again using the Kapton adhesive tapes with excellent light transmittance energy, keep whole original position tank main body sealing.
Described entrance pupil is at 45 ° with pond front in situ, and incident X-ray can pass through entrance pupil and positive
Unthreaded hole is injected, and is projected by the loophole at the back side, and not only can collect incident illumination, transmission light data can also connect in pond front in the original location
Receive its fluorescence data.And when its fluorescence data is not needed, X-ray then can be directly incident by positive loophole.
Original position electrification of the pond in situ of the present utility model suitable for catalyst acidic electrolysis bath or alkaline electrolyte
Optical spectra is tested, and not only can be obtained reacting the electrochemical data and corresponding spectroscopic data of either phase, and can be obtained
Electrochemical data and spectroscopic data under any voltage, highly versatile.
Description of the drawings
Fig. 1 is application schematic diagram of the pond in situ of the present utility model in the original location in electrochemistry spectrum experiment；
Fig. 2 is the structural representation in pond in situ；
Fig. 3 is the front view in pond in situ.
Fig. 4 is the top view in pond in situ.
In figure：1 is inlet opening, and 2 are tank main body front in situ, and 3 is that, to electrode slot, 4 is working electrode slot, and 5 are ginseng
Than electrode slot, 6 is loophole, and 7 is entrance pupil, and 8 is liquid outlet.
Specific embodiment
In conjunction with the embodiments this utility model is described further below against accompanying drawing：Reference picture 1-4, it is of the present utility model
Pond in situ, including base and the tank main body in situ being installed on base, are cavity inside described tank main body in situ, in the original location pond
Body top be provided with connect with cavity to electrode slot 3, working electrode slot 4, reference electrode slots 5, tank main body in the original location
Both sides have the inlet opening 1 and liquid outlet 8 connected with cavity, and tank main body positive 2 is provided with groove in the original location, pond in situ in groove
A loophole 6 is provided with main body, 6 two ends of loophole affix kapton adhesive tapes, from tank main body in situ just towards recess sidewall
An entrance pupil 7 for tiltedly stabbing is provided with, is in 45 ° with tank main body front in situ.When specifically used, as shown in figure 1, described feed liquor
Hole and liquid outlet connect the two ends of circulation pump, and the another two ends of circulation pump form electrolyte closed circuit in being immersed in electrolytic solution；
It is 1 that the catalyst of certain mass is scattered in isopropanol and water volume ratio:In 1 mixed solution, while adding one
Quantitative mass fraction be 0.05% Nafion solution as binding agent, ultrasonic several minutes are prepared into ink.
Carbon cloth and carbon paper are cut by the pool size in situ of design, and weighs quality respectively, by the above-mentioned ink for preparing
It is coated onto on carbon cloth and carbon paper, cryogenic vacuum drying weighs quality, is repeated a number of times, until reaching targeted loads amount 5mg/
cm2。
Experimental provision and equipment are connected as shown in Figure 1.
Regulation light source incident ray so as to reach perfect condition.
To the logical object gas several minutes of the electrolyte solution for preparing, until other gases in guaranteeing whole solution are
It is discharged totally, whole solution is in object gas atmosphere.
Pond in situ is placed on target object stage, circulation pump and circulation line is connected, connect three electrodes and
Electrochemical workstation, the position in the good original position pond of calibration guarantee it is errorless after, turn on pump makes which circulate several minutes.
Experiment hatch door is closed, light source is opened and electrochemical workstation is tested, needed for electrochemical workstation is adjusted to
The current potential wanted, carries out electrochemical in-situ spectrum test.The voltage or electric current of control working electrode, collects spectroscopic data and circulation
Voltammetric data.
Specific embodiment of the utility model is exemplified as more than, it is clear that this utility model is not limited to above example, this
The those of ordinary skill in field is directly derived from this utility model disclosure or the deformation associated all should belong to this reality
With new protection domain.
Claims (5)
1. a kind of pond in situ that can carry out electrochemistry spectrum experiment, it is characterised in that including base and be installed on base
Tank main body in situ, inside described tank main body in situ be cavity, in the original location tank main body top be provided with connect with cavity to electrode
Slot, working electrode slot, reference electrode slots, in the original location tank main body both sides have the inlet opening that connects with cavity and go out
Fluid apertures, described inlet opening and liquid outlet connect the two ends of circulation pump, and the another two ends of circulation pump are formed in being immersed in electrolytic solution
Electrolyte closed circuit；Tank main body front is provided with groove in the original location, is provided with a loophole, printing opacity in groove on tank main body in situ
Hole two ends affix kapton adhesive tapes, are just provided with an entrance pupil for tiltedly stabbing towards recess sidewall from tank main body in situ, with original
Position tank main body front is in 45 °.
2. the pond in situ of electrochemistry spectrum experiment can be carried out as claimed in claim 1, it is characterised in that described pond in situ
Main body is 3D printing politef cell body.
3. the pond in situ of electrochemistry spectrum experiment can be carried out as claimed in claim 1, it is characterised in that described to electrode
Circular socket of the slot for diameter 1.5cm, described reference electrode slots are the circular socket of diameter 1cm, described work electricity
Rectangle slot of the pole slot for 1cm × 0.3cm.
4. the pond in situ of electrochemistry spectrum experiment can be carried out as claimed in claim 3, it is characterised in that described to electrode
Using carbon-point, reference electrode adopts calomel electrode, and working electrode is the carbon cloth and carbon paper for scribbling catalyst.
5. the pond in situ of electrochemistry spectrum experiment can be carried out as claimed in claim 1, it is characterised in that described loophole
Positioned at a diameter of 0.5cm of tank main body face side in situ, a diameter of 1.5cm of opposite side.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621170358.XU CN206146875U (en) | 2016-10-26 | 2016-10-26 | Can carry out normal position pond of electrochemistry spectrum experiment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621170358.XU CN206146875U (en) | 2016-10-26 | 2016-10-26 | Can carry out normal position pond of electrochemistry spectrum experiment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206146875U true CN206146875U (en) | 2017-05-03 |
Family
ID=58622822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621170358.XU Expired - Fee Related CN206146875U (en) | 2016-10-26 | 2016-10-26 | Can carry out normal position pond of electrochemistry spectrum experiment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206146875U (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107555549A (en) * | 2017-10-10 | 2018-01-09 | 佛山科学技术学院 | A kind of 3D printing electrocatalysis device for laboratory |
| CN109470725A (en) * | 2018-09-10 | 2019-03-15 | 上海交通大学 | The synchrotron radiation in-situ testing device of catalyst in fuel cell catalyst layer |
| CN111220673A (en) * | 2018-11-25 | 2020-06-02 | 中国科学院大连化学物理研究所 | Electrochemical testing device for in-situ Mossbauer spectra and application |
| CN112824887A (en) * | 2019-11-21 | 2021-05-21 | 中国科学院大连化学物理研究所 | Three-electrode electrochemical testing device |
-
2016
- 2016-10-26 CN CN201621170358.XU patent/CN206146875U/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107555549A (en) * | 2017-10-10 | 2018-01-09 | 佛山科学技术学院 | A kind of 3D printing electrocatalysis device for laboratory |
| CN109470725A (en) * | 2018-09-10 | 2019-03-15 | 上海交通大学 | The synchrotron radiation in-situ testing device of catalyst in fuel cell catalyst layer |
| CN111220673A (en) * | 2018-11-25 | 2020-06-02 | 中国科学院大连化学物理研究所 | Electrochemical testing device for in-situ Mossbauer spectra and application |
| CN111220673B (en) * | 2018-11-25 | 2021-06-11 | 中国科学院大连化学物理研究所 | Electrochemical testing device for in-situ Mossbauer spectra and application |
| CN112824887A (en) * | 2019-11-21 | 2021-05-21 | 中国科学院大连化学物理研究所 | Three-electrode electrochemical testing device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN206146875U (en) | Can carry out normal position pond of electrochemistry spectrum experiment | |
| Hegge et al. | Efficient and stable low iridium loaded anodes for PEM water electrolysis made possible by nanofiber interlayers | |
| Govindaraju et al. | Methods for electrochemical synthesis and photoelectrochemical characterization for photoelectrodes | |
| Garcia-Navarro et al. | Measuring and modeling mass transport losses in proton exchange membrane water electrolyzers using electrochemical impedance spectroscopy | |
| Binninger et al. | Electrochemical flow-cell setup for in situ X-ray investigations | |
| Chakrabarti et al. | Modelling of redox flow battery electrode processes at a range of length scales: a review | |
| Zhang et al. | Oxygen vacancies unfold the catalytic potential of NiFe-layered double hydroxides by promoting their electronic transport for oxygen evolution reaction | |
| Etzold et al. | Understanding the activity transport nexus in water and CO2 electrolysis: State of the art, challenges and perspectives | |
| Schellenberger et al. | Accessing the solid electrolyte interphase on silicon anodes for lithium-ion batteries in-situ through transmission soft X-ray absorption spectroscopy | |
| Nageswaran | Operando X-ray spectroscopic techniques: a focus on hydrogen and oxygen evolution reactions | |
| Trovo et al. | Multichannel Electrochemical Impedance Spectroscopy and equivalent circuit synthesis of a large-scale vanadium redox flow battery | |
| CN103884728B (en) | A kind of synchrotron radiation in situ detection device for electrocatalytic reaction | |
| Zhang et al. | In-situ measurement of electrode kinetics in porous electrode for vanadium flow batteries using symmetrical cell design | |
| Liu et al. | Kinetic insights of proton exchange membrane water electrolyzer obtained by operando characterization methods | |
| Zago et al. | Physically-based impedance modeling of the negative electrode in All-Vanadium Redox Flow Batteries: insight into mass transport issues | |
| CN107014884A (en) | A kind of in-situ test fixture and system for solid polymer electrolyte system | |
| CN104828867B (en) | Solvent-thermal method prepares three-dimensional manometer layer structure WS2and electrochemical applications | |
| Amini et al. | A two-dimensional transient model for a zinc-cerium redox flow battery validated by extensive experimental data | |
| Schlüter et al. | Nonlinear electrochemical analysis: worth the effort to reveal new insights into energy materials | |
| Unocic et al. | In situ electrochemical scanning/transmission electron microscopy of electrode–electrolyte interfaces | |
| Xu et al. | Tuning electrolyte solvation structures to enable stable aqueous Al/MnO2 battery | |
| Hahn et al. | Concentration-dependent ion correlations impact the electrochemical behavior of calcium battery electrolytes | |
| Voronova et al. | Systematic degradation analysis in renewable energy-powered proton exchange membrane water electrolysis | |
| Kubannek et al. | Studying the interaction of mass transport and electrochemical reaction kinetics by species frequency response analysis | |
| Baker et al. | Cerium migration in polymer electrolyte membranes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170503 Termination date: 20211026 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |