CN206124369U - Compound thermal -insulated light control glass - Google Patents
Compound thermal -insulated light control glass Download PDFInfo
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- CN206124369U CN206124369U CN201621118924.2U CN201621118924U CN206124369U CN 206124369 U CN206124369 U CN 206124369U CN 201621118924 U CN201621118924 U CN 201621118924U CN 206124369 U CN206124369 U CN 206124369U
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Abstract
The utility model provides a compound thermal -insulated light control glass, relates to photoelectric product technical field, including the first film substrate, second film substrate, a glass substrate and the 2nd glass substrate, the first film substrate, second film substrate are located between a glass substrate and the 2nd glass substrate, the sputter has a transparent conducting film on the first film substrate, and the sputter has the 2nd transparent conducting film on the second film substrate, the PDLC liquid crystal layer coats on the 2nd transparent conducting film of a transparent conducting film, the first substratum transparent that coats on the first film substrate / glass substrate, a first film substrate and a glass substrate through the laminating of first substratum transparent together, the second substratum transparent that coats on second film substrate / the 2nd glass substrate, second film substrate and the 2nd glass substrate pass through the second substratum transparent and laminate together, it has ultraviolet absorber and infrared ray separation agent to add in the first substratum transparent, and it has infrared ray separation agent to add in the second substratum transparent.
Description
Technical field
This utility model is related to photovoltaic technical field, more particularly to a kind of compound heat-insulation dimming glass.
Background technology
Glass used by automobile is mostly the organic transparent materials such as simple unorganic glass or PC, PMMA, these material sheets
Body does not have the effect for absorbing infrared ray and ultraviolet, and Jing after long-time is exposed to the sun, in-car usually has one unpleasant modeling to automobile
Expect burned abnormal smells from the patient, in fact, these abnormal flavour are mostly that automotive trim is irradiated by sunlight and high temperature is scorched and come out, and
Under long-term being exposed to the sun, automotive trim can gradually aging deformation, can also affect normally to use when serious.
In order to avoid in-car is by the problem that direct sunlight causes temperature too high and interior trim is aging, Application No.
201210132697.9 Chinese utility model patent discloses a kind of automobile smart glass, and its concrete structure is in one layer of conduction
Light modulation film(Aluminum porous oxide film)Both sides cover there is heat insulating compound film to infrared ray high reflectance metal, and extremely
Glass substrate is fixedly connected on the outside of few one layer of heat insulating compound film.The automobile smart glass needs will be each using technique laminated into type
Layer material is pressed to together, and it is higher to glass surface flatness requirement(If glass surface flatness is not up to standard will easily produce
The defects such as bubble, layering), when manufacturing dimming glass especially with bend glass, it is desirable to the surfacing of two panels bend glass
Degree and the goodness of fit are higher, and because the structure of aluminum porous oxide film is limited, in the case where being bent, its dimming effect and saturating
Light consistency can be affected, it is ensured that dimming effect is accomplished by the special preparation aluminum porous oxidation corresponding with glass curvature
Film, thus will further improve manufacture difficulty and product fraction defective.
Utility model content
The technical problems to be solved in the utility model is:A kind of low to glass substrate surface flatness requirement being combined is provided
Heat-insulated dimming glass, for substituting existing automobile smart glass.Further, this utility model is also provided and prepares above-mentioned compound heat-insulation
The method of dimming glass, the method step is simple, need the process node for controlling few in production process, the product yield for obtaining
It is high.
In order to solve above-mentioned technical problem, this utility model is adopted the following technical scheme that:A kind of compound heat-insulation dimming glass,
Including the first film base material, the second film substrate, the first glass substrate and the second glass substrate;
The first film base material, the second film substrate are located between the first glass substrate and the second glass substrate;
Sputter has the first transparency conducting layer on the first film base material, and sputter has second saturating on second film substrate
Bright conductive layer;
PDLC liquid crystal layers are coated on first transparency conducting layer or the second transparency conducting layer, the PDLC liquid crystal layers are in
Stick together between first transparency conducting layer and the second transparency conducting layer and with the first transparency conducting layer and the second transparency conducting layer;
The first substratum transparent, the first film base material and are coated on the first film base material or the first glass substrate
One glass substrate is fit together by the first substratum transparent, and in second film substrate or the second glass substrate second is coated
Substratum transparent, together with second film substrate and the second glass substrate are fitted by the second substratum transparent;
UV absorbent and infrared barrier are added with first substratum transparent, in second substratum transparent
It is added with infrared barrier;
After the solidification of the PDLC liquid crystal layers, the first substratum transparent and the second substratum transparent, the first film base material, second
Film substrate, the first glass substrate and the second glass substrate are binded into an entirety.
Wherein, the first film base material and the second film substrate are PET film.
Wherein, PET film light transmittance >=90%.
Preferably, first transparency conducting layer and the second transparency conducting layer are nano-silver thread layer, graphene layer, ITO layer
In composite transparent that is a kind of or being optional two kinds and above Material cladding from nano-silver thread, Graphene, ITO it is conductive
Layer.
It is also preferred that first transparency conducting layer and the second transparency conducting layer are PEDOT or PEDOT:PSS material systems
Into conductive layer.
Further, the PEDOT or PEDOT:Nano-silver thread, the conduction are mixed with conductive layer made by PSS materials
After layer solidification, the nano-silver thread and PEDOT or PEDOT:PSS forms cross-linked network.
Further, the PDLC liquid crystal layers are made using the liquid crystal coating of UV-curable, first substratum transparent and
Two substratum transparents are acrylic glue layer.
Or, the PDLC liquid crystal layers are made using heat-setting liquid crystal coating, first substratum transparent and second
Substratum transparent is silica gel or epoxy glue or polyurethane adhesive water layer.
Preferably, the gross thickness of the compound heat-insulation dimming glass is within 8mm.
As another aspect of the present utility model, the method for preparing above-mentioned compound heat-insulation dimming glass, comprise the following steps:
Sided corona treatment is made on step one, the two sides to the first film base material and the second film substrate, it is ensured that its surface reaches value
≥52;
Step 2, it is mixed with the PEDOT or PEDOT of nano-silver thread in a side surface sputter of the first film base material:PSS materials
Material, formed the first transparency conducting layer, one layer of the opposite side surface-coated of the first film base material be added with UV absorbent and
With the acrylic glue of infrared barrier, the first substratum transparent is formed;
Step 3, it is mixed with the PEDOT or PEDOT of nano-silver thread in a side surface sputter of the second film substrate:PSS materials
Material, forms the second transparency conducting layer, and in one layer of the opposite side surface-coated of the second film substrate infrared barrier is added with
Acrylic glue, forms the second substratum transparent;
Step 4 and then the liquid crystal of one layer of UV-curable is coated on the first transparency conducting layer or the second transparency conducting layer apply
Material, forms PDLC liquid crystal layers;
Step 5, complete under the conditions of vacuum defoamation the first film base material, the second film substrate, the first glass substrate and
Two glass substrates it is compound so that the first substratum transparent pastes the first glass substrate surface, and the second substratum transparent pastes the
Two glass substrate surfaces, the first transparency conducting layer and the second transparency conducting layer paste PDLC liquid crystal layers;
Step 6, PDLC liquid crystal layers, the first substratum transparent and the second substratum transparent are entered using wavelength 365nm low pressure mercury lamps
Row illumination curing, light energy is about 200mj/cm2, the compound heat-insulation dimming glass is obtained after the completion of solidification.
This utility model obtain beneficial effect be:The compound heat-insulation dimming glass collection uv blocking light that this utility model is provided
With infrared ray, the transparent power-off masking of being powered, glass explosion prevention function in one, this utility model by coating PDLC liquid crystal layers, the
One substratum transparent and the second substratum transparent are by the first film base material, the second film substrate, the first glass substrate and the second glass base
Piece binds into an entirety, and the flatness error of glass substrate can be saturating by PDLC liquid crystal layers, the first substratum transparent and second
Gelatin layer is filled up, relatively low to the flatness requirement of glass substrate.It is thin with second using the first film base material when making bend glass
The characteristic that film base material can be curved according to the shape of glass substrate, can first on the first film base material or the first glass substrate
The first substratum transparent is coated, is splashed in the another side of the first film base material again after the first film base material is fitted with the first glass substrate
The first transparency conducting layer and coating PDLC liquid crystal layers are plated, then in the second transparency conducting layer of face sputter of the second film substrate one, will
Second film substrate is combined with the first film base material(Second transparency conducting layer is attached on PDLC liquid crystal layers), then in the second thin film
The another side of base material coats the second substratum transparent, and the second glass substrate is fitted with the second film substrate through the second substratum transparent
To together(To ensure laminating effect, above-mentioned laminating process should be carried out under the conditions of vacuum defoamation), finally by PDLC liquid crystal layers
And substratum transparent solidification.Due to PDLC liquid crystal layers, the first substratum transparent and the second transparent adhesive tape in dimming glass manufacturing process
Layer is to be coated on the first film base material, the second film substrate surface(First substratum transparent and the second substratum transparent also can be coated
In the first glass substrate and the second glass substrate surface)And it is uncured, it can well fit in glass curve, finally give
The each position light transmission of dimming glass and dimming effect uniformity.View of the above, it will be seen that the compound heat-insulation light modulation glass
The production method step of glass is less, needs the process node for controlling also less in production process, and it compares existing curved surface light modulation glass
The production technology of glass is simply too much, thus can ensure that higher product yield.
Description of the drawings
Fig. 1 is the overall structure diagram of embodiment of the present utility model;
Reference is:
1 --- the first film base material 2 --- second film substrate
3 --- the first glass substrate 4 --- the second glass substrate 5 --- the first transparency conducting layers
6 --- the second transparency conducting layer 7 --- PDLC liquid crystal layers 8 --- the first substratum transparents
9 --- the second substratum transparent.
Specific embodiment
For the ease of the understanding of those skilled in the art, further is made to this utility model with reference to embodiment and accompanying drawing
Explanation, the content that embodiment is referred to is not to restriction of the present utility model.
It is emphasized that in description of the present utility model, term " first ", " second " are only used for describing purpose, and
It is not intended that indicating or implying relative importance or the implicit quantity for indicating indicated technical characteristic.In this utility model
Description in, " multiple " are meant that two or more, unless otherwise expressly limited specifically.
Additionally, " glass substrate " is referred to the hard material layer with the same translucent effect of glass, can be except glass
Other outer transparent materials, such as PC, PMMA etc..
As shown in figure 1, a kind of compound heat-insulation dimming glass, including the first film base material 1, the second film substrate 2, the first glass
The glass substrate 4 of glass substrate 3 and second;
The first film base material 1, the second film substrate 2 are located between the first glass substrate 3 and the second glass substrate 4;
Sputter has the first transparency conducting layer 5 on the first film base material 1, and sputter has second transparent to lead on the second film substrate 2
Electric layer 6;
PDLC liquid crystal layers 7 are coated on first transparency conducting layer 5 or the second transparency conducting layer 6, PDLC liquid crystal layers 7 are in first
Stick together between the transparency conducting layer 6 of transparency conducting layer 5 and second and with the first transparency conducting layer 5 and the second transparency conducting layer 6;
The first substratum transparent 8, the glass of the first film base material 1 and first are coated in the glass substrate 3 of the first film base material 1 or first
Glass substrate 3 is fit together by the first substratum transparent 8, and coating second is transparent on the second film substrate 2 or the second glass substrate 4
Glue-line 9, together with the second film substrate 2 and the second glass substrate 4 are fitted by the second substratum transparent 9;
UV absorbent and infrared barrier are added with first substratum transparent 8, are added with the second substratum transparent 9
Infrared barrier;
After PDLC liquid crystal layers 7, the first substratum transparent 8 and the second substratum transparent 9 solidify, the first film base material 1, the second thin film
Base material 2, the first glass substrate 3 and the second glass substrate 4 are binded into an entirety.
Compound heat-insulation dimming glass collection uv blocking light and infrared ray, the transparent power-off masking of energization, glass that above-described embodiment is provided
In one, the embodiment is by coating PDLC liquid crystal layers 7, the first substratum transparent 8 and the second substratum transparent 9 by for glass explosion prevention function
One film substrate 1, the second film substrate 2, the first glass substrate 3 and the second glass substrate 4 bind into an entirety, glass substrate
Flatness error can be filled up by PDLC liquid crystal layers 7, the first substratum transparent 8 and the second substratum transparent 9, it is right so as to reduce
The requirement of glass substrate flatness.
It should be noted that Fig. 1 show flat glass, when making bend glass, using the first film base material 1 and second
The characteristic that film substrate 2 can be curved according to the shape of glass substrate, can first in the glass base of the first film base material 1 or first
The first substratum transparent 8 is coated on piece 3, again in the first film base material 1 after the first film base material 1 is fitted with the first glass substrate 3
The first transparency conducting layer of another side sputter 5 and coating PDLC liquid crystal layers 7, then in the face sputter second of the second film substrate 2 one
Transparency conducting layer 6, the second film substrate 2 and the first film base material 1 are combined(Second transparency conducting layer 6 is attached to PDLC liquid crystal layers 7
On), then the another side in the second film substrate 2 coat the second substratum transparent 9, through the second substratum transparent 9 by the second glass
Together with substrate 4 is fitted to the second film substrate 2(To ensure laminating effect, above-mentioned laminating process should be in vacuum defoamation condition
Under carry out), finally PDLC liquid crystal layers 7 and substratum transparent are solidified.Due to PDLC liquid crystal layers in dimming glass manufacturing process
7th, the first substratum transparent 8 and the second substratum transparent 9 are to be coated on the first film base material 1, the surface of the second film substrate 2(First
The substratum transparent 9 of substratum transparent 8 and second can also be coated on the first glass substrate 3 and the surface of the second glass substrate 4)And it is uncured,
It can well fit in glass curve, each position light transmission of the dimming glass for finally giving and dimming effect uniformity.From
The production method step that above description can be seen that the compound heat-insulation dimming glass is less, needs what is controlled in production process
Process node is also less, and the production technology that it compares existing curved surface dimming glass is simply too much, thus can ensure that higher
Product yield.
In the above-described embodiments, it is preferred that the film substrate 2 of the first film base material 1 and second is PET film, and the PET is thin
Film light transmittance >=90%.PET film has good ageing-resistant performance, and with higher tensile strength, can protect for a long time
Hold compound heat-insulation dimming glass not stratified, be the transparency for ensureing energization vehicle rear window due to being dimmed using PDLC liquid crystal layers 7,
PET film light transmittance is unsuitable too low, and more than 90% light transmittance is preferably to select.
Wherein, the first transparency conducting layer 5 and the second transparency conducting layer 6 can be selected from nano-silver thread layer, graphene layer, ITO
One kind in layer is that optional two kinds and above Material cladding are conductive into composite transparent from nano-silver thread, Graphene, ITO
Layer.Above material is to make the more common material of nesa coating in display screen, and more typical uses for single, and in order to improve
The light transmittance and electric conductivity of ITO, it will usually mix Sn wherein, applicant Jing experiments find, in the tin indium oxide for making ITO
Middle addition nano-silver thread and Graphene can carry its light transmittance and electric conductivity to higher level, naturally it is also possible to first using oxygen
Change indium stannum and make bottom, nano-silver thread makees the composite construction on upper strata, the light transmittance of the conductive layer of this kind of structure also can reach 85% with
On, and its electric conductivity compares incorporation Sn and can also obtain more obvious raising(The conductive layer of this structure is more suitable for curved surface glass
Glass).
Additionally, in the above-described embodiments, the first transparency conducting layer 5 and the second transparency conducting layer 6 can also for PEDOT or
PEDOT:Conductive layer made by PSS materials.Certainly, it is furthermore preferred that can be with PEDOT or PEDOT:Lead made by PSS materials
Nano-silver thread is mixed with electric layer, after the conductive layer for making solidifies, nano-silver thread can be with PEDOT or PEDOT:PSS forms net
Shape cross-linked structure.PEDOT or PEDOT:PSS materials make simple conducting layer craft, easily operated control and heat resistance is higher,
And in PEDOT:Mix in PSS materials and reticulate the nano-silver thread of cross-linked structure as conductive reinforcement with it, conduction can be reduced
The sheet resistance of layer, while further improving transparency conducting layer electric conductivity in the bent state.
In the above-described embodiments, preferably, PDLC liquid crystal layers 7 are made using the liquid crystal coating of UV-curable, with this phase
Adapt to, the first substratum transparent 8 and the second substratum transparent 9 are acrylic glue layer.Thus can just pass through UV lamp by PDLC
Liquid crystal layer 7, the first substratum transparent 8 and the second substratum transparent 9 solidify together.Certainly, PDLC liquid crystal layers 7 can also using can heat
The liquid crystal coating of solidification is made, consequently, it is possible to realize PDLC liquid crystal layers 7, the first substratum transparent 8 and the second substratum transparent 9
Solidify together, the first substratum transparent 8 and the second substratum transparent 9 should select silica gel/epoxy glue/polyurethane adhesive water layer.To ensure
The versatility of above-mentioned compound heat-insulation dimming glass and existing vehicle glass, its gross thickness is preferably controlled within 8mm.
A kind of method of the compound heat-insulation dimming glass prepared in above-described embodiment is finally introduced, is comprised the following steps:
Sided corona treatment is made on step one, the two sides to the film substrate 2 of the first film base material 1 and second, it is ensured that its surface reaches sound
Value >=52;
Step 2, it is mixed with the PEDOT or PEDOT of nano-silver thread in a side surface sputter of the first film base material 1:PSS
Material, forms the first transparency conducting layer 5, and in one layer of the opposite side surface-coated of the first film base material 1 ultra-violet absorption is added with
Agent and the acrylic glue with infrared barrier, form the first substratum transparent 8;
Step 3, it is mixed with the PEDOT or PEDOT of nano-silver thread in a side surface sputter of the second film substrate 2:PSS
Material, forms the second transparency conducting layer 6, is added with infrared ray in one layer of the opposite side surface-coated of the second film substrate 2 and intercepts
The acrylic glue of agent, forms the second substratum transparent 9;
Step 4 then on the first transparency conducting layer 5 or the second transparency conducting layer 6 coat one layer of UV-curable liquid crystal
Coating, forms PDLC liquid crystal layers 7;
Step 5, complete under the conditions of vacuum defoamation the first film base material 1, the second film substrate 2, the first glass substrate 3
And second glass substrate 4 it is compound so that the first substratum transparent 8 pastes the surface of the first glass substrate 3, the second substratum transparent 9
The surface of the second glass substrate 4 is pasted, the first transparency conducting layer 5 and the second transparency conducting layer 6 paste PDLC liquid crystal layers 7;
Step 6, using wavelength 365nm low pressure mercury lamps to PDLC liquid crystal layers 7, the first substratum transparent 8 and the second substratum transparent
9 carry out illumination curing, and light energy is about 200mj/cm2, the compound heat-insulation dimming glass is obtained after the completion of solidification.
It is emphasized that the compound heat-insulation dimming glass prepared in this utility model is not limited to above method, row
The purpose for lifting above-mentioned preparation process is intended merely to help those skilled in the art to more clearly understand compound heat-insulation dimming glass
Structure, it will be appreciated by those skilled in the art that, some of said method step has no strict sequencing in fact, actual raw
Some adjustment can be made to the sequencing of some steps according to working condition during product.
Above-described embodiment is this utility model preferably implementation, and in addition, this utility model can be with other sides
Formula realizes that any obvious replacement is in protection model of the present utility model on the premise of conceiving without departing from the technical program
Within enclosing.
In order to allow those of ordinary skill in the art more easily understand this utility model relative to prior art improvement it
Place, some accompanying drawings of the present utility model and description have been simplified, and for the sake of clarity, present specification is omitted one
A little other elements, those of ordinary skill in the art should be aware that these elements for omitting also may make up in of the present utility model
Hold.
Claims (9)
1. a kind of compound heat-insulation dimming glass, including the first film base material(1), the second film substrate(2), the first glass substrate
(3)With the second glass substrate(4), it is characterised in that:
The first film base material(1), the second film substrate(2)Located at the first glass substrate(3)With the second glass substrate(4)It
Between;
The first film base material(1)Upper sputter has the first transparency conducting layer(5), second film substrate(2)Upper sputter has
Second transparency conducting layer(6);
First transparency conducting layer(5)Or second transparency conducting layer(6)Upper coating PDLC liquid crystal layers(7), the PDLC liquid crystal
Layer(7)In the first transparency conducting layer(5)With the second transparency conducting layer(6)Between and with the first transparency conducting layer(5)With second
Transparency conducting layer(6)Stick together;
The first film base material(1)Or first glass substrate(3)The first substratum transparent of upper coating(8), the first film base
Material(1)With the first glass substrate(3)By the first substratum transparent(8)Fit together, second film substrate(2)Or second
Glass substrate(4)The second substratum transparent of upper coating(9), second film substrate(2)With the second glass substrate(4)By second
Substratum transparent(9)Laminating is together;
First substratum transparent(8)In be added with UV absorbent and infrared barrier, second substratum transparent(9)
In be added with infrared barrier;
The PDLC liquid crystal layers(7), the first substratum transparent(8)And second substratum transparent(9)After solidification, the first film base material
(1), the second film substrate(2), the first glass substrate(3)And second glass substrate(4)Binded into an entirety.
2. compound heat-insulation dimming glass according to claim 1, it is characterised in that:The first film base material(1)With
Two film substrates(2)It is PET film.
3. compound heat-insulation dimming glass according to claim 2, it is characterised in that:PET film light transmittance >=90%.
4. the compound heat-insulation dimming glass according to any one in claim 1-3, it is characterised in that:Described first is transparent
Conductive layer(5)And second transparency conducting layer(6)For the one kind in nano-silver thread layer, graphene layer, ITO layer or be from nanometer silver
The composite transparent conductive layer of optional two kinds and above Material cladding in line, Graphene, ITO.
5. the compound heat-insulation dimming glass according to any one in claim 1-3, it is characterised in that:Described first is transparent
Conductive layer(5)With the second transparency conducting layer(6)For PEDOT or PEDOT:Conductive layer made by PSS materials.
6. compound heat-insulation dimming glass according to claim 5, it is characterised in that:The PEDOT or PEDOT:PSS materials
Made by nano-silver thread is mixed with conductive layer, after the conductive layer solidification, the nano-silver thread and PEDOT or PEDOT:PSS
Form cross-linked network.
7. compound heat-insulation dimming glass according to claim 6, it is characterised in that:The PDLC liquid crystal layers(7)Using can
The liquid crystal coating of UV solidifications is made, first substratum transparent(8)With the second substratum transparent(9)For acrylic glue layer.
8. compound heat-insulation dimming glass according to claim 6, it is characterised in that:The PDLC liquid crystal layers(7)Using can
The liquid crystal coating of heat cure is made, first substratum transparent(8)With the second substratum transparent(9)For silica gel or epoxy glue or poly- ammonia
Ester gum water layer.
9. the compound heat-insulation dimming glass according to any one in claim 1-3, it is characterised in that:The compound heat-insulation
The gross thickness of dimming glass is within 8mm.
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CN201621118924.2U CN206124369U (en) | 2016-10-13 | 2016-10-13 | Compound thermal -insulated light control glass |
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CN201621118924.2U CN206124369U (en) | 2016-10-13 | 2016-10-13 | Compound thermal -insulated light control glass |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106313794A (en) * | 2016-10-13 | 2017-01-11 | 衡山县佳诚新材料有限公司 | Composite heat insulation dimming glass and preparation method thereof |
CN107892491A (en) * | 2017-09-29 | 2018-04-10 | 太仓耀华玻璃有限公司 | A kind of heat-insulated dimming laminated glass |
-
2016
- 2016-10-13 CN CN201621118924.2U patent/CN206124369U/en active Active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106313794A (en) * | 2016-10-13 | 2017-01-11 | 衡山县佳诚新材料有限公司 | Composite heat insulation dimming glass and preparation method thereof |
CN106313794B (en) * | 2016-10-13 | 2023-09-19 | 衡山县佳诚新材料有限公司 | Composite heat-insulating dimming glass and preparation method thereof |
CN107892491A (en) * | 2017-09-29 | 2018-04-10 | 太仓耀华玻璃有限公司 | A kind of heat-insulated dimming laminated glass |
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