CN206096773U - Timepiece - Google Patents
Timepiece Download PDFInfo
- Publication number
- CN206096773U CN206096773U CN201490001290.5U CN201490001290U CN206096773U CN 206096773 U CN206096773 U CN 206096773U CN 201490001290 U CN201490001290 U CN 201490001290U CN 206096773 U CN206096773 U CN 206096773U
- Authority
- CN
- China
- Prior art keywords
- clock
- watch
- component
- photoluminescent material
- embedded photoluminescent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims abstract description 65
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 230000000694 effects Effects 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 12
- 239000010980 sapphire Substances 0.000 claims description 12
- 229910052594 sapphire Inorganic materials 0.000 claims description 12
- 239000013078 crystal Substances 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 229910052771 Terbium Inorganic materials 0.000 claims description 6
- 239000002223 garnet Substances 0.000 claims description 6
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 6
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000004049 embossing Methods 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 239000010437 gem Substances 0.000 claims description 4
- 229910001751 gemstone Inorganic materials 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 230000004913 activation Effects 0.000 claims description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910000976 Electrical steel Inorganic materials 0.000 abstract 1
- 238000005424 photoluminescence Methods 0.000 abstract 1
- 239000002019 doping agent Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- -1 YLF Chemical compound 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910009372 YVO4 Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 230000005670 electromagnetic radiation Effects 0.000 description 4
- 229910052747 lanthanoid Inorganic materials 0.000 description 4
- 150000002602 lanthanoids Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000010979 ruby Substances 0.000 description 4
- 229910001750 ruby Inorganic materials 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052691 Erbium Inorganic materials 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
- 229910052769 Ytterbium Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 3
- 229910052692 Dysprosium Inorganic materials 0.000 description 2
- 229910052689 Holmium Inorganic materials 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910052775 Thulium Inorganic materials 0.000 description 2
- PXMLGXWGOVHNQX-UHFFFAOYSA-N [Y].[Eu] Chemical compound [Y].[Eu] PXMLGXWGOVHNQX-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052586 apatite Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
- 239000005383 fluoride glass Substances 0.000 description 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 2
- 239000005365 phosphate glass Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 description 2
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 239000005084 Strontium aluminate Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 230000004064 dysfunction Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- RFHAOTPXVQNOHP-UHFFFAOYSA-N fluconazole Chemical compound C1=NC=NN1CC(C=1C(=CC(F)=CC=1)F)(O)CN1C=NC=N1 RFHAOTPXVQNOHP-UHFFFAOYSA-N 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical class O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- HIQSCMNRKRMPJT-UHFFFAOYSA-J lithium;yttrium(3+);tetrafluoride Chemical compound [Li+].[F-].[F-].[F-].[F-].[Y+3] HIQSCMNRKRMPJT-UHFFFAOYSA-J 0.000 description 1
- 239000005101 luminescent paint Substances 0.000 description 1
- 229910003443 lutetium oxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- LXRWZZFNYNSWPB-UHFFFAOYSA-N potassium yttrium Chemical compound [K].[Y] LXRWZZFNYNSWPB-UHFFFAOYSA-N 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium(III) oxide Inorganic materials O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- FNWBQFMGIFLWII-UHFFFAOYSA-N strontium aluminate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Sr+2].[Sr+2] FNWBQFMGIFLWII-UHFFFAOYSA-N 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B45/00—Time pieces of which the indicating means or cases provoke special effects, e.g. aesthetic effects
- G04B45/0007—Light-, colour-, line-, or spot-effects caused by parts or pictures moved by the clockwork
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B15/00—Escapements
- G04B15/14—Component parts or constructional details, e.g. construction of the lever or the escape wheel
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/32—Component parts or constructional details, e.g. collet, stud, virole or piton
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B19/00—Indicating the time by visual means
- G04B19/30—Illumination of dials or hands
- G04B19/32—Illumination of dials or hands by luminescent substances
-
- G—PHYSICS
- G04—HOROLOGY
- G04G—ELECTRONIC TIME-PIECES
- G04G17/00—Structural details; Housings
- G04G17/08—Housings
-
- G—PHYSICS
- G04—HOROLOGY
- G04G—ELECTRONIC TIME-PIECES
- G04G9/00—Visual time or date indication means
- G04G9/0023—Visual time or date indication means by light valves in general
- G04G9/0029—Details
- G04G9/0035—Details constructional
- G04G9/0041—Illumination devices
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
Abstract
The utility model relates to a timepiece (10), this timepiece is including external component (8) of wherein arranging core (32). According to according to the automatic silicon steel sheet leveling machine of the transformer, core (32) or in external component (8) at least one include timepiece component (14, 16, 18, 20, 22, 24, 26, 28, 30, 34, 36, 38, 40, 42, 44, 46, 48, 0, 52, 54), the body of timepiece component is wholly made by the photoluminescence material, in order to allow timepiece strengthens easily nature identifyd and/or observability under no any other luminescent coating's the condition.
Description
Technical field
The utility model is related to a kind of clock and watch of the visible luminescent effect of offer mankind.
Background technology
Clock and watch such as watch is typically provided with some species of light-emitting component.For example, the pointer or embossing of clock and watch can be coated with
Phosphorescent or similar material, even if the leglibility and/or observability so as to also provide the time under dark or dim environment.
Generally, embossing and/or pointer can be coated with the luminous paint by made by strontium aluminate.
Such luminescent coating may adversely stick on specific material and/or rapidly be lost thin or scrape damage,
And/or the deposition process of this coating can not be reliably formed the predetermined pattern of tolerance adverse circumstances on complex surface.
Document DE10 2,012 004 100 discloses the fluorescence that a kind of activation is embedded in the waveguide in the pointer of conformable display
The ultraviolet source of effect.Disclosed this embodiment is very troublesome and usually needs power supply.
Utility model content
The purpose of this utility model is overcome by providing a kind of clock and watch that specific and unique luminescent properties are presented
These defects, described specific and unique luminescent properties can strengthen in the case of without any other luminescent coating and can
Energetically help the aesthetic appearance of this clock and watch.
Therefore, the utility model is related to a kind of clock and watch, and the clock and watch include wherein being disposed with the external component of movement, its feature
It is that at least one of the movement or the external component include such clock and watch component, the body of the clock and watch component
It is overall to be made up of embedded photoluminescent material, to allow the clock and watch to strengthen leglibility in the case of without any other luminescent coating
And/or observability.
Advantageously, the clock and watch component being made up of the embedded photoluminescent material not only includes in its surface luminescence generated by light
Material, and including bulk and substantial amounts of embedded photoluminescent material on three-dimensional macro.Preferably, at least one clock and watch component is by light
Electroluminescent material is constituted and therefore may include the uncoated structure of homogeneous.
In the case of the clock and watch with the overall at least one clock and watch component be made up of embedded photoluminescent material or manufactured, clock
The coating with phosphorescent material or luminescent material of the selected component of table actually becomes unnecessary.Therefore, the system of corresponding clock and watch
Making and assembling to be simplified.
Additionally, the embedded photoluminescent material for making the clock and watch component may also include outside specific and attractive
See, this can improve the overall aesthetic appearance of clock and watch.
Additionally, compared with the Conventional luminescent paint of applying to the selection area of clock and watch component, it is overall by embedded photoluminescent material system
Into clock and watch component can have higher luminescent effect.By this way, clock and watch can effectively be strengthened under dark or dim environment
Observability and leglibility.
Generally, any place that can be in clock and watch uses the luminous clock and watch component.It is alternative or replaces in clock and watch
A part for virtually any of component or the component in movement or external component.
According to further feature of the present utility model：
The material of-clock and watch the component includes crystal structure and/or glass and/or glass fibre and/or ceramics；
- material of the clock and watch component is made including at least one or combination in following material or by following material
In at least one or combination constitute：
Mix the yttrium-aluminium-garnet (YAG) of cerium and terbium；Mix europium Yttrium Orthovanadate (YVO4)；Mix the sapphire (Al of chromium, iron or titanium2O3)；
- clock and watch the component is at least partially formed watchcase, dial plate, table mirror, watch rim, button, table hat, bonnet, embossing, table
Band, motherboard, bridge clamping plate, jewel bearing, bar axle, escapement, wheel, heart axle, escapement lever, pendulum, escape wheel or hairspring；
- the clock and watch are also included for causing at least one of the luminescent effect of the clock and watch component to excite unit；
- it is described excite unit include by control unit activate ultraviolet source；
- described excite unit to be integrated in electronic core；
- it is described excite unit to be integrated in irradiation module (66), the irradiation module be individually assembled to electronic core or
Mechanical movement.
Description of the drawings
Read referring to the drawings by non-limiting way be given it is described further below when, further feature of the present utility model
Manifest with will be apparent from advantage, and wherein：
- Fig. 1 is the decomposition view according to clock and watch of the present utility model；
- Fig. 2 is the decomposition view according to watch and clock movement of the present utility model；
- Fig. 3 schematically shows the enforcement for exciting unit according to first embodiment of the present utility model；
- Fig. 4 schematically shows the enforcement for exciting unit according to second embodiment of the present utility model.
Specific embodiment
In the view of Fig. 1, it is schematically shown that multiple structures of the external component 8 of the clock and watch 10 provided in watch form
Part.External component 8 generally includes the watchcase 12 for supporting two watchbands 30.Watchcase 12 passes through bonnet 24 at the lower surface of watchcase 12
Close and closed by table mirror 16 at the upper surface of watchcase 12, so as to protect timepiece movement 32.In watchcase 12, in movement
Generally it is disposed between 32 and table mirror 16 on dial plate 14, and the dial plate 14 and there is multiple embossings 26 and pointer 28.The table mirror
16 can be kept by watch rim 18.
External component 8 may also include one or more buttons 20 for for example extending from the intermediate member of watchcase 12 and/or
Table hat 22, with setting time and/or enables the various different function of clock and watch 10.
Little but typical component of mechanical movement 32 is only shown in fig. 2.Certainly, as being explained below, also may be used
Using other types of movement such as electronic core or mixed type electro-mechanical movement.Movement 32 generally includes motherboard 34, various
Other components such as bridge clamping plate 36 and component such as jewel bearing 38, bar axle various movable and/or be bonded with each other
40th, escapement 42, various wheels 44, heart axle 46, escapement lever 48, pendulum 50, escape wheel 52 and hairspring 54 can cloth in a well defined manner
Put on the motherboard.
According to the utility model, at least one of above-mentioned component or a part are illustrated in fig 1 and 2, but clock and watch 10
Any other feature and/or with aesthetic beauty but the component that is not specifically shown also can be made up of luminescent material.Especially
It is that the clock and watch component can be the functional component of clock and watch, the functional component provides specific and clear and definite in this clock and watch
Mechanically or electrically airway dysfunction.
According to the utility model, it is preferable that the luminescent material can be natural in such as ultraviolet spectral range
Or non-natural electromagnetic radiation provides the luminescence response in the range of human sight when exciting.
In a preferred embodiment, the clock and watch component includes embedded photoluminescent material.Therefore, embedded photoluminescent material can be wrapped
Include phosphor material and fluorescent material.Fluorescent material and phosphor material are suitable to absorption of electromagnetic radiation, especially in the visible model of the mankind
Enclose or ultraviolet spectral range in electromagnetic radiation.Electron excitation is typically resulted in after photonic absorption to higher energy state.With phase
Launch again --- launching again for the photon causes visible luminescent effect --- of the photon of same or relatively low photon frequency is electronics
Return to the result of its ground state.Especially for phosphorescent glow, excited electron must not be without undergoing vibration relaxation and intersystem crossing
(intersystem crossing) is to different spin states.Such relaxation phenomenon is along with wavelength compared to exciting radiation
The luminosity that initial wavelength is longer therefore energy is less.
Suitable luminescent material is selected according to a part for the particular elements or the component for treating to be substituted by luminescent material.Allusion quotation
Type ground, with regard to escapement lever 48, the alternative pallet stone of luminescent material and/or escapement fork arm (anchor lever).Therefore, one
In individual specific embodiment, the clock and watch component includes mono-crystalline structures and polycrystalline structure.Luminous clock and watch component includes three-dimensional structure
And as suitable for substituting existing clock and watch component or clock generally by made by metal, plastics, sapphire, ceramics or glass
The three-dimensional body of a part for table component is provided.Generally, clock and watch component also not only can replace by made by specific luminescent material
Or substitute the metal and/or plastic member of clock and watch, but also can substitute and replace existing clock and watch, including such as sapphire or
It is ruby or by made by such as sapphire or ruby other crystal and non-luminescent component.
Therefore, above-mentioned clock and watch component 14,16,18,20,22,24,26,28,30,34,36,38,40,42,44,46,48,
50th, 52, at least one of 54 or a part also can be made up of different monocrystalline but luminous material such as Yttrium Orthovanadate (YVO4).
Other suitable materials not only can be fluoride, such as YLF, BYF or KYF, and can be sesquichloride such as Sc2O3With
Lu2O3, each of which is doped with suitable dopant material.
Especially there is following benefit, the feature of the clock and watch component may be in especially in the visible spectral region of the mankind
Electromagnetic radiation stimulated emission.Such monocrystal material may can also provide specific mechanical function.Single crystal luminescent material
Mechanical hardness may with sapphire or ruby quite and therefore alternative such as clock and watch mechanical movement corresponding indigo plant
Jewel-part or ruby-part.In a preferred embodiment, making the material of at least one clock and watch component includes
At least one in below：Oxide, vanadate, tungstates, borate, apatite, garnet, sapphire, aluminate, sesquialter
Oxide, silicate, chalkogenide, fluoride.
For example, the original sapphire component of clock and watch 10 can be mixed by doped sapphire, by doped ruby, by Jing
Miscellaneous quartz, substitute and replace by doped diamond or by doped yag crystal.Especially, neodymium-doped, erbium or
The yag crystal of ytterbium provides big rigidity and the at a fairly low absorption in visible range.
In another preferred embodiment, the luminous clock and watch component of the clock and watch is mixed with the master for being embedded in corresponding clock and watch component
Internal at least one dopant.By properly selecting specific dopant, the spectrum model of light sent from clock and watch component is treated
Enclosing can be precisely determined and select with color.Here, the not only dopant in the selection of specific dopant but also luminescent material
Concentration all can arbitrarily be changed, to provide desired luminescent effect as clock and watch.
In another preferred embodiment, dopant includes at least one or its combination in following material：Neodymium (Nd), ytterbium
(Yb), erbium (Er), cerium (Ce), Nd:Ce, thulium (Tm), holmium (Ho), dysprosium (Dy), samarium (Sm), terbium (Tb), europium (Eu), chromium (Cr), iron
(Fe), titanium (Ti).Generally, monocrystalline oxide luminescent material such as yttrium-aluminium-garnet (YAG) or Yttrium Orthovanadate (YVO4) can adulterate almost
Any lanthanide series or rare earth material are providing the transmitting in limit of visible spectrum.
In another preferred aspect, making the material of at least one clock and watch component includes appointing in following material
A kind of or its combination is made up of any one in following material or its combination：
- mix the yttrium-aluminium-garnet (YAG) of cerium and terbium；
- mix europium Yttrium Orthovanadate (YVO4)；
- mix the sapphire (Al of chromium, iron or titanium2O3)。
Especially when to mix chrome blue jewel, Cr3+Ion generally substitutes the aluminium in sapphire structures.
For example, Ce (III):YAG crystal provides the yellow emission generally between 530 nanometers and 550 nanometers.Additionally, yellow
Green emission spectrum also can use mixes the acquisition of terbium yag crystal.
Process for sapphire-based monocrystalline clock and watch component can be presented in 600 nanometers of range above, for example even in 700 rans or
The emission spectrum of 800 rans.
In above-mentioned tungstates, material such as Gadolinium Tungstate potassium (KGW), Potassium Yttrium Tungstate (KYW) can be used as the material of clock and watch component
Material.Additionally, fluoride such as lithium yttrium fluoride (YLF) or calcirm-fluoride (CAF) and borate salts such as Yb3+Sr3Y (BO3) 3 (Yb:
) or apatite such as S-FAP or SYS can also provide the overall structure (bulk structure, bulk structure) of monocrystalline to carry BOYS
For and/or replace clock and watch component.
Additionally, above-mentioned clock and watch component 14,16,18,20,22,24,26,28,30,34,36,38,40,42,44,46,48,
50th, 52, at least one of 54 or a part can by luminescent ceramic materials for example based on yttrium-aluminium-garnet (YAG) ceramics system
Into.Such ceramic material can also adulterate suitable lanthanide series or rare earth material such as cerium or terbium.
Alternatively or additionally, described at least one luminous clock and watch component may include glass material, such as glassy silicate
Glass, phosphate glass, fluoride glass, germanate glass or fluozirconate, its can suitably adulterate lanthanide series or rare earth ion.
Compared with mono-crystalline structures, the material of this clock and watch component can be unbodied.Glass or glass fibre component can be with a fairly low
Cost and with sizable three-dimensional structure acquisition.In a preferred embodiment, wherein, the material of clock and watch component includes various glass
The glass of type is made up of the glass of various type of glass, such as silicate glass, phosphate glass, fluoride glass, germanic acid
Salt glass and/or fluozirconate.
Glass base clock and watch component can with flat board (slab) form provide or with similar to it is with rare earth doped element, be based on
The form of the optical fiber laser component of the active gain medium of optical fiber is provided, the rare earth element such as lanthanide series (La-
Lu), erbium (Er), ytterbium (Yb), neodymium (Nd), dysprosium (Dy), praseodymium (Pr), holmium (Ho) and/or thulium (Tm).Substantially the clock and watch component is made
Described doped active gain medium can be surrounded by least one of which covering at least in part.By this way, or even can lead to
Cross clock and watch component itself reinforcing luminescent effect.
In another embodiment, the clock and watch also excite unit 60 including at least one, to cause luminous clock and watch structure
The one of part 14,16,18,20,22,24,26,28,30,34,36,38,40,42,44,46,48,50,52,54 or the clock and watch component
Partial luminescent effect.For example, clock and watch 10 may include light source, and the light source is suitable to the electricity outside the visible spectral region of the mankind
The magnetic radiation irradiation at least one luminous clock and watch component 14,16,18,20,22,24,26,28,30,34,36,38,40,
42、44、46、48、50、52、54.Excite in response to ultraviolet, the luminous clock and watch component 14,16,18,20,22,24,26,
28th, 30,34,36,38,40,42,44,46,48,50,52,54 can be by the electromagnetism spoke that is transmitted in the range of human visible light spectrum
Penetrate and fluorescence or phosphorescence response is presented.
In the system block diagram of Fig. 3, watchcase 12 and movement 32 are included by made by luminescent material or comprising such
The clock and watch component 14,34 of material.The sketch of Fig. 3 is related to electronic watch 10, wherein, movement 32 includes energy source 64 and control unit
62.Additionally, movement 32 includes exciting unit 60, this excites unit for example in ultraviolet source form, excites the unit can by this
Cause the luminescent effect of the clock and watch component 14,34 of watchcase 12 and/or movement 32.
For the clock and watch component 14 as shown in fig 1 and 2,16,18,20,22,24,26,28,30,34,36,38,40,
42nd, in 44,46,48,50,52,54 for any one or a part, clock and watch component as shown in Figure 3 14,34 is only to show
Example property.Therefore, the pendulum 50 of movement 32 or above-mentioned any other component rather than motherboard 34 can be embodied as comprising luminescent material
Or by made by luminescent material clock and watch component.
By exciting unit 60, clock and watch component 14,34 and therefore the luminescent effect of whole clock and watch 10 can be according to instruction especially
There is provided under dark or dim environment.Unit 60 is excited to may include the ultraviolet source activated by control unit 62.Generally, it is described
Control unit can be user-operably with the help of such as button 20 or table hat 22, and the control unit may also include electricity
The energy 64 couples with electric energy 64.
By using ultraviolet source as unit is excited, luminous exciting for clock and watch component can substantially in the visible model of the mankind
Occur outside enclosing.Additionally, can also implement dynamic cumulative or diminuendo effect based on the time constant of the luminescent effect of clock and watch component
Really.
In the particular embodiment shown in figure 3, unit 60 is excited to be integrated in the electronic core 32 of clock and watch 10.In the present embodiment
In, clock and watch 10 are preferably designed and are embodied as electronic watch 10.Here, excite unit 60 can as electronic core 32 in it is additional
Part is provided.The enforcement for exciting unit 60 is not relied on, each luminous clock and watch component 14,34 can excite unit 60 by single simultaneously
Excite.Accordingly, it is possible to belong to the external component 8 of clock and watch 10 luminous clock and watch component can with the clock being integrated in electronic core
The similar mode of the situation of table component is by exciting unit 60 to irradiate or excite.
On the other hand, it is described to excite unit can be incorporated in individually to be assembled to electronics or machinery clock and watch 10
Irradiation module 66 in.
Particularly with mechanical clock, unit 60, control unit 62 and energy source 64 is excited to be integrated into single module
In or can be prepackage accessory, the prepackage accessory can be assembled in mechanical clock 10 or be assembled to mechanical clock as overall
10.And here, excite unit 60 to be used not only for the component of optically exciting irradiation module, and can also generally provide and appoint
What the irradiation of luminous clock and watch component and excite.
Therefore, as in the diagram schematically, compared with the configuration of Fig. 3, movement 32 is simultaneously not provided with electric energy 64.
According in the configuration of Fig. 4, be provided with irradiation module 66, it include energy source 64, control unit 62 and be respectively used to excite and/or
The luminous clock and watch component 34,14 of irradiation movement 32 and/or external component 8 excites such as ultraviolet source of unit 60.
As in the diagram, in addition illustratively, irradiation module 66 may also include user interface 68, can basis by the user interface
Need to cause exciting for luminous clock and watch component 14,34.User interface 68 may include that allowing user to enable excites unit 60 for example
Button 20, the table hat 22 or the like of one predetermined amount of time.
Irradiation module 66 as shown in FIG. 4 can be preassembled and can be arranged in the watchcase 12 of clock and watch 10 or table
At shell 12.Here, being commonly considered, existing watchcase 12 and/or mechanical movement 32 also can be retrofitted to such photograph
Penetrate module 66.
Certainly, the utility model is not limited to shown example, but there may be for those skilled in the art will show
The a variety of variations and modifications being clear to.Particularly, the utility model can be applicable to relative in the remote field of horology.
For example, it can be applicable in automobile, aviation and/or jewelry art.
Additionally, according to selected luminescent material, manufacture method can be different.Therefore, for hard material such as monocrystalline or many
Brilliant material, can be ground and/or drill and/or polish and/or etch (wet or dry) process.Under the particular case of ceramics,
Can be molded and sinter.
Laser and/or plasma process can be also carried out finally, for most above-mentioned material.
Claims (13)
1. clock and watch (10), the clock and watch include wherein being disposed with the external component (8) of movement (32), it is characterised in that the outside
At least one of part (8) includes clock and watch component (34,36,38,40,42,44,46,48,50,52,54), the clock and watch structure
The body of part is integrally made up of embedded photoluminescent material, to allow the clock and watch to strengthen in the case of without any other luminescent coating
Leglibility and/or observability, the clock and watch also include for cause the clock and watch component (14,16,18,20,22,24,26,28,
30th, 34,36,38,40,42,44,46,48,50,52, at least one of luminescent effect 54) excites unit (60).
2. clock and watch (10) according to claim 1, it is characterised in that the clock and watch component is at least partially formed watchcase
(12), dial plate (14), table mirror (16), watch rim (18), button (20), table hat (22), bonnet (24), embossing (26) or watchband
(30)。
3. clock and watch (10), the clock and watch include wherein being disposed with the external component (8) of movement (32), it is characterised in that the movement
(32) at least a portion includes clock and watch component (14,16,18,20,22,24,26,28,30), and the body of the clock and watch component is whole
Body is made up of embedded photoluminescent material, to allow the clock and watch to strengthen leglibility in the case of without any other luminescent coating
And/or observability, the clock and watch also include for cause the clock and watch component (14,16,18,20,22,24,26,28,30,34,
36th, 38,40,42,44,46,48,50,52, at least one of luminescent effect 54) excites unit (60).
4. clock and watch (10) according to claim 3, it is characterised in that the clock and watch component is at least partially formed motherboard
(34), bridge clamping plate (36), jewel bearing (38), bar axle (40), escapement (42), wheel (44), heart axle (46), escapement lever (48), pendulum
Hammer (50), escape wheel (52) or hairspring (54).
5. clock and watch according to any one of claim 1 to 4, it is characterised in that the clock and watch component (14,16,18,20,
22nd, 24,26,28,30,34,36,38,40,42,44,46,48,50,52, the embedded photoluminescent material 54) is tied including crystal
Structure.
6. clock and watch (10) according to claim 5, it is characterised in that the embedded photoluminescent material include chromium-doped, iron or
The sapphire host of titanium atom.
7. clock and watch (10) according to claim 5, it is characterised in that the embedded photoluminescent material includes that doping cerium or terbium are former
The yttrium-aluminium-garnet main body of son.
8. clock and watch (10) according to claim 5, it is characterised in that the embedded photoluminescent material includes europium doped atom
Yttrium Orthovanadate main body.
9. clock and watch according to any one of claim 1 to 4, it is characterised in that the clock and watch component (14,16,18,20,
22nd, 24,26,28,30,34,36,38,40,42,44,46,48,50,52, embedded photoluminescent material 54) includes glass and/or glass
Glass fiber.
10. clock and watch according to any one of claim 1 to 4, it is characterised in that the clock and watch component (14,16,18,
20th, 22,24,26,28,30,34,36,38,40,42,44,46,48,50,52, embedded photoluminescent material 54) includes ceramics.
11. clock and watch (10) according to claim 1 or 3, it is characterised in that described to excite unit (60) to include by control
The ultraviolet source of unit (62) activation.
12. clock and watch (10) according to claim 11, it is characterised in that described to excite unit (60) to be integrated in electronic machine
In core (32).
13. clock and watch (10) according to claim 12, wherein, it is described to excite unit (60) to be integrated in irradiation module (66)
In, the irradiation module is used to be individually assembled in electronic core or mechanical movement.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2014/050989 WO2015106828A1 (en) | 2014-01-20 | 2014-01-20 | Timepiece with at least one photoluminescent component |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206096773U true CN206096773U (en) | 2017-04-12 |
Family
ID=50002706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201490001290.5U Expired - Lifetime CN206096773U (en) | 2014-01-20 | 2014-01-20 | Timepiece |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP3208267U (en) |
| CN (1) | CN206096773U (en) |
| CH (1) | CH710869B1 (en) |
| DE (1) | DE212014000245U1 (en) |
| WO (1) | WO2015106828A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110632839A (en) * | 2018-06-25 | 2019-12-31 | 劳力士有限公司 | Variable timepiece component |
| CN111221237A (en) * | 2017-05-29 | 2020-06-02 | 斯沃奇集团研究及开发有限公司 | Universal watch winding and time setting device |
| US11650546B2 (en) | 2018-05-21 | 2023-05-16 | The Swatch Group Research And Develonment Ltd | Universal watch winding and time-setting device |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102014007331A1 (en) * | 2014-05-17 | 2015-11-19 | Volker Schell | Optically active dials for wristwatches |
| FR3039292B1 (en) * | 2015-07-24 | 2019-05-31 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | SPIRAL SPRING AND METHOD OF MAKING THE SPIRAL SPRING |
| DE102017201676B4 (en) | 2017-02-02 | 2019-08-14 | Realization Desal Ag | Watch glass with luminescent element |
| EP3879354A1 (en) * | 2020-03-09 | 2021-09-15 | The Swatch Group Research and Development Ltd | Oscillating winding mass provided with a decorative element for automatic movement of a timepiece |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH319646A (en) * | 1955-02-22 | 1957-02-28 | Ed Kummer S A Fabrique D Horlo | Automatic wristwatch |
| DE69434300T2 (en) * | 1993-12-14 | 2005-12-29 | Citizen Watch Co., Ltd., Nishitokyo | SOLAR CELL |
| CH693307A5 (en) * | 1999-11-26 | 2003-05-30 | Swatch Ag | Transparent cover e.g. for clock has design with variable density phosphorescent pigment giving different decorative effects by day and night |
| EP3719586B1 (en) * | 2009-06-18 | 2023-03-01 | ETA SA Manufacture Horlogère Suisse | Timepiece with special aesthetic effects |
| CH704601B1 (en) | 2011-03-12 | 2017-09-29 | Daniel Rytz Dr | Pointer for measuring instruments, in particular watches, with optically excited waveguide. |
| CH707060B1 (en) * | 2012-10-04 | 2017-05-31 | Swatch Group Res & Dev Ltd | Luminous watch display. |
-
2014
- 2014-01-20 DE DE212014000245.1U patent/DE212014000245U1/en not_active Expired - Lifetime
- 2014-01-20 CN CN201490001290.5U patent/CN206096773U/en not_active Expired - Lifetime
- 2014-01-20 JP JP2016600089U patent/JP3208267U/en not_active Expired - Lifetime
- 2014-01-20 WO PCT/EP2014/050989 patent/WO2015106828A1/en active Application Filing
- 2014-01-20 CH CH00921/16A patent/CH710869B1/en unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111221237A (en) * | 2017-05-29 | 2020-06-02 | 斯沃奇集团研究及开发有限公司 | Universal watch winding and time setting device |
| CN111221237B (en) * | 2017-05-29 | 2021-08-24 | 斯沃奇集团研究及开发有限公司 | Universal watch winding and time setting device |
| US11650546B2 (en) | 2018-05-21 | 2023-05-16 | The Swatch Group Research And Develonment Ltd | Universal watch winding and time-setting device |
| CN110632839A (en) * | 2018-06-25 | 2019-12-31 | 劳力士有限公司 | Variable timepiece component |
| CN110632839B (en) * | 2018-06-25 | 2023-09-26 | 劳力士有限公司 | Variable timepiece component |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3208267U (en) | 2017-01-05 |
| CH710869B1 (en) | 2017-11-15 |
| DE212014000245U1 (en) | 2016-08-24 |
| WO2015106828A1 (en) | 2015-07-23 |
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