CN206089535U - Golden pigment of mica titanium with blue effect - Google Patents
Golden pigment of mica titanium with blue effect Download PDFInfo
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- CN206089535U CN206089535U CN201621032719.4U CN201621032719U CN206089535U CN 206089535 U CN206089535 U CN 206089535U CN 201621032719 U CN201621032719 U CN 201621032719U CN 206089535 U CN206089535 U CN 206089535U
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Abstract
The utility model relates to a pearl pigment field discloses a golden pigment of mica titanium with blue effect, and comprises a base material, at least two -layer cationic layer and at least two -layer pigment negative ion layer, the substrate is nexine, substrate surface cladding first layer cationic layer, first layer cationic layer surface cladding first layer pigment negative ion layer, then cationic layer and pigment negative ion layer cladding in turn, the outermost one deck is pigment negative ion layer, cationic layer's thickness is 5~45nm, pigment negative ion layer's thickness is 5~40nm, titanate coupling agent coupling cationic layer for the substrate surface, carry out the transition with the blue or green anion of phthalein through molecular self -assembly again, build multi -storied orderly self -assembly structure. The utility model discloses can be at the controllable blue or green pigment of phthalein of building the different numbers of piles of nano -scale in mica titanium -pearlescent pigment surface to improve the blue effect and the visual effect on pearl pigment surface.
Description
Technical field
This utility model is related to pearlescent pigment field, more particularly to a kind of gold of the mica titanium with blue effect face
Material.
Background technology
Pearlescent pigment refers to that it is with Muscovitum, tabular quartz, tabular alumina or piece with nacreous ornamental pigment
Shape glass powder is base material, then the metal oxide transparent Film laminated of its floor height refractive index of Surface coating one forms, and works as illumination
When being mapped to the smooth interface of Opacifying pigment, reflected light and refraction-reflected light can be produced, generation be interfered between them a kind of three-dimensional
The strong pearly-lustre color of sense.It is excellent that pearlescent pigment is because its gloss is strong, good decorating effect, nontoxic, fast light, heat-resisting, chemical stability are good etc.
Good characteristic, is widely used in fields such as auto industry, plastic, printer's ink, decorative paint, artwork Ornaments.Current full generation
The total output of boundary's mica titanium nacreous material has crossed ten thousand tons, big 22～55 dollars/Kg of price of international market.Current nacreous mica face
The preparation method of material mainly makes the metal salt solution of solubility using wet chemistry method, and by changing its pH value the hydrogen of indissoluble is become
Oxide fine particle is simultaneously covered in the surface of sheet mica, and drying, roasting process obtain pearlescent pigment product.
One kind of Application No. 201420559497.6 is super to dodge silver-coloured lustre pigment, is with synthetic mica or glass flake
Base material, has one layer of silverskin in the Surface coating of base material, with dynamic mica surface it is silver-plated replace traditional argentum powder silver plating process so as to
A kind of super sudden strain of a muscle silver-coloured lustre pigment of plating silverskin is generated, with advantage with low cost.Application No. 201410052600.21.
A kind of metallic cover pearlescent pigment, the pearlescent pigment include flat substrates, be formed with its flat substrates surface multiple
Spaced titanium dioxide nano-rod, described flat substrates have full roughness Rz DIN between 5-500, wherein described every
Multiple metallics are all deposited on one titanium dioxide nano-rod and the flat substrates, the metallic is silver.Current pearl
Delustering pigment production cladding is mainly adopted this method, and obtains surface layer structure thickness than larger and controllability not enough, surface lamella
The uneven of coating causes refraction-reflected light out photochromic very miscellaneous.
With pearlescent pigment from coloring sexual function gradually to antifalsification function development, it is desirable to the color and luster degree of purity of pearlescent pigment
It is especially high, the characteristics of both possess pearlescent pigment, the function of character recognition can be improved again.And surface coated nanometer grade thickness control
System is that current method is difficult to.
Utility model content
This utility model is directed to prior art media layer damage, thickness degree and the uncontrollable shortcoming of layer number, there is provided a kind of
A kind of gold of the mica titanium with blue effect pigment that Rotating fields are controllable, thickness degree is controllable and layer number is controllable.
In order to solve above-mentioned technical problem, this utility model is addressed by following technical proposals：
A kind of gold of the mica titanium with blue effect pigment, including base material, at least two-layer cationic layer and at least two-layer
Pigment anion layer, base material is innermost layer, substrate surface cladding ground floor cationic layer, ground floor cationic layer Surface coating the
One layer pigment anion layer, then cationic layer replace cladding with pigment anion layer, one layer of outermost is pigment anion layer,
Base material is that cat gold is titanium nacreous, and the thickness of cationic layer is 5～45nm, and the thickness of pigment anion layer is 5～40nm.
Preferably, cationic layer is PAH (PAH) layer, PDDA
(PDDA) one or two combinations in layer.
Preferably, pigment anion layer is the one kind or two in copper phthalein green grass or young crops disulfonic acid salt deposit, copper phthalein green grass or young crops polysulfonate layer
The combination planted.Copper phthalein green grass or young crops disulfonate, copper phthalein green grass or young crops polysulfonate are thick phthalocyanine blue oleum sulfonation gained.
This utility model as a result of above technical scheme, with significant technique effect：This utility model is by dividing
Mica titanium with blue effect gold pigment prepared by sub- self-assembling method is by control PAH, PDDA and copper phthalein green grass or young crops sulfonate
Concentration key-course thickness, such that it is able to produce the pearl effect of the blue effect of different depth.It is of the present utility model with indigo plant
The preparation method of the mica titanium gold pigment of chromatic effect, can overcome the Rotating fields of metal-oxide deposition process in prior art
Uncontrollable, thickness degree is uncontrollable and the uncontrollable difficult problem of layer number, can be designed system according to the special demands of different purposes
The pearlescent pigment of standby different-thickness, the different numbers of plies, can effectively strengthen the visual effect of product, make that decorative parts are concavo-convex to have levels,
More third dimension with can identification, and the environmental friendly simple, production economy of this method is profitable.It is of the present utility model with indigo plant
The mica titanium gold pigment of chromatic effect can apply to the effect of auto industry, anti-counterfeit paint, ornament, printer's ink etc. and build,
With wide variety of prospect.
Description of the drawings
Fig. 1 is the structural representation of this utility model embodiment 1；
The toponym that each number designation is referred in accompanying drawing is as follows：1-base material, 2-ground floor cationic layer, 3-the
One layer pigment anion layer, 4-second layer cationic layer, the 5-the second layer pigment anion layer.
Specific embodiment
Below in conjunction with the accompanying drawings this utility model is described in further detail with embodiment.
Embodiment 1
A kind of gold of the mica titanium with blue effect pigment, as shown in figure 1, including base material 1, two-layer cationic layer and two
Layer pigment anion layer, base material 1 be innermost layer, the Surface coating ground floor cationic layer 2 of base material 1, the surface of ground floor cationic layer 2
Coat the first layer pigment anion layer 3, the cladding second layer of the first layer pigment anion layer 3 cationic layer 4, second layer cationic layer
4 the second layer pigment of Surface coating anion layers 5；Base material is that cat gold is titanium nacreous, and the thickness of cationic layer is 45nm, face
The thickness of material anion layer is 40nm, and cationic layer is PAH layers, and pigment cationic layer is copper phthalein green grass or young crops disulfonic acid salt deposit.
Embodiment 2
A kind of gold of the mica titanium with blue effect pigment, including base material, three layers of cationic layer and three layer pigments it is cloudy from
Sublayer, base material is innermost layer, and substrate surface coats ground floor cationic layer, ground floor cationic layer the first layer pigment of Surface coating
Anion layer, then cationic layer replace cladding with pigment anion layer, one layer of outermost is pigment anion layer, and base material is gold
Color mica titanium nacreous material, the thickness of cationic layer is 14nm, and the thickness of pigment anion layer is 28nm, and cationic layer is PAH
The combination of layer and PDDA layers, pigment cationic layer is copper phthalein green grass or young crops disulfonic acid salt deposit.
Embodiment 3
A kind of gold of the mica titanium with blue effect pigment, including base material, four layers of cationic layer and four layer pigments it is cloudy from
Sublayer, base material is innermost layer, and substrate surface coats ground floor cationic layer, the sub- layer pigment of Surface coating first of ground floor sun absciss layer
Anion layer, then cationic layer replace cladding with pigment anion layer, one layer of outermost is pigment anion layer, and base material is gold
Color mica titanium nacreous material, the thickness of cationic layer is 5nm, and the thickness of pigment anion layer is 20nm, and cationic layer is PDDA
Layer, pigment cationic layer is copper phthalein green grass or young crops polysulfonate layer.
Embodiment 4
A kind of gold of the mica titanium with blue effect pigment, including base material, five layers of cationic layer and five-layer pigment it is cloudy from
Sublayer, base material is innermost layer, and substrate surface coats ground floor cationic layer, ground floor cationic layer the first layer pigment of Surface coating
Anion layer, then cationic layer replace cladding with pigment anion layer, one layer of outermost is pigment anion layer, and base material is gold
Color mica titanium nacreous material, the thickness of cationic layer is 32nm, and the thickness of pigment anion layer is 5nm, and cationic layer is PDDA
Layer, pigment cationic layer is copper phthalein green grass or young crops polysulfonate layer.
A kind of method of the mica titanium gold pigment prepared with blue effect, comprises the following steps：
Step one, is 1 by volume ratio:The sulphuric acid that 4 mass fraction is 30% hydrogen peroxide and mass fraction is 98% is mixed
Close, obtain mixed solution；By base material immerse mixed solution in, embathe at 80 DEG C 30 minutes, solid is obtained after filtration, spend from
The post-drying of sub- water flushing；
Step 2, the base material immersion titanate coupling agent that Jing steps one were processed and the PAH that mass fraction is 2.5%,
The consumption of titanate coupling agent is the 19% of substrate mass fraction for the consumption of 0.01%, PAH of substrate mass fraction, at 24 DEG C
Under embathe 32 minutes, after filtration wash, make substrate surface coat monolayer cationic layer；
Step 3, in immersing the copper phthalein green grass or young crops disulfonate solution that mass fraction is 8.0%, the consumption of copper phthalein green grass or young crops disulfonate
For the 15% of substrate mass fraction, embathe at 30 DEG C 47 minutes and filter afterwards, wash, drying up, make cationic layer Surface coating
Monolayer pigment anion layer；
Step 4, immersion mass fraction is that in 2.5% solution of PAH, the consumption of PAH is substrate mass fraction
19%, embathe at 24 DEG C and washed after filtering within 32 minutes, make pigment anion layer Surface coating monolayer cationic layer；
Step 5, in immersing the copper phthalein green grass or young crops disulfonate solution that mass fraction is 8.0%, the consumption of copper phthalein green grass or young crops disulfonate
For the 10% of substrate mass fraction, embathe at 30 DEG C 47 minutes and filter afterwards, wash, drying up, make cationic layer Surface coating
Monolayer pigment anion layer；
Step 6, repeat step three, step 4 obtains the cationic layer and pigment anion layer of five layers of cladding nano thickness.
In a word, preferred embodiment of the present utility model is the foregoing is only, it is all according to this utility model claim institute
The impartial change of work and modification, should all belong to the covering scope of this utility model patent.
Claims (3)
1. it is a kind of with blue effect mica titanium gold pigment, it is characterised in that：Including base material, at least two-layer cationic layer and
At least two layer pigment anion layers, base material is innermost layer, and substrate surface coats ground floor cationic layer, ground floor cationic layer table
Bread covers the first layer pigment anion layer, and then cationic layer replaces cladding with pigment anion layer, and one layer of outermost is pigment
Anion layer, base material is that cat gold is titanium nacreous, and the thickness of cationic layer is 5～45nm, the thickness of pigment anion layer
For 5～40nm.
2. it is according to claim 1 it is a kind of with blue effect mica titanium gold pigment, it is characterised in that：Cationic layer
For PAH layer or PDDA layer.
3. it is according to claim 1 it is a kind of with blue effect mica titanium gold pigment, it is characterised in that：Pigment it is cloudy from
Sublayer is copper phthalein green grass or young crops disulfonic acid salt deposit or copper phthalein green grass or young crops polysulfonate layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621032719.4U CN206089535U (en) | 2016-08-31 | 2016-08-31 | Golden pigment of mica titanium with blue effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621032719.4U CN206089535U (en) | 2016-08-31 | 2016-08-31 | Golden pigment of mica titanium with blue effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206089535U true CN206089535U (en) | 2017-04-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621032719.4U Active CN206089535U (en) | 2016-08-31 | 2016-08-31 | Golden pigment of mica titanium with blue effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206089535U (en) |
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2016
- 2016-08-31 CN CN201621032719.4U patent/CN206089535U/en active Active
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Address after: 311501 No. 599, Baiyun East Road, Tonglu Economic Development Zone, Hangzhou, Zhejiang Patentee after: Hangzhou Huada Haitian Technology Co.,Ltd. Address before: 311501 No. 599, Baiyun East Road, Tonglu Economic Development Zone, Hangzhou, Zhejiang Patentee before: HANGZHOU HYDROTECH Co.,Ltd. |
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