CN206069583U - A kind of processing meanss of antimony and association slag landfill percolate - Google Patents

A kind of processing meanss of antimony and association slag landfill percolate Download PDF

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CN206069583U
CN206069583U CN201620974757.5U CN201620974757U CN206069583U CN 206069583 U CN206069583 U CN 206069583U CN 201620974757 U CN201620974757 U CN 201620974757U CN 206069583 U CN206069583 U CN 206069583U
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filter
pipe
high rate
kdf
adsorption column
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游建军
钟儒波
胡志鑫
唐传祥
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Hunan Aibulu environmental Polytron Technologies Inc
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HUNAN AIRBLUER ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Abstract

The utility model discloses the processing meanss of a kind of antimony and association slag landfill percolate, the processing meanss include the regulating reservoir (1) for being sequentially connected connection, flocculation tank (2), primary sedimentation basin (3), secondary flocculation tank (4), secondary sedimentation tank (5), elevator pump (6), circular regeneration high rate filter (7), reinforcing adsorption column (8), regenerated liquid make-up tank (9), waste liquid tank (10), KDF cartridge filters (11), bed mud heavy metal accumulation pond (12), sterilization pool (13), reuse pool (14), air header (15).Antimony and association slag landfill percolate are processed using this utility model device, the percolate high treating effect containing heavy metal is made, controllability is strong, stable, percolate Jing after processing can be back in landfill yard flushes the toilet, clears away, afforesting, carwash, pouring and spill road, has saved the energy.

Description

A kind of processing meanss of antimony and association slag landfill percolate
Technical field
This utility model is related to heavy metal waste slag Treatment process field, and in particular to a kind of antimony and association slag landfill yard ooze The processing meanss of filtrate.
Background technology
Antimony belongs to chalophile element, but also has certain oxytropism, and with amphoteric element characteristic, its ion is mainly Sb3+, There is Sb5+.Antimony there are about more than 120 kinds of antimony mineral and antimony-containing mineral in nature, mainly exist with 4 kinds of forms, i.e. 1. natural chemical combination Thing and interphase, such as antimony, wretbladite;2. sulfide and sulfosalt class, such as stibnite, chalcostibite, gudmundite, brightness Tripuhyite, black tetrahedrite, bournonite, boulangerite, jamesonite, plagionite, pyrargyrite, miargyrite, brightness antimony Lead silver ore, livingstonite, brown red antimony sulfide etc.;3. halogenide or halide, such as antimony oxychloride lead ore etc.;4. oxide, such as antimony bloom, Stibiconite, cervantite, romeite, water romeite, senarmontite etc..
At present, although antimony-containing mineral is found on the earth's crust up to kind more than 120, suitable with industrial utility value is selected now Smelting condition, only 10 kinds of the antimony mineral containing antimony more than 20%, i.e. stibnite (containing Sb71.4%), senarmontite (contain Sb83.3%), antimony bloom (containing Sb83.3%), cervantite (containing Sb74%~79%), stibiconite (containing Sb74.5%), brown red antimony sulfide It is (contain Sb75.2%), antimony (containing Sb100%), livingstonite (containing Sb51.6%), jamesonite (containing Sb35.5%), black Tetrahedrite (contains Sb25%).
The smelting process of antimony has two kinds of pyrogenic process and wet method.Either antimony pyrometallurgical smelting or antimony hydrometallurgy, can all produce a large amount of Arsenic alkaline slag and the heavy metal such as a number of arsenic, lead, zinc, chromium, cadmium, hydrargyrum.These waste residues are mainly by selecting and purchasing barren rock and fire refining Slag is constituted, it is difficult to separated, and is unfavorable for that resource is recycled.At present for the disposal of antimony and association slag is mainly adopted Security landfill.After security landfill, landfill yard can produce a certain amount of containing the diafiltration of the heavy metals such as antimony, arsenic, lead, zinc, chromium, cadmium, hydrargyrum Liquid.
Percolate containing heavy metal brings very big threat to health and ecological environment.Conventional processing method bag Include chemical precipitation method, electrochemical process, active carbon adsorption, membrane separation process etc..But all there is cost of equipment height, Yi Zao in these methods Into secondary pollution, the percolate being particularly present after treatment is difficult to the discharge standard for reaching national regulation, let alone reuse.
Utility model content
The purpose of this utility model is to provide the processing meanss of a kind of antimony and association slag landfill percolate, with solution The problem of prior art presence is stated, the percolate high treating effect containing heavy metal is made, controllability is strong, stable, Jing process Percolate afterwards can be back in landfill yard flushes the toilet, clears away, afforesting, carwash, pouring and spill road, has saved the energy.
For achieving the above object, this utility model provides following scheme:A kind of antimony and association slag landfill percolate Processing meanss, including:The regulating reservoir that is sequentially connected by pipeline, flocculation tank, primary sedimentation basin, a secondary flocculation are anti- Ying Chi, secondary sedimentation tank, elevator pump, circular regeneration high rate filter, reinforcing adsorption column, KDF cartridge filters, sterilization pool and return Millpond;
The bottom of flocculation tank is provided with the first air stirring pipe, and the first medicine machine is provided with by pond;
The bottom of the primary sedimentation basin is provided with primary sedimentation basin discharge pipeline;
The bottom of the secondary flocculation tank is provided with the second air stirring pipe, and the second medicine machine is provided with by pond;
It is disposed with base plate inside the circular regeneration high rate filter from the bottom up, supports short tube, filter plate filter group Component, supporting layer, attapulgite filter material filter layer, synthesis media filtration layer;
The reinforcing adsorption column is more than two sets, and by pipeline communication, often set strengthen inside adsorption column from the bottom up according to Secondary setting abacus net, bed course, adsorption layer;The reinforcing adsorption column top side is provided with reinforcing adsorption column water inlet pipe, by force The bottom for changing adsorption column is provided with reinforcing adsorption column outlet pipe and the reinforcing absorption being arranged at by the reinforcing adsorption column outlet pipe Column regeneration waste liquid drain pipe, is provided with the 3rd medicine machine at the top of the reinforcing adsorption column;
It is disposed with many metals of supporting clapboard component, transition zone, KDF inside the KDF cartridge filters from the bottom up Media filtration layer, is provided with KDF cartridge filter water inlet pipes at the top of KDF cartridge filters, KDF cartridge filters bottom sets respectively KDF cartridge filters outlet pipe and KDF cartridge filter backwash water pipes are equipped with, the KDF cartridge filters top tank skin sets It is equipped with KDF cartridge filter backwash drain pipies;
The bottom difference of the primary sedimentation basin, secondary sedimentation tank, circular regeneration high rate filter and KDF cartridge filters Connect with bed mud heavy metal accumulation pond.
Optionally, the pond type of the secondary sedimentation tank is tube settler, and inclined-tube support and inclined tube, pond are provided with the middle part of pond Bottom is provided with secondary sedimentation tank discharge pipeline.
Optionally, also including filtrate circulating pump, the filtrate circulating pump is a filtrate bypass circuit system, and the filtrate is followed The import of ring pump is provided with filtrate circulating pump water inlet pipe, and filtrate circulating pump water intaking valve is provided with the filtrate circulating pump water inlet pipe Door;The outlet of the filtrate circulating pump is provided with filtrate circulation water pump outlet pipe;The bottom of the circular regeneration high rate filter sets Circular regeneration high rate filter outlet pipe is equipped with, circular regeneration is installed at a high speed on the circular regeneration high rate filter outlet pipe Filter outlet pipe valve;Set beside the circular regeneration high rate filter outlet pipe of the circular regeneration high rate filter bottom Circular regeneration high rate filter backwash water inlet pipe is equipped with, is provided with the circular regeneration high rate filter backwash water inlet pipe Circular regeneration high rate filter backwash water inlet tube valve;It is provided with the tank skin on the circular regeneration high rate filter top and follows Ring regenerates high rate filter backwash drain pipe, is provided with circulation again on the circular regeneration high rate filter backwash drain pipe Raw high rate filter backwash draining tube valve.
Optionally, also including regenerated liquid make-up tank and waste liquid tank, at the top of the regenerated liquid make-up tank, it is provided with regenerated liquid throwing Plus pump, the regenerated liquid adds pump discharge and is provided with regenerated liquid and adds and pump out liquid pipe, and the regenerated liquid adds that to pump out liquid pipe Jing strong The top for changing adsorption column is entered in post, and the regenerated liquid is added to pump out liquid pipe and be provided with regenerated liquid and add and pumps out liquid pipe valve;Institute State the container that waste liquid is discharged when waste liquid tank strengthens absorption column regeneration by a receiving.
Optionally, valve is equipped with each connecting line of the processing meanss.
A kind of processing method that antimony and association slag landfill percolate are carried out using above-mentioned processing meanss, including following step Suddenly:
The antimony of collection and association slag landfill percolate are adjusted, with after, entering into regulating reservoir by feed tube Flocculation tank, by the first medicine machine being arranged on by a flocculation tank, adds to a flocculation tank NaOH aqueous solutions, the concentration of NaOH aqueous solutions is 8~10%, and control ph 8~9, unlatching are arranged on the first air of bottom of pond and stir Pipe is mixed, to stir hybrid reaction, the percolate after hybrid reaction is precipitated into primary sedimentation basin;
The supernatant of primary sedimentation basin enter secondary flocculation tank, by be arranged on by secondary flocculation tank second Medicine machine, adds NaOH and Na to secondary flocculation tank2S mixed aqueous solutions, NaOH and Na2The concentration of S mixed aqueous solutions is 10~13%, control ph 10~11 opens the second air stirring pipe, the diafiltration to stir hybrid reaction, after hybrid reaction Liquid is precipitated into secondary sedimentation tank;
The supernatant of secondary sedimentation tank is lifted by elevator pump, and boosted water pump outlet pipe to circular regeneration high rate filter is intake Pipe is filtered into circular regeneration high rate filter top layer, and filtrate circulating pump, filtrate circulating pump water inlet pipe valve are closed during filtration Door, circular regeneration high rate filter backwash water inlet tube valve, circular regeneration high rate filter backwash draining tube valve;Open Circular regeneration high rate filter water inlet tube valve, circular regeneration high rate filter water outlet tube valve;Synthesis filtrate is followed through filtrate Filter layer, attapulgite filter material filter layer, supporting layer, filter plate filter molectron, base plate carry out forward filter;
Backwash is carried out after filtration, filtrate circulating pump, filtrate circulating pump water inlet tube valve, circular regeneration during backwash, is opened High rate filter backwash water inlet tube valve, circular regeneration high rate filter back flush valves;Close circular regeneration high-rate fitration Device water inlet tube valve, circular regeneration high rate filter water outlet tube valve;Backwashing water Jing base plates, filter plate filter molectron, support Layer, attapulgite filter material filter layer, synthesis media filtration layer carry out reverse backwash;The turbid mud of backwash is discharged into bed mud heavy metal Enrichment pond;
Circular regeneration high rate filter water outlet Jing circular regeneration high rate filter outlet pipes, reinforcing adsorption column water inlet pipe Jing again Reinforcing adsorption column top layer is adsorbed in adsorption column;Reinforcing adsorption column regeneration liquid waste drain pipe valve, again is closed during absorption Raw liquid adds pump, regenerated liquid and adds and pumps out liquid pipe;Open reinforcing adsorption column carry out tube valve, reinforcing adsorption column water outlet tube valve, 3rd medicine machine;Jing adsorption liquids follow adsorption layer, bed course, orifice plate net and carry out positive absorption;Set when the water outlet of reinforcing adsorption column exceedes During meter standard, another post is concatenated immediately, the first post stops absorption, carries out regenerative operation;Reinforcing adsorption column is opened during regenerative operation Regeneration liquid waste drain pipe valve, regenerated liquid add pump, regenerated liquid and add and pump out liquid pipe;Closing reinforcing adsorption column feed liquor tube valve, Reinforcing adsorption column water outlet tube valve, the 3rd medicine machine;Regeneration Sequence is also positive regeneration;Regeneration liquid waste row after regeneration Toward waste liquid tank;
Reinforcing adsorption column water outlet Jing reinforcing adsorption column outlet pipe, KDF cartridge filter water inlet pipe Jing KDF cartridge filters Filtered in KDF cartridge filter filters on top;During filtration close KDF cartridge filter backwashing water tube valves, KDF cartridge filter backwash water discharging valves;The many metal media filtration layers of KDF, transition zone, supporting clapboard component are followed through filtrate Carry out forward filter;
Backwash is carried out after filtration, KDF cartridge filter backwashing water tube valves, Filter Back Washing during backwash, is opened Supply mains, KDF cartridge filter backwash draining tube valves;Backwashing water follows many metals of supporting clapboard component, transition zone, KDF Media filtration layer, reverse backwash is carried out, the turbid mud of backwash is discharged into bed mud heavy metal accumulation pond.
Optionally, the job step of the circular regeneration high rate filter includes:
1. filter;Drawn water from secondary sedimentation tank by elevator pump during filtration and send into circular regeneration high rate filter, water leads to downwards Cross synthesis media filtration layer, attapulgite filter material filter layer, supporting layer, filter plate filter molectron, base plate outflow filter;
2. filtrate circulation;At the end of filtration, controlling filter carries out backwash, and backwash is first used filtrate circulating pump, made Water in filter is circulated between filter and filtrate circulating pump, and filtrate circulating pump is first used in backwash, makes the water in filter exist Circulate between filter and filtrate circulating pump;
3. water is rinsed;By backwash water inlet pipe filter bottom up water flowing.
Optionally, the job step of the reinforcing adsorption column 8 includes:
1. prepare;The adsorption layer that will be filled with the weathered coal humic acid granule of 0.7~2.1mm is first soaked with tap water, is made Granule fully expands;During dress post, fill water in adsorption column in advance, make the adsorption layer natural subsidence of loading, it is uniform to pile up;
2. adsorb;Reinforcing adsorption column is entered from circular regeneration high rate filter outlet pipe Jing reinforcing adsorption column water inlet pipe 8-4; And dilute hydrochloric acid solution is added by the 3rd medicine machine 8-10 for being arranged on reinforcing adsorption column crown center, make pH pull back to 6~6.5 Between, adsorption conditionses are better met with profit;
3. regenerate;Reinforcing adsorption column is provided with three posts altogether, when the second post aqueous concentration is above standard, concatenates the 3rd immediately Post, the first post stop absorption, carry out regenerative operation, i.e., by compound concentration in the regenerated liquid make-up tank being arranged on by reinforcing adsorption column For 10~15% dilute hydrochloric acid regenerated liquid, pumping is added by regenerated liquid then rise regenerated liquid Jing regenerated liquids and add and pump out liquid pipe entrance In reinforcing adsorption column, adsorption layer is regenerated, regenerated liquid enters waste liquid tank.
Optionally, the manufacture method of described adsorption layer adsorbent is:In air slaking coal dust, thermosol is added in distilled water The aqueous solution of polyvinyl alcohol, is squeezed into the graininess of 0.7~2.1mm after mix homogeneously, be put into 100 DEG C of bakings in air dry oven It is dry.
Optionally, the technological design and operational factor are:
Amount of inlet water:60m/d, influent quality:Antimony≤15mg/L, arsenic≤20mg/L, lead≤80mg/L, zinc≤60mg/L, Chromium≤40mg/L, cadmium≤70mg/L, hydrargyrum≤10mg/L;
(1) flocculation tank:1. response time:10~15min, 2. origin or beginning aperture flow velocity:1.5~2.5m/s, 3. End aperture flow velocity:0.3~0.8m/s, 4. GT values:104~105s, 5. NaOH aqueous solutions add concentration:8~10%, 6. pH Value:8~9;
(2) primary sedimentation basin:1. time of staying:4h, 2. upflow velocity:0.3~0.35mm/s, 3. surface loading: 1.0m3/m2·h;
(3) secondary flocculation tank:1. response time:15~20min, 2. origin or beginning aperture flow velocity:2.5~3.0m/s, 3. End aperture flow velocity:0.7~0.9m/s, 4. GT values:104~105s, 5. NaOH and Na2S mixed aqueous solutions add concentration:10~ 13%, 6. pH value:10~11;
(4) secondary sedimentation tank:1. time of staying:2.5h, 2. liquid level upflow velocity V=3.0mm/s, 3. particle sinking speed Than u=0.4mm/s, 4. inclined tube material is Propylene polymerization, internal diameter 80mm, plagioclase 1m, 60 ° of level inclination, 5. water distributing area height 0.8 ~1.6m, inclined tube area height 0.87m, gathering ground 0.8~1.2m of height;
(5) circular regeneration high rate filter:1. filtering velocity:≤ 30m/h, 2. filter cycle:≤ 14h, 3. back washing strength:15 ~20L/ (sm2), 4. backwashing time:5min, 5. pH value:10~11,6. temperature:10~30 DEG C, 7. the backwash water yield account for Filter the water yield:1.4%;
(6) strengthen adsorption column:1. adsorb column flow rate:3~3.5m/h, 2. adsorption cycle:≤ 16h, 3. regeneration velocity: 0.8m/h, 4. pH value:6~6.5,5. temperature:10~30 DEG C;
(7) KDF cartridge filters:1. filtering velocity:≤ 10m/h, 2. filter cycle:≤ 16h, 3. back washing strength:14~ 16L/(s·m2), 4. backwashing time:10min, 5. pH value:6~6.5,6. temperature:10~30 DEG C, 7. dissolved oxygen DO:4~ 5mg/L。
This utility model achieves following technique effect relative to prior art:
1. multiplexed combination technology is adopted, and to antimony and the intensive treatment of association slag landfill percolate, high treating effect goes out Water circulation flushing the toilet, clearing away, afforesting inside landfill yard, carwash, pour and spill road etc..
2. using secondary response and secondary precipitation+circular regeneration high rate filter as one-level coarse filtration, emphasis process diafiltration Each heavy metal ion of the concentration of heavy metal ion such as antimony, arsenic, lead, zinc, cadmium, chromium, hydrargyrum in the range of 10~150mg/L in liquid;With , used as secondary reinforcement processing unit, in emphasis process percolate, the heavy metal ion such as antimony, arsenic, lead, zinc, cadmium, chromium, hydrargyrum is dense for adsorption column The each heavy metal ion spent in the range of 1~10mg/L;Using KDF cartridge filters as three-level precision processing unit, it is ensured that final Process water outlet and remove antimony≤1.0mg/L, reach《Stannum, antimony, hydrargyrum emission of industrial pollutants standard》(GB30770-2014) outside standard, its Remaining arsenic≤0.05mg/L, lead≤0.1mg/L, zinc≤5.0mg/L, cadmium≤0.01mg/L, chromium (6+)≤0.1mg/L, hydrargyrum≤ 0.01mg/L, reaches《Groundwater Environmental Quality standard》(GB/T14848-1993) standard.
Description of the drawings
In order to be illustrated more clearly that this utility model embodiment or technical scheme of the prior art, below will be to embodiment Needed for accompanying drawing to be used be briefly described, it should be apparent that, drawings in the following description are only of the present utility model Some embodiments, for those of ordinary skill in the art, without having to pay creative labor, can be with basis These accompanying drawings obtain other accompanying drawings;
Fig. 1 is the structural representation of the processing meanss of this utility model antimony and association slag landfill percolate;
Fig. 2 is the A-A profiles of Fig. 1;
Fig. 3 is the structural representation of the circular regeneration high rate filter of this utility model processing meanss;
Fig. 4 is the structural representation of the reinforcing adsorption column of this utility model processing meanss;
Fig. 5 is the structural representation of the KDF cartridge filters of this utility model processing meanss;
Fig. 6 is the process chart of the processing method of this utility model antimony and association slag landfill percolate;
Description of reference numerals:1- regulating reservoirs;1-1- feed tubes;Flocculation tank of 2-;The first air stirring pipes of 2-1-; The first medicine machines of 2-2-;3- primary sedimentation basins;3-1- primary sedimentation basin discharge pipelines;Bis- flocculation tanks of 4-;4-1- second Air stirring pipe;The second medicine machines of 4-2-;5- secondary sedimentation tanks;5-1- inclined-tube supports and inclined tube;5-2- secondary sedimentation tanks are arranged Mud pipe;6- elevator pumps;6-1- lifts water pump outlet pipe;6-2- circular regeneration high rate filter water inlet pipes;6-3- circular regenerations are at a high speed Filter inleting pipe valve;7- circular regeneration high rate filters;7-1- base plates;7-2- supports short tube;7-3- filter plates filter is combined Part;7-4- supporting layers;7-5- attapulgite filter material filter layers;7-6- synthesizes media filtration layer;7-7- filtrate circulating pumps;7-8- is filtered Material circulating pump water inlet pipe;7-9- filtrates circulating pump water inlet tube valve;7-10- filtrates circulate water pump outlet pipe;7-11- circular regenerations are high Fast filter outlet pipe;7-12- circular regeneration high rate filter water outlet tube valves;7-13- circular regenerations high rate filter recoils Wash water inlet pipe;7-14- circular regeneration high rate filters backwash water inlet tube valve;7-15- circular regenerations high rate filter recoils Wash drain pipe;7-16- circular regeneration high rate filter backwash draining tube valves;8- strengthens adsorption column;8-1- orifice plate nets;8-2- Bed course;8-3- adsorption layers;8-4- strengthens adsorption column water inlet pipe;8-5- reinforcing adsorption column water inlet tube valves;8-6- strengthens adsorption column Outlet pipe;8-7- strengthens adsorption column water outlet tube valve;8-8- strengthens adsorption column regeneration liquid waste drain pipe;8-9- reinforcings adsorption column is again Raw waste liquid drain pipe valve;The 3rd medicine machines of 8-10-;9- regenerated liquid make-up tanks;9-1- regenerated liquids add pump;9-2- regenerated liquids Add and pump out liquid pipe;10- waste liquid tanks;11-KDF cartridge filters;11-1- supporting clapboard components;11-2- transition zones;11-3- The many metal media filtration layers of KDF;11-4-KDF cartridge filter water inlet pipes;11-5-KDF cartridge filters water inlet tube valve;11- 6-KDF cartridge filter outlet pipes;11-7-KDF cartridge filter water outlet tube valves;11-8-KDF cartridge filter backwashing waters Pipe;11-9-KDF cartridge filter backwashing water tube valves;11-10-KDF cartridge filter backwash drain pipies;11-11-KDF Cartridge filter backwash draining tube valve;12- bed mud heavy metal accumulations pond;13- sterilization pools;13-1- disinfection apparatus;14- is returned Millpond;14-1- reuse water pumps;14-2- reuse pumping lines;14-3- reuse pumping line valves;14-4- filters Backwashing water house steward;14-5- Filter Back Washing supply mains's valves;15- air headers.
Specific embodiment
Below in conjunction with the accompanying drawing in this utility model embodiment, the technical scheme in this utility model embodiment is carried out Clearly and completely describe, it is clear that described embodiment is only this utility model a part of embodiment, rather than whole Embodiment.Based on the embodiment in this utility model, those of ordinary skill in the art are not under the premise of creative work is made The every other embodiment for being obtained, belongs to the scope of this utility model protection.
The purpose of this utility model is to provide the processing meanss and method of a kind of antimony and association slag landfill percolate, with Above-mentioned prior art is solved the problems, such as, the percolate high treating effect containing heavy metal is made, controllability is strong, stable, Percolate Jing after processing can be back in landfill yard flushes the toilet, clears away, afforesting, carwash, pouring and spill road, has saved the energy.
It is understandable to enable above-mentioned purpose of the present utility model, feature and advantage to become apparent from, below in conjunction with the accompanying drawings and tool Body embodiment is described in further detail to this utility model.
Embodiment 1
As shown in Figure 1, Figure 2, shown in Fig. 3, Fig. 4, Fig. 5, the present embodiment provides a kind of antimony and association slag landfill percolate Processing meanss, the processing meanss include 1, flocculation tank 2 of regulating reservoir, primary sedimentation basin 3, secondary flocculation tank 4, two Secondary sedimentation tank 5, elevator pump 6, circular regeneration high rate filter 7, reinforcing adsorption column 8, regenerated liquid make-up tank 9, waste liquid tank 10, KDF Cartridge filter 11, bed mud heavy metal accumulation pond 12, sterilization pool 13, reuse pool 14, air header 15.Before the regulating reservoir 1 Feed tube 1-1 is provided with the pool wall of end.The function of regulating reservoir is equal and water quality, regulating pondage.A described flocculation tank 2 Bottom be provided with the first air stirring pipe 2-1, the first medicine machine 2-2 is provided with by pond.The bottom of the primary sedimentation basin 3 It is provided with primary sedimentation basin discharge pipeline 3-1.Flocculation tank 2 and primary sedimentation basin 3 are used in combination, and during operation, lead to The first medicine machine 2-2 being arranged on by a flocculation tank is crossed, and NaOH aqueous solutions is added to a flocculation tank;NaOH Compound concentration be 8~10%, control ph 8~9 or so.Its function is to remove in antimony and association slag landfill percolate The heavy metal ion such as the antimony of 10~150mg/L higher concentrations, arsenic, lead, zinc, chromium, hydrargyrum.The bottom of described secondary flocculation tank 4 Portion is provided with the second air stirring pipe 4-1, and the second medicine machine 4-2 is provided with by pond.The pond type of described secondary sedimentation tank 5 is Tube settler, is provided with inclined-tube support and inclined tube 5-1 in the middle part of pond.Inclined-tube support is made of 60 × 6mm of ∠ angle steel, inclined-tube support Inclined tube is provided with above, and inclined tube material is Propylene polymerization, and inclined tube aperture is 80mm, and mounted angle is 60 °, and bottom of pond is provided with secondary Sludge from sedimentation tank pipe 5-2.The secondary flocculation tank 4 and secondary sedimentation tank 5 are used in combination, during operation, by being arranged on two The second medicine machine 4-2 by secondary flocculation tank, adds NaOH and Na to secondary flocculation tank2S mixed aqueous solutions, NaOH And Na2The compound concentration of S is 10~13%, control ph 10~11 or so.Its function predominantly removes antimony and association slag is filled out Bury the heavy metal ion such as 10~150mg/L in a percolate or so the cadmium of higher concentration.The elevator pump 6 is the latent dirt of rustless steel Pump, lifting water pump outlet pipe 6-1 and circular regeneration high rate filter water inlet pipe 6-2 connections that elevator pump is arranged, circular regeneration is at a high speed Circular regeneration high rate filter water inlet tube valve 6-3 is installed on filter inleting pipe.Described circular regeneration high rate filter 7 Inside is disposed with base plate 7-1 (base plate is steel plate, and thickness is 10mm) from the bottom up, (support short tube is steel to support short tube 7-2 Pipe, specification be DN100 × 8mm, length is 200mm), (filter plate is steel plate to filter plate filter molectron 7-3, and thickness is 8mm, in steel It is provided with plateHole, install short-handled filter head, spacing is 100mm), supporting layer 7-4 (supporting layer from particle diameter be 2~ The rubble sand of 4mm, supporting layer thickness be 100mm), attapulgite filter material filter layer 7-5 (attapulgite filter material filter layer select Particle diameter be the attapulgite of 1.6~2.5mm, filtrate thickness be 800mm), synthesis media filtration layer 7-6 (synthesis media filtration layer From expandability polyethylene particle that particle diameter is 0.8~1.2mm add oil liquefied gas foam made by pearl it is white little Ball, filter layer thickness are 600mm).The filtrate circulating pump 7-7 is a filtrate bypass circuit system, and filtrate pump inlet sets Filtrate circulating pump water inlet pipe 7-8 is equipped with, filtrate circulating pump water inlet tube valve 7-9 is installed on filtrate circulating pump water inlet pipe;Filtrate Circulating-pump outlet is provided with filtrate circulation water pump outlet pipe 7-10.Circular regeneration high rate filter outlet pipe 7-11 is arranged on circulation again The bottom of raw high rate filter, is provided with circular regeneration high rate filter water outlet pipe valve on circular regeneration high rate filter outlet pipe Door 7-12;Circular regeneration high rate filter backwash water inlet pipe 7-13 is arranged on the circulation of circular regeneration high rate filter bottom again The side of raw high rate filter outlet pipe, is provided with circular regeneration high speed mistake on circular regeneration high rate filter backwash water inlet pipe Filter backwash water inlet tube valve 7-14;Circular regeneration high rate filter backwash drain pipe 7-15 is arranged on circular regeneration at a high speed On the tank skin on filter top, circular regeneration high rate filter is installed on circular regeneration high rate filter backwash drain pipe anti- Flush discharge tube valve 7-16.
The advantage of circular regeneration high rate filter is the synthesis filtrate using shape and uniform particle diameter, so whole filtrates are thick Degree can make full use of, therefore filtrate cuts dirty ability greatly, and filter cycle is long, and backwash effect is good, and the filter is used for containing various Heavy metal ion percolate high treating effect.
The above secondary response and secondary precipitation+circular regeneration high-rate fitration as one-level bulk processing unit, at emphasis In reason percolate each heavy metal of the concentration of heavy metal ion in the range of 10~150mg/L such as antimony, arsenic, lead, zinc, cadmium, chromium, hydrargyrum from Son.
Described reinforcing adsorption column 8 has three sets, often cover it is internal set gradually from the bottom up abacus net 8-1 (orifice plate net Size is 600 × 600mm, and it is laid in more than adsorption column bottom at 0.3~0.4m with buttress.Orifice plate net is poured with armored concrete System, thickness of slab 100mm, eyelet make bar seam, the nylon wire of 1-2 layer 30-40 mesh is repaved on plate), (bed course selects particle diameter to bed course 8-2 For the garnet of 3~6mm, cushion thickness is 150mm), (adsorption layer is from the air slaking that particle diameter is 0.7~2.1mm for adsorption layer 8-3 Coal humic acid granule, adsorbent layer thickness are 1600mm).Reinforcing adsorption column top side is provided with reinforcing adsorption column water inlet pipe 8- 4, reinforcing adsorption column water inlet tube valve 8-5 is installed on reinforcing adsorption column water inlet pipe, reinforcing adsorption column outlet pipe 8-6 is arranged on The bottom of reinforcing adsorption column, is provided with reinforcing adsorption column water outlet tube valve 8-7 on reinforcing adsorption column outlet pipe, reinforcing adsorption column is again Raw waste liquid drain pipe 8-8 is arranged on the side of the reinforcing adsorption column outlet pipe of reinforcing absorption column bottom, strengthens adsorption column regenerated Adsorption column water outlet tube valve 8-9 is installed on liquid drain pipe, the crown center of reinforcing adsorption column is provided with the 3rd medicine machine 8-10。
The regenerated liquid make-up tank 9 is a plastic containers, and container top is provided with regenerated liquid and adds pump 9-1, and regenerated liquid is thrown Plus pump discharge is provided with regenerated liquid and adds and pumps out liquid pipe 9-2, regenerated liquid adds and pumps out the top of liquid pipe Jing reinforcing adsorption column 8 and enter In post, add to pump out liquid pipe and regenerated liquid is installed adds in regenerated liquid and pump out liquid pipe valve 9-3.
The waste liquid tank 10 is accommodated by one strengthens the plastic containers that waste liquid is discharged when adsorption column 8 regenerates.
The reaction mechanism of reinforcing adsorption column 8:Adsorption layer 8-3 adsorbents (the weathered coal humic acid granule of 0.7~2.1mm) are in Faintly acid, the carboxyl, phenol carboxyl isoreactivity function in its molecular structure are used, and determine its chemical property and excellent adsorptivity Can, its absorption to heavy metal ion such as antimony, arsenic, lead, zinc, cadmium, chromium, hydrargyrum mainly has ion exchange, complexation (or chelating) and table The reactions such as face absorption.
The above using adsorption column 8 as secondary reinforcement processing unit, emphasis process antimony in percolate, arsenic, lead, zinc, cadmium, Each heavy metal ion of the concentration of heavy metal ion such as chromium, hydrargyrum in the range of 1~10mg/L.
It is disposed with supporting clapboard component 11-1 (supporting clapboards inside described KDF cartridge filters 11 from the bottom up Component is steel plate, and thickness is 8mm, is drilled with dividing plateHole, pitch-row are 60mm, and ABS short-handled filter heads are provided with hole), mistake Cross a layer 11-2 (transition zone is 2~4mm magnetic iron ores from particle diameter, and transition region thickness is 150mm), many metal media filtration layers of KDF 11-3 (many metal media filtration layer choosing particle diameters of KDF are many metal filtrates of 1~2mmKDF, and thickness is 1600mm).KDF ensured public security KDF cartridge filter water inlet pipe 11-4 are provided with the top of filter, cartridge filter is installed on KDF cartridge filter water inlet pipes Water inlet tube valve 11-5, KDF cartridge filters bottom is respectively arranged with KDF cartridge filter outlet pipe 11-6, ensured public security in KDF KDF cartridge filter water outlet tube valve 11-7 are installed on filter outlet pipe;KDF cartridge filter backwash water pipe 11-8, Cartridge filter backwashing water tube valve 11-9 is installed on KDF cartridge filter backwash water pipes.On KDF cartridge filters Portion's tank skin is provided with KDF cartridge filter backwash drain pipe 11-10, installs on KDF cartridge filter backwash drain pipies There are KDF cartridge filter backwash draining tube valve 11-11.
The mechanism of the KDF cartridge filters 11:The filtrate adopted by many metal media filtration layers of KDF 11 is a kind of granule Shape high-purity alloy, surface have extremely strong oxidation resistance, and it carries out process work by light electrolysis oxidation-reduction reaction, When contacting with percolate, two kinds of metals in alloy constitute countless little galvanic element systems on submicroscopic yardstick.This material Material has powerful respond and the response speed that is exceedingly fast in water, can remove in percolate up to 99% antimony, arsenic, The heavy metal ion such as lead, zinc, cadmium, chromium, hydrargyrum.
The above KDF cartridge filter 11 is used as three-level Jing processing unit, it is ensured that final outflow water removes antimony≤1.0mg/L, Reach《Stannum, antimony, hydrargyrum emission of industrial pollutants standard》(GB30770-2014) outside standard, remaining arsenic≤0.05mg/L, lead≤ 1.0mg/L, zinc≤5.0mg/L, cadmium≤0.01mg/L, chromium (6+)≤0.1mg/L, hydrargyrum≤0.01mg/L reach《Underground water ring Border quality standard》(GB/T14848-1993) standard.
The bed mud heavy metal accumulation pond 12 receive arranged by primary sedimentation basin discharge pipeline 3-1 primary sedimentation basin bed mud, The arranged secondary sedimentation tank bed muds of secondary sedimentation tank discharge pipeline 5-2, circular regeneration high rate filter backwash drain pipe 7-15 are arranged Turbid mud during circular regeneration high rate filter backwash.The arranged circular regenerations of KDF cartridge filter backwash discharge pipeline 11-10 are high Turbid mud during fast Filter Back Washing.Heavy metal bed mud after enriched carries out useless process or resource time of endangering by qualified unit Receive.
Disinfection apparatus 13-1 is provided with the sterilization pool 13.
Reuse water pump 14-1, reuse pumping line 14-2 are provided with described reuse pool 14, are pumped out in recycle-water Reuse pumping line valve 14-3 is installed on water pipe, reuse water pump passes through reuse pumping line, after process up to standard Percolate is delivered in landfill yard flushes the toilet, clears away, afforesting, carwash, pouring and spill road etc..In addition, pacifying on reuse pumping line Equipped with shunt valve, i.e. circular regeneration high rate filter and two Filter Back Washing supply mains of KDF cartridge filters, in filter Filter Back Washing supply mains's valve is installed on backwashing water house steward.
The first air stirring pipe 2-1 that 2 bottom of flocculation tank is arranged, 4 bottom of pond of secondary flocculation tank are arranged The second air stirring pipe 4-1 access from air header 15.
Embodiment 2
As shown in fig. 6, present embodiments providing the processing method of a kind of antimony and association slag landfill percolate, the method Brief description of the process it is as follows:
Antimony containing heavy metal ion such as antimony, arsenic, lead, zinc, cadmium, chromium, hydrargyrum and association slag landfill percolate Jing are collected, by Feed tube 1-1 is adjusted with after, into a flocculation tank 2, by being arranged on a flocculation reaction into regulating reservoir 1 The first medicine machine 2-2 by pond, adds NaOH aqueous solutions to a flocculation tank;The compound concentration of NaOH is 8~10%, Control ph 8~9 or so, unlatching are arranged on the first air stirring pipe 2-1 of bottom of pond, to stir hybrid reaction, hybrid reaction Percolate afterwards is precipitated into primary sedimentation basin 3.Flocculation tank and primary sedimentation basin are primarily to remove antimony And the heavy metal such as the antimony of 10~150mg/L in association slag landfill percolate or so higher concentration, arsenic, lead, zinc, chromium, hydrargyrum Ion;Primary sedimentation basin supernatant enters secondary flocculation tank 4.By the second dosing being arranged on by secondary flocculation tank Equipment 4-2, adds NaOH and Na to secondary flocculation tank2S mixed aqueous solutions, NaOH and Na2The compound concentration of S be 10~ 13%, control ph 10~11 or so opens the second air stirring pipe 4-1, to stir hybrid reaction, oozing after hybrid reaction Filtrate is precipitated into secondary sedimentation tank 5, and secondary flocculation tank and secondary sedimentation tank are primarily to remove antimony and association The cadmium ion of 10~150mg/L in slag landfill percolate or so higher concentration.The supernatant of second pond is carried by elevator pump 6 Rise, boosted water pump outlet pipe 6-1 to circular regeneration high rate filter water inlet pipe 6-2 enters 7 top layer of circular regeneration high rate filter Filtered, filtrate circulating pump 7-7, filtrate circulating pump water inlet tube valve 7-9, circular regeneration high rate filter are closed during filtration anti- It is flushed into aqueduct valve 7-14, circular regeneration high rate filter backwash draining tube valve 7-16;ON cycle regenerates high speed mistake Filter water inlet tube valve 6-3, circular regeneration high rate filter water outlet tube valve 7-12.Filtrate follow synthesis media filtration layer 7-6, Attapulgite filter material filter layer 7-5, supporting layer 7-4, filter plate filter molectron 7-3, base plate 7-1 carry out forward filter.Filter one Backwash is carried out after individual cycle (24h), filtrate circulating pump 7-7, filtrate circulating pump water inlet tube valve 7-9 is opened during backwash, is followed Ring regeneration high rate filter backwash water inlet tube valve 7-14, circular regeneration high rate filter back flush valves 7-16;Closing is followed Ring regeneration high rate filter water inlet tube valve 6-3, circular regeneration high rate filter water outlet tube valve 7-12.Backwashing water Jing base plates 7-1, filter plate filter molectron 7-3, supporting layer 7-4, attapulgite filter material filter layer 7-5, synthesis media filtration layer 7-6 are carried out instead To backwash.The turbid mud of backwash is discharged into bed mud heavy metal accumulation pond 12.
The course of work of the circular regeneration high rate filter 7:
1. filter.Drawn water from secondary sedimentation tank 5 by elevator pump 6 during filtration and send into circular regeneration high rate filter 7, water is downward By synthesizing media filtration layer 7-6, attapulgite filter material filter layer 7-5, supporting layer 7-4, filter plate filter molectron 7-3, base plate 7-1 outflow filters.Because using the synthesis filtrate of shape and uniform particle diameter, the full depth for synthesizing filtrate can rise To the effect for cutting dirt.
2. filtrate circulation.At the end of filtration, controlling filter carries out backwash.Filtrate circulating pump is first used in backwash, is made Water in filter is circulated between filter and filtrate circulating pump.Now, the water in filter to upstream, filter by the little synthesis of proportion When material and water are circulated together, the dirt of retention is peeled off from synthesis filtrate, and mud ball is also crushed, becomes trickle granular.During circulation Between adopt 3 minutes.
3. water is rinsed.By backwash water inlet pipe filter bottom up water flowing because in the cyclic process of filtrate, The dirt of filtrate retention is completely exfoliated from synthesis filtrate, therefore just filtrate can be cleaned completely with a small amount of water backwashing, The water backwashing time adopts 5 minutes.
The advantage of circular regeneration high rate filter is the synthesis filtrate using shape and uniform particle diameter, so whole filtrates are thick Degree can make full use of, therefore filtrate cuts dirty ability greatly, and filter cycle is long, and backwash effect is good, and the filter is used for containing various Heavy metal ion percolate high treating effect.
The above secondary response and secondary precipitation+circular regeneration high rate filter are used as one-level bulk processing unit, emphasis In treatment and purification percolate, the concentration of heavy metal ion such as antimony, arsenic, lead, zinc, cadmium, chromium, hydrargyrum is each heavy in the range of 10~150mg/L Metal ion.
Circular regeneration high rate filter water outlet Jing circular regeneration high rate filter outlet pipe 7-11, reinforcing adsorption column water inlet pipe 8-4 Jing reinforcing 8 top layers of adsorption column are adsorbed in adsorption column.Reinforcing adsorption column regeneration liquid waste drain pipe valve is closed during absorption Door 8-9, regenerated liquid add pump 9-1, regenerated liquid and add and pump out liquid pipe 9-3;Opening reinforcing adsorption column carries out tube valve 8-5, reinforcing Adsorption column water outlet tube valve 8-7, the 3rd medicine machine 8-10.Adsorption liquid follows adsorption layer 8-3, bed course 8-2, orifice plate net 8-1 and carries out Positive absorption.When adsorption column water outlet is strengthened more than design standard, the 3rd post is concatenated immediately, the first post stops absorption, carries out again Raw operation.Open reinforcing adsorption column regeneration liquid waste drain pipe valve 8-9, regenerated liquid to add pump 9-1, regenerated liquid and throw during regenerative operation Plus pump out liquid pipe 9-3;Closing reinforcing adsorption column feed liquor tube valve 8-5, reinforcing adsorption column water outlet tube valve 8-7, the 3rd dosing set Standby 8-10.Regeneration Sequence is also positive regeneration.Regeneration liquid waste after regeneration is discharged into waste liquid tank 10.
The course of work of the reinforcing adsorption column 8:
1. prepare.Adsorption layer 8-3 (the weathered coal humic acid granule of 0.7~2.1mm) is first soaked one week with tap water, is made Granule fully expands.During dress post, fill water in adsorption column in advance, make the adsorption layer natural subsidence of loading, it is uniform to pile up.
2. adsorb.Reinforcing is entered from circular regeneration high rate filter outlet pipe 7-11 Jing reinforcing adsorption column water inlet pipe 8-4 to inhale Attached column 8;And dilute hydrochloric acid solution is added by the 3rd medicine machine 8-10 for being arranged on reinforcing adsorption column crown center, pull back to pH Between 6~6.5, adsorption conditionses are better met with profit.
3. regenerate.Reinforcing adsorption column 8 is provided with three posts altogether, when the second post aqueous concentration is above standard, concatenates the immediately Three posts, the first post stop absorption, carry out regenerative operation, i.e., by preparation in the regenerated liquid make-up tank 9 being arranged on by reinforcing adsorption column Concentration is 10~15% dilute hydrochloric acid regenerated liquid, then adds pump 9-1 by regenerated liquid and takes out a liter regenerated liquid Jing regenerated liquids and add and pumps out Liquid pipe 9-2 is entered in reinforcing adsorption column, and adsorption layer 8-3 is regenerated, and regenerated liquid enters waste liquid tank 10.
The manufacture method of described adsorption layer 8-3 adsorbents (the weathered coal humic acid granule of 0.7~2.1mm):(100 Weight portion) in air slaking coal dust (drying of 80~100 mesh), thermosol is added in (11 weight portion) polyethylene of (80 weight portion) distilled water The aqueous solution of alcohol.Extrusion molding (0.7~2.1mm graininess) after mix homogeneously, is put in air dry oven (100 DEG C) drying i.e. Into.
Adsorbent is after using the front immersion 16h with HCl, then is washed to without Cl- ions with distillation, is put into 100 DEG C of drying baker Lower drying.Adsorbent after drying acidifying is soaked into 20min with 10% formalin, with distillation water wash it is clean, dry and treat With.
The above using adsorption column as secondary reinforcement processing unit, emphasis process antimony in percolate, arsenic, lead, zinc, cadmium, Each heavy metal ion of the concentration of heavy metal ion such as chromium, hydrargyrum in the range of 1~10mg/L.
Reinforcing adsorption column water outlet Jing reinforcing adsorption column outlet pipe 8-6, KDF cartridge filter water inlet pipe 11-4 Jing KDF security personnel Filtered in filter on the top of filter 11.During filtration close KDF cartridge filter backwashing water tube valve 11-9, KDF cartridge filter backwash water discharging valve 11-11.Filtrate follow many metal media filtration layer 11-3 of KDF, transition zone 11-2, Supporting clapboard component 11-1 carries out forward filter.Backwash is carried out after filtering a cycle (16h), KDF is opened during backwash and is protected Peace Filter Back Washing aqueduct valve 11-9, Filter Back Washing supply mains's 14-4, KDF cartridge filter backwash draining pipe valve Door 11-11.Backwashing water follows supporting clapboard component 11-1, many metal media filtration layer 11-3 of transition zone 11-2, KDF, carries out instead To backwash, the turbid mud of backwash is discharged into bed mud heavy metal accumulation pond 12.
The above KDF cartridge filter 11 is used as three-level precision processing unit, it is ensured that final outflow water removes antimony≤1.0mg/L, Reach《Stannum, antimony, hydrargyrum emission of industrial pollutants standard》(GB30770-2014) outside standard, remaining arsenic≤0.05mg/L, lead≤ 1.0mg/L, zinc≤5.0mg/L, cadmium≤0.01mg/L, chromium (6+)≤0.1mg/L, hydrargyrum≤0.01mg/L reach《Underground water ring Border quality standard》(GB/t14848-1993) standard.
11 water outlet Jing KDF cartridge filters outlet pipe of KDF cartridge filters enters sterilization pool 13, and sterilized facility 13-1 disappears Reuse pool 14 is entered after poison, by the reuse water pump 14-1 being arranged in pond, will process it is up to standard after percolate (after process most Whole water outlet) Jing reuse pumping line 14-2 are delivered in landfill yard and flush the toilet, clear away, afforesting, carwash, pouring and spill road etc..
Receive the primary sedimentation basin bed mud, secondary arranged by primary sedimentation basin discharge pipeline 3-1 in bed mud heavy metal accumulation pond 12 The arranged circulation of the arranged secondary sedimentation tank bed muds of sludge from sedimentation tank pipe 5-2, circular regeneration high rate filter backwash drain pipe 7-15 Turbid mud during regeneration high rate filter backwash.The arranged circular regeneration high speed mistakes of KDF cartridge filter backwash discharge pipeline 11-10 Turbid mud during filter backwash.Heavy metal bed mud after enriched carries out useless process or resource reclaim of endangering by qualified unit.
This utility model applies specific case and principle of the present utility model and embodiment is set forth, above reality The explanation for applying example is only intended to help and understands method of the present utility model and its core concept;Simultaneously for the general of this area Technical staff, according to thought of the present utility model, will change in specific embodiments and applications.To sum up institute State, this specification content is should not be construed as to restriction of the present utility model.

Claims (5)

1. processing meanss of a kind of antimony and association slag landfill percolate, it is characterised in that:Including:It is sequentially connected by pipeline Regulating reservoir (1), flocculation tank (2), primary sedimentation basin (3), secondary flocculation tank (4), secondary sedimentation tank (5), Elevator pump (6), circular regeneration high rate filter (7), reinforcing adsorption column (8), KDF cartridge filters (11), sterilization pool (13) and Reuse pool (14);
The bottom of flocculation tank (2) is provided with the first air stirring pipe (2-1), is provided with the first dosing and sets by pond Standby (2-2);
The bottom of the primary sedimentation basin (3) is provided with primary sedimentation basin discharge pipeline (3-1);
The bottom of the secondary flocculation tank (4) is provided with the second air stirring pipe (4-1), is provided with the second dosing and sets by pond Standby (4-2);
It is disposed with base plate (7-1) inside the circular regeneration high rate filter (7) from the bottom up, supports short tube (7-2), filter Plate filter molectron (7-3), supporting layer (7-4), attapulgite filter material filter layer (7-5), synthesis media filtration layer (7-6);
Reinforcing adsorption column (8) is more than two sets, and by pipeline communication, often set reinforcing adsorption column (8) is internal from the bottom up Set gradually abacus net (8-1), bed course (8-2), adsorption layer (8-3);It is provided with reinforcing adsorption column (8) top side Reinforcing adsorption column water inlet pipe (8-4), the bottom for strengthening adsorption column (8) are provided with reinforcing adsorption column outlet pipe (8-6) and are arranged at Other reinforcing adsorption column regeneration liquid waste drain pipe (8-8) of reinforcing adsorption column outlet pipe (8-6), reinforcing adsorption column (8) Top be provided with the 3rd medicine machine (8-10);
Supporting clapboard component (11-1), transition zone (11- are disposed with from the bottom up inside the KDF cartridge filters (11) 2), many metal media filtration layers (11-3) of KDF, are provided with KDF cartridge filter water inlet pipes at the top of KDF cartridge filters (11) (11-4), KDF cartridge filters (11) bottom is respectively arranged with KDF cartridge filter outlet pipes (11-6) and KDF security personnel and filters Device backwash water pipe (11-8), KDF cartridge filters (11) top tank skin are provided with KDF cartridge filter backwash drainings Pipe (11-10);
The primary sedimentation basin (3), secondary sedimentation tank (5), circular regeneration high rate filter (7) and KDF cartridge filters (11) Bottom connect with bed mud heavy metal accumulation pond (12) respectively.
2. processing meanss of antimony according to claim 1 and association slag landfill percolate, it is characterised in that:Described two The pond type of secondary sedimentation tank (5) is tube settler, and inclined-tube support and inclined tube (5-1) are provided with the middle part of pond, and bottom of pond is provided with secondary Sludge from sedimentation tank pipe (5-2).
3. processing meanss of antimony according to claim 1 and association slag landfill percolate, it is characterised in that:Also include Filtrate circulating pump (7-7), the filtrate circulating pump (7-7) are a filtrate bypass circuit system, the filtrate circulating pump (7-7) Import is provided with filtrate circulating pump water inlet pipe (7-8), is provided with filtrate circulating pump and enters on the filtrate circulating pump water inlet pipe (7-8) Penstock (7-9);The outlet of the filtrate circulating pump (7-7) is provided with filtrate circulation water pump outlet pipe (7-10);The circulation is again The bottom of raw high rate filter (7) is provided with circular regeneration high rate filter outlet pipe (7-11), the circular regeneration high speed mistake Circular regeneration high rate filter water outlet tube valve (7-12) is installed on filter outlet pipe (7-11);The circular regeneration high speed mistake The recoil of circular regeneration high rate filter is provided with beside circular regeneration high rate filter outlet pipe (7-11) of filter (7) bottom Water inlet pipe (7-13) is washed, circular regeneration high speed mistake is installed on the circular regeneration high rate filter backwash water inlet pipe (7-13) Filter backwash water inlet tube valve (7-14);Circulation is provided with the tank skin on circular regeneration high rate filter (7) top again Raw high rate filter backwash drain pipe (7-15), installs on the circular regeneration high rate filter backwash drain pipe (7-15) There is circular regeneration high rate filter backwash draining tube valve (7-16).
4. processing meanss of antimony according to claim 1 and association slag landfill percolate, it is characterised in that:Also include Regenerated liquid make-up tank (9) and waste liquid tank (10), are provided with regenerated liquid at the top of the regenerated liquid make-up tank (9) and add pump (9-1), institute State regenerated liquid and add pump (9-1) outlet and be provided with regenerated liquid and add and pump out liquid pipe (9-2), the regenerated liquid is added and pumps out liquid pipe (9-2) Jing reinforcing adsorption column (8) top enter post in, the regenerated liquid add pump out liquid pipe (9-2) be provided with regenerated liquid throwing Plus pump out liquid pipe valve (9-3);The waste liquid tank (10) is accommodated by one strengthens the appearance that waste liquid is discharged when adsorption column (8) regenerates Device.
5. processing meanss of antimony according to claim 1 and association slag landfill percolate, it is characterised in that:The place Valve is equipped with each connecting line of reason device.
CN201620974757.5U 2016-08-29 2016-08-29 A kind of processing meanss of antimony and association slag landfill percolate Active CN206069583U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106115982A (en) * 2016-08-29 2016-11-16 湖南艾布鲁环保科技有限公司 A kind of antimony and the processing means of association slag landfill percolate and method
CN111646599A (en) * 2020-06-18 2020-09-11 厦门嘉戎技术股份有限公司 System and method for integrated treatment of leachate of garbage transfer station

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106115982A (en) * 2016-08-29 2016-11-16 湖南艾布鲁环保科技有限公司 A kind of antimony and the processing means of association slag landfill percolate and method
CN111646599A (en) * 2020-06-18 2020-09-11 厦门嘉戎技术股份有限公司 System and method for integrated treatment of leachate of garbage transfer station

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