CN206033506U - High chlorine organic wastewater system of difficult degradation based on electricity flocculation - Google Patents

High chlorine organic wastewater system of difficult degradation based on electricity flocculation Download PDF

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Publication number
CN206033506U
CN206033506U CN201620987109.3U CN201620987109U CN206033506U CN 206033506 U CN206033506 U CN 206033506U CN 201620987109 U CN201620987109 U CN 201620987109U CN 206033506 U CN206033506 U CN 206033506U
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China
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electric flocculation
oxidation ditch
mud
flocculation device
pond
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CN201620987109.3U
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李辰
宋彤悦
李�诚
苏建明
沈计
王海阳
李超
李万江
魏建明
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Tianjin Hua Bo Water Co Ltd
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Tianjin Hua Bo Water Co Ltd
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Abstract

The utility model belongs to the technical field of dirty waste water treatment, a high chlorine organic wastewater system of difficult degradation based on electricity flocculation is disclosed to the first pond connection oxidation ditch that sinks, the oxidation ditch includes that the anaerobism that connects gradually is distinguished, becoming reconciled in the anoxic zone, oxygen is distinguished, two heavy ponds, two heavy ponds connection electric flocculation device, electric flocculation device connection disinfection contact chamber are connected to the oxidation ditch, two sink the blowdown mud refluxing a part of ponds institutes distinguishes to the anaerobism, and another part and electric flocculation device blowdown mud together discharges to storing up the mud sump. The utility model discloses an oxidation ditch carries out strengthening treatment as biological treatment, follow -up electric flocculation device, and it is well stable not only to go out water quality of water to can also suitably reduce the energy consumption when the treatment effeciency is higher, do not need to add the flocculation medicament in addition, it is better to go out water water quality, and the processing set -up is compact moreover, and area is little, existing biological treatment's effect has coagulating sedimentation's the effect of getting rid of again, still has degradation difficult degradation organic matter and decolorization concurrently, kill many birds with one stone, and energy saving consumed the festival, easily control.

Description

A kind of difficult degradation high-chlorine organic wastewater processing system based on electric flocculation
Technical field
This utility model belongs to stain disease processing technology field, specifically, is to be related to one kind for hardly degraded organic substance The high sewage and wastewater treatment system of many, chloride ion content.
Background technology
So-called hardly degraded organic substance refers to that microorganism can not be degraded, or can not be with sufficiently fast speed under any environmental condition Degraded and make the Organic substance that it accumulates in the environment.If BOD5/COD < 0.3, then it is assumed that the wastewater biodegradability is poor, belongs to Organic wastewater with difficult degradation thereby.And chloride ion is most commonly seen a kind of anion in water and waste water, the chloride ion content of excessive concentrations The problems such as dead cell dehydration, sludge decomposition can be caused.
As modern industry production is particularly the development of chemical engineering industry, the composition of industrial wastewater is increasingly complicated, especially changes The Organic substance of work synthesis, belongs to hardly degraded organic substance mostly;In water, chloride ion content is higher simultaneously, it tends to be difficult to given up with traditional Method for treating water (mainly biological treatment) is removed, therefore is processed and this kind of be difficult to biodegradable organic wastewater and become a difficult problem.
At present, mainly there are bioanalysises, physico-chemical process and oxidizing process to the processing method of hardly degraded organic substance waste water both at home and abroad, it is all Such as catalytic oxidation, hydrolysis acidification method, ozone contact method, Fenton process etc. have certain effect, but there is also treatment effeciency The problems such as low, floor space is big, reagent cost is high, control program is complicated.
Utility model content
To be solved in the utility model is that current difficult degradation high-chlorine organic wastewater is difficult to process or treatment effect is not good A kind of technical problem, there is provided difficult degradation high-chlorine organic wastewater processing system based on electric flocculation, can not only ensure effluent quality Stablizing effect is good, and treatment effeciency high energy consumption is low.
In order to solve above-mentioned technical problem, this utility model is achieved by following technical scheme:
A kind of difficult degradation high-chlorine organic wastewater processing system based on electric flocculation, including preliminary sedimentation tank, oxidation ditch, second pond, Electric flocculation device, antisepsis contact tank and storage basin, anaerobic zone that wherein described oxidation ditch includes being sequentially connected, anoxic zone and aerobic Area;
The outlet of the preliminary sedimentation tank connects the water inlet of the oxidation ditch, the outlet connection described two of the oxidation ditch The water inlet in heavy pond, the outlet of the second pond connect the water inlet of the electric flocculation device, and the electric flocculation device goes out The mouth of a river connects the water inlet of the antisepsis contact tank;
The mud discharging mouth of the second pond connects entering for the mud return mouth and storage basin of anaerobic zone described in the oxidation ditch respectively Mud mouth, the mud discharging mouth of the electric flocculation device connect the mud inlet of storage basin.
Wherein, second pond institute blowdown mud is according to 1:1 ratio is divided into two parts, and a part is back to the oxidation ditch In the anaerobic zone, another part and electric flocculation device institute blowdown mud are together emitted into storage basin.
The beneficial effects of the utility model are:
(1) effective combination of the Waste Water Treatment of the present utility model based on oxidation ditch and electric flocculation technique, using oxidation The characteristics of ditch hydraulic detention time is longer, capacity of resisting impact load is stronger mitigates the process load of subsequent technique to greatest extent, together In Shi Liyong waste water, chloride ion content is higher, electrical conductivity is high, without the need for the characteristic of additional electrolyte, oxidation ditch biological treatment it Electric flocculation device intensive treatment is adopted afterwards, and not only effluent quality is well stable, and can be with while treatment effeciency is higher Appropriate reducing energy consumption;
(2) Waste Water Treatment of the present utility model goes out without the need for separately adding flocculation medicament compared with traditional coagulation-settlement process More preferably, and technology arrangement is compact for water Effects of Water Quality, and floor space is little;
(3) Waste Water Treatment of the present utility model need not additionally adopt hydrolysis acidification, O3 contacted oxidation etc. The technique of degraded hardly degraded organic substance, make use of relatively small number of technological process just can reach preferable treatment effect, existing The effect of biological treatment, the removal effect for having coagulating sedimentation again also have degraded hardly degraded organic substance and decolorization concurrently, many at one stroke , save energy consumption, it is easy to control.
Description of the drawings
Fig. 1 is the structural representation of Waste Water Treatment provided by the utility model;
Fig. 2 is the water outlet COD variation diagrams in test example;
Fig. 3 is the water outlet ss variation diagrams in test example.
In above-mentioned figure:1. preliminary sedimentation tank, 2. oxidation ditch, 3. second pond, 4. electric flocculation device, 5. antisepsis contact tank, 6. stores up mud Pond.
Specific embodiment
For content of the present utility model, feature and effect can be further appreciated that, following examples are hereby enumerated, and coordinates accompanying drawing Describe in detail as follows:
As shown in figure 1, a kind of difficult degradation high-chlorine organic wastewater processing system based on electric flocculation is present embodiments provided, should System is mainly made up of preliminary sedimentation tank 1, oxidation ditch 2, second pond 3, electric flocculation device 4, antisepsis contact tank 5 and storage basin 6.Wherein, Oxidation ditch 2 includes anaerobic zone, anoxic zone and the aerobic zone being sequentially connected.The outlet of preliminary sedimentation tank 1 connects the water inlet of oxidation ditch 2 Mouthful, the outlet of oxidation ditch 2 connects the water inlet of second pond 3, and the outlet of second pond 3 connects the water inlet of electric flocculation device 4, The outlet of electric flocculation device 4 connects the water inlet of antisepsis contact tank 5.The mud discharging mouth of second pond 3 is divided into 1:1 two branch roads, The mud return mouth of anaerobic zone in one branch road connection oxidation ditch 2, the pipe of another branch road and the mud discharging mouth for being connected to electric flocculation device 4 Road bout is simultaneously connected to the mud inlet of storage basin 6.
Waste water initially enters preliminary sedimentation tank 1, through simple physics settlement action, removes small part float and pollutant Afterwards, water outlet is carried out a biological disposal upon into oxidation ditch 2, sequentially enters anaerobic zone, anoxic zone and aerobic zone, utilize in oxidation ditch 2 Sludge system biological treatment effect removes most of pollutant.DO controls in anaerobic zone exist in below 0.1mg/L, anoxic zone DO controls Below 0.3mg/L, aerobic zone DO are controlled between 2.0-2.5mg/L, are played biological carbon and phosphorous removal in 2 process section of oxidation ditch and are made With the most pollutant of removal.2 water outlet of oxidation ditch enters second pond 3, and Jing after mud-water separation precipitation, water outlet enters electric flocculation Device 4, by various action breaks hardly degraded organic substances such as electric flocculation, electro-redox, electric floating, water pollutant is entered The reinforcing of one step is removed, and further reduces the index such as COD, TP, ss and colourity, and final reaction water outlet enters back into antisepsis contact tank 5 and enters Places sodium chlorate disinfects heel row accepting/ordering system, and effluent quality can be stably reached《Urban wastewater treatment firm pollutant are arranged Put standard》In GB18918-2002, one-level A is below the mark.
The returned sludge of second pond 3 is according to exteenal reflux 1:1 ratio is back to the anaerobic zone of oxidation ditch 2 again, supplements system Biomass needed for system, another part returned sludge then together drain into storage basin with the precipitating sludge that formed in electric flocculation device 4 6, finally processed is carried out using sludge dewatering equipment.
The electric flocculation of electric flocculation device 4 process can saboteur's stability, which makes ring molecule open loop, macromole chain rupture Characteristic can improve the biodegradability of waste water;If chloride ion content is high in water, water body electrical conductivity is high, electric flocculation processing method efficiency Also can be higher and can appropriate reducing energy consumption;Simultaneously because chloride ion radius is little, penetration capacity strong, be easily adsorbed in anode and with gold Category forms soluble compound, therefore the higher passivating film for making electrode surface of chloride ion content is more easy to perforation rupture, accelerates gold The dissolving of category passivation layer.
Test example:
Certain sewage treatment plant intakes based on industry water in industry park, and hardly degraded organic substance is more, and in water, chloride ion contains Amount is in 4000mg/L or so.The Sewage Plant chooses oxidation ditch as biological treatment according to prior art, and advanced treating is adopted Be traditional coagulation sedimentation method for adding flocculant.Transformation is being carried out using Waste Water Treatment of the present utility model Afterwards, under same secondary clarifier effluent water quality situation, system effluent quality has and is obviously improved:As shown in Figures 2 and 3, electric flocculation 4 water outlet COD of device can be controlled in below 30mg/L, and water outlet ss can be controlled substantially in 5mg/L or so;And effluent color dilution is reduced To 8 or so, the clearance of each pollutant improves.
Although being described to preferred embodiment of the present utility model above in conjunction with accompanying drawing, this utility model is not Above-mentioned specific embodiment is confined to, above-mentioned specific embodiment is only schematic, is not restricted, ability The those of ordinary skill in domain under enlightenment of the present utility model, without departing from invention objective and scope of the claimed protection feelings Under condition, the concrete conversion of many forms can also be made, and these are belonged within protection domain of the present utility model.

Claims (2)

1. a kind of difficult degradation high-chlorine organic wastewater processing system based on electric flocculation, it is characterised in that including preliminary sedimentation tank, oxidation Ditch, second pond, electric flocculation device, antisepsis contact tank and storage basin, wherein described oxidation ditch include the anaerobic zone being sequentially connected, lack Oxygen area and aerobic zone;
The outlet of the preliminary sedimentation tank connects the water inlet of the oxidation ditch, and the outlet of the oxidation ditch connects the second pond Water inlet, the outlet of the second pond connects the water inlet of the electric flocculation device, the outlet of the electric flocculation device Connect the water inlet of the antisepsis contact tank;
The mud discharging mouth of the second pond connects the mud inlet of the mud return mouth and storage basin of anaerobic zone described in the oxidation ditch respectively, The mud discharging mouth of the electric flocculation device connects the mud inlet of storage basin.
2. a kind of difficult degradation high-chlorine organic wastewater processing system based on electric flocculation according to claim 1, its feature exist In, second pond institute blowdown mud according to 1:1 ratio is divided into two parts, and what a part was back in the oxidation ditch described detests Oxygen area, another part are together emitted into storage basin with electric flocculation device institute blowdown mud.
CN201620987109.3U 2016-08-29 2016-08-29 High chlorine organic wastewater system of difficult degradation based on electricity flocculation Active CN206033506U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107522327A (en) * 2017-09-30 2017-12-29 中铁第四勘察设计院集团有限公司 The oxidation integrated papermaking wastewater treatment device of electric flocculation precipitate high grade
CN111499102A (en) * 2020-04-27 2020-08-07 中南林业科技大学 Step purification process for complex organic sewage
CN114940560A (en) * 2022-05-05 2022-08-26 中创宏远(北京)环保科技有限公司 Electric flocculation air-flotation sewage treatment process of upflow activated sludge-biofilm system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107522327A (en) * 2017-09-30 2017-12-29 中铁第四勘察设计院集团有限公司 The oxidation integrated papermaking wastewater treatment device of electric flocculation precipitate high grade
CN107522327B (en) * 2017-09-30 2020-08-18 中铁第四勘察设计院集团有限公司 Electric flocculation-precipitation-advanced oxidation integrated papermaking wastewater treatment device
CN111499102A (en) * 2020-04-27 2020-08-07 中南林业科技大学 Step purification process for complex organic sewage
CN114940560A (en) * 2022-05-05 2022-08-26 中创宏远(北京)环保科技有限公司 Electric flocculation air-flotation sewage treatment process of upflow activated sludge-biofilm system
CN114940560B (en) * 2022-05-05 2023-08-22 中创宏远(北京)环保科技有限公司 Up-flow activated sludge-biofilm system electric flocculation air floatation sewage treatment process

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