Utility model content
The purpose of this utility model is to provide a kind of Waste Water Treatment, for solving due to the salt content in waste water relatively
Height causes reaction member to corrode, and then leads to the problem that the operation of whole Waste Water Treatment and maintenance cost increase.
To achieve these goals, the utility model provides following technical scheme:
The utility model provides a kind of Waste Water Treatment, and described Waste Water Treatment includes:Separative element, for inciting somebody to action
Brine waste is separated into aqueous phase substance and nonaqueous phase material;The desalination unit being connected with described separative element, described for reducing
The salt content of aqueous phase substance;The reaction member being connected with described desalination unit, described reaction member also with described separative element phase
Even, described reaction member is used for the aqueous phase substance mixing after reducing described nonaqueous phase material and salt content, and to mixed
Waste water is degraded.
When being processed using the above-mentioned Waste Water Treatment waste water higher to salt content, first with separative element by saliferous
Waste water is separated into aqueous phase substance and nonaqueous phase material, and the nonaqueous phase material isolated is conveyed to reaction member, and aqueous phase substance is then defeated
Give the process that desalination unit carries out salt content reduction, then aqueous phase substance relatively low for salt content is conveyed to reaction member,
The aqueous phase substance in reaction member, salt content being reduced and nonaqueous phase material mixing, and this mixed waste water is degraded.
Waste water due to carrying out degradation treatment in the reaction cell had been carried out the place of salt content reduction before entering reaction member
Reason, the salt content of the waste water degraded hence into reaction member is relatively low, process waste water degraded in reaction member
In, waste water will not cause to reaction member to corrode, and reduces operation and the maintenance cost of whole Waste Water Treatment.
Specific embodiment
Understandable for enabling above-mentioned purpose of the present utility model, feature and advantage to become apparent from, below in conjunction with accompanying drawing, right
The technical solution of the utility model is clearly and completely described.Obviously, described embodiment is only the utility model one
Section Example, rather than whole embodiments.Based on the embodiment in the utility model, those of ordinary skill in the art are not having
There is all other embodiment being obtained on the premise of making creative work, belong to the scope of the utility model protection.
As shown in figure 1, this example provides a kind of Waste Water Treatment, this Waste Water Treatment includes:Separative element 11,
Desalination unit 22 and reaction member 33.Separative element 11 is used for for brine waste being separated into aqueous phase substance and nonaqueous phase material;De-
Salt unit 22 is connected with separative element 11, for reducing the salt content of aqueous phase substance;Reaction member 33 respectively with separative element 11
It is connected with desalination unit 22, this reaction member 33 is used for the aqueous phase substance mixing after reducing nonaqueous phase material and salt content, and
Mixed waste water is degraded.
The detailed process referring again to the Waste Water Treatment in Fig. 1, this example can be:First, brine waste is sent into
Separative element 11, brine waste is separated into aqueous phase substance and nonaqueous phase material by separative element 11, and wherein, nonaqueous phase material conveys
To reaction member 33;And aqueous phase substance is then conveyed to desalination unit 22, and complete the place of salt content reduction in desalination unit 22
Reason, the aqueous phase substance after reducing salt content afterwards is conveyed to reaction member 33, in this reaction member 33, after salt content reduces
Aqueous phase substance and nonaqueous phase material mixing, and mixed waste water degrades, thus completing the process work of waste water, now
Waste water after the completion of degraded can be discharged.
Reduce because the waste water of degradation treatment in the reaction cell had been carried out salt content before entering reaction member
Process, the salt content of the waste water degraded hence into reaction member is relatively low, in reaction member, waste water is degraded
During, waste water will not cause to reaction member to corrode, and reduces operation and the maintenance cost of whole Waste Water Treatment.
In order to preferably nonaqueous phase material be isolated from waste water, as shown in Fig. 2 the separative element 11 in the present embodiment
Preferably may include:Solid-liquid separator 1, and it is connected to the oil water separator 2 between solid-liquid separator 1 and desalination unit 22, Gu
Liquid/gas separator 1 is also all connected with reaction member 33 with oil water separator 2.Wherein, solid-liquid separator 1 is used for being separated into admittedly waste water
Phase material and liquid phase substance, the solid matter isolated is delivered directly to reaction member 33, and liquid phase substance is then conveyed to profit
Separator 2, oil water separator 2 is used for for liquid phase substance being separated into oil phase substance and aqueous phase substance, and the aqueous phase substance isolated is entered
Enter to carry out the process of salt content reduction in desalination unit 22, the oil phase substance isolated then is conveyed to reaction member 33.Due to entering
Enter waste water in desalination unit 22 by water-fast macromolecular particle or solid granulates (i.e. solid matter and oil phase thing
Matter) isolate, it is only the aqueous phase substance of saliferous, thus ensure that desalination unit 22 preferably can carry out saliferous to aqueous phase substance
Amount carries out reduction process, and avoids macromolecular particle in waste water or solid granulates cause to desalination unit to damage.
Preferably may include desalination modular array 3, concentrated water pond 4 and light referring to mentioned desalination unit 22 in Fig. 2, this example
Pond 5.Desalination modular array 3 is connected with separative element 11, for aqueous phase substance is separated into less salt aqueous phase substance and high salt aqueous phase
Material.Concentrated water pond 4 is connected with desalination modular array 3, for storing the high salt aqueous phase substance that desalination modular array 3 is isolated.Fresh-water pool 5
It is connected between desalination modular array 3 and reaction member 33, for storing the less salt aqueous phase substance that desalination modular array 3 is isolated.?
In wastewater treatment process, less salt aqueous phase substance is conveyed to reaction member 33, and in reaction member 33, less salt aqueous phase substance (contains
Aqueous phase substance after the reduction of salt amount) mix with the solid matter isolated and oil phase substance from separative element 11, wait at degraded
Reason.
The desalination modular array that the present embodiment refers to preferably may include milipore filter, NF membrane, reverse osmosis membrane and Bipolar Membrane
Any one or a few.In desalination modular array, aqueous phase substance is carried out in the processing procedure of salt content reduction, can be according to aqueous-phase material
In matter, one or more of contained concrete salt component selections milipore filter, NF membrane, reverse osmosis membrane and Bipolar Membrane are applied in combination, and
The aqueous phase substance needing the process carrying out salt content reduction can be processed repeatedly, so that the salt content required for obtaining is relatively low
Aqueous phase substance.
Refer again to Fig. 2, in order to carry out degradation treatment to waste water, make waste water reach the reaction in discharge standard, this example
Unit 33 preferably may include:Pond 6 with slurry, heat exchanger 7, reactor 8 and pressure unit 9.In pond 6 with slurry and desalination unit 22
Fresh-water pool 5 is connected, and pond 6 with slurry is used for transferring out by the nonaqueous phase material isolated from separative element 11 with from fresh-water pool 5
Less salt aqueous phase material mixing.Heat exchanger 7 is connected with pond 6 with slurry, and heat exchanger 7 is used for mixing that pond 6 with slurry conveying comes
Waste water is preheated, so that waste water is close to or up the temperature required for degraded.Reactor 8 is connected with heat exchanger 7, reactor 8
Waste water for completing to preheating carries out degradation treatment, and the waste water that degraded is completed is transmitted back to heat exchanger 7.Now, conveyed
The waste water after the completion of degraded in heat exchanger 7 carries out cooling process in the heat exchanger 7.Pressure unit 9 is connected with heat exchanger 7,
Pressure unit 9 is used for carrying out step-down process to the waste water after the completion of the degraded being transported in heat exchanger 7.
The specific work process of this reaction member can be:The solid matter isolated in separative element 11 and oil phase substance quilt
It is transported to the pond with slurry 6 of reaction member 33, less salt aqueous phase substance is transported to pond 6 with slurry from fresh-water pool 5, now, in pond 6 with slurry
Interior, carry out the mixing to solid matter, oil phase substance and less salt aqueous phase substance.Preferably should accomplish during mixing to be sufficiently mixed, this
It is more thorough that sample can make subsequent degradation process, and reduces follow-up work amount.Mixed waste water is transported to heat exchanger from pond 6 with slurry
In 7, in the heat exchanger 7 the pre-heat treatment is carried out to waste water, the temperature making waste water is close to or up the required temperature of degraded.Afterwards will
Preheat the waste water completing and be delivered in reactor 8 and carry out wastewater degradation process, that is, under high pressure and high temperature condition, wastewater degradation is become
The simply nontoxic micromolecular compound such as water, carbon dioxide.Then, the waste water after the completion of degraded is transmitted back to heat exchanger 7
In carry out cooling process.In actual motion, the processing procedure of waste water is continual, in order to make full use of resource, after mixing
The required heat of waste water preheating can directly utilize the heat produced by waste water cooling after the completion of degraded.The present embodiment is preferred
, heat exchanger 7 can be arranged to double-tube structure, the mixed waste water (waste water to be preheated) transferring out from pond 6 with slurry enters
Enter a sleeve pipe of heat exchanger 7, and the waste water (waste water to be lowered the temperature) after the completion of the degraded that reactor 8 is transmitted back to enters heat exchange
Another sleeve pipe of device 7, because the waste water after the completion of degraded needs to carry out cooling process, mixed waste water needs to be preheated
Process, therefore just as the heat that preheating is required, such design cycle decreases wastewater treatment to cooling dispersed heat
Operating procedure, also makes heat resources be fully utilized simultaneously.Finally, the waste water after cooling (waste water after the completion of degraded)
Enter pressure unit 9 and carry out step-down process, can discharge after the completion of process.
The reaction member 33 of the present embodiment may also include positioned at the low-lift pump between pond 6 with slurry and heat exchanger 7 and high-pressure pump,
Pond 6 with slurry, low-lift pump, high-pressure pump and heat exchanger 7 are sequentially connected.Above-mentioned low-lift pump is used for making the pressure of the waste water from low-lift pump output
Power meets the inlet pressure requirements of high-pressure pump, if the inlet pressure requirements of high-pressure pump are 0.1MPa~0.6MPa, from low-lift pump
The pressure of the waste water transferring out can be preferably 0.3MPa.Above-mentioned high-pressure pump is used for making the pressure of the waste water from high-pressure pump output full
Foot degrades required pressure requirements it is preferred that the pressure from the waste water of high-pressure pump output should reach 22.1MPa in reactor 8
More than, to reach the pressure requirements needed for degrading waste water.
Reactor 8 concretely overcritical water oxidization reactor in the present embodiment, thus can be utilized supercritical water oxidation
The slurry that method completes to preheating carries out degradation treatment, and above-mentioned slurry is degraded into the simply nontoxic small molecule such as water, carbon dioxide
Compound, reaches discharge standard.
In order to make full use of resource, heat exchanger 7 can be connected with concentrated water pond 4, the waste heat that heat exchanger 7 is produced is transported to dense
In pond.In actual moving process, the waste heat that heat exchanger 7 produces can reach 150 DEG C, is therefore conveyed to this part of waste heat dense
Pond 4, can promote the moisture in concentrated water pond 4 to evaporate further.Specifically, can be by guide cylinder by heat exchanger 7 in this example
The waste heat producing is transported in concentrated water pond 4.
The above, specific embodiment only of the present utility model, but protection domain of the present utility model does not limit to
In this, any those familiar with the art, in the technical scope that the utility model discloses, can readily occur in change
Or replace, all should cover within protection domain of the present utility model.Therefore, protection domain of the present utility model should be with described power
The protection domain that profit requires is defined.