CN205907208U - A anti -icing antifog transparent conducting film of electrical heating for invisbile plane - Google Patents
A anti -icing antifog transparent conducting film of electrical heating for invisbile plane Download PDFInfo
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- CN205907208U CN205907208U CN201620814940.9U CN201620814940U CN205907208U CN 205907208 U CN205907208 U CN 205907208U CN 201620814940 U CN201620814940 U CN 201620814940U CN 205907208 U CN205907208 U CN 205907208U
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 69
- 239000010410 layer Substances 0.000 claims abstract description 370
- 239000011521 glass Substances 0.000 claims abstract description 25
- 239000002346 layers by function Substances 0.000 claims abstract description 24
- 239000012528 membrane Substances 0.000 claims abstract description 21
- 239000011241 protective layer Substances 0.000 claims abstract description 13
- 238000005485 electric heating Methods 0.000 claims abstract description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 72
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 46
- 229910052719 titanium Inorganic materials 0.000 claims description 46
- 239000010936 titanium Substances 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 32
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 32
- 229910052710 silicon Inorganic materials 0.000 claims description 32
- 239000010703 silicon Substances 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 30
- 238000000576 coating method Methods 0.000 claims description 30
- 239000012790 adhesive layer Substances 0.000 claims description 25
- 239000000758 substrate Substances 0.000 claims description 25
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 23
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 20
- 229910000611 Zinc aluminium Inorganic materials 0.000 claims description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- 229910000484 niobium oxide Inorganic materials 0.000 claims description 12
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims description 12
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 238000003475 lamination Methods 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229920005479 Lucite® Polymers 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- DUFGEJIQSSMEIU-UHFFFAOYSA-N [N].[Si]=O Chemical compound [N].[Si]=O DUFGEJIQSSMEIU-UHFFFAOYSA-N 0.000 claims 1
- 230000003287 optical effect Effects 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 63
- 238000005260 corrosion Methods 0.000 description 13
- 230000007797 corrosion Effects 0.000 description 13
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 238000002834 transmittance Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 230000005611 electricity Effects 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000000007 visual effect Effects 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000011253 protective coating Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000012780 transparent material Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- JYMITAMFTJDTAE-UHFFFAOYSA-N aluminum zinc oxygen(2-) Chemical compound [O-2].[Al+3].[Zn+2] JYMITAMFTJDTAE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
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- 238000004134 energy conservation Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
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- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- Surface Heating Bodies (AREA)
Abstract
The utility model discloses an anti -icing antifog transparent conducting film of electrical heating for invisbile plane, a anti -icing antifog transparent conducting film of electrical heating for invisbile plane includes A face and B face, be provided with different transparent film on A face and the B face respectively, the A face is electric heating film system, and the B face is stealthy function membrane system, electric heating film system is electrical heating adhesion layer, electrical heating functional layer and electrical heating protective layer by the glass basement from inside to outside in proper order, stealthy function membrane system is stealthy adhesion layer, stealthy functional layer and stealthy protective layer by the glass basement from inside to outside in proper order. The utility model discloses realizing radar stealth and the anti -icing anti -fog function of electrical heating, controllable, the radar wave reflective capability of optical property, satisfying the stealthy and demand of aircraft, the characteristic signal who reflects back the radar reduces more than the 10dB, and the visible light transmissivity can improve to more than 80%.
Description
Technical field
This utility model is related to electro-conductive glass manufacturing technology field and in particular to a kind of electrical heating for invisbile plane is prevented
The antifog nesa coating of ice.
Background technology
Stealthyization is one of aircraft future important development technology, and passenger cabin, radar module, air intake duct are that aircraft is most important
Three scattering sources, substrate of glass, as Transparent Parts, first meets Stealth Fighter first, that is, has stronger radar reflection ability, seat
Cabin is stealthy mainly to control thin film that cavity strong scattering is converted into outside substrate of glass by being coated with one layer of electromagnetic wave on the glass substrate
Surface weak scattering, improves Stealth Fighter.The stealthy membrane system of current passenger cabin adopts tin indium oxide monofilm or titanium oxide/titanium/oxidation
Titanium multilayer film, its functional realiey is completed by tin indium oxide and Titanium, and other layers are used for the protection to functional layer, for improving radar
Film layer thickening simply can be brought the aspects such as color, visible light transmissivity, film adhesion to lose by reflecting properties.
In flight course, typically run into sleety weather or the impact due to state of flight change causes substrate of glass substrate
Produce fogging or even icing phenomenon, aircraft runs into low latitude high humidity in the internal-external temperature difference of high-altitude flying for long time or flight from high to low
During environment, passenger cabin occurs fogging phenomenon, and this icing fogging phenomenon causes pilot visual field comfort level to be deteriorated, or even occurs regarding
Feel distortion, serious threat airfight tasks secure.In order to improve flight safety, should ensure that the sufficient pilot visual field, this
One requires to comprise two aspect contents, and one is high visible light transmissivity, and two is in-flight to have serious icing fogging phenomenon,
This requires aircraft to have further requirement in the performance such as anti-icing anti-fog performance or even energy-conservation.Aircraft Transparent Parts anti-icing antifog
Can be realized by electrical heating nesa coating, take into account visible light transmissivity and anti-icing antifog demand simultaneously.By online or from
Line plated film production technology is sequentially depositing single or multiple lift transparent conductive film layer according to design requirement canopy transparent materials are two-sided, realizes
The high reflection of multiple frequency electromagnetic, improves passenger cabin Stealth Fighter, and comprehensive visible ray, ultrared alternative are passed through and cut
Only, meet the visual field to require, further, the suitable low resistance of passenger cabin nesa coating can meet electrical heating demand, solves passenger cabin saturating
The anti-icing antifog phenomenon of bright part.
Stealthy aircraft for fighting may face different combat environments it is necessary to due regard to wet environment, wet
Salt environment, high temperature low temperature environment etc., the nesa coating of inevitable requirement canopy transparent materials is in acid and alkali-resistance salt corrosion performance, outstanding
Weather resistance and mechanical performance, to meet the work requirements of advanced stealthy aircraft.
The substrate of glass being presently used for invisbile plane all realizes electromagnetic wave using single oxide film or simple metal film layer
Reflection, adopts merely that tin indium oxide film layer light transmittance is relatively low and radar reflection effect is slightly worse, and adopts simple metal film, corrosion resistant
Erosion, weatherability, rub resistance are poor;Simultaneously it is contemplated that flight safety problem, lack a kind of anti-icing anti-fog performance for stealthy
The anti-icing antifog nesa coating of electrical heating of aircraft.
Utility model content
The purpose of this utility model is for the problems referred to above, provides a kind of electricity for invisbile plane of anti-icing anti-fog performance
Heat anti-icing antifog nesa coating.
For reaching above-mentioned purpose, this utility model employs following technical proposal: one kind of the present utility model is for stealthy
The anti-icing antifog nesa coating of electrical heating of aircraft, the anti-icing antifog nesa coating of the described electrical heating for invisbile plane includes
A face and b face, described a face and b face are respectively arranged with different transparent membranes, and a face is electrical heating membrane system, and b face is stealthy function
Membrane system;
Described electrical heating membrane system is followed successively by electrical heating adhesive layer, electric heating function layer and electricity from inside to outside by substrate of glass and adds
Thermal-protective coating;Described stealthy functional film system is followed successively by stealthy adhesive layer, stealthy functional layer and stealthy from inside to outside by substrate of glass
Protective layer.Two sides adhesive layer is used for stoping foreign ion element from entering film layer functional layer impact effect, and improves adhesive force, and then
Adjustment film layer visible light transmissivity, color matching;Two sides protective layer used in protection a/b face mask series functional layer, improve membrane system weather-proof
Property, corrosion resistance and mechanical performance.
Further, described substrate of glass is passenger cabin lucite substrate.
Further, described electrical heating adhesive layer is made up of two continuous film layers, and described two continuous film layers include
First silicon oxide layer or the first silicon oxynitride layer, the first zinc aluminium oxide layer, described first silicon oxide layer or the first silicon oxynitride layer
Thicknesses of layers be 18~25nm, the thicknesses of layers of the first zinc aluminium oxide layer is 75~115nm.Electrical heating adhesive layer can improve film
Possess certain conductive capability while layer adhesive force, be conducive to improving anti-icing anti-fog effect;
Further, described electric heating function layer is made up of four continuous film layers, described four continuous film layer bags
Include the first layer of titanium metal or metallic silver layer, the first titanium oxide layer, niobium oxide layer, the first indium tin oxide layer, described first Titanium
The thicknesses of layers of layer or metallic silver layer is 6~11nm, and the thicknesses of layers of the first titanium oxide layer is 15~22nm, the film of niobium oxide layer
Thickness degree is 10~15nm, and the thicknesses of layers of the first indium tin oxide layer is 120~165nm.
In functional layer, each layer is realized low resistance and is ensured light transmittance demand, and low resistance is used for the anti-icing antifog work(of electrified regulation
Can, it is provided simultaneously with certain radar, infrared external reflection ability;
Further, described electric heater frost protection layer be the second titanium oxide layer or titanium nitride layer, described second titanium oxide layer or
The thicknesses of layers of titanium nitride layer is 65~150nm;Described a face electrical heating transparent conductive film layer both sides coating conductive silver paste or copper electricity
Pole is connected with electrical heating power supply.
Further, described stealthy adhesive layer is followed successively by the second silicon oxide layer or the second silicon oxynitride layer and from inside to outside
Zinc oxide aluminium lamination, the thicknesses of layers of described second silicon oxide layer or the second silicon oxynitride layer is 18~25nm, the second zinc oxide
The thicknesses of layers of aluminium lamination is 25~40nm.
Further, described stealthy functional layer be followed successively by from inside to outside the first zirconia layer, the second layer of titanium metal, second
Zirconia layer, the 3rd layer of titanium metal and the 3rd zirconia layer, the thicknesses of layers of described first zirconia layer is 20~40nm, described
The thicknesses of layers of the second zirconia layer is 10~15nm, and the thicknesses of layers of described 3rd zirconia layer is 2~20nm, the second metal
The thicknesses of layers of titanium layer is 6~8nm, and the thicknesses of layers of described 3rd layer of titanium metal is 4~6nm.
First layer of titanium metal and the second layer of titanium metal are the stealthy functional layer of passenger cabin, realize radar reflection ability, simultaneously simultaneous
Turn round and look at infrared energy-conserving and ultraviolet cut-on performance, three layers of zirconia layer improve to Stealth Fighter certain assosting effect;
Further, described stealthy protective layer includes the second indium tin oxide layer and the 3rd silicon oxynitride from inside to outside successively
Layer, the thicknesses of layers of described second indium tin oxide layer is 150~265nm, the thicknesses of layers of the 3rd silicon oxynitride layer is 65~
150nm.Tin indium oxide possesses outstanding corrosion-resistant and conductive capability, meets weatherability, corrosion resistance simultaneously and improves stealth
Can, silicon oxynitride has outstanding crocking resistance and decay resistance, and strong with tin indium oxide adhesion, for whole film
The protection further of system, and improve service life.
Beneficial effect: this utility model realizes radar invisible and the anti-icing anti-fog function of electrical heating, optical property be controlled, radar wave
Reflectance, meets Stealth and demand simultaneously, and the characteristic signal that simultaneously, can be reflected back radar reduces more than 10db, can
See that light transmission rate can improve to more than 80%.The anti-icing anti-fog function of electrical heating is realized in inner side, and radar reflection ability is realized in outside, and two
Side form layer function is complementary to one another auxiliary, realizes the anti-icing anti-fog function of high transmission rate, high Stealth Fighter, and film layer is corrosion-resistant strong, resistance to
Time property is outstanding, and stable processing technique is controlled, and parameter can achieve autonomy-oriented adjustment.
Compared with prior art, this utility model has the advantage that
(1) between each functional layer of structure adjusting double-sided transparent conducting film layer, oxide conducting film layer and other film layers
Matching relationship and deposition process parameters, the scattering of achievable electromagnetism wave height, visible ray be highly transmissive, low areal resistance from main modulation, film
System, in addition to meeting necessary Stealth Fighter, anti-icing anti-fog performance, is also equipped with infrared high reflection, ultraviolet cutoff performance.
(2) stability under the bad weather condition such as high temperature low temperature environment, wet salt environment, hygrothermal environment and longevity are considered
Life, provides insulation blocking using protective layer to functional film layer;The adhesive layer that internal layer increases can improve film adhesion, meanwhile, every
From functional film layer contact with glass impurities ion, improve film performance parameter.Comprehensive adopt the sandwich of zirconium oxide and Titanium
Formula realizes radar high reflection, low resistance, simultaneously adjustment visible light transmittance rate, infrared and ultraviolet cut-off adjustment, the oxygen of join protection layer
Change indium stannum, lift Stealth Fighter further, and ensure the relatively stable of each performance parameter.
(3) stealthy membrane system and electrical heating membrane system adopt the Titanium of stable chemical performance and corrosion resistant conductive oxide:
Zirconium oxide, tin indium oxide etc., comprehensively improve the stability of performance parameter, can meet the corrosion-resistant of double-sided transparent conducting film simultaneously
Performance, mechanical performance and weatherability.Electrical heating film layer combines the conductive film layer such as Titanium and tin indium oxide, and surface resistance can adjust,
There is provided the energy by external power supply, improve substrate of glass temperature, prevent substrate of glass icing fogging, and can be to Stealth Fighter one
Determine to have auxiliaring effect in degree.
Brief description
The schematic diagram of the anti-icing antifog nesa coating of Fig. 1 electrical heating for invisbile plane of the present utility model;
Wherein, 0 substrate of glass, to a face, 1-11 first silicon oxide or the first silicon oxynitride layer, 1-12 first zinc oxide aluminum
Layer, 1-21 first layer of titanium metal or metallic silver layer, 1-22 first titanium oxide layer, 1-23 niobium oxide layer, 1-24 first tin indium oxide
Layer, 1-3 second titanium oxide layer or titanium nitride layer;To b face, 2-11 second silicon oxide or the second silicon oxynitride layer, 2-12 second oxygen
Change zinc-aluminium layer, 2-21 first zirconia layer, 2-22 second layer of titanium metal, 2-23 second zirconia layer, 2-24 the 3rd layer of titanium metal,
2-25 the 3rd zirconia layer, 2-31 second indium tin oxide layer, 2-32 the 3rd silicon oxynitride layer.
Specific embodiment
For making the purpose of this utility model, technical scheme and advantage clearer, new to this practicality below in conjunction with accompanying drawing
The embodiment of type is described in further detail.
Embodiment 1
A kind of anti-icing antifog nesa coating of electrical heating for invisbile plane of the present utility model, described flies for stealthy
The anti-icing antifog nesa coating of electrical heating of machine includes a face and b face, described a face and b face being respectively arranged with different thin transparent
Film, a face is electrical heating membrane system, and b face is stealthy functional film system;
Described electrical heating membrane system is followed successively by electrical heating adhesive layer, electric heating function layer and electricity from inside to outside by substrate of glass and adds
Thermal-protective coating;Described stealthy functional film system is followed successively by stealthy adhesive layer, stealthy functional layer and stealthy from inside to outside by substrate of glass
Protective layer.
Two sides adhesive layer is used for stoping foreign ion element from entering film layer functional layer impact effect, and improves adhesive force, enters
And adjust film layer visible light transmissivity, color matching;Two sides protective layer used in protection a/b face mask series functional layer, improve membrane system resistance to
Hou Xing, corrosion resistance and mechanical performance.
Described substrate of glass is passenger cabin lucite substrate.
Described electrical heating adhesive layer is made up of two continuous film layers, and described two continuous film layers include the first silicon oxide
Layer 1-11, the first zinc aluminium oxide layer 1-12, the thicknesses of layers of described first silicon oxide layer 1-11 is 18nm, the first zinc aluminium oxide layer
The thicknesses of layers of 1-12 is 115nm,
Electrical heating adhesive layer possesses certain conductive capability while can improving film adhesion, is conducive to improving anti-icing anti-
Fog effect;
Described electric heating function layer is made up of four continuous film layers, and described four continuous film layers include metallic silver layer 1-
21st, the first titanium oxide layer 1-22, niobium oxide layer 1-23, the first indium tin oxide layer 1-24, the film layer of described metallic silver layer 1-21 is thick
Spend for 6nm, the thicknesses of layers of the first titanium oxide layer 1-22 is 22nm, the thicknesses of layers of niobium oxide layer 1-23 is 10nm, the first oxygen
The thicknesses of layers changing indium tin layer 1-24 is 155nm.
In functional layer, each layer is realized low resistance and is ensured light transmittance demand, and low resistance is used for the anti-icing antifog work(of electrified regulation
Can, it is provided simultaneously with certain radar, infrared external reflection ability;
Described electric heater frost protection layer is the second titanium oxide 1-3, and the thicknesses of layers of described second titanium oxide 1-3 is 65nm;Institute
State a face electrical heating transparent conductive film layer both sides coating conductive silver paste electrode to be connected with electrical heating power supply.
Described stealthy adhesive layer is followed successively by the second silicon oxide layer 2-11 and the second zinc aluminium oxide layer 2-12 from inside to outside, described
The thicknesses of layers of the second silicon oxide layer 2-11 is 25nm, and the thicknesses of layers of the second zinc aluminium oxide layer 2-12 is 25nm;
Described stealthy functional layer is followed successively by the first zirconia layer 2-21, the second layer of titanium metal 2-22, the second oxygen from inside to outside
Change zirconium layer 2-23, the 3rd layer of titanium metal 2-24 and the 3rd zirconia layer 2-25, the thicknesses of layers of described first zirconia layer 2-21
For 20nm, the thicknesses of layers of described second zirconia layer 2-23 is 15nm, and the thicknesses of layers of described 3rd zirconia layer 2-25 is
2nm, the thicknesses of layers of the second layer of titanium metal 2-22 is 8nm, and the thicknesses of layers of described 3rd layer of titanium metal 2-24 is 4nm.
Second layer of titanium metal 2-22 and the 3rd layer of titanium metal 2-24 are the stealthy functional layer of passenger cabin, realize radar reflection energy
Power, takes into account infrared energy-conserving and ultraviolet cut-on performance, three layers of zirconia layer improve to Stealth Fighter certain assosting effect simultaneously;
Described stealthy protective layer includes the second indium tin oxide layer 2-31 and the 3rd silicon oxynitride layer 2-32 from inside to outside successively,
The thicknesses of layers of described second indium tin oxide layer 2-31 is 150nm, and the thicknesses of layers of the 3rd silicon oxynitride layer 2-32 is 150nm.
Described tin indium oxide possesses outstanding corrosion-resistant and conductive capability, meets weatherability, corrosion resistance simultaneously and improves Stealth Fighter,
Silicon oxynitride has outstanding crocking resistance and decay resistance, and strong with tin indium oxide adhesion, for whole membrane system
Protection further, and improve service life.
This utility model adopts magnetron sputtering mode to deposit two kinds of functional film system on substrate of glass two sides respectively, realizes respectively
Stealthy and electrical heating, membrane system has Stealth Fighter high (characteristic signal being reflected back radar reduces more than 10db), electrical heating performance
Outstanding feature, and ensure that enough light transmittances (more than 80%) meet the flight visual field, consider mechanical performance, film layer causes simultaneously
Density is high, uniformity is good, has higher adhesive force and outstanding wear-resisting weather-proof.
Embodiment 2
Embodiment 2 is with the difference of embodiment 1:
A kind of anti-icing antifog nesa coating of electrical heating for invisbile plane of the present utility model, described flies for stealthy
The anti-icing antifog nesa coating of electrical heating of machine includes a face and b face, described a face and b face being respectively arranged with different thin transparent
Film, a face is electrical heating membrane system, and b face is stealthy functional film system;
Described electrical heating adhesive layer is made up of two continuous film layers, and described two continuous film layers include the first nitrogen oxidation
Silicon layer 1-11, the first zinc aluminium oxide layer 1-12, the thicknesses of layers of described first silicon oxynitride layer 1-11 is 22nm, the first zinc oxide
The thicknesses of layers of aluminium lamination 1-12 is 75nm,
Electrical heating adhesive layer possesses certain conductive capability while can improving film adhesion, is conducive to improving anti-icing anti-
Fog effect;
Described electric heating function layer is made up of four continuous film layers, and described four continuous film layers include the first Titanium
Layer 1-21, the first titanium oxide layer 1-22, niobium oxide layer 1-23, the first indium tin oxide layer 1-24, described first layer of titanium metal 1-21
Thicknesses of layers be 8nm, the thicknesses of layers of the first titanium oxide layer 1-22 is 15nm, and the thicknesses of layers of niobium oxide layer 1-23 is
The thicknesses of layers of 15nm, the first indium tin oxide layer 1-24 is 120nm.
In functional layer, each layer is realized low resistance and is ensured light transmittance demand, and low resistance is used for the anti-icing antifog work(of electrified regulation
Can, it is provided simultaneously with certain radar, infrared external reflection ability;
Described electric heater frost protection layer is titanium nitride layer 1-3, and the thicknesses of layers of described titanium nitride layer 1-3 is 90nm;Described a face
The coating of electrical heating transparent conductive film layer both sides is led copper electrode and is connected with electrical heating power supply.
Described stealthy adhesive layer is followed successively by the second silicon oxynitride layer 2-11 and the second zinc aluminium oxide layer 2-12, institute from inside to outside
The thicknesses of layers stating the second silicon oxynitride layer 2-11 is 20nm, and the thicknesses of layers of the second zinc aluminium oxide layer 2-12 is 30nm;
Described stealthy functional layer is followed successively by the first zirconia layer 2-21, the second layer of titanium metal 2-22, the second oxygen from inside to outside
Change zirconium layer 2-23, the 3rd layer of titanium metal 2-24 and the 3rd zirconia layer 2-25, the thicknesses of layers of described first zirconia layer 2-21
For 30nm, the thicknesses of layers of described second zirconia layer 2-23 is 10nm, and the thicknesses of layers of described 3rd zirconia layer 2-25 is
13nm, the thicknesses of layers of the second layer of titanium metal 2-22 is 6nm, and the thicknesses of layers of described 3rd layer of titanium metal 2-24 is 5nm.
Second layer of titanium metal 2-22 and the 3rd layer of titanium metal 2-24 are the stealthy functional layer of passenger cabin, realize radar reflection energy
Power, takes into account infrared energy-conserving and ultraviolet cut-on performance, three layers of zirconia layer improve to Stealth Fighter certain assosting effect simultaneously,
Described stealthy protective layer includes the second indium tin oxide layer 2-31 and the 3rd silicon oxynitride layer 2-32 from inside to outside successively,
The thicknesses of layers of described second indium tin oxide layer 2-31 is 265nm, and the thicknesses of layers of the 3rd silicon oxynitride layer 2-32 is 120nm.
Described tin indium oxide possesses outstanding corrosion-resistant and conductive capability, meets weatherability, corrosion resistance simultaneously and improves Stealth Fighter,
Silicon oxynitride has outstanding crocking resistance and decay resistance, and strong with tin indium oxide adhesion, for whole membrane system
Protection further, and improve service life.
Embodiment 3
Embodiment 3 is with the difference of embodiment 1:
A kind of anti-icing antifog nesa coating of electrical heating for invisbile plane of the present utility model, described flies for stealthy
The anti-icing antifog nesa coating of electrical heating of machine includes a face and b face, described a face and b face being respectively arranged with different thin transparent
Film, a face is electrical heating membrane system, and b face is stealthy functional film system;
Described electrical heating membrane system is followed successively by electrical heating adhesive layer, electric heating function layer and electricity from inside to outside by substrate of glass and adds
Thermal-protective coating;Described stealthy functional film system is followed successively by stealthy adhesive layer, stealthy functional layer and stealthy from inside to outside by substrate of glass
Protective layer.
Described electrical heating adhesive layer is made up of two continuous film layers, and described two continuous film layers include the first silicon oxide
Layer or the first silicon oxynitride layer 1-11, the first zinc aluminium oxide layer 1-12, described first silicon oxide layer or the first silicon oxynitride layer 1-
11 thicknesses of layers is 25nm, and the thicknesses of layers of the first zinc aluminium oxide layer 1-12 is 95nm,
Electrical heating adhesive layer possesses certain conductive capability while can improving film adhesion, is conducive to improving anti-icing anti-
Fog effect;
Described electric heating function layer is made up of four continuous film layers, and described four continuous film layers include the first Titanium
Layer 1-21, the first titanium oxide layer 1-22, niobium oxide layer 1-23, the first indium tin oxide layer 1-24, described first layer of titanium metal 1-21
Thicknesses of layers be 11nm, the thicknesses of layers of the first titanium oxide layer 1-22 is 18nm, and the thicknesses of layers of niobium oxide layer 1-23 is
The thicknesses of layers of 12nm, the first indium tin oxide layer 1-24 is 165nm.
In functional layer, each layer is realized low resistance and is ensured light transmittance demand, and low resistance is used for the anti-icing antifog work(of electrified regulation
Can, it is provided simultaneously with certain radar, infrared external reflection ability;
Described electric heater frost protection layer is the second titanium oxide layer or titanium nitride layer 1-3, described second titanium oxide layer or titanium nitride
The thicknesses of layers of layer 1-3 is 150nm;Described a face electrical heating transparent conductive film layer both sides coating conductive silver paste electrode and electrical heating
Power supply is connected.
Described stealthy adhesive layer is followed successively by the second silicon oxide layer 2-11 and the second zinc aluminium oxide layer 2-12 from inside to outside, described
The thicknesses of layers of the second silicon oxide layer 2-11 is 18nm, and the thicknesses of layers of the second zinc aluminium oxide layer 2-12 is 40nm;
Described stealthy functional layer is followed successively by the first zirconia layer 2-21, the second layer of titanium metal 2-22, the second oxygen from inside to outside
Change zirconium layer 2-23, the 3rd layer of titanium metal 2-24 and the 3rd zirconia layer 2-25, the thicknesses of layers of described first zirconia layer 2-21
For 40nm, the thicknesses of layers of described second zirconia layer 2-23 is 12nm, and the thicknesses of layers of described 3rd zirconia layer 2-25 is
20nm, the thicknesses of layers of the second layer of titanium metal 2-22 is 7nm, and the thicknesses of layers of described 3rd layer of titanium metal 2-24 is 6nm.
Described stealthy protective layer includes the second indium tin oxide layer 2-31 and the 3rd silicon oxynitride layer 2-32 from inside to outside successively,
The thicknesses of layers of described second indium tin oxide layer 2-31 is 235nm, and the thicknesses of layers of the 3rd silicon oxynitride layer 2-32 is 65nm.
Although more employing substrate of glass 0 herein, the first silicon oxide or the first silicon oxynitride layer 1-11, the first oxidation
Zinc-aluminium layer 1-12, the first layer of titanium metal or metallic silver layer 1-21, the first titanium oxide layer 1-22, niobium oxide layer 1-23, the first oxidation
Indium tin layer 1-24, the second titanium oxide layer or titanium nitride layer 1-3, the second silicon oxide or the second silicon oxynitride layer 2-11, the second oxidation
Zinc-aluminium layer 2-12, the first zirconia layer 2-21, the second layer of titanium metal 2-22, the second zirconia layer 2-23, the 3rd layer of titanium metal 2-
24, the 3rd zirconia layer 2-25, second indium tin oxide layer 2-31, the term such as the 3rd silicon oxynitride layer 2-32, but be not precluded from making
Probability with other terms.It is used for the purpose of more easily describing and explaining essence of the present utility model using these terms;
It is all contrary with this utility model spirit for being construed as any additional restriction.
Specific embodiment described herein is only explanation for example to this utility model spirit.This utility model institute
Belong to those skilled in the art described specific embodiment can be made with various modifications or supplement or using similar
Mode substitute, but without departing from of the present utility model spirit or surmount scope defined in appended claims.
Claims (8)
1. a kind of anti-icing antifog nesa coating of the electrical heating for invisbile plane it is characterised in that: described for invisbile plane
The anti-icing antifog nesa coating of electrical heating include a face and b face, described a face and b face being respectively arranged with different thin transparent
Film, a face is electrical heating membrane system, and b face is stealthy functional film system;
Described electrical heating membrane system is followed successively by electrical heating adhesive layer, electric heating function layer and electrical heating from inside to outside by substrate of glass and protects
Sheath;Described stealthy functional film system is followed successively by stealthy adhesive layer, stealthy functional layer and stealthy protection from inside to outside by substrate of glass
Layer.
2. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to claim 1 it is characterised in that: institute
Stating substrate of glass is passenger cabin lucite substrate.
3. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to claim 1 it is characterised in that: institute
State electrical heating adhesive layer to be made up of two continuous film layers, described two continuous film layers include the first silicon oxide layer or the first nitrogen
Silicon oxide layer (1-11), the first zinc aluminium oxide layer (1-12), described first silicon oxide layer or the first silicon oxynitride layer (1-11)
Thicknesses of layers is 18~25nm, and the thicknesses of layers of the first zinc aluminium oxide layer (1-12) is 75~115nm.
4. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to claim 1 it is characterised in that: institute
State electric heating function layer to be made up of four continuous film layers, described four continuous film layers include the first layer of titanium metal or argent
Layer (1-21), the first titanium oxide layer (1-22), niobium oxide layer (1-23), the first indium tin oxide layer (1-24),
The thicknesses of layers of described first layer of titanium metal or metallic silver layer (1-21) is 6~11nm, the first titanium oxide layer (1-22)
Thicknesses of layers is 15~22nm, and the thicknesses of layers of niobium oxide layer (1-23) is 10~15nm, the first indium tin oxide layer (1-24)
Thicknesses of layers is 120~165nm.
5. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to claim 1 it is characterised in that: institute
Stating electric heater frost protection layer is the second titanium oxide layer or titanium nitride layer (1-3), described second titanium oxide layer or titanium nitride layer (1-3)
Thicknesses of layers is 65~150nm;Described a face electrical heating transparent conductive film layer both sides coating conductive silver paste or copper electrode and electrical heating
Power supply is connected.
6. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to claim 1 it is characterised in that: institute
State stealthy adhesive layer and be followed successively by the second silicon oxide layer or the second silicon oxynitride layer (2-11) and the second zinc aluminium oxide layer from inside to outside
(2-12), the thicknesses of layers of described second silicon oxide layer or the second silicon oxynitride layer (2-11) is 18~25nm, the second zinc oxide
The thicknesses of layers of aluminium lamination (2-12) is 25~40nm.
7. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to claim 1 it is characterised in that: institute
State stealthy functional layer and be followed successively by the first zirconia layer (2-21), the second layer of titanium metal (2-22), the second zirconia layer from inside to outside
(2-23), the 3rd layer of titanium metal (2-24) and the 3rd zirconia layer (2-25), the film layer of described first zirconia layer (2-21) is thick
Spend for 20~40nm, the thicknesses of layers of described second zirconia layer (2-23) is 10~15nm, described 3rd zirconia layer (2-
25) thicknesses of layers is 2~20nm, and the thicknesses of layers of the second layer of titanium metal (2-22) is 6~8nm, described 3rd layer of titanium metal
(2-24) thicknesses of layers is 4~6nm.
8. the anti-icing antifog nesa coating of the electrical heating for invisbile plane according to any one of claim 1 to 7, it is special
Levy and be: described stealthy protective layer includes the second indium tin oxide layer (2-31) and the 3rd silicon oxynitride layer (2- from inside to outside successively
32), the thicknesses of layers of described second indium tin oxide layer (2-31) is 150~265nm, the film layer of the 3rd silicon oxynitride layer (2-32)
Thickness is 65~150nm.
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CN201620814940.9U CN205907208U (en) | 2016-07-29 | 2016-07-29 | A anti -icing antifog transparent conducting film of electrical heating for invisbile plane |
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CN201620814940.9U CN205907208U (en) | 2016-07-29 | 2016-07-29 | A anti -icing antifog transparent conducting film of electrical heating for invisbile plane |
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