CN205856367U - A kind of platinum catalyst microcapsule - Google Patents

A kind of platinum catalyst microcapsule Download PDF

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Publication number
CN205856367U
CN205856367U CN201620758136.3U CN201620758136U CN205856367U CN 205856367 U CN205856367 U CN 205856367U CN 201620758136 U CN201620758136 U CN 201620758136U CN 205856367 U CN205856367 U CN 205856367U
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CN
China
Prior art keywords
platinum catalyst
layer
microcapsule
liquid
polycaprolactone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201620758136.3U
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Chinese (zh)
Inventor
徐正华
王艳艳
许成勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Zhengjie High-Tech Materials Compamy Ltd By Share
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Anhui Zhengjie High-Tech Materials Compamy Ltd By Share
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Priority to CN201620758136.3U priority Critical patent/CN205856367U/en
Application granted granted Critical
Publication of CN205856367U publication Critical patent/CN205856367U/en
Expired - Fee Related legal-status Critical Current
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Abstract

This utility model relates to a kind of platinum catalyst microcapsule, and described microcapsule center is liquid platinum catalyst, also includes the polyvinyl chloride layer of central outer surface that from-inner-to-outer is coated on successively, liquid platinum catalyst layer, polycaprolactone layer;The ring and ball softening point of described polycaprolactone layer is less than the ring and ball softening point of polyvinyl chloride layer;Described liquid platinum catalyst layer is 1:3 4 with the volume ratio of liquid platinum catalyst;The thickness of described polycaprolactone layer and polyvinyl chloride layer is than for 1:0.5 1.Platinum catalyst microcapsule of the present utility model is particularly well-suited to the silicone rubber of add-on type of middle hot setting, the curing system of silicones, has the advantage that catalytic efficiency is high, catalytic reaction is gentle.

Description

A kind of platinum catalyst microcapsule
Technical field
This utility model relates to platinum catalyst production technical field, particularly relates to a kind of platinum catalyst microcapsule.
Background technology
Along with the development of silicone rubber, for knitwear, cotton goods, the decorative pattern of Lycra elastic woven material and the silica gel of mark Also getting more and more, the forming temperature of these product needed is the most relatively low, generally below 100 degree, is therefore accomplished by micro encapsulation The wall material of platinum catalyst possesses low softening point temperature, when temperature rises to 100 degree, and platinum catalyst can flow out soon, And select the high thermoplastic resin of toughness as epidermis to prevent microcapsule embrittlement in whipping process from needing.But, this The platinum catalyst microcapsule catalytic efficiency of monolayer is the highest.
Summary of the invention
In order to solve above-mentioned technical problem, it is provided that the platinum platinum catalyst that a kind of catalytic efficiency is high, catalytic reaction is gentle Microcapsule, this utility model offer techniques below scheme:
A kind of platinum catalyst microcapsule, described microcapsule center is liquid platinum catalyst, also includes that from-inner-to-outer depends on The polyvinyl chloride layer of the secondary central outer surface being coated on, liquid platinum catalyst layer, polycaprolactone layer;Described polycaprolactone layer Ring and ball softening point is less than the ring and ball softening point of polyvinyl chloride layer.
Platinum catalyst microcapsule of the present utility model is stirred with silica gel materials and starts to warm up, when temperature raises During to the softening point of polycaprolactone layer, the liquid platinum catalyst of liquid platinum catalyst layer flows out, and starts to play catalytic action; Following temperature continues to raise, and when being increased to the softening point of polrvinyl chloride, the platinum catalyst at center flows out.
Further, described liquid platinum catalyst layer is 1:3-4 with the volume ratio of liquid platinum catalyst.Liquid platinum Silica gel molding is reacted with liquid platinum catalyst and is catalyzed by catalyst layer at twice, temperature when liquid platinum catalyst flows out Spending the forming temperature closer to silica gel product, therefore, the liquid platinum catalyst amount at center requires more.
Further, the thickness of described polycaprolactone layer and polyvinyl chloride layer is than for 1:0.5-1, the thickness of polycaprolactone layer More than or equal to polyvinyl chloride layer, being because polycaprolactone layer needs to consider its pliability as the outermost layer of microcapsule.
Further, described polycaprolactone layer is 1:1-2 with the thickness of liquid platinum catalyst layer.
The beneficial effects of the utility model are: be particularly well-suited to the silicone rubber of the add-on type of middle hot setting, silicones Curing system;The catalyst system and catalyzing design of layering has the advantage that catalytic efficiency is high, catalytic reaction is gentle.
Accompanying drawing explanation
Fig. 1, primary structure schematic diagram of the present utility model.
In figure: 1, liquid platinum catalyst, 2, polyvinyl chloride layer, 3, liquid platinum catalyst layer, 4, polycaprolactone layer.
Detailed description of the invention
A kind of platinum catalyst microcapsule as shown in Figure 1, described microcapsule center is liquid platinum catalyst, also includes The polyvinyl chloride layer 2 of the central outer surface that from-inner-to-outer is coated on successively, liquid platinum catalyst layer 3, polycaprolactone layer 4;Institute State the ring and ball softening point ring and ball softening point less than polyvinyl chloride layer 2 of polycaprolactone layer 4.
Described liquid platinum catalyst layer 3 is 1:3 with the volume ratio of liquid platinum catalyst 1.Liquid platinum catalyst layer 3 Reacting silica gel molding at twice with liquid platinum catalyst 1 and be catalyzed, temperature when liquid platinum catalyst 1 flows out more connects The forming temperature of nearly silica gel product, therefore, the liquid platinum catalyst amount at center requires more.
The thickness of described polycaprolactone layer 4 and polyvinyl chloride layer 2 ratio for 1:0.5, the thickness of polycaprolactone layer 4 more than or Equal to polyvinyl chloride layer 2, being because polycaprolactone layer 4 needs to consider its pliability as the outermost layer of microcapsule.
Described polycaprolactone layer 4 is 1:1 with the thickness of liquid platinum catalyst layer 3.
Platinum catalyst microcapsule of the present utility model is stirred with silica gel materials and starts to warm up, when temperature raises During to the softening point of polycaprolactone layer 4, the liquid platinum catalyst of liquid platinum catalyst layer 3 flows out, and starts to play catalysis and makees With;Following temperature continues to raise, and when being increased to the softening point of polrvinyl chloride, the platinum catalyst at center flows out.
With above-mentioned foundation this utility model desirable embodiment for enlightenment, by above-mentioned description, relevant staff Various change and amendment can be carried out completely in the range of without departing from this utility model technological thought.This practicality The content that novel technical scope is not limited in description, it is necessary to determine that it is technical according to right Scope.

Claims (4)

1. a platinum catalyst microcapsule, it is characterised in that: described microcapsule center is liquid platinum catalyst, also includes certainly In and outer be coated on successively the polyvinyl chloride layer of central outer surface, liquid platinum catalyst layer, polycaprolactone layer;Described poly-own The ring and ball softening point of interior ester layer is less than the ring and ball softening point of polyvinyl chloride layer.
2. platinum catalyst microcapsule as claimed in claim 1 a kind of, it is characterised in that: described liquid platinum catalyst layer with The volume ratio of liquid platinum catalyst is 1:3-4.
3. a kind of platinum catalyst microcapsule as claimed in claim 1, it is characterised in that: described polycaprolactone layer and polychlorostyrene second The thickness of alkene layer is than for 1:0.5-1.
4. a kind of platinum catalyst microcapsule as claimed in claim 3, it is characterised in that: described polycaprolactone layer and liquid platinum The thickness of Au catalyst layer is 1:1-2.
CN201620758136.3U 2016-07-16 2016-07-16 A kind of platinum catalyst microcapsule Expired - Fee Related CN205856367U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201620758136.3U CN205856367U (en) 2016-07-16 2016-07-16 A kind of platinum catalyst microcapsule

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620758136.3U CN205856367U (en) 2016-07-16 2016-07-16 A kind of platinum catalyst microcapsule

Publications (1)

Publication Number Publication Date
CN205856367U true CN205856367U (en) 2017-01-04

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CN201620758136.3U Expired - Fee Related CN205856367U (en) 2016-07-16 2016-07-16 A kind of platinum catalyst microcapsule

Country Status (1)

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CN (1) CN205856367U (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108752608A (en) * 2018-04-26 2018-11-06 东莞市博恩复合材料有限公司 Addition-type silicon rubber catalyst of low-temperature setting and preparation method thereof
CN110237785A (en) * 2019-06-11 2019-09-17 扬州工业职业技术学院 A kind of catalyst micro capsule and preparation method thereof
CN114933805A (en) * 2022-06-15 2022-08-23 湖南柯盛新材料有限公司 Single-component transfer printing silica gel and preparation method thereof
CN114940826A (en) * 2022-06-15 2022-08-26 湖南柯盛新材料有限公司 Liquid silicone rubber with high tear strength and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108752608A (en) * 2018-04-26 2018-11-06 东莞市博恩复合材料有限公司 Addition-type silicon rubber catalyst of low-temperature setting and preparation method thereof
CN108752608B (en) * 2018-04-26 2021-08-24 东莞市博恩复合材料有限公司 Catalyst for low-temperature cured addition type silicone rubber and preparation method thereof
CN110237785A (en) * 2019-06-11 2019-09-17 扬州工业职业技术学院 A kind of catalyst micro capsule and preparation method thereof
CN114933805A (en) * 2022-06-15 2022-08-23 湖南柯盛新材料有限公司 Single-component transfer printing silica gel and preparation method thereof
CN114940826A (en) * 2022-06-15 2022-08-26 湖南柯盛新材料有限公司 Liquid silicone rubber with high tear strength and preparation method thereof
CN114940826B (en) * 2022-06-15 2023-09-08 湖南柯盛新材料有限公司 Liquid silicone rubber with high tearing strength and preparation method thereof
CN114933805B (en) * 2022-06-15 2023-09-08 湖南柯盛新材料有限公司 Single-component pad printing silica gel and preparation method thereof

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170104

Termination date: 20200716

CF01 Termination of patent right due to non-payment of annual fee