CN205846135U - A kind of Novel lithium-ion storage battery - Google Patents

A kind of Novel lithium-ion storage battery Download PDF

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Publication number
CN205846135U
CN205846135U CN201620875002.XU CN201620875002U CN205846135U CN 205846135 U CN205846135 U CN 205846135U CN 201620875002 U CN201620875002 U CN 201620875002U CN 205846135 U CN205846135 U CN 205846135U
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China
Prior art keywords
pole
lithium
negative pole
electrolysis bath
positive pole
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CN201620875002.XU
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Chinese (zh)
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武永鑫
张良
李力舟
徐雷
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The utility model discloses a kind of Novel lithium-ion storage battery; including battery cell case, insulation board, barrier film, positive pole, negative pole, PTC-element, positive terminal and protection valve; described battery cell case is internally provided with electrolysis bath; in described electrolysis bath, electrolyte is set; positive pole and negative pole it is provided with in described electrolysis bath; being provided with barrier film between described positive pole and negative pole, described electrolysis bath top and bottom are provided with insulation board.This utility model reasonable in design, does not use the aqueous solution electrolysis liquid of such as lead-acid accumulator or nickel-hydrogen accumulator, but uses organic electrolyte;In charging process, the lithium in positive pole is ionic condition, moves in the electrolytic solution, and is adsorbed by the carbonizable substance in negative pole;Electric discharge is then the back reaction of charging process;In this course of reaction, usual lithium exists with ionic forms, the not lithium of precipitating metal state;Voltage is higher, and lightweight;The energy density of lithium-ions battery, power density is the highest, has the biggest using value.

Description

A kind of Novel lithium-ion storage battery
Technical field
This utility model relates to a kind of Novel lithium-ion storage battery.
Background technology
Lithium-ions battery has environmental protection, the little feature such as frivolous, more can adapt to development and the need of industry of science and technology Asking, so lithium-ions battery is just in fast development, but in its charging process, the heat dissipation problem of dissipative cell is restriction development A factor.
Lithium ion battery is widely used to the fields such as mobile phone, notebook computer, electric bicycle, electric tool, the most several Nian Lai, also begins to application in electric automobile, large-scale dynamical system, requires that battery has higher defeated in these applications Go out energy.The lithium ion battery kind of comparative maturity has polymer battery, square battery, cylindrical battery, electrokinetic cell now Deng, wherein cylindrical battery has the advantages such as high energy density per unit volume, ripe production technology, stable discharge performance, applies For extensively.For meeting the input energy requirement of electrical equipment, multiple battery series-parallel connections must be combined in the application. It addition, on some equipment except dynamical system require power supply in addition to, the instrument and meter on equipment too need power supply, and this two Voltage range and the capacity of planting power reguirements are different from.Therefore, under limited space and weight, produce and most adapt to set The lithium-ions battery group that standby use requires is most important.Meanwhile, the Li-ion batteries piles that dynamical system uses to shock resistance and The requirement of vibration performance is high, and the combinative structure of set of cells requires safe and reliable, it is ensured that set of cells is energy under complicated working environment Enough safety and stability electrical equipment is powered.
Now by the combination technique of many battery series-parallel connections immature, cylindrical battery have high energy density per unit volume and The advantage that safety is good, is widely used on notebook computer and small-sized electric tool, and the number of batteries of combination is generally individually Less than 20, get up to be combined into the accumulator battery of needs, by many battery series-parallel connection groups by nickel strap welding connection in series-parallel Conjunction could meet requirement, and number of batteries increase and use the severe structure to set of cells of environment design propose the highest Requirement.
Utility model content
The technical problems to be solved in the utility model is to provide a kind of simple in construction, easy to operate new type lithium ion electric power storage Pond.
For solving the problems referred to above, this utility model adopts the following technical scheme that
A kind of Novel lithium-ion storage battery, including battery cell case, insulation board, barrier film, positive pole, negative pole, PTC-element, just Pole binding post and protection valve, described battery cell case is internally provided with electrolysis bath, arranges electrolyte, described electricity in described electrolysis bath Being provided with positive pole and negative pole in solving groove, be provided with barrier film between described positive pole and negative pole, described electrolysis bath top and bottom are all provided with Being equipped with insulation board, the insulation board at described electrolysis bath top is provided with PTC-element, described PTC-element is provided above pad, institute Stating and be provided with protection valve on pad, described electrolysis bath is connected above being provided with positive terminal, described positive pole and positive terminal Being connected, described negative pole is connected with negative wire, described protection valve is provided above steam vent.
As preferably, described positive pole uses LiMnO4Lamellar compound raw material designs.
As preferably, described negative pole is made up by organic solvent mediation of the mixture of material with carbon element with binding agent, and coating On Copper substrate.
As preferably, described positive pole has power supply to be connected with load with negative pole by wire respectively.
This utility model reasonable in design, does not use the aqueous solution electrolysis of such as lead-acid accumulator or nickel-hydrogen accumulator Liquid, but use organic electrolyte;In charging process, the lithium in positive pole is ionic condition, moves in the electrolytic solution, and is born Carbonizable substance absorption in extremely;Electric discharge is then the back reaction of charging process;In this course of reaction, usual lithium is deposited with ionic forms , the not lithium of precipitating metal state;Voltage is higher, and lightweight;The energy density of lithium-ions battery, power density is very Height, has the biggest using value.
Accompanying drawing explanation
In order to be illustrated more clearly that this utility model embodiment or technical scheme of the prior art, below will be to embodiment Or the required accompanying drawing used is briefly described in description of the prior art, it should be apparent that, the accompanying drawing in describing below is only It is embodiments more of the present utility model, for those of ordinary skill in the art, in the premise not paying creative work Under, it is also possible to other accompanying drawing is obtained according to these accompanying drawings;
Fig. 1 is structural representation of the present utility model;
Fig. 2 is lithium ion battery charging-discharging structure schematic diagram of the present utility model.
Detailed description of the invention
Below in conjunction with the accompanying drawings preferred embodiment of the present utility model is described in detail, so that advantage of the present utility model Can be easier to be readily appreciated by one skilled in the art with feature, thus protection domain of the present utility model is made apparent clearly Define.
Refering to shown in Fig. 1-2, a kind of Novel lithium-ion storage battery, including battery cell case 1, insulation board 2, barrier film 3, positive pole 4, negative pole 6, PTC-element 8, positive terminal 9 and protection valve 11, described battery cell case 1 is internally provided with electrolysis bath, described electricity In solving groove, electrolyte 14 is set, is provided with positive pole 4 and negative pole 6 in described electrolysis bath, is provided with between described positive pole 4 and negative pole 6 Barrier film 3, described electrolysis bath top and bottom are provided with insulation board 2, the insulation board 2 at described electrolysis bath top are provided with PTC Element 8, described PTC-element 8 is provided above pad 7, described pad 7 is provided with protection valve 11, connects above described electrolysis bath Connecing and be provided with positive terminal 9, described positive pole 4 is connected with positive terminal 9, and described negative pole 6 is connected with negative wire 5, described protection valve 11 is provided above steam vent 10.
It should be noted that described positive pole 4 uses LiMnO4Lamellar compound raw material designs.
It should be noted that described negative pole 6 is made up by organic solvent mediation of the mixture of material with carbon element with binding agent, and It is coated on Copper substrate.
It should be noted that described positive pole 4 has power supply 12 to be connected with load 13 with negative pole 6 by wire respectively.
This utility model reasonable in design, does not use the aqueous solution electrolysis of such as lead-acid accumulator or nickel-hydrogen accumulator Liquid, but use organic electrolyte;In charging process, the lithium in positive pole is ionic condition, moves in the electrolytic solution, and is born Carbonizable substance absorption in extremely;Electric discharge is then the back reaction of charging process;In this course of reaction, usual lithium is deposited with ionic forms , the not lithium of precipitating metal state;Voltage is higher, and lightweight;The energy density of lithium-ions battery, power density is very Height, has the biggest using value.
Dividing plate or title isolation diaphragm, its function plays the effect closed or block passage, generally uses polyethylene or poly-third The micro-porous film of alkene material.So-called closedown or block function are that battery occurs that abnormal temperature rises, and block or block as ion The pore of passage, makes accumulator stop discharge and recharge reaction.Dividing plate can effectively prevent the super-high-current caused because of external short circuit etc. And make battery produce abnormal heating phenomenon.
Electrolyte is the organic electrolyte based on mixed solvent.In order to make the lithium salts of main electrolyte composition dissolve, Must have high-dielectric constant, and have the solvent good with the lithium ion compatibility, that does not the most hinder that ion moves is low viscous Organic solution is advisable, and in the operating temperature range of lithium-ions battery, it is necessary in liquid condition, freezing point is low, boiling point High.Electrolyte has chemical stability for active substance, it is necessary to occur in good conformity discharge and recharge course of reaction is violent Redox condition.
In order to ensure the safety in utilization of lithium-ions battery, typically by the control to external circuit or in accumulator Inside is provided with the safety device that abnormal current cuts off.Even if so, being in use also possible to other reasons to cause electric power storage The intrinsic pressure abnormal rising in pond, so, relief valve release gas, to prevent accumulator from rupturing.Relief valve is actually the most non-repairing Compound fracturing diaphragm, once enters duty, and protection accumulator makes it quit work, is therefore the last protection of accumulator Means.
Operation principle: lithium ion battery is actually a lithium ion concentration cell, positive and negative electrode is by two kinds of different lithiums The intercalation compound structure of ion.During charging, Li+ embeds negative pole from positive pole deintercalation through electrolyte, and now negative pole is in rich lithium state, just Pole is in lean lithium state;During electric discharge then on the contrary, Li+, from negative pole deintercalation, embeds positive pole through electrolyte, and positive pole is in rich lithium state, negative Pole is in lean lithium state.The running voltage of lithium ion battery with constitute the dense of the Lithium-ion embeding compound of electrode itself and lithium ion Spend relevant.Therefore, when charge and discharge cycles, there is " embedding-deintercalation " reaction in Li+ on both positive and negative polarity, Li+ just at both positive and negative polarity respectively Between move back and forth.
Lithium battery has following characteristic in charging:
Half section the most before charging, voltage is gradually increasing;
2., after voltage reaches 4.2V, internal resistance changes, and voltage remains unchanged;
During the most whole, electricity is continuously increased;
4., close to when being full of, charging current can reach the least value.
Through years of researches, have found preferable charge control method:
1. trickle charge reaches final discharging voltage 2.7V;
2. use constant current to be charged, make voltage basically reach 4.2V.Safe current is less than 0.8C;
3. constant-current phase can reach the 80% of electricity substantially
4. transferring constant-voltage charge to, electric current is gradually reduced;
5., when electric current reaches less value (such as 0.05C), battery reaches full state.
The standardized element that this utility model uses all can commercially, shaped piece according to description and accompanying drawing Record all can carry out customized, the concrete connected mode of each part all uses in prior art ripe bolt, rivet, weldering The conventional means such as connecing, machinery, part and equipment all use in prior art, and conventional model adds that circuit is connected by existing Connected mode conventional in technology, is not described in detail in this.
Of the present utility model ultimate principle and principal character and of the present utility model advantage have more than been shown and described.One's own profession Skilled person will appreciate that of industry, this utility model is not restricted to the described embodiments, described in above-described embodiment and description Principle of the present utility model is simply described, on the premise of without departing from this utility model spirit and scope, this utility model is also Have various changes and modifications, in the range of these changes and improvements both fall within claimed this utility model.This utility model Claimed scope is defined by appending claims and equivalent thereof.

Claims (4)

1. a Novel lithium-ion storage battery, it is characterised in that: include battery cell case (1), insulation board (2), barrier film (3), just Pole (4), negative pole (6), PTC-element (8), positive terminal (9) and protection valve (11), described battery cell case (1) is internal to be arranged Have electrolysis bath, electrolyte (14) be set in described electrolysis bath, in described electrolysis bath, be provided with positive pole (4) and negative pole (6), described just Being provided with barrier film (3) between pole (4) and negative pole (6), described electrolysis bath top and bottom are provided with insulation board (2), described electricity Solving and be provided with PTC-element (8) on the insulation board (2) at groove top, described PTC-element (8) is provided above pad (7), described pad Being provided with protection valve (11) on sheet (7), described electrolysis bath is connected above being provided with positive terminal (9), described positive pole (4) with just Pole binding post (9) is connected, and described negative pole (6) is connected with negative wire (5), described protection valve (11) row of being provided above Pore (10).
A kind of Novel lithium-ion storage battery the most according to claim 1, it is characterised in that: described positive pole (4) uses LiMnO4 Lamellar compound raw material designs.
A kind of Novel lithium-ion storage battery the most according to claim 1, it is characterised in that: described negative pole (6) is by material with carbon element Made by organic solvent mediation with the mixture of binding agent, and be coated on Copper substrate.
A kind of Novel lithium-ion storage battery the most according to claim 1, it is characterised in that: described positive pole (4) and negative pole (6) There is power supply (12) to be connected with load (13) respectively by wire.
CN201620875002.XU 2016-08-02 2016-08-02 A kind of Novel lithium-ion storage battery Expired - Fee Related CN205846135U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111816811A (en) * 2020-07-22 2020-10-23 平潭诚信智创科技有限公司 Solid-state battery pack and control method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111816811A (en) * 2020-07-22 2020-10-23 平潭诚信智创科技有限公司 Solid-state battery pack and control method thereof

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20161228

Termination date: 20170802