CN205832902U - A kind of online circular regeneration organic waste gas treatment device - Google Patents

A kind of online circular regeneration organic waste gas treatment device Download PDF

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Publication number
CN205832902U
CN205832902U CN201620640034.1U CN201620640034U CN205832902U CN 205832902 U CN205832902 U CN 205832902U CN 201620640034 U CN201620640034 U CN 201620640034U CN 205832902 U CN205832902 U CN 205832902U
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absorbent
organic
eddy flow
absorbent particles
particles ball
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CN201620640034.1U
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Chinese (zh)
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刘定平
崔静
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South China University of Technology SCUT
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South China University of Technology SCUT
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Abstract

The utility model discloses a kind of online circular regeneration organic waste gas treatment device;Including eddy flow tower, liquid storage tank, sedimentation tank, biological desorption room, it is located at the storage compartment of side, biological desorption room;Eddy flow tower bottom connects sedimentation tank by pipeline;The bottom of sedimentation tank is provided with centrifugal pump, by centrifugal pump, the absorbent particles ball in it with microcellular structure is delivered to biological desorption room;The downside perisporium of eddy flow tower is intervally distributed with the vortex atomizing nozzle that multiple circle of contact is arranged;Absorbent particles ball after organic absorbent agent solution, desorption and organic exhaust gas, sprayed in the way of the circle of contact by vortex atomizing nozzle and be sufficiently mixed to eddy flow tower, and along eddy flow inner wall of tower circumferential flow, spiral.Absorption absorption method, absorption process and bioanalysis are integrated in a set of new equipment by this device, overcome the deficiency of conventional purge, achieve the online circular regeneration of adsorbent, improve purification efficiency, reduce operating cost, solve the inefficient problem of adsorbent reactivation.

Description

A kind of online circular regeneration organic waste gas treatment device
Technical field
This utility model relates to circular regeneration VOCs treatment, particularly relates at a kind of online circular regeneration organic exhaust gas Reason method and apparatus.
Background technology
It is the great environmental pollution problem that faces of our province that urban atmosphere haze and ozone exceed standard, and VOCs is that its formation is important Precursor, VOCs is the most of a great variety, and most poisonous, and part is carcinogenic, seriously pollutes environment and harm human health.With The fast development of economy, organic exhaust gas (VOCs) pollutes day by day serious, and latent row has a high potential, and advances its improvement to be put into Country's prevention and control of air pollution major tasks.
The method administering industrial organic exhaust gas at present mainly has absorption process, condensation method, catalysis burning, absorption-absorption method, life Thing method and plasma method etc..Wherein absorption-absorption process has preferable treatment effect, and can be by high added value after absorption Separating organic matters reclaim, therefore suffer from the extensive concern of people.
Traditional absorption-recovery process uses many empty materials such as activated carbons as adsorbent, is put into by adsorbent fixing In Chuan, make Organic substance be adsorbed by bed organic exhaust gas, after utilize hot-air or high-temperature water vapor etc. as desorption be situated between Matter, by adsorbent bed, makes the high-enriched organics after absorption be desorbed under high temperature action, then through condensation, separation etc. Mode makes Organic substance be recycled.The absorption of organic gas is had " selectivity " by adsorbent, selects the adsorbed of macromole, little Being missed of molecule.Use fixed bed to carry out the adsorbing separation of organic exhaust gas, have that adsorbent mechanical wear is little, structure is the simplest The advantages such as list.But have the disadvantage that:
(1) fixed bed local " overheated " adsorption process is an exothermic process, may be due to the excessive release of heat of adsorption Or fixed-bed heat transfer poor effect, cause fixed bed local " overheated ", even cause activated carbon class adsorbent catching fire.
(2) in the excessive fixed bed of pressure drop, absorbent particles arrangement closely, causes organic exhaust gas pressure drop excessive, thus limits Flow velocity, makes the VOCs treatment amount of Wind Volume reduce.
(3) " channel " easily occurs for adsorbent bed is piled up the loosest region, air-flow can preferentially by and form " ditch Stream ", make adsorbent bed penetrate too early, partial adsorbates agent can not be fully contacted with organic exhaust gas, causes the reduction of adsorption efficiency.
Traditional desorption method is to utilize the methods such as hot-air blowing desorption, has the advantages such as simple, but has simultaneously Following shortcoming: the organic exhaust gas of enrichment is mixed into again air;Subsequent treatment is loaded down with trivial details;Energy consumption is high.
Summary of the invention
The purpose of this utility model is the shortcoming overcoming above-mentioned fixed bed " overheated " and " channel " phenomenon easily occur, it is provided that A kind of integrate absorption, floated absorption and the online circular regeneration organic waste gas treatment method being desorbed and device, to reach Effectively remove organic exhaust gas, non-secondary pollution, low energy consumption, and avoid the purpose that environment is contaminated.
This utility model is achieved through the following technical solutions:
A kind of online circular regeneration organic waste gas treatment device, including eddy flow tower 8, the liquid storage that contains organic absorbent solution Pond 4, the sedimentation tank 10 being arranged in liquid storage tank 4, biological desorption room 5, it is arranged on the storage compartment 9 of side, biological desorption room 5;Described The bottom of eddy flow tower 8 connects sedimentation tank 10 by pipeline;
The bottom of sedimentation tank 10 is provided with centrifugal pump, will have the absorbent particles ball 5-of microcellular structure by centrifugal pump in it 1 is delivered to biological desorption room 5;The downside perisporium of described eddy flow tower 8 is intervally distributed with the vortex atomizing nozzle that multiple circle of contact is arranged 7;
Described biological desorption room 5 is interworking architecture with storage compartment 9, and arranges valve plate 6 between which;Biological desorption room 5 The absorbent particles ball 5-1 carried by sedimentation tank 10 for splendid attire;By regulating the height of valve plate 6, control the suction after desorption Attached dose of granule ball 5-1 flows into the amount of storage compartment 9;
Described liquid storage tank 4 and storage compartment 9 by induction system, connect the straight entrance of vortex atomizing nozzle 7, by defeated respectively System is sent respectively the absorbent particles ball 5-1 after the organic absorbent agent solution in liquid storage tank 4 and desorption to be delivered to swirling flow atomizing The straight entrance of nozzle 7;The side of described vortex atomizing nozzle 7 is provided with side entrance 7-1, side entrance 7-1 and is used for being passed through organic exhaust gas;
Absorbent particles ball 5-1 after described organic absorbent agent solution, desorption and organic exhaust gas, by vortex atomizing nozzle 7 Spray in the way of the circle of contact and be sufficiently mixed to eddy flow tower 8, and along eddy flow tower 8 inwall circumferential flow, spiral.
The top of described eddy flow tower 8 is provided with demister 1;Organic exhaust gas macromole when spiral, in organic exhaust gas The absorbent particles ball 5-1 absorption that gas is suspended in uphill process, the micro-molecular gas in organic exhaust gas is at uphill process Middle by organic absorbent drop absorption;The organic gas warp gradually purified by organic absorbent drop and absorbent particles ball 5-1 Cross demister 1, arranged by the top exit of eddy flow tower 8 after removing the absorbent drop and absorbent particles ball 5-1 carried in gas Put to air;Meanwhile, by organic absorbent drop and saturated absorbent particles ball 5-1 under gravity, return Sedimentation tank 10, the absorbent after the clarification of sedimentation tank 10 top overflows, and flows into liquid storage tank 4.
Described biological desorption room 5 built with microorganism fungus kind, organic for twice decomposition absorbent particles ball 5-1 surface Waste gas.
Top exit at eddy flow tower 8 is provided with removable ultrafiltration escaper 11;Remove the absorbent liquid carried in gas Drip and after absorbent particles ball 5-1, then be emitted into air through ultrafiltration escaper 11.
Described demister 1 be arranged over the spraying layer 12 for periodic flushing demister 1, be used for preventing demister 1 from tying Dirt, blocking.
Described demister 1 uses any one in mesh mist eliminator, deflection plate demister or centrifugal type demister.
A kind of online circular regeneration organic waste gas treatment method is as follows:
Step 1;Organic absorbent agent solution, absorbent particles ball 5-1 and the injecting step of organic exhaust gas: organic absorbent is molten Liquid, absorbent particles ball 5-1 and organic exhaust gas are sprayed to eddy flow tower 8 the most mixed by vortex atomizing nozzle 7 in the way of the circle of contact Close, and along eddy flow tower 8 inwall circumferential flow, spiral;
Step 2;The purifying step of organic exhaust gas: organic exhaust gas is when spiral, and macromole gas therein is rising During be suspended absorbent particles ball 5-1 absorption, the micro-molecular gas in organic exhaust gas in uphill process by organic suction Receive agent drop absorption;Gradually by the organic gas of organic absorbent drop and absorbent particles ball 5-1 purification through demister 1, It is emitted into air by the top exit of eddy flow tower 8 after removing the absorbent drop and absorbent particles ball 5-1 carried in gas;
Step 3;Organic absorbent drop and the recycling step of saturated absorbent particles ball 5-1:
By organic absorbent drop and saturated absorbent particles ball 5-1 under gravity, return sedimentation tank 10, heavy Absorbent after the clarification of top, pond, shallow lake 10 overflows, and flows into liquid storage tank 4;
Now, by regulating the height of valve plate 6, the absorption on upper strata after secondary biological desorption, the biological desorption room 5 is made Agent granule ball 5-1 flows in storage compartment 9;Induction system is again by the organic absorbent agent solution in liquid storage tank 4 and secondary through two Absorbent particles ball 5-1 after thing desorption is delivered to the straight entrance of vortex atomizing nozzle 7, and with from vortex atomizing nozzle 7 side The organic exhaust gas of entrance 7-1 together, sprays in the way of the circle of contact and is sufficiently mixed to eddy flow tower 8, and along eddy flow tower 8 inwall week To flowing, spiral;
Circulate with this, complete purification and machine absorbent solution and the recovery of absorbent particles ball 5-1 of organic exhaust gas.
Described organic absorbent is any in usual diethyl hydroxylamine, PEG400, silicone oil, used oil or diesel oil A kind of.
Described absorbent particles ball 5-1 is micro activated carbon particle or molecular sieve particles.
The particle diameter of described micro activated carbon particle or molecular sieve particles is 4mm~0.25mm.
This utility model, relative to prior art, has such advantages as and effect:
Absorbent particles ball after organic absorbent agent solution, desorption and organic exhaust gas, by vortex atomizing nozzle with the circle of contact Mode is sprayed and is sufficiently mixed to eddy flow tower, and along eddy flow inner wall of tower circumferential flow, spiral.Use this injection side The vortex atomizing nozzle that formula, absorbent (absorbent solution drop) and adsorbent (absorbent particles ball) are arranged from the circle of contact is ejected into In eddy flow tower, drive organic exhaust gas to form circumferential flow trend, make the mixing that organic exhaust gas and the two are full and uniform, organic exhaust gas Climb at eddy flow tower internal coiling, increase organic exhaust gas movement travel in eddy flow tower, when prolongation organic exhaust gas stops in tower Between, improve further and absorb and adsorption efficiency.Due to organic exhaust gas swirling motion, eliminate that organic exhaust gas is adherent ramps stream Dynamic phenomenon.Macromole in organic exhaust gas is adsorbed, and is absorbed by absorbent in uphill process.Absorb and carry out with absorption simultaneously, Little molecule is difficult to be adsorbed by adsorbent, but can preferably be absorbed by absorbent.Therefore, organic exhaust gas carry out simultaneously secondary be combined Purification substantially increases purification efficiency.
As mentioned above.This utility model absorbent particles ball as fluid in eddy flow tower suspended motion.This fluidised form The peculair motion form changed, makes absorbent particles ball contact with fluid with suspended state in tower, and gas and solid contact area Relatively big, improve purification efficiency;And the fierce mixing in eddy flow tower of absorbent particles ball, make temperature and reactant in eddy flow tower Even concentration is consistent, can be prevented effectively from the overheated generation with excessive concentration phenomenon of local temperature.
Absorbent particles ball carries out secondary bioanalysis desorption, have high treating effect, technique is simple, energy consumption is low, small investment, The advantages such as non-secondary pollution.
Absorption-absorption method, absorption process and bioanalysis are integrated in a set of new equipment by this utility model, it is possible to overcome tradition Purification method and the deficiency of device, it is achieved good clean-up effect.
This utility model absorption reaches saturated absorbent particles ball with absorbent after sedimentation tank separates, isolated absorption Agent enters tower and recycles, and isolated solid particle (absorbent particles ball) enters biological desorption room, and after biological desorption, this is solid Body microgranule mixes with absorbent again to be entered eddy flow tower by rotational flow atomizer and continue cycling through use.This utility model achieves adsorbent Online circular regeneration, improve purification efficiency, reduce operating cost, simplify cleaning systems and maintenance, solve absorption The problem that agent regeneration efficiency is low.
Accompanying drawing explanation
Fig. 1 is this utility model online circular regeneration VOCs treatment structural representation;In figure, A represents organic absorbent Drop, saturated absorbent particles ball.
Fig. 2 is the absorbent particles ball after organic absorbent agent solution, desorption and organic exhaust gas, by vortex atomizing nozzle to cut The mode of circle is sprayed to eddy flow tower, and along eddy flow inner wall of tower circumferential flow, spiralling schematic diagram.
Detailed description of the invention
Below in conjunction with specific embodiment, this utility model is more specifically described in detail.
Embodiment
As shown in Figure 1, 2.The utility model discloses a kind of online circular regeneration organic waste gas treatment device, including eddy flow Tower 8, the liquid storage tank 4 containing organic absorbent solution, the sedimentation tank 10 being arranged in liquid storage tank 4, biological desorption room 5, it is arranged on The storage compartment 9 of side, biological desorption room 5;The bottom of described eddy flow tower 8 connects sedimentation tank 10 by pipeline;The height of sedimentation tank 10 Higher than liquid storage tank 4.
The bottom of sedimentation tank 10 is provided with centrifugal pump, will have the absorbent particles ball 5-of microcellular structure by centrifugal pump in it 1 is delivered to biological desorption room 5;The downside perisporium of described eddy flow tower 8 is intervally distributed with the vortex atomizing nozzle that multiple circle of contact is arranged 7;The quantity of the present embodiment vortex atomizing nozzle 7 is 4, the most symmetrical, and particular number can require increase and decrease according to concrete application.
Described biological desorption room 5 is interworking architecture with storage compartment 9, and arranges valve plate 6 (can periodically open) between which, This valve plate 6 actually one piece of baffle plate, this biological desorption room 5 and a storage compartment 9 actually entirety, by baffle plate by its every Open two chambers.Biological desorption room 5 is for containing the absorbent particles ball 5-1 carried by sedimentation tank 10;By regulation valve plate 6 Height, control desorption after absorbent particles ball 5-1 flow into storage compartment 9 amount;
Described liquid storage tank 4 and storage compartment 9 by induction system (centrifugal pump), connect directly entering of vortex atomizing nozzle 7 respectively Mouthful, respectively the absorbent particles ball 5-1 after the organic absorbent agent solution in liquid storage tank 4 and desorption is delivered to by induction system The straight entrance of vortex atomizing nozzle 7;The side of described vortex atomizing nozzle 7 is provided with side entrance 7-1, side entrance 7-1 and is used for being passed through Organic exhaust gas;
Absorbent particles ball 5-1 after described organic absorbent agent solution, desorption and organic exhaust gas, by vortex atomizing nozzle 7 Spray in the way of the circle of contact and be sufficiently mixed to eddy flow tower 8, and along eddy flow tower 8 inwall circumferential flow, spiral.
The top of described eddy flow tower 8 be provided with demister 1 (depending on the number of plies of demister 1 requires according to concrete application, this enforcement Example uses layer 2-3);Organic exhaust gas is when spiral, and the macromole gas in organic exhaust gas is suspended in uphill process Absorbent particles ball 5-1 adsorb, the micro-molecular gas in organic exhaust gas in uphill process by organic absorbent drop absorption;By The organic gas gradually purified by organic absorbent drop and absorbent particles ball 5-1 carries in demister 1, removing gas It is emitted into air by the top exit of eddy flow tower 8 after absorbent drop and absorbent particles ball 5-1;Meanwhile, by organic suction Receipts agent drop and saturated absorbent particles ball 5-1 under gravity, return sedimentation tank 10, after the clarification of sedimentation tank 10 top Absorbent overflow, flow into liquid storage tank 4.
Described biological desorption room 5 built with microorganism fungus kind, organic for twice decomposition absorbent particles ball 5-1 surface Waste gas.
Top exit at eddy flow tower 8 is provided with removable ultrafiltration escaper 11;Remove the absorbent liquid carried in gas Drip and after absorbent particles ball 5-1, then be emitted into air through ultrafiltration escaper 11.
Described demister 1 be arranged over the spraying layer 12 for periodic flushing demister 1, be used for preventing demister 1 from tying Dirt, blocking.
Described demister 1 uses any one in mesh mist eliminator, deflection plate demister or centrifugal type demister.
Organic absorbent circulating path: spin current tower, sedimentation tank, liquid storage tank.
Absorbent particles ball 5-1 circulating path: eddy flow tower, sedimentation tank, biological desorption room 5 and storage compartment 9.
This utility model online circular regeneration organic waste gas treatment method can be achieved by the steps of:
Step 1;Organic absorbent agent solution, absorbent particles ball 5-1 and the injecting step of organic exhaust gas: organic absorbent is molten Liquid, absorbent particles ball 5-1 and organic exhaust gas are sprayed to eddy flow tower 8 the most mixed by vortex atomizing nozzle 7 in the way of the circle of contact Close, and along eddy flow tower 8 inwall circumferential flow, spiral;
Step 2;The purifying step of organic exhaust gas: organic exhaust gas is when spiral, and macromole gas therein is rising During be suspended absorbent particles ball 5-1 absorption, the micro-molecular gas in organic exhaust gas in uphill process by organic suction Receive agent drop absorption;Gradually by the organic gas of organic absorbent drop and absorbent particles ball 5-1 purification through demister 1, It is emitted into air by the top exit of eddy flow tower 8 after removing the absorbent drop and absorbent particles ball 5-1 carried in gas;
Step 3;Organic absorbent drop and the recycling step of saturated absorbent particles ball 5-1:
By organic absorbent drop and saturated absorbent particles ball 5-1 under gravity, return sedimentation tank 10, heavy Absorbent after the clarification of top, pond, shallow lake 10 overflows, and flows into liquid storage tank 4;
Now, by regulating the height of valve plate 6, the absorption on upper strata after secondary biological desorption, the biological desorption room 5 is made Agent granule ball 5-1 flows in storage compartment 9;Induction system (employing centrifugal pump) is again by the organic absorbent agent solution in liquid storage tank 4 And the absorbent particles ball 5-1 after secondary biological desorption is delivered to the straight entrance of vortex atomizing nozzle 7, and with carry out spin current The organic exhaust gas of atomizer 7 side entrance 7-1 together, sprays in the way of the circle of contact and is sufficiently mixed to eddy flow tower 8, and along rotation Stream tower 8 inwall circumferential flow, spiral;
Circulate with this, complete purification and machine absorbent solution and the recovery of absorbent particles ball 5-1 of organic exhaust gas.
The organic vapors such as benzene,toluene,xylene dissolubility in organic solvent is very big, and this is by " similar mix " principle Being determined, be also an empirical law in material solubility property, its essence is the active force between the particle that structure is similar Active force between particle more diverse than structure is strong.Organic solvent is that polarity is more weak even without polarity, dielectric constant very Little liquid, therefore organic exhaust gas is soluble in organic solvent.Therefore this utility model organic absorbent uses diethyl hydroxylamine, gathers Ethylene glycol 400, silicone oil, used oil or (0#) diesel oil.Absorbent particles ball 5-1 be activated carbon particle size be the micro-of 4mm~0.25mm Grain or molecular sieve particles.
As it has been described above, just can preferably realize this utility model.
Embodiment of the present utility model is also not restricted to the described embodiments, and other are any without departing from of the present utility model The change made under spirit and principle, modify, substitute, combine, simplify, all should be the substitute mode of equivalence, be included in Within protection domain of the present utility model.

Claims (6)

1. an online circular regeneration organic waste gas treatment device, it is characterised in that: include eddy flow tower (8), contain organic absorbent The liquid storage tank (4) of agent solution, the sedimentation tank (10) being arranged in liquid storage tank (4), biological desorption room (5), be arranged on biological desorption The storage compartment (9) of room (5) side;The bottom of described eddy flow tower (8) connects sedimentation tank (10) by pipeline;
The bottom of sedimentation tank (10) is provided with centrifugal pump, will have the absorbent particles ball (5-of microcellular structure by centrifugal pump in it 1) biological desorption room (5) it is delivered to;The downside perisporium of described eddy flow tower (8) is intervally distributed with the swirling flow atomizing that multiple circle of contact is arranged Nozzle (7);
Described biological desorption room (5) and storage compartment (9) are interworking architecture, and arrange valve plate (6) between which;Biological desorption room (5) for containing the absorbent particles ball (5-1) come by sedimentation tank (10) conveying;By the height of regulation valve plate (6), control de- Attached absorbent particles ball (5-1) flows into the amount of storage compartment (9);
Described liquid storage tank (4) and storage compartment (9) by induction system, connect the straight entrance of vortex atomizing nozzle (7), pass through respectively Absorbent particles ball (5-1) after organic absorbent agent solution in liquid storage tank (4) and desorption is delivered to rotation by induction system respectively The straight entrance of stream atomizer (7);The side of described vortex atomizing nozzle (7) is provided with side entrance (7-1), and side entrance (7-1) uses In being passed through organic exhaust gas;
Absorbent particles ball (5-1) after described organic absorbent agent solution, desorption and organic exhaust gas, by vortex atomizing nozzle (7) Spray in the way of the circle of contact and be sufficiently mixed to eddy flow tower (8), and along eddy flow tower (8) inwall circumferential flow, spiral.
The most online circular regeneration organic waste gas treatment device, it is characterised in that: described eddy flow tower (8) Top be provided with demister (1);Organic exhaust gas macromole gas quilt in uphill process when spiral, in organic exhaust gas Suspend absorbent particles ball (5-1) absorption, the micro-molecular gas in organic exhaust gas in uphill process by organic absorbent liquid Drip and absorb;The organic gas gradually purified by organic absorbent drop and absorbent particles ball (5-1), through demister (1), removes It is emitted into air by the top exit of eddy flow tower (8) after removing the absorbent drop carried in gas and absorbent particles ball (5-1);
Meanwhile, by organic absorbent drop and saturated absorbent particles ball (5-1) under gravity, precipitation is returned Pond (10), the absorbent after the clarification of sedimentation tank (10) top overflows, and flows into liquid storage tank (4).
The most online circular regeneration organic waste gas treatment device, it is characterised in that: described biological desorption room (5) built with microorganism fungus kind, for the organic exhaust gas on twice decomposition absorbent particles ball (5-1) surface.
The most online circular regeneration organic waste gas treatment device, it is characterised in that: at eddy flow tower (8) Top exit is provided with removable ultrafiltration escaper (11);Remove the absorbent drop and absorbent particles ball carried in gas (5-1) after, then it is emitted into air through ultrafiltration escaper (11).
The most online circular regeneration organic waste gas treatment device, it is characterised in that: described demister (1) The spraying layer (12) being arranged over for periodic flushing demister (1), be used for preventing demister (1) fouling, blocking.
The most online circular regeneration organic waste gas treatment device, it is characterised in that: described demister (1) Use in mesh mist eliminator, deflection plate demister or centrifugal type demister any one.
CN201620640034.1U 2016-06-23 2016-06-23 A kind of online circular regeneration organic waste gas treatment device Withdrawn - After Issue CN205832902U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017219623A1 (en) * 2016-06-23 2017-12-28 华南理工大学 Online cyclic regeneration organic waste gas treatment method and device
CN109529584A (en) * 2018-12-26 2019-03-29 陈瑞德 A kind of waste gas purification spray equipment
CN109925862A (en) * 2018-12-25 2019-06-25 四川大学 A kind of VOC exhaust treatment system and its processing method
CN110652854A (en) * 2018-06-29 2020-01-07 福建爱溥环保设备有限公司 VOC waste gas treatment device and treatment method thereof
CN111346505A (en) * 2018-12-20 2020-06-30 恩特格里斯公司 Active wet type washing and filtering system

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017219623A1 (en) * 2016-06-23 2017-12-28 华南理工大学 Online cyclic regeneration organic waste gas treatment method and device
CN110652854A (en) * 2018-06-29 2020-01-07 福建爱溥环保设备有限公司 VOC waste gas treatment device and treatment method thereof
CN111346505A (en) * 2018-12-20 2020-06-30 恩特格里斯公司 Active wet type washing and filtering system
CN109925862A (en) * 2018-12-25 2019-06-25 四川大学 A kind of VOC exhaust treatment system and its processing method
CN109529584A (en) * 2018-12-26 2019-03-29 陈瑞德 A kind of waste gas purification spray equipment
CN109529584B (en) * 2018-12-26 2021-08-27 金华康扬环境科技有限公司 Waste gas purification spray set

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Granted publication date: 20161228

Effective date of abandoning: 20180622