CN205832882U - A kind of equipment of fume treatment - Google Patents

A kind of equipment of fume treatment Download PDF

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Publication number
CN205832882U
CN205832882U CN201620822734.2U CN201620822734U CN205832882U CN 205832882 U CN205832882 U CN 205832882U CN 201620822734 U CN201620822734 U CN 201620822734U CN 205832882 U CN205832882 U CN 205832882U
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China
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equipment
electric cleaner
outlet
waste water
pipeline
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余学海
孙平
刘毅
张军营
张翼
赵永椿
廖海燕
赵志刚
赵瑞
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Huazhong University of Science and Technology
China Shenhua Energy Co Ltd
Beijing Guohua Electric Power Co Ltd
Shenhua Guohua Beijing Electric Power Research Institute Co Ltd
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Huazhong University of Science and Technology
China Shenhua Energy Co Ltd
Beijing Guohua Electric Power Co Ltd
Shenhua Guohua Beijing Electric Power Research Institute Co Ltd
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Abstract

This utility model relates to fume treatment field, disclose the equipment of a kind of fume treatment, this equipment includes electric cleaner (2), desulfurization unit (3), wet cottrell (4), this equipment also includes atomising device (6) and waste water separator (7), the wastewater outlet of desulfurization unit (3) is connected with the entrance of waste water separator (7), the liquid outlet of described waste water separator (7) is connected with the water inlet of atomising device (6), and the outlet of atomising device (6) is connected with the pipeline of electric cleaner (2) upstream.Use equipment of the present utility model, by electric cleaner and the coupling of wet cottrell, it is possible to be effectively improved the removal efficiency of dust granules thing, it is also possible to realize the zero-emission of waste water.

Description

A kind of equipment of fume treatment
Technical field
This utility model relates to fume treatment field, in particular it relates to the equipment of a kind of fume treatment.
Background technology
Particulate matter is the primary pollutant of current China city atmospheric environment, and China's flue dust 90% comes spontaneous combustion coal, Qi Zhongchao Fine particle (PM2.5) pollution problem more serious.Although the efficiency of dust collection of existing dust arrester is up to more than 99%, but this A little cleaner units are relatively low to the capture rate of superfine particulate matter, still have substantial amounts of superfine particulate matter to enter in air, with the quantity of granule Meter can reach more than the 90% of fly ash granule sum.The concentration of emission of particulate matter is limited by the up-to-date environmental protection standard that country promulgates Bring up to 50mg/Nm3, this proposes challenge, existing electrostatic precipitator greatly to China's coal-fired plant flue gas emission control Mostly it is unable to reach this standard.Use wet cottrell, for SO3, hydrargyrum and desulfurated plaster there is preferable removal effect, But superfine particulate matter still needed to be improved further removal efficiency.
All there is waste water handling problem in the most traditional limestone-gypsum wet desulfuration technique and wet static dedusting technique. The impurity of heat-engine plant desulfurized waste water from flue gas and the limestone of desulfurization, mainly include float, oversaturated sulphite, Sulfate and heavy metal, be the most much the first kind pollutant requiring in national environmental standard to control.Generally desulfurization wastewater In faintly acid, pH value is 4.5~6.5, and suspension content is generally 1~10g/L, containing Cl-、F-、SO42-、Ca2+、Mg2+Deng cloudy Cation and micro heavy ion, directly environment can be impacted by outer row.General employing chemistry adding method thereof processes, this method Technology maturation, but owing to wastewater treatment capacity is big, need substantial amounts of chemical agent, investment and operating cost are higher.Wet electrostatic removes The waste water of dirt device generally enters desulfurization wastewater treatment system.
At present, the control technological development direction of superfine particulate matter predominantly arranges pretreatment before conventional dust removal equipment and arranges Execute so that it is by being removed after physically or chemically acting on long great achievement larger particles, including acoustic agglomeration, electrocoagulation, magnetic coagulation, Chemical agglomeration, steam phase transforming etc..Chemical agglomeration technology can neither change normal production conditions, does not the most change existing electric precipitation Under conditions of equipment and operating parameter, it is effectively improved electric dust-removing equipment to fine grain removal efficiency, but in the agglomerator sprayed into, In addition to containing binding agent and wetting agent, also need to add inorganic additives and pH value regulator (such as phosphoric acid), and fresh water (FW) consumption is relatively Greatly.
Therefore, the equipment developing the superfine particulate matter of a kind of environmental protection and the process of waste water is very important.
Utility model content
In order to overcome prior art, in fume treatment, in dust granules thing, superfine particulate matter removal efficiency is low and waste water Processing cost is high, the defect of inadequate environmental protection, and this utility model provides the equipment of a kind of fume treatment, uses of the present utility model Equipment, by electric cleaner and the coupling of wet cottrell, it is possible to be effectively improved the removal efficiency of dust granules thing, also may be used To realize the zero-emission of waste water.
Specifically, this utility model provides the equipment of a kind of fume treatment, and this equipment includes electric cleaner, desulfurization list Unit, wet cottrell, the fume emission mouth of described electric cleaner is connected by the smoke inlet of pipeline with described desulfurization unit Connecing, the exhanst gas outlet of described desulfurization unit is connected with the smoke inlet of described wet cottrell by pipeline, and this equipment is also Including atomising device and waste water separator, the wastewater outlet of desulfurization unit is connected with the entrance of waste water separator, described useless The liquid outlet of water separation device is connected with the water inlet of atomising device, the outlet of atomising device and the pipeline of electric cleaner upstream Connect.
Preferably, the liquid outlet of described waste water separator includes supernatant liquid outlet and lower floor's liquid outlet, described Supernatant liquid outlet is connected with the sulfur removal technology water inlet of desulfurization unit, described lower floor liquid outlet and the water inlet of atomising device Connect.
Preferably, described supernatant liquid outlet and described wet cottrell wastewater outlet all with desulfurization unit take off Sulfur fresh water (FW) entrance connects.
Preferably, the equipment of described fume treatment also includes wastewater treatment equipment, the liquid discharge of described waste water separator Mouth includes that supernatant liquid outlet and lower floor's liquid outlet, the outlet of described supernatant liquid are connected with the water inlet of described atomising device, Described lower floor liquid outlet is connected with the entrance of described waste water separator, the outlet of described wastewater treatment equipment and described wet type The water inlet of electrostatic precipitator connects, and the wastewater outlet of described wet cottrell connects with the entrance of described waste water separator Connect.
Preferably, described atomising device is blast injection atomising device.
Preferably, described waste water separator is gravity-type solid-liquid separator.
Preferably, described wastewater treatment equipment is chemical flocculation precipitation device.
Preferably, described electric cleaner is electrostatic precipitator and/or electrostatic fabric filter.
Preferably, described desulfurization unit is wet desulphurization device.
Preferably, the position that the outlet of described atomising device is connected with the pipeline of electric cleaner upstream and described electric cleaner The distance of entrance be not less than 5 meters.
Preferably, described equipment also includes that boiler, the pipeline of described electric cleaner upstream are between boiler and electric cleaner Pipeline, and there is no it between position and the electric cleaner 2 of the pipeline that sprays into electric cleaner upstream of the drop after described atomization Its equipment.
This utility model combines the feature of electric cleaner, wet desulphurization and wet cottrell, it is achieved that three's Organically combine, the most effectively solve desulfurization and the wastewater problem of wet cottrell, realize wastewater zero discharge by circulating and recovering, Achieve the gathering of superfine particulate matter and grow up, making granular material discharged concentration less than 5mg/Nm3, it is truly realized dust granules thing Near-zero release.Specifically, this utility model is by spraying into partial desulfurization waste water in the pipeline of electric cleaner upstream, it is not necessary to Increase any assistant medicament, neither change normal production conditions, the most do not change existing electric dust-removing equipment structurally and operationally parameter, just The electric dust-removing equipment removal efficiency to dust granules thing can be improved;Meanwhile, this partial desulfurization waste water sprays into the upper of electrostatic precipitator Evaporating completely in the pipeline of trip, the pollutant in waste water are converted into solid and separate out, and with the dust in flue gas by electric precipitation Device traps.And another part desulfurization wastewater or enter desulfurization unit as sulfur removal technology water and recycle, or through waste water Realize recycling as the flushing water of wet cottrell after processing means purified treatment, really realize wastewater zero discharge With the near-zero release of dust granules thing, reduce operating cost.
The principle of the near-zero release that this utility model is capable of dust granules thing is probably: after the atomization of partial desulfurization waste water Spray into the pipeline of the upstream of electric cleaner, on the one hand cause flue-gas temperature to reduce, under the ratio resistance of dust after desulfurization wastewater evaporation Fall, meanwhile, the inorganic salts material of precipitation is (such as CaCl2·2H2O、MgSO4·H2O, NaCl) also can suitably reduce dust than electricity Resistance, this removal efficiency being all conducive to improving electrostatic precipitator;On the other hand, after flue gas spraying into water smoke, fine particle is had one Fixed agglomeration, in supersaturated vapor environment, steam is with PM2.5Microgranule is that the nuclei of condensation undergo phase transition, and makes particle size increase Greatly, quality increases, and produces the effect of diffusion and thermophoresis simultaneously, promotes Particles transport motion and mutually collides, making PM2.5Group Gather and grow up.Fine water-spray can produce trapping effect to respirable dust, and dust is all increased by the moistening rear particle diameter of water smoke, quality, And become easily to be removed, even if water smoke is not charged, the humidification uniquely relying on water smoke just can promote the reunion of subparticle, carries The efficiency of dust collection of high follow-up electric cleaner.
Other features and advantages of the utility model will be described in detail in detailed description of the invention part subsequently.
Accompanying drawing explanation
Accompanying drawing is used to offer and is further appreciated by of the present utility model, and constitutes a part for description, with following Detailed description of the invention be used for explaining this utility model together, but be not intended that restriction of the present utility model.In the accompanying drawings:
Fig. 1 be the one of the equipment of fume treatment of the present utility model preferred embodiment;
Fig. 2 is another preferred embodiment of the equipment of fume treatment of the present utility model.
Description of reference numerals
1 boiler 2 electric cleaner
3 desulfurization unit 4 wet cottrells
5 chimney 6 atomising devices
7 waste water separator 8 wastewater treatment equipments
A fuel B desulfurization wastewater
C supernatant liquid D lower floor liquid
E compressed air F dust waste water
G Gypsum Fibrosum and body refuse H flushing water
I solid residue
Detailed description of the invention
Hereinafter detailed description of the invention of the present utility model is described in detail.It should be appreciated that it is described herein Detailed description of the invention is merely to illustrate and explains this utility model, is not limited to this utility model.
The end points of scope disclosed in this article and any value are not limited to this accurate scope or value, these scopes or Value should be understood to the value comprised close to these scopes or value.For numerical range, between the endpoint value of each scope, respectively Between endpoint value and the single point value of individual scope, and can obtain one or more between single point value with combination with one another New numerical range, these numerical rangies should be considered the most specifically to disclose.
This utility model provides the equipment of a kind of fume treatment, and this equipment includes electric cleaner 2, desulfurization unit 3, wet type Electrostatic precipitator 4, the fume emission mouth of described electric cleaner 2 is connected with the smoke inlet of described desulfurization unit 3 by pipeline, institute The exhanst gas outlet stating desulfurization unit 3 is connected with the smoke inlet of described wet cottrell 4 by pipeline, and this equipment also includes Atomising device 6 and waste water separator 7, the wastewater outlet of desulfurization unit 3 is connected with the entrance of waste water separator 7, described useless The liquid outlet of water separation device 7 is connected with the water inlet of atomising device 6, the outlet of atomising device 6 and electric cleaner 2 upstream Pipeline connects.
Flue gas sequentially passes through electric cleaner 2, desulfurization unit 3, wet cottrell 4, the desulfurization produced by desulfurization unit 3 Waste water obtains liquid and solid residue through waste water separator 7, and the liquid obtained by waste water separator 7 is through atomization dress After putting the atomization of 6 atomized after drop, the drop after described atomization is sprayed into the pipeline of the upstream of electric cleaner 2.
According to this utility model one preferred embodiment, as it is shown in figure 1, the liquid discharge of described waste water separator 7 Mouth includes supernatant liquid outlet and lower floor's liquid outlet, the outlet of described supernatant liquid and the sulfur removal technology water inlet of desulfurization unit 3 Connecting, described lower floor liquid outlet is connected with the water inlet of atomising device 6.It is highly preferred that the outlet of described supernatant liquid is with described The wastewater outlet of wet cottrell 4 is all connected with the sulfur removal technology water inlet of desulfurization unit 3.
The liquid that waste water separator 7 obtains includes supernatant liquid and lower floor's liquid, and described supernatant liquid is as desulfurization work Skill water enters desulfurization unit 3, and described lower floor liquid enters in atomising device 6.It is highly preferred that described supernatant liquid and and described wet The dust waste water that formula electrostatic precipitator 4 produces all enters desulfurization unit 3 as sulfur removal technology water.
According to another preferred embodiment of the present utility model, as in figure 2 it is shown, the equipment of described fume treatment also wraps Including wastewater treatment equipment 8, the liquid outlet of described waste water separator 7 includes supernatant liquid outlet and lower floor's liquid outlet, institute State supernatant liquid outlet to be connected with the water inlet of described atomising device 6, described lower floor liquid outlet and described waste water separator 8 Entrance connect, the outlet of described wastewater treatment equipment 8 is connected with the water inlet of described wet cottrell 4, described wet type The wastewater outlet of electrostatic precipitator 4 is connected with the entrance of described waste water separator 7.
The liquid that waste water separator 7 obtains includes supernatant liquid and lower floor's liquid, and described supernatant liquid enters atomization dress Putting 6, lower floor's liquid enters waste water separator 8 and carries out purified treatment, and using the water after purified treatment as wet static dedusting The flushing water of device 4.
In this utility model, described atomising device 6 can be blast injection atomising device, and the condition of atomization includes Pressure can be 0.3-0.5MPa, and the liquid drop speed after atomising device is atomized can be 30-50m/s.Compressed air E is used for carrying Medium for liquid water atomization.
In this utility model, described waste water separator 7 can be gravity-type solid-liquid separator.Described waste water separates dress Put 7 one aspects and float is had filtration, on the other hand, it is possible to achieve waste water is efficiently separated.Described waste water separates dress Put 7 and can realize three layers of separating effect according to density difference, including supernatant liquid, lower floor's liquid and solid residue.Wherein, on Layer liquid and the subnatant decorum liquid that referred to as waste water separator 7 obtains.The density of supernatant liquid is less than 1010kg/m3, excellent Elect 1000-1009kg/m as3;Containing a small amount of particulate matter and float in lower floor's liquid, density can be 1010-1050kg/m3。 The bottom is solid residue, and described solid residue can include Gypsum Fibrosum and the body refuse G of solid-state.
According to one of the present utility model preferred embodiment, described supernatant liquid C and described wet cottrell 4 Produce dust waste water F all as sulfur removal technology water enter desulfurization unit 3 mode there is no particular limitation, such as can first by Described supernatant liquid C and described dust waste water F mixes in entering the pipeline before desulfurization unit 3, it is also possible to pass through respectively into Mouth entrance desulfurization unit 3.Correspondingly, can set on the pipeline of sulfur removal technology water between desulfurization unit 3 and waste water separator 7 Put the entrance of described dust waste water, it is also possible to the pipeline of the sulfur removal technology water between wet cottrell 4 and desulfurization unit 3 On the entrance of described supernatant liquid is set, or between desulfurization unit 3 and waste water separator 7 pipeline of sulfur removal technology water with wet The pipeline of the sulfur removal technology water between formula electrostatic precipitator 4 and desulfurization unit 3 be arranged in parallel.
According to another preferred embodiment of the present utility model, desulfurization wastewater D and wet type that desulfurization unit 3 produces are quiet There is no particular limitation for the mode of the dust waste water B entrance waste water separator 7 that electric cleaner 4 produces, such as can be first by institute State desulfurization wastewater and described dust waste water to mix in entering the pipeline before waste water separator 7, it is also possible to pass through respectively into Mouth enters waste water separator 7.Correspondingly, can arrange on the pipeline between desulfurization unit 3 and waste water separator 7 described The entrance of dust waste water, it is also possible to described desulfurization is set on the pipeline between wet cottrell 4 and waste water separator 7 Pipeline between the entrance of waste water, or desulfurization unit 3 with waste water separator 7 separates with waste water with wet cottrell 4 Pipeline between device 7 be arranged in parallel.
In this utility model, described wastewater treatment equipment 8 can be chemical flocculation precipitation device.Preferred according to one Embodiment, the liquid that waste water separator 7 obtains includes that supernatant liquid and lower floor's liquid, lower floor's liquid enter waste water and separates dress Put 8 and carry out purified treatment, be purified the water after process and solid residue I, and using the water after purified treatment as wet electrostatic The flushing water of cleaner unit 4.Purified treatment includes using chemical agent to carry out flocculation sediment, and the condition of flushing water includes that pH value is 6.8-7.5, solid suspension < 100ppm.
In this utility model, described electric cleaner 2 can be connected with boiler 1, and described boiler 1 is those skilled in the art Known, do not repeat them here.
In this utility model, described flue gas can be the various flue gases needing to remove dust granules thing, can be various The flue gas that fuel A (such as coal) burns, such as, can be the flue gas from boiler 1 without any process, such as, can come From the flue gas of boiler of power plant, it is also possible to be the flue gas from steel-making boiler.Described flue gas can also be the cigarette processed through denitration Gas.
According to this utility model one preferred embodiment, described equipment also includes being arranged on electric cleaner 2 upstream Denitrification apparatus.Flue gas was carrying out denitration process before electric cleaner 2.The routine that technique is this area that described denitration processes Select.Such as, described denitration processes and can be selected from low nitrogen burning, SCR (SCR) technique and selective non-catalytic At least one in reduction denitration (SNCR) technique.Concrete equipment and condition are well known to those skilled in the art, at this not Repeat again.According to preferred a kind of embodiment, flue gas produces in boiler 1, is passed through electric cleaner after denitration processes 2.There is no particular limitation for the component of flue gas and flow, can be the conventional selection of this area, not repeat them here.
In this utility model, there is no particular limitation for the kind of described electric cleaner 2, can be the conventional choosing of this area Select.Such as, described electric cleaner 2 can be electrostatic precipitator and/or electrostatic fabric filter, and described electrostatic precipitator is usually dry type Electrostatic precipitator.The operation flue-gas temperature of described electric cleaner 2 can be 95-160 DEG C.
In this utility model, described desulfurization unit 3 can be wet desulphurization device, the kind of described wet desulphurization device Can be the conventional selection of this area with structure and service condition.Such as, described wet desulphurization device can include connecting successively Logical pulping system, absorption tower and gypsum dehydration system.The fume emission mouth of described electric cleaner 2 is by pipeline and described desulfurization The smoke inlet connection of unit 3 refers to be connected with the smoke inlet on the absorption tower of wet method release unit.When upstream, absorption tower cloth When being equipped with concentration tower, it is connected the flue gas referring to the concentration tower with wet desulphurization device with the smoke inlet of described desulfurization unit 3 Entrance connects.
In this utility model, the composition of the desulfurization wastewater B that described desulfurization unit 3 produces is ripe by those skilled in the art Knowing, the most described desulfurization wastewater is generally in faintly acid, and pH value is 4.5-6, and suspension content is 1-10g/L, containing Cl-、F-、 SO4 2-、Ca2+、Mg2+And micro heavy ion.
In this utility model, described wet cottrell 4 is the conventional selection of this area.Such as can use flexibility Pole plate dedusting, deashing is by the full surface uniform water film gravity flow of pole plate.Preferably, the dedusting that described wet cottrell 4 produces Waste water F contains a small amount of fine dust and Gypsum Fibrosum drop.
In this utility model, the drop after described atomization sprays into the position of the pipeline of electric cleaner upstream can be bigger In the range of change, remove as long as heat contained by flue gas can be utilized not have liquid water to enter electricity the droplet evaporation after atomization and guarantee Dirt device 2.Drop after the most described atomization sprays into the position of the pipeline of electric cleaner upstream and entering of described electric cleaner 2 The distance of mouth is not less than 5 meters (preferably 5-10 rice).Preferably, the flow velocity of flue gas is about 10-15 meter per second, after described atomization The drop time of staying in the duct is not less than 0.5 second (preferably 0.5-0.8 second).
According to this utility model, the time of staying in the duct of the drop after described atomization refers to the drop after atomization from spray The pipeline entering electric cleaner upstream starts to electric cleaner 2 the required time.The pipeline of electric cleaner 2 upstream refers to Flue gas enters the pipeline of electric cleaner 2, the pipeline being i.e. connected with electric cleaner 2 entrance.According to one preferred embodiment, institute Stating the pipeline of electric cleaner upstream is that the drop after the pipeline between boiler 1 and electric cleaner 2, and described atomization sprays into electricity and removes Miscellaneous equipment is not had between position and the electric cleaner of the pipeline of dirt device upstream.
In this utility model, the straying quatity of the drop after described atomization can change in a big way, this straying quatity Can determine according to the temperature of flue gas.Flue-gas temperature before routine Precipitator is generally at 120-150 DEG C at present, Drop after atomization can evaporate after spraying into, and carries out heat exchange with flue gas, and flue-gas temperature reduces 8-15 DEG C.Preferably implement according to one Mode, the straying quatity of the drop after described atomization makes the inlet temperature of electric cleaner 2 be not less than 105 DEG C, more preferably 120- 130℃。
In this utility model, electric cleaner 2 outlet flue gas enter desulfurization unit 3 carry out desulfurization, desulfuration efficiency up to 99%, SO in the flue gas after desulfurization2Concentration is less than 35mg/Nm3.Flue gas after desulfurization enters in wet cottrell 4 Carry out ultimate process, can be by the Gypsum Fibrosum carried in flue gas, fine grained, SO3And the heavy metal removing such as Hg.After tested, described wet type The outlet particle concentration of electrostatic precipitator 4 is less than 5mg/Nm3, it is achieved the near-zero release of dust granules thing.
According to one of the present utility model preferred embodiment, wet cottrell 4 is with chimney 5 by pipeline even Connect.Flue gas after wet cottrell 4 processes finally is discharged from chimney 5.
Hereinafter by embodiment, this utility model will be described in detail.
In following example, particle concentration, flue gas flow, smoke moisture, flue-gas temperature etc. are all according to coal-fired power plant Universal testing method and instrument record, with specific reference to GB/T 13931-2002 (electric precipitator performance method of testing).
In embodiment and comparative example, enter in the flue gas of electric cleaner 2 containing following components (representing with volume content): CO2Content 14.34%, O2Content 3.25%, N2Content 73.47%, SO2Content 0.06%, H2The content of O 8.61%, remaining is the foreign gas of trace.
Electric cleaner 2 is electrostatic precipitator, and desulfurization unit 3 is wet desulphurization device, and wet cottrell 4 is purchased from China Energy-saving and emission-reduction company limited, atomising device 6 is blast injection atomising device, and waste water separator 7 divides for gravity-type solid-liquid From device, wastewater treatment equipment 8 is chemical flocculation precipitation device.
Embodiment 1
As it is shown in figure 1, by boiler 1, electric cleaner 2, desulfurization unit 3, wet cottrell 4, chimney 5, atomising device 6 Being attached with waste water separator 7, wherein, the exhanst gas outlet of boiler 1 is connected with the smoke inlet of electric cleaner 2, described electricity The fume emission mouth of cleaner unit 2 is connected with the smoke inlet of described desulfurization unit 3 by pipeline, the flue gas of described desulfurization unit 3 Outlet is connected by the smoke inlet of pipeline with described wet cottrell 4, the exhanst gas outlet of wet cottrell 4 and cigarette Chimney 5 connects.The wastewater outlet of desulfurization unit 3 and the wastewater outlet of described wet cottrell 4 all with waste water separator 7 Entrance connects, and the supernatant liquid outlet of described waste water separator 7 is connected with the sulfur removal technology water inlet of desulfurization unit 3, lower floor Liquid outlet is connected with the water inlet of atomising device 6, and the outlet of atomising device 6 is connected with the pipeline of electric cleaner 2 upstream.Described The exhanst gas outlet of wet cottrell 4 is connected with chimney 5.
Power is the unit of 300MW, and fuel A (specially coal) burns in boiler 1 and produces flue gas, processes through denitration Rear entrance electric cleaner 2, the condition that denitration processes includes: using SCR technique, catalyst is vanadium Titanium series catalyst, temperature range For 290-400 DEG C.
The entrance flue gas temperature of electric cleaner 2 about 130 DEG C, flue gas flow about 1,100,000 Nm3/ h, the particulate matter in flue gas is dense Degree is 12g/Nm3.The particle concentration of the flue gas after electric cleaner 2 processes is 21mg/Nm3.After electric cleaner 2 processes Flue gas enters desulfurization unit 3 and processes.SO in desulfurization unit 3, in flue gas2React with lime stone slurry, thus SO2From Flue gas removes.From absorption tower discharge lime stone slurry through cyclonic separation, wash and be dehydrated after obtain Gypsum Fibrosum, produce simultaneously Desulfurization wastewater B.The pH value of desulfurization wastewater B is 5.2, and suspension content is 6.3g/L, containing Cl in described desulfurization wastewater-、F-、 SO4 2-、Ca2+、Mg2+.The weight of desulfurization wastewater D about 3.8 tons.
Flue gas desulfuration efficiency after desulfurization unit 3 processes has reached 99%.Flue gas after desulfurization processes enters wet type Electrostatic precipitator 4.Described wet cottrell 4 uses flexible plate dedusting, and deashing leans on the full surface uniform water film of pole plate certainly Stream.The dust waste water F that described wet cottrell 4 produces contains a small amount of fine dust and Gypsum Fibrosum drop.Wet cottrell 4 The dust waste water F about 1.2 tons produced.
Desulfurization wastewater B, after the separation of waste water separator 7, realizes three layers of separating effect according to density difference, is divided into Supernatant liquid, lower floor's liquid and solid residue.Wherein, lower floor's liquid F density about 1030kg/m3, weight about 3 tons, water temperature is about 40 DEG C, enter in atomising device 6 and be atomized under the effect of compressed air E, atomizing pressure about 0.4MPa, the liquid drop speed after atomization For 40m/s.Drop after atomization sprays into the upstream line of electric cleaner 2, and spraying into a little distance with electric cleaner 2 is 5 meters, flue gas Flow velocity about 10m/s, the time of staying in the duct of the drop after atomization is 0.5 second.
Through measuring and calculating, lower floor liquid F through atomization after enter electric cleaner 2 upstream line evaporate completely after, in pipeline Smoke moisture is increased to 9.13% by 8.61%, and flue-gas temperature is reduced to 124 DEG C.Flue gas is in undersaturated condition, higher than acid dew Point temperature (acid dew-point temperature about 80-95 DEG C), will not produce corrosion to flue and electric cleaner, therefore, there is no need to spray waste water After access point, pipeline and cleaner unit carry out reforming processing.Meanwhile, the increase of smoke moisture and the reduction of flue-gas temperature, also reduce electricity The ratio resistance that cleaner unit is mellow lime, is conducive to improving efficiency of dust collection.It addition, because of the reduction of flue-gas temperature and the increasing of humidity of flue gas Add, decrease the water consumption of FGD (flue gas desulfurization) system.(heavy metal, impurity and each additionally, solids in desulfurization wastewater Plant slaine etc.) it is suspended in together with ash in flue gas and enters electric cleaner with flue gas, caught by electrode in electric cleaner, with Ash outer row together, because in desulfurization wastewater, amount of solid and various metal salt concentration are less, physical property and comprehensive utilization to ash will not be produced Raw impact.
The flue gas that wet cottrell 4 processed discharges through chimney 5, the supernatant liquid C that waste water separator 7 produces (density 1003kg/m3) and the dust waste water F mixing that produces of wet cottrell 4 after as the sulfur removal technology of desulfurization unit 3 Water, it is achieved that recycle.It addition, collect Gypsum Fibrosum and the body refuse G of the solid-state that waste water separator 7 produces, carry out subsequent treatment, Solid-state Gypsum Fibrosum is transported to stockyard, body refuse is abandoned.
After tested, outlet particle concentration (dust concentration) the about 21mg/Nm of electric cleaner 23, the outlet of desulfurization unit 3 Particulate matter (carrying containing Gypsum Fibrosum) concentration about 16mg/Nm3, the outlet particle concentration about 4mg/Nm of wet cottrell 43, it is achieved The near-zero release of dust (< 5mg/Nm3).Sprayed into by cycling utilization of wastewater and pipeline, desulfurization unit and wet static dedusting Device, without arranging outside waste water, is truly realized wastewater zero discharge.
Embodiment 2
Use the equipment of fume treatment same as in Example 1.
The method using fume treatment same as in Example 1, except for the difference that, under waste water separator 7 isolated The density of layer liquid F is 1010kg/m3, the atomizing pressure in atomising device 6 is about 0.3MPa, and the liquid drop speed after atomization is about For 30m/s, the drop after atomization sprays into the upstream line of electric cleaner 2, and spraying into a little distance with electric cleaner 2 is 8 meters, flue gas Flow velocity about 12m/s, the time of staying in the duct of the drop after atomization is 0.6 second.Lower floor liquid F enters electricity after atomization and removes After the upstream line of dirt device 2 is evaporated completely, the smoke moisture in pipeline is increased to 9.18% by 8.61%, and flue-gas temperature is reduced to 120℃。
After tested, outlet particle concentration (dust concentration) the about 21mg/Nm of electric cleaner 23, the outlet of desulfurization unit 3 Particulate matter (carrying containing Gypsum Fibrosum) concentration about 12mg/Nm3, the outlet particle concentration about 3mg/Nm of wet cottrell 43, it is achieved The near-zero release of dust (< 5mg/Nm3)。
Embodiment 3
Use the equipment of fume treatment same as in Example 1.
The method using fume treatment same as in Example 1, except for the difference that, under waste water separator 7 isolated The density of layer liquid F is 1050kg/m3, the atomizing pressure in atomising device 6 is about 0.5MPa, and the liquid drop speed after atomization is about For 50m/s, the drop after atomization sprays into the upstream line of electric cleaner 2, and spraying into a little distance with electric cleaner 2 is 10 meters, cigarette Gas velocity about 12m/s, the time of staying in the duct of the drop after atomization is 0.8 second.Lower floor liquid F enters electricity after atomization After the upstream line of cleaner unit 2 is evaporated completely, the smoke moisture in pipeline is increased to 9.02% by 8.61%, and flue-gas temperature reduces To 125 DEG C.
After tested, outlet particle concentration (dust concentration) the about 21mg/Nm of electric cleaner 23, the outlet of desulfurization unit 3 Particulate matter (carrying containing Gypsum Fibrosum) concentration about 18mg/Nm3, the outlet particle concentration about 4.5mg/Nm of wet cottrell 43, real Show near-zero release (the < 5mg/Nm of dust3)。
Embodiment 4
As in figure 2 it is shown, by boiler 1, electric cleaner 2, desulfurization unit 3, wet cottrell 4, chimney 5, atomising device 6, waste water separator 7 and wastewater treatment equipment 8 are attached, wherein, and the exhanst gas outlet of boiler 1 and the flue gas of electric cleaner 2 Entrance connects, and the fume emission mouth of described electric cleaner 2 is connected with the smoke inlet of described desulfurization unit 3 by pipeline, described The exhanst gas outlet of desulfurization unit 3 is connected with the smoke inlet of described wet cottrell 4 by pipeline, desulfurization unit 3 and wet The wastewater outlet of formula electrostatic precipitator 4 all entrances with waste water separator 7 are connected, the upper liquid of described waste water separator 7 Body outlet is connected with the water inlet of atomising device 6, and the outlet of atomising device 6 is connected with the pipeline of electric cleaner 2 upstream;Described useless Lower floor's liquid outlet of water separation device 7 is connected with the entrance of wastewater treatment equipment 8, the water out of described wastewater treatment equipment 8 It is connected with the water inlet of wet cottrell 4, the wastewater outlet of described wet cottrell 4 and described waste water separator The entrance of 7 connects.The exhanst gas outlet of described wet cottrell 4 is connected with chimney 5.
Power is the unit of 300MW, and fuel A (specially coal) burns in boiler 1 and produces flue gas, processes through denitration Rear entrance electric cleaner 2, the condition that denitration processes includes: using SCR technique, catalyst is vanadium Titanium series catalyst, temperature range For 290-400 DEG C.
The entrance flue gas temperature of electric cleaner 2 about 130 DEG C, flue gas flow about 1,100,000 Nm3/ h, the particulate matter in flue gas is dense Degree is 12g/Nm3.The particle concentration of the flue gas after electric cleaner 2 processes is 21mg/Nm3.After electric cleaner 2 processes Flue gas enters wet desulphurization device 3 and processes.SO in wet desulphurization device 3, in flue gas2React with lime stone slurry, Thus SO2Remove from flue gas.From absorption tower discharge lime stone slurry through cyclonic separation, wash and be dehydrated after obtain stone Cream, creates desulfurization wastewater B simultaneously.The pH value of desulfurization wastewater B is 5.5, and suspension content is 4.5g/L, in described desulfurization wastewater Containing Cl-、F-、SO4 2-、Ca2+、Mg2+.The weight of desulfurization wastewater B about 5 tons.
Flue gas desulfuration efficiency after wet desulphurization device 3 processes has reached 99%.Flue gas after desulfurization processes enters Wet cottrell 4.Described wet cottrell 4 uses flexible plate dedusting, and deashing is by the uniform water in full surface of pole plate Film flows automatically.The dust waste water F that described wet cottrell 4 produces contains a small amount of fine dust and Gypsum Fibrosum drop.Wet electrostatic removes The dust waste water about 1.5 tons that dirt device 4 produces.
Desulfurization wastewater B, after the separation of waste water separator 7, realizes three layers of separating effect according to density difference, is divided into Supernatant liquid C, lower floor liquid F and solid residue.Wherein, the density of supernatant liquid C about 1005kg/m3, weight about 2 tons, water Temperature about 40 DEG C, enters in atomising device 6 and is atomized under the effect of compressed air E, atomizing pressure about 0.4MPa, the drop after atomization Speed is 40m/s.Drop after atomization sprays into the upstream line of electric cleaner 2, and spraying into a little distance with electric cleaner 2 is 5 meters, Drop after the atomization time of staying in the duct is 0.5 second.
Through measuring and calculating, supernatant liquid C through atomization after enter electric cleaner 2 upstream line evaporate completely after, in pipeline Smoke moisture is increased to 8.91% by 8.61%, and flue-gas temperature is reduced to 126 DEG C.Flue gas is in undersaturated condition, higher than acid dew Point temperature (acid dew-point temperature about 80-95 DEG C), will not produce corrosion to flue and electric cleaner, therefore, there is no need to spray waste water After access point, pipeline and cleaner unit carry out reforming processing.Meanwhile, the increase of smoke moisture and the reduction of flue-gas temperature, also reduce electricity The ratio resistance that cleaner unit is mellow lime, is conducive to improving efficiency of dust collection.It addition, because of the reduction of flue-gas temperature and the increasing of humidity of flue gas Add, decrease the water consumption of FGD (flue gas desulfurization) system.(heavy metal, impurity and each additionally, solids in desulfurization wastewater Plant slaine etc.) it is suspended in together with ash in flue gas and enters electric cleaner with flue gas, caught by electrode in electric cleaner, with Ash outer row together, because in desulfurization wastewater, amount of solid and various metal salt concentration are less, physical property and comprehensive utilization to ash will not be produced Raw impact.
The flue gas that wet cottrell 4 processed discharges through chimney 5, lower floor's liquid D that waste water separator 7 produces Through the purified treatment of wastewater treatment equipment 8, purified treatment includes using chemical agent to carry out flocculation sediment, and by purified treatment After water as the flushing water of wet cottrell 4.The condition of flushing water includes that pH value is 7.2, and solid suspension is 65ppm。
It addition, collect solid-state Gypsum Fibrosum that waste water separator 7 produces and body refuse H and wastewater treatment equipment 8 produce consolidates Body residue carries out subsequent treatment, and solid-state Gypsum Fibrosum is transported to stockyard, body refuse and solid residue is abandoned.
After tested, outlet particle concentration (dust concentration) the about 21mg/Nm of electric cleaner 23, wet desulphurization device 3 Outlet particulate matter (carrying containing Gypsum Fibrosum) concentration about 16mg/Nm3, the outlet particle concentration about 4mg/Nm of wet cottrell 43, Achieve near-zero release (the < 5mg/Nm of dust3).Sprayed into by cycling utilization of wastewater and pipeline, wet desulphurization device and wet type Electrostatic precipitator, without arranging outside waste water, is truly realized wastewater zero discharge.
Comparative example 1
According to the same manner as in Example 1 by boiler 1, electric cleaner 2, desulfurization unit 3, wet cottrell 4, cigarette Chimney 5 is attached.Except for the difference that, atomising device 6 and waste water separator 7 are not included.
Power is the unit of 300MW, and fuel A (specially coal) burns in boiler 1 and produces flue gas, processes through denitration Rear entrance electric cleaner 2.Process according to condition same as in Example 1.
Flue gas discharges through chimney 5 after passing sequentially through electric cleaner 2, desulfurization unit 3, wet cottrell 4.
Through measuring and calculating, the entrance flue gas temperature of electric cleaner 2 130 DEG C, (dust is dense for the outlet particle concentration of electric cleaner 2 Degree) 35mg/Nm3, outlet particulate matter (carrying containing Gypsum Fibrosum) concentration 25mg/Nm of desulfurization unit 33, going out of wet cottrell 4 Mouth particle concentration 7mg/Nm3.The desulfurization wastewater 3.8 tons that desulfurization unit 3 produces, the dedusting that wet cottrell 4 produces is given up 1.2 tons of water, standard discharge after needing to process.
From the result of embodiment and comparative example it can be seen that use the equipment of the fume treatment of this utility model offer, warp Cross the flue gas after processing, it is achieved that near-zero release (the < 5mg/Nm of dust3), additionally, wet desulphurization device and wet electrostatic remove Dirt device is without arranging outside waste water, it is achieved that the zero-emission of waste water.And in contrast, in comparative example 1, wet cottrell 4 goes out Particle concentration in the flue gas of mouth, apparently higher than embodiment 1, also creates a large amount of waste water, in addition it is also necessary to through follow-up place simultaneously Reason can be discharged.
Preferred implementation of the present utility model described in detail above, but, this utility model is not limited to above-mentioned reality Execute the detail in mode, in technology concept of the present utility model, the technical solution of the utility model can be entered The multiple simple variant of row, these simple variant belong to protection domain of the present utility model.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance In the case of shield, can be combined by any suitable means.In order to avoid unnecessary repetition, this utility model is to respectively Plant possible compound mode to illustrate the most separately.
Additionally, combination in any can also be carried out, as long as it is not disobeyed between various different embodiment of the present utility model Carrying on the back thought of the present utility model, it should be considered as content disclosed in the utility model equally.

Claims (11)

1. an equipment for fume treatment, this equipment includes electric cleaner (2), desulfurization unit (3), wet cottrell (4), The fume emission mouth of described electric cleaner (2) is connected with the smoke inlet of described desulfurization unit (3) by pipeline, described desulfurization list The exhanst gas outlet of unit (3) is connected with the smoke inlet of described wet cottrell (4) by pipeline, it is characterised in that this sets Standby atomising device (6) and the waste water separator (7) of also including, the wastewater outlet of desulfurization unit (3) and waste water separator (7) Entrance connects, and the liquid outlet of described waste water separator (7) is connected with the water inlet of atomising device (6), atomising device (6) Outlet is connected with the pipeline of electric cleaner (2) upstream.
Equipment the most according to claim 1, it is characterised in that the liquid outlet of described waste water separator (7) includes Layer liquid outlet and lower floor's liquid outlet, the outlet of described supernatant liquid is connected with the sulfur removal technology water inlet of desulfurization unit (3), institute State lower floor's liquid outlet to be connected with the water inlet of atomising device (6).
Equipment the most according to claim 2, it is characterised in that the outlet of described supernatant liquid and described wet cottrell (4) wastewater outlet all sulfur removal technology water inlets with desulfurization unit (3) are connected.
Equipment the most according to claim 1, it is characterised in that the equipment of described fume treatment also includes wastewater treatment equipment (8), the liquid outlet of described waste water separator (7) includes supernatant liquid outlet and lower floor's liquid outlet, described supernatant liquid Outlet is connected with the water inlet of described atomising device (6), described lower floor liquid outlet and the entrance of described waste water separator (8) Connecting, the outlet of described wastewater treatment equipment (8) is connected with the water inlet of described wet cottrell (4), and described wet type is quiet The wastewater outlet of electric cleaner (4) is connected with the entrance of described waste water separator (7).
5. according to the equipment described in any one in claim 1-4, it is characterised in that described atomising device (6) is compression sky Gas jet atomising device.
6. according to the equipment described in any one in claim 1-4, it is characterised in that described waste water separator (7) is attached most importance to Power type solid-liquid separator.
Equipment the most according to claim 4, it is characterised in that described wastewater treatment equipment (8) is chemical flocculation precipitation dress Put.
8. according to the equipment described in any one in claim 1-4, it is characterised in that described electric cleaner (2) is that electrostatic removes Dirt device and/or electrostatic fabric filter.
Equipment the most according to claim 1, it is characterised in that described desulfurization unit (3) is wet desulphurization device.
10. according to the equipment described in any one in claim 1-4, it is characterised in that the outlet of described atomising device (6) with The position that the pipeline of electric cleaner (2) upstream connects is not less than 5 meters with the distance of the entrance of described electric cleaner (2).
11. according to the equipment described in any one in claim 1-4, it is characterised in that described equipment also includes boiler (1), The pipeline of described electric cleaner (2) upstream is the pipeline between boiler (1) and electric cleaner (2), and the liquid after described atomization Drip and there is no miscellaneous equipment between position and the electric cleaner (2) of the pipeline spraying into electric cleaner upstream.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106039911A (en) * 2016-07-29 2016-10-26 中国神华能源股份有限公司 Equipment and method for flue gas treatment
CN107051084A (en) * 2017-04-27 2017-08-18 浙江菲达环保科技股份有限公司 Deep temperature reduction coupling humidification puies forward the wastewater zero discharge dust pelletizing system of effect

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106039911A (en) * 2016-07-29 2016-10-26 中国神华能源股份有限公司 Equipment and method for flue gas treatment
CN107051084A (en) * 2017-04-27 2017-08-18 浙江菲达环保科技股份有限公司 Deep temperature reduction coupling humidification puies forward the wastewater zero discharge dust pelletizing system of effect
CN107051084B (en) * 2017-04-27 2023-01-06 浙江菲达环保科技股份有限公司 Wastewater zero-discharge dedusting system with deep cooling, humidifying and efficiency improving functions

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