CN205803169U - A kind of algin production waste water recycling system - Google Patents

A kind of algin production waste water recycling system Download PDF

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Publication number
CN205803169U
CN205803169U CN201620525326.0U CN201620525326U CN205803169U CN 205803169 U CN205803169 U CN 205803169U CN 201620525326 U CN201620525326 U CN 201620525326U CN 205803169 U CN205803169 U CN 205803169U
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ultrafiltration
flocculation
water
reverse osmosis
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赵玲
刘淇
曹荣
温锦力
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Yellow Sea Fisheries Research Institute Chinese Academy of Fishery Sciences
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Yellow Sea Fisheries Research Institute Chinese Academy of Fishery Sciences
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Abstract

一种褐藻胶生产废水回收利用系统,属于水产加工、环保技术领域,它包括沉降单元、絮凝单元、板框压滤单元、微滤单元、超滤单元、反渗透单元和超滤浓水储存罐;其中沉降单元、絮凝单元、板框压滤单元、微滤单元、超滤单元、反渗透单元依次通过水管相连通;超滤浓液储存罐单元与超滤单元和絮凝单元相连通;本实用新型结构简单,处理成本低,处理费用为1.5~2.1元/吨,与使用自来水相比节约大量成本;本实用新型可以去掉钙镁和钠离子、氯离子,去除率90%以上,处理效果好,废水回收率为50%~60%,有效去除了废水中的有机物、钠离子和钙离子等,能够满足褐藻胶生产用水的要求,最后经过反渗透膜处理的浓水液达到排放指标。

A recycling system for alginate production wastewater, which belongs to the technical field of aquatic products processing and environmental protection, and includes a settling unit, a flocculation unit, a plate and frame filter unit, a microfiltration unit, an ultrafiltration unit, a reverse osmosis unit and an ultrafiltration concentrated water storage tank Among them, the settling unit, flocculation unit, plate and frame filter unit, microfiltration unit, ultrafiltration unit, and reverse osmosis unit are connected through water pipes in sequence; the ultrafiltration dope storage tank unit is connected with the ultrafiltration unit and the flocculation unit; The new structure is simple, the treatment cost is low, and the treatment cost is 1.5-2.1 yuan/ton, which saves a lot of cost compared with the use of tap water; the utility model can remove calcium, magnesium, sodium ions, and chloride ions, and the removal rate is over 90%, and the treatment effect is good , The wastewater recovery rate is 50% to 60%, effectively removing organic matter, sodium ions and calcium ions in the wastewater, which can meet the water requirements for alginate production, and finally the concentrated water treated by the reverse osmosis membrane reaches the discharge index.

Description

一种褐藻胶生产废水回收利用系统A recycling system for alginate production wastewater

技术领域technical field

本实用新型属于水产加工、环保技术领域,具体地涉及一种褐藻胶生产废水回收利用系统。The utility model belongs to the technical field of aquatic product processing and environmental protection, and in particular relates to a recycling system for alginate production wastewater.

背景技术Background technique

褐藻胶是以褐藻为原料提取生产的,生产过程中耗水巨大,生产1吨褐藻胶需要用淡水800—1200吨;同时生产工艺中使用酸碱和钙盐,造成废水中盐分含量高、成分复杂,生化处理难度大。目前褐藻胶生产废水的治理采用曝气生化法,处理后废水无法回用,需要污水处理厂再次处理,企业需要负担巨大的污水处理费。专利200610069057.2采用多种技术处理褐藻胶废水,其中对废钙水进行预处理、脱钙、循环氧化、过滤、生物氧化、蛋白处理和反渗透处理等步骤,能够将废钙水处理回用,但该方法操作复杂、电力消耗大、水处理费用高,无法满足生产需要。因此,急需一种成本低、经济实用的褐藻胶生产废水回收利用系统,实现节约用水、保护环境、提高企业经济效益的目标。Alginate is extracted and produced from brown algae. The production process consumes a lot of water. The production of 1 ton of alginate requires 800-1200 tons of fresh water. At the same time, acid-base and calcium salts are used in the production process, resulting in high salt content in waste water. Complex, biochemical treatment is difficult. At present, the treatment of alginate production wastewater adopts the aeration biochemical method. After treatment, the wastewater cannot be reused and needs to be treated again by sewage treatment plants. Enterprises need to bear huge sewage treatment fees. Patent 200610069057.2 uses a variety of technologies to treat alginate wastewater, including pretreatment, decalcification, cyclic oxidation, filtration, biological oxidation, protein treatment, and reverse osmosis treatment of waste calcium water, which can reuse calcium waste water. This method is complicated to operate, consumes a lot of power, and the cost of water treatment is high, so it cannot meet the production needs. Therefore, there is an urgent need for a low-cost, economical and practical alginate production wastewater recycling system to achieve the goals of saving water, protecting the environment, and improving economic benefits for enterprises.

发明内容Contents of the invention

本实用新型要解决的技术问题是提供一种褐藻胶生产废水回收利用系统,实现褐藻胶生产废水的部分回收利用,节约用水,保护环境,且本发明系统操作简单,处理成本低,经济实用。The technical problem to be solved by the utility model is to provide a recycling system for alginate production wastewater, realize partial recycling of alginate production wastewater, save water, protect the environment, and the system of the invention is simple in operation, low in treatment cost, economical and practical.

本实用新型是通过以下技术方案实现:The utility model is realized through the following technical solutions:

一种褐藻胶生产废水回收利用系统,它包括沉降单元、絮凝单元、板框压滤单元、微滤单元、超滤单元、反渗透单元和超滤浓水储存罐;A recycling system for alginate production wastewater, which includes a sedimentation unit, a flocculation unit, a plate and frame filter unit, a microfiltration unit, an ultrafiltration unit, a reverse osmosis unit, and an ultrafiltration concentrated water storage tank;

其中沉降单元、絮凝单元、板框压滤单元、微滤单元、超滤单元、反渗透单元依次通过水管相连通;超滤浓液储存罐单元与超滤单元和絮凝单元相连通;Among them, the settling unit, flocculation unit, plate and frame filter unit, microfiltration unit, ultrafiltration unit, and reverse osmosis unit are connected through water pipes in sequence; the ultrafiltration concentrated liquid storage tank unit is connected with the ultrafiltration unit and the flocculation unit;

褐藻胶生产废水首先收集于沉降单元,经过斜板沉降池进行沉降,除去部分悬浮物及杂质;经过沉降的废水后进入絮凝单元,在絮凝单元,加入絮凝剂聚丙烯酰胺,混匀后,进行絮凝沉降;经过絮凝沉降后的废水进入板框压滤单元,采用板框压滤机进行压滤;压滤出水进入微滤单元,进行微滤处理;微滤水进入超滤单元,进行超滤处理,超滤浓水在超滤浓水罐储存单元进行储存,然后进入絮凝单元,进一步处理;超滤水进入反渗透单元,进行反渗透处理,反渗透浓水达标排放,渗透水回收利用。Alginate production wastewater is first collected in the settling unit, and settles through the inclined plate settling tank to remove part of the suspended solids and impurities; after the settled wastewater enters the flocculation unit, the flocculant polyacrylamide is added to the flocculation unit, and after mixing, the Flocculation and sedimentation; the waste water after flocculation and sedimentation enters the plate-and-frame filter press unit, and the plate-and-frame filter press is used for press filtration; the press-filtered water enters the microfiltration unit for microfiltration treatment; the microfiltration water enters the ultrafiltration unit for ultrafiltration Treatment, the ultrafiltration concentrated water is stored in the ultrafiltration concentrated water tank storage unit, and then enters the flocculation unit for further treatment; the ultrafiltration water enters the reverse osmosis unit for reverse osmosis treatment, the reverse osmosis concentrated water is discharged up to the standard, and the permeated water is recycled.

本实用新型与现有技术相比的有益效果:The utility model has the beneficial effects compared with the prior art:

本实用新型结构简单,处理成本低,处理费用为1.5~2.1元/吨,与使用自来水相比节约大量成本;本发明系统可以去掉钙镁和钠离子、氯离子,去除率90%以上,处理效果好,废水回收率为50%~60%,有效去除了废水中的有机物、钠离子和钙离子等,能够满足褐藻胶生产用水的要求,最后经过反渗透膜处理的浓水液达到排放指标。The utility model has the advantages of simple structure, low treatment cost, and the treatment cost is 1.5-2.1 yuan/ton, which saves a lot of cost compared with the use of tap water; The effect is good, the wastewater recovery rate is 50% to 60%, and the organic matter, sodium ion and calcium ion in the wastewater are effectively removed, which can meet the requirements of alginate production water, and finally the concentrated water treated by the reverse osmosis membrane reaches the discharge index .

附图说明Description of drawings

图1是本实用新型一种褐藻胶生产废水回收利用系统示意图:沉降单元1、絮凝单元2、板框压滤单元3、微滤单元4、超滤单元5、反渗透单元6和超滤浓水储存罐7。Fig. 1 is a schematic diagram of a recycling system for alginate production wastewater of the present invention: settling unit 1, flocculation unit 2, plate and frame filter unit 3, microfiltration unit 4, ultrafiltration unit 5, reverse osmosis unit 6 and ultrafiltration concentration Water storage tank7.

具体实施方式detailed description

下面通过实施例结合附图来对本实用新型的技术方案作进一步解释,但本实用新型的保护范围不受实施例任何形式上的限制。The technical scheme of the utility model will be further explained below through the embodiments in conjunction with the accompanying drawings, but the protection scope of the utility model is not limited in any form by the embodiments.

实施例Example

一种褐藻胶生产废水回收利用系统,它包括沉降单元1、絮凝单元2、板框压滤单元3、微滤单元4、超滤单元5、反渗透单元6和超滤浓水储存罐7。A recycling system for alginate production wastewater, which includes a settling unit 1, a flocculation unit 2, a plate and frame filter unit 3, a microfiltration unit 4, an ultrafiltration unit 5, a reverse osmosis unit 6 and an ultrafiltration concentrated water storage tank 7.

其中沉降单元1、絮凝单元2、板框压滤单元3、微滤单元4、超滤单元5、反渗透单元6依次通过水管相连通;超滤浓液储存罐单元7与超滤单元5和絮凝单2元相连通;Among them, the settling unit 1, the flocculation unit 2, the plate and frame filter unit 3, the microfiltration unit 4, the ultrafiltration unit 5, and the reverse osmosis unit 6 are sequentially connected through water pipes; the ultrafiltration dope storage tank unit 7 is connected with the ultrafiltration unit 5 and Flocculation unit 2-unit connected;

利用上述系统对褐藻胶生产废水进行处理,处理前藻胶生产废水COD640mg/L,硬度53德国度,盐分(以氯化钠计)0.2%。具体处理步骤如下:The above-mentioned system is used to treat the alginate production wastewater. Before the treatment, the COD of the alginate production wastewater is 640 mg/L, the hardness is 53 German degrees, and the salinity (calculated as sodium chloride) is 0.2%. The specific processing steps are as follows:

(1)褐藻胶生产废水收集于沉降单元1,经斜板沉降池沉降处理,除去部分悬浮物及杂质,降低废水中的COD。(1) The alginate production wastewater is collected in the settling unit 1, and settled in the inclined plate settling tank to remove part of the suspended solids and impurities and reduce the COD in the wastewater.

(2)经过沉降的废水随后进入絮凝单元2,在絮凝单元2,按40mg/L水体的用量加入絮凝剂聚丙烯酰胺,混匀后进行絮凝沉降。(2) The settled wastewater then enters the flocculation unit 2, where the flocculant polyacrylamide is added in an amount of 40mg/L water body, and then flocculated and settled after mixing.

(3)经过絮凝沉降后的废水进入板框压滤单元3,进行压滤。(3) The waste water after flocculation and sedimentation enters the plate and frame filter press unit 3 for press filtration.

(4)压滤水进入微滤单元4,进行微滤处理,去除板框压滤过程中没有除去的固形物,保证超滤进水水质。(4) The press-filtered water enters the microfiltration unit 4 for microfiltration treatment to remove solids not removed during the plate-and-frame press-pressing process to ensure the quality of ultrafiltration influent water.

(5)微滤水进入超滤单元5,进行超滤处理,超滤浓水在超滤浓水罐储存单元7,然后进入絮凝单元2,进一步处理。(5) The microfiltration water enters the ultrafiltration unit 5 for ultrafiltration treatment, and the ultrafiltration concentrated water is stored in the ultrafiltration concentrated water tank storage unit 7, and then enters the flocculation unit 2 for further processing.

(6)超滤水随后进入反渗透单元6,进行反渗透处理,反渗透浓水达标排放,渗透水回收利用。(6) The ultrafiltered water then enters the reverse osmosis unit 6 for reverse osmosis treatment, the concentrated reverse osmosis water is discharged up to the standard, and the permeated water is recycled.

本实施例处理后的清水COD 11mg/L,硬度0.7德国度,盐分(以氯化钠计)0.01%。反渗透浓水COD210mg/L(符合排放要求),本实施例海藻酸钠生产废水处理费用为1.5~2.1元/吨水。The clear water treated in this embodiment has a COD of 11 mg/L, a hardness of 0.7 German degrees, and a salt content (calculated as sodium chloride) of 0.01%. The COD of reverse osmosis concentrated water is 10 mg/L (meeting discharge requirements), and the waste water treatment cost of sodium alginate production in this embodiment is 1.5-2.1 yuan/ton of water.

Claims (1)

1.一种褐藻胶生产废水回收利用系统,它包括沉降单元、絮凝单元、板框压滤单元、微滤单元、超滤单元、反渗透单元和超滤浓水储存罐;其中沉降单元、絮凝单元、板框压滤单元、微滤单元、超滤单元、反渗透单元依次通过水管相连通;超滤浓液储存罐单元与超滤单元和絮凝单元相连通;1. A system for recycling waste water from alginate production, which includes a settling unit, a flocculation unit, a plate and frame filter press unit, a microfiltration unit, an ultrafiltration unit, a reverse osmosis unit and an ultrafiltration concentrated water storage tank; wherein the settling unit, the flocculation unit The unit, plate and frame filter unit, microfiltration unit, ultrafiltration unit, and reverse osmosis unit are connected through water pipes in sequence; the ultrafiltration concentrate storage tank unit is connected with the ultrafiltration unit and the flocculation unit; 褐藻胶生产废水首先收集于沉降单元,经过斜板沉降池进行沉降,除去部分悬浮物及杂质;经过沉降的废水后进入絮凝单元,在絮凝单元,加入絮凝剂聚丙烯酰胺,混匀后,进行絮凝沉降;经过絮凝沉降后的废水进入板框压滤单元,采用板框压滤机进行压滤;压滤出水进入微滤单元,进行微滤处理;微滤水进入超滤单元,进行超滤处理,超滤浓水在超滤浓水罐储存单元进行储存,然后进入絮凝单元,进一步处理;超滤水进入反渗透单元,进行反渗透处理,反渗透浓水达标排放,渗透水回收利用。Alginate production wastewater is first collected in the settling unit, and settles through the inclined plate settling tank to remove part of the suspended solids and impurities; after the settled wastewater enters the flocculation unit, the flocculant polyacrylamide is added to the flocculation unit, and after mixing, the Flocculation and sedimentation; the waste water after flocculation and sedimentation enters the plate-and-frame filter press unit, and the plate-and-frame filter press is used for press filtration; the press-filtered water enters the microfiltration unit for microfiltration treatment; the microfiltration water enters the ultrafiltration unit for ultrafiltration Treatment, the ultrafiltration concentrated water is stored in the ultrafiltration concentrated water tank storage unit, and then enters the flocculation unit for further treatment; the ultrafiltration water enters the reverse osmosis unit for reverse osmosis treatment, the reverse osmosis concentrated water is discharged up to the standard, and the permeated water is recycled.
CN201620525326.0U 2016-06-02 2016-06-02 A kind of algin production waste water recycling system Expired - Fee Related CN205803169U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106977007A (en) * 2017-03-29 2017-07-25 中国石油大学(华东) The system and method for bi-membrane method advanced treating brown alga chemical industry waste Ca water
CN110963594A (en) * 2019-12-04 2020-04-07 南京工业大学连云港工业技术研究院 Double-membrane method sodium alginate sewage treatment recycling process
CN119430585A (en) * 2025-01-06 2025-02-14 金科环境股份有限公司 A treatment system and method for sodium alginate production wastewater

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106977007A (en) * 2017-03-29 2017-07-25 中国石油大学(华东) The system and method for bi-membrane method advanced treating brown alga chemical industry waste Ca water
CN110963594A (en) * 2019-12-04 2020-04-07 南京工业大学连云港工业技术研究院 Double-membrane method sodium alginate sewage treatment recycling process
CN119430585A (en) * 2025-01-06 2025-02-14 金科环境股份有限公司 A treatment system and method for sodium alginate production wastewater
CN119430585B (en) * 2025-01-06 2025-04-18 金科环境股份有限公司 System and method for treating sodium alginate production wastewater

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