CN205784769U - A kind of refrigerant hydrate circulation cold storage system - Google Patents
A kind of refrigerant hydrate circulation cold storage system Download PDFInfo
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- CN205784769U CN205784769U CN201620445872.3U CN201620445872U CN205784769U CN 205784769 U CN205784769 U CN 205784769U CN 201620445872 U CN201620445872 U CN 201620445872U CN 205784769 U CN205784769 U CN 205784769U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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Abstract
A kind of refrigerant hydrate circulation cold storage system, including hydrate reaction bucket, absorber, solution pump, generator, the mixed liquor that condenser and the DMF solvent run in the entire system are formed with refrigerant R134a, DMF solvent and refrigerant R134a form mixed solution in absorber, and by solution pump to generator, in generator, evaporation produces R134a steam, the most condensed device cooling liquid enters in the evaporator coil being positioned at hydrate reaction bucket, cold is provided for hydrate reaction, then return in absorber, surplus solution in generator mixes in also returning to absorber again.This utility model achieves on temperature higher daytime, by the purpose absorbing heat to be reached for room cooling of melting of hydrate, and at night, utilizes used heat or electric energy at a low price, by charge cycle system, to reach the purpose of refrigerant gas hydrate cold-storage.
Description
Technical field
This utility model relates to industrial refrigeration field, a kind of refrigerant hydrate circulation cold storage system.
Background technology
Due to the raising of people's living standard, air-conditioning is more and more universal, but owing to the energy consumption of air-conditioning is very big, its concentration
Use causes electricity consumption peak-valley difference in city away from day by day increasing.For the peak load shifting of electrical network, advocate now energy accumulation air conditioner, reasonable
A kind of selection is to use ice-storage system, and user can save a lot of running cost.But ice-storage system also has the shortcoming of self,
Such as initial cost is big, refrigeration unit during ice making is because there to be the lowest evaporating temperature, and its COP reduces.So from energy-conservation angle
For degree, ice cold-storage is not a kind of energy-saving scheme, simply can reduce running cost, can regulate network load.
Utility model content
The city electricity consumption peak-valley difference caused owing to being concentrated use in air-conditioning for solution is serious away from increase and energy resource consumption day by day
Problem, this utility model provides a kind of refrigerant hydrate circulation cold storage system, on the daytime that temperature is higher, by hydration
The thawing absorption heat of thing is to be reached for the purpose of room cooling, and at night, utilizes used heat or low price electric energy, is followed by cold-storage
Loop systems, to reach the purpose of refrigerant gas hydrate cold-storage.
The technological means that this utility model is used by the above-mentioned technical problem of solution is: a kind of refrigerant hydrate circulation stores
Cooling system, molten including hydrate reaction bucket, absorber, solution pump, generator, condenser and the DMF run in the entire system
The mixed liquor that agent is formed with refrigerant R134a, wherein, the upper and lower in described absorber is respectively arranged with solvent spray nozzle
With refrigerant holes pipe, DMF solvent and refrigerant R134a respectively after solvent spray nozzle and refrigerant holes pipe spray in absorber
Packing layer I at form mixed solution, and by solution pump to generator, and sprayed in generator by mixed liquor nozzle
Packing layer II on, generator is provided with the heater to the mixed solution heating after spray, so that the system in mixed solution
Cryogen R134a evaporation produce R134a steam, and the vapour pressure in generator more than top pressure-control valve value is set
Time, it being sent in condenser carry out cooling liquid by R134a steam, the R134a part after liquefaction is stored in fluctuation-type liquid storage
In device, another part enters the evaporator coil in hydrate reaction bucket that puts in place after thermal expansion valve regulation pressure flow
In, R134a absorbs heat in evaporator coil and again evaporates, and makes the temperature in hydrate reaction bucket reduce, the end of evaporator coil
End is connected with the refrigerant holes pipe in absorber by the road;
The solvent spray that in described generator, surplus solution after heated evaporation R134a is back in absorber by the road
Mouth;
Being provided with short-range missile skirt and the long guide wire with stop valve in described hydrate reaction bucket, both respectively will hydration
Through a canned motor pump mix homogeneously after the cold water of thing reaction container internal upper part and the R134a liquid extraction of bottom, then by with cut-off
The bye-pass I of valve and the mixing spray nozzle being arranged on hydrate reaction bucket internal upper part spray in hydrate reaction bucket, make cold water
Uniform with R134a liquid mixing, improve the production rate of hydrate;
Being parallel with a bye-pass II on described bye-pass I, bye-pass II connects fan coil and stop valve, so that screen
The hydrate covering pump discharge is sprayed in hydrate reaction bucket by mixing spray nozzle after fan coil heat exchange again, and at hydrate
Discharge R134a gas in reaction container, discharge R134a gas and enter into through the steam vent that hydrate reaction bucket top is offered
In pipeline III, bye-pass III is connected with the refrigerant holes pipe in absorber by stop valve and device for drying and filtering;
The top of described generator is provided with bye-pass IV and the hydrate reaction bucket inner bottom part of stop valve by one
Cold-producing medium nozzle connects, and the temperature/pressure sensor that the stop valve of bye-pass IV is arranged by hydrate reaction bucket inner top controls.
It is provided with heat exchanger between described solution pump and generator, so that through the mixed solution of solution pump and from generation
There is heat exchange in the surplus solution discharged in device in heat exchanger, temperature enters back in generator after raising.
It is provided with check (non-return) valve and hand control valve between described solution pump and heat exchanger.
It is provided with heating heat exchanger on described bye-pass I.
Pressure in described pressure-control valve constraint generator is less than 1MPa.
The heat exchange coil being passed through cooling water it is embedded with in described packing layer I.
Described heater position heating wire or be connected with the heat exchange coil of high temperature exhaust steam.
Described heat exchanger is shell-tube type solution heat exchanger.
Described condenser is finned cooler.
Described temperature/pressure sensor in hydrate reaction bucket pressure less than 0.4MPa time, control bye-pass IV stop valve beat
Open.
Beneficial effect: this utility model initially with the higher refrigerant hydrate of phase transition temperature as cool storage material, it is achieved
With mating of air conditioning condition (5 ~ 8 DEG C), solve ice cold-storage and release the big different transfer of heat of cold process and the energy loss that causes is asked
Topic, thus system has higher COP, refrigerant hydrate phase change amount of latent heat is suitable with ice, and cold-storage ability is considerable, solves water
The shortcoming that cold-storage apparatus is huge, compared with eutectic salt cold-storage, refrigerant hydrate cold-storage repeatedly release cold during, do not have
As eutectic salts cold-storage repeatedly release cold during cool storage material aging, the problem such as cold-storage ability rapid drawdown;
Furthermore, this utility model mentality of designing is the most intensive, is not only refrigeration system side apparatus such as generator, is also freezed
Agent hydrate is prepared side and is used;The canned motor pump that the long short tube of parallel connection on reaction container connects can be not only that hydrate preparation provides fully
The effect of mix refrigerant and cold water, also have release daytime cold during, provide power for chilled water circulation in blower fan end
Effect etc..
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model;
Reference: 1, hydrate reaction bucket, 2, mixing spray nozzle, 3, heating heat exchanger, 4, fan coil, 5, dried
Filter, 6, canned motor pump, 7, absorber, 8, solvent spray nozzle, 9, packing layer I, 10, heat exchange coil, 11, refrigerant holes pipe, 12, molten
Liquid pump, 13, check (non-return) valve, 14, heat exchanger, 15, generator, 16, heater, 17, packing layer II, 18, mixed liquor nozzle, 19,
Pressure-control valve, 20, fluctuation-type reservoir, 21, condenser, 22, heating power expansion valve, 23, cold-producing medium nozzle, 24, evaporator plate
Pipe, 25, temperature/pressure sensor, 26, bye-pass IV, 27, short-range missile skirt, 28, long guide wire, 29, bye-pass I, 30, bye-pass II,
31, bye-pass III.
Detailed description of the invention
As it can be seen, a kind of refrigerant hydrate circulation cold storage system, including hydrate reaction bucket 1, absorber 7, solution
The mixed liquor that pump 12, generator 15, condenser 21 and the DMF solvent run in the entire system are formed with refrigerant R134a, its
In, the upper and lower in described absorber 7 is respectively arranged with solvent spray nozzle 8 and refrigerant holes pipe 11, DMF solvent and refrigeration
It is molten that agent R134a forms mixing at the packing layer I 9 in absorber 7 respectively after solvent spray nozzle 8 and refrigerant holes pipe 11 spray
Liquid, and be pumped in generator 15 by solution pump 12, and the packing layer II 17 sprayed in generator 15 by mixed liquor nozzle 18
On, generator 15 is provided with the heater 16 to the mixed solution heating after spray, so that the cold-producing medium in mixed solution
R134a evaporation produce R134a steam, and the vapour pressure in generator 15 more than top pressure-control valve 19 value is set
Time, R134a steam is sent in condenser 21 carry out cooling liquid, the R134a part after liquefaction is stored in fluctuation-type storage
In liquid device 20, another part enters the evaporation in hydrate reaction bucket 1 that puts in place after heating power expansion valve 22 regulates pressure flow
In device coil pipe 24, R134a absorbs heat in evaporator coil 24 and again evaporates, and makes the temperature in hydrate reaction bucket 1 reduce, evaporation
The end of device coil pipe 24 is connected with the refrigerant holes pipe 11 in absorber 7 by the road;
In described generator 15, the surplus solution after heated evaporation R134a is back to the solvent in absorber 7 by the road
Spray nozzle 8;
Being provided with short-range missile skirt 27 and the long guide wire 28 with stop valve in described hydrate reaction bucket 1, both are respectively
Through canned motor pump 6 mix homogeneously after the cold water of hydrate reaction bucket 1 internal upper part and the R134a liquid of bottom are drawn, then pass through
Bye-pass I 29 and mixing spray nozzle 2 spray being arranged on hydrate reaction bucket 1 internal upper part with stop valve arrive hydrate reaction
In bucket 1, make cold water and R134a liquid mixing uniform, improve the production rate of hydrate;
It is parallel with a bye-pass II 30 on described bye-pass I 29, bye-pass II 30 connects and has fan coil 4 and cut-off
Valve, so that the hydrate that canned motor pump 6 is discharged is sprayed hydrate reaction bucket 1 by mixing spray nozzle 2 after fan coil 4 heat exchange again
In, and in hydrate reaction bucket 1, discharge R134a gas, discharge R134a gas and offer through hydrate reaction bucket 1 top
Steam vent enter in bye-pass III 31, bye-pass III 31 is by stop valve and device for drying and filtering 5 and the refrigeration in absorber 7
Agent hole pipe 11 connects;
The top of described generator 15 sets with hydrate reaction bucket 1 inner bottom part with the bye-pass IV 26 of stop valve by one
Some cold-producing medium nozzles 23 connect, and the temperature and pressure sensing that the stop valve of bye-pass IV 26 is arranged by hydrate reaction bucket 1 inner top
Device 25 controls.
It is more than basic embodiment of the present utility model, can further optimize, limit and change on the basis of above
Enter:
As, it is provided with heat exchanger 14 between described solution pump 12 and generator 15, so that through the mixing of solution pump 12 pumping
There is heat exchange with the surplus solution discharged from generator 15 in solution in heat exchanger 14, temperature enters back into generation after raising
In device 15;
Further, it is provided with check (non-return) valve 13 and hand control valve between described solution pump 12 and heat exchanger 14;
And for example, described bye-pass I 29 is provided with heating heat exchanger 3;
And for example, the pressure in described pressure-control valve 19 constraint generator 15 is less than 1MPa;
And for example, be embedded with in described packing layer I 9 be passed through cooling water heat exchange coil 10;
And for example, 16 heating wire of described heater or be connected with the heat exchange coil of high temperature exhaust steam;
For another example, described heat exchanger 14 is shell-tube type solution heat exchanger;
For another example, described condenser 21 is finned cooler;
Finally, described temperature/pressure sensor 25 in hydrate reaction bucket 1 pressure less than 0.4MPa time, control bye-pass IV 26
Stop valve open.
Below in conjunction with the accompanying drawings mode of operation of the present utility model is described in detail:
This utility model has night and two kinds of working methods on daytime
One) work at night mode:
Mode of working at night includes that again refrigerating part and hydrate prepare two relatively independent parts of part, therefore again can be by
Principle of working at night is split as above-mentioned two parts and introduces respectively:
Refrigerating part:
Now, native system uses Absorption Cooling System, and working medium is to using solvent DMF and refrigerant R134a, at generator
In 15, utilize heater 16 that the DMF saturated solution dissolved with R134a is heated, after being heated, the R134a steaming that boiling point is relatively low
Issuing, gas rises through packing layer II 17 and assembles in generator 15 top, after heating a period of time, along with R134a steam
The increase of amount, the pressure of generator 15 reaches about 1mpa, and the pressure-control valve 19 being positioned at generator 15 top is backed down,
R134a high temperature and high pressure steam is after check (non-return) valve, stop valve enter condenser 21, with cross-ventilation heat exchange, at condenser 21 end
Section coil pipe, R134a has become highly pressurised liquid, and a portion will be stored in fluctuation-type reservoir 20, and another part then passes through
Stop valve regulates pressure flow through heating power expansion valve 22, and the R134a liquid of low pressure enters evaporator coil 24 and evaporates, this vaporizer
Coil pipe 24 is positioned at hydrate reaction bucket 1, provides cold for hydrate reaction of formation.After evaporation, the R134a steam of low-pressure low-temperature
In taking away bucket, heat enters absorber 7, and in absorber 7, R134a steam enters in bottom through refrigerant holes pipe 11, DMF solvent
Being sprayed by upper solvent spray nozzle 8, steam rises, and solvent falls, and both converge in packing layer I in the middle part of absorber 7, packing layer
Be embedded with in I 9 be connected with cooling water heat exchange coil 10, with take away R134a steam be dissolved in DMF solvent produce heat, promote inhale
The generation of receipts process.The pressure of absorber 7 is similar to evaporator coil 24, about 0.3mpa, and the pressure of generator 15 is big
About 1mpa, so the saturated solution bottom absorber 7 needs to increase pressure could enter generator 15, therefore selects solution pump 12 to add
Pressure, then solution carries out heat exchange entrance generator 15 through heat exchanger 14 with from the DMF solvent that the temperature of generator 15 is higher, for
Improving luminous efficiency and reduce DMF solvent evaporation, using the mode that sprays as shown in the figure, spray to use nozzle, nozzle is placed in generation
Between the two-layer filler of device 15 top;
Hydrate prepares part
When the pressure of hydrate reaction bucket 1 is less than 0.4mpa, it is positioned at the temperature and pressure sensor 25 at hydrate reaction bucket 1 top
Receiving pressure signal, the stop valve controlling to be installed on bye-pass IV 26 is opened, and the R134a steam of High Temperature High Pressure sprays through cold-producing medium
Mouth 23 enters water from reaction container bottom, and steam can relatively evenly enter in water, and beneficially hydrate generates.Steam is made at buoyancy
Using lower rising, with the cold water heat exchange of surrounding in uphill process, R134a molecular kinetic energy constantly reduces, and steam is progressively changed by gaseous state
For liquid, under hypersaturated state, be combined generation refrigerant gas hydrate with cold water around.The most direct with high steam state
Being passed through the R134a of reaction container after around cold water is condensed into liquid, small part directly participates in generating hydrate, due to R134a liquid
Body is more than the density of water, so major part R134a liquid sinks converges at bottom reaction container.For improving the generation effect of hydrate
Rate, processes two holes bottom this design reaction container, short-range missile skirt 27 is installed in a hole, and long guide wire 28, design are installed in another hole
As it can be seen, long guide wire 28 draws the cold water on top, short-range missile skirt 27 draws the R134a liquid of bottom, and both draw reaction container, warp
Canned motor pump 6 is admixed, and is passed through the blended spray nozzle in reaction container top 2 and sprays, and both mix substantially uniform, beneficially the life of hydrate
Become.The general pressure requirements of generation of hydrate is 0.4mpa, and temperature controls at about 0 DEG C.Pressure is by being passed through reaction container
R134a high steam ensure, temperature by the evaporator coil 24 being placed in reaction container by controlling with ambient water heat exchange.Reaction
Bucket top is provided with temperature and pressure sensor 25, receives temperature and pressure signal in reaction container, controls refrigeration system heating plant and arm respectively
The start and stop of the stop valve on road IV 26.Heating heat exchanger 3 only serves the effect of insurance, anti-in order to prevent too much vapours from entering
Ying Tong, condenses into liquid deposition bottom reaction container, and does not participate in hydration reaction.Liquid level raise certain altitude or, pressure
In the case of excessive temperature is low, heater will be opened.
Two) work by day mode
Work by day is to be melted by the hydrate prepared night to provide cold.Now, by controller control, bottom reaction container
Long guide wire 28 on stop valve and be provided with heating heat exchanger 3 bye-pass I stop valve close, connect have fan coil
The stop valve of the bye-pass II 30 of 4 is opened.Owing to the ice content in reaction container is about 50%, and hydrate crystal is the softest,
Density is the highest, and canned motor pump 6 extracts chilled water bottom reaction container, introduces the fan coil 4 in room, after heat exchange, from reaction container
The blended spray nozzle in top sprays in reaction container.In hydrate melting process, in reaction container, pressure is relatively low, discharges R134a
Gas is assembled in reaction container top, and in bucket, pressure gradually rises, and affects the further generation of melting process, so on reaction container top
Portion has opened another hole and has installed bye-pass III 31, and this branch road drying filter 5 is connected with absorber 7.Top gas contains on a small quantity
Water vapour, drying filter 5 is dried and enters absorber 7 bottom, and when the time comes, solution pump 12 is opened, absorber 7 and generator 15 it
Interior DMF solvent circulates between, completes the absorption to the R134a steam from reaction container top.
Claims (10)
1. a refrigerant hydrate circulation cold storage system, it is characterised in that: include hydrate reaction bucket (1), absorber (7),
Solution pump (12), generator (15), condenser (21) and the DMF solvent run in the entire system are formed with refrigerant R134a
Mixed liquor, wherein, the upper and lower in described absorber (7) is respectively arranged with solvent spray nozzle (8) and refrigerant holes pipe
(11), DMF solvent and refrigerant R134a respectively after solvent spray nozzle (8) and refrigerant holes pipe (11) spray in absorber (7)
Interior packing layer I (9) place forms mixed solution, and is pumped in generator (15) by solution pump (12), and by mixed liquor nozzle
(18), on spray packing layer II (17) in generator (15), generator (15) is provided with the mixed solution heating after spray
Heater (16) so that the refrigerant R134a evaporation in mixed solution produces R134a steam, and in generator (15)
Vapour pressure more than when the arranging value of pressure-control valve (19) at top, be sent to R134a steam in condenser (21) carry out
Cooling liquid, the R134a part after liquefaction is stored in fluctuation-type reservoir (20), and another part is through heating power expansion valve (22)
Entering after regulation pressure flow and put in place in the evaporator coil (24) in hydrate reaction bucket (1), R134a is at evaporator coil
(24) in, heat absorption is evaporated again, makes the temperature in hydrate reaction bucket (1) reduce, the end of evaporator coil (24) by the road with
Refrigerant holes pipe (11) in absorber (7) connects;
In described generator (15), the surplus solution after heated evaporation R134a is back to the solvent in absorber (7) by the road
Spray nozzle (8);
Short-range missile skirt (27) and the long guide wire (28) with stop valve, Liang Zhefen it is provided with in described hydrate reaction bucket (1)
Through a canned motor pump (6) mix homogeneously after the cold water of hydrate reaction bucket (1) internal upper part and the R134a liquid of bottom not being drawn,
Pass through the bye-pass I (29) with stop valve again and be arranged on mixing spray nozzle (2) spray of hydrate reaction bucket (1) internal upper part
In hydrate reaction bucket (1), make cold water and R134a liquid mixing uniform, improve the production rate of hydrate;
Being parallel with a bye-pass II (30) on described bye-pass I (29), the upper connection of bye-pass II (30) has fan coil (4) and cuts
Only valve, so that the hydrate that canned motor pump (6) is discharged is sprayed hydration by mixing spray nozzle (2) after fan coil (4) heat exchange again
In thing reaction container (1), and discharge R134a gas in hydrate reaction bucket (1), discharge R134a gas anti-through hydrate
The steam vent answering bucket (1) top to offer enters in bye-pass III (31), and bye-pass III (31) is by stop valve and dry filter
Device (5) is connected with the refrigerant holes pipe (11) in absorber (7);
The top of described generator (15) by one with the bye-pass IV (26) of stop valve and hydrate reaction bucket (1) inner bottom part
The cold-producing medium nozzle (23) that is provided with connects, and the stop valve of bye-pass IV (26) is arranged by hydrate reaction bucket (1) inner top
Temperature/pressure sensor (25) controls.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described solution pump
(12) and between generator (15), be provided with heat exchanger (14), so that the mixed solution pumped through solution pump (12) with from generator
(15) there is heat exchange in the surplus solution discharged in heat exchanger (14), temperature enters back in generator (15) after raising.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 2, it is characterised in that: described solution pump
And between heat exchanger (14), be provided with check (non-return) valve (13) and hand control valve (12).
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described bye-pass I
(29) heating heat exchanger (3) it is provided with on.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described Stress control
Pressure in valve (19) constraint generator (15) is less than 1MPa.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described packing layer I
(9) heat exchange coil (10) being passed through cooling water it is embedded with in.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described heater
(16) position heating wire or be connected with the heat exchange coil of high temperature exhaust steam.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described heat exchanger
(14) it is shell-tube type solution heat exchanger.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described condenser
(21) it is finned cooler.
A kind of refrigerant hydrate circulation cold storage system the most according to claim 1, it is characterised in that: described temperature and pressure pass
Sensor (25) in hydrate reaction bucket (1) pressure less than 0.4MPa time, control bye-pass IV (26) stop valve open.
Priority Applications (1)
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CN201620445872.3U CN205784769U (en) | 2016-05-17 | 2016-05-17 | A kind of refrigerant hydrate circulation cold storage system |
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CN201620445872.3U CN205784769U (en) | 2016-05-17 | 2016-05-17 | A kind of refrigerant hydrate circulation cold storage system |
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Publication Number | Publication Date |
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ID=58118576
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106017178A (en) * | 2016-05-17 | 2016-10-12 | 河南科技大学 | Refrigerant hydrate circulating cool storage system |
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2016
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106017178A (en) * | 2016-05-17 | 2016-10-12 | 河南科技大学 | Refrigerant hydrate circulating cool storage system |
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Granted publication date: 20161207 Termination date: 20170517 |