CN205782979U - A kind of incinerator for processing high saliferous Waste Sulfuric Acid - Google Patents

A kind of incinerator for processing high saliferous Waste Sulfuric Acid Download PDF

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Publication number
CN205782979U
CN205782979U CN201620445819.3U CN201620445819U CN205782979U CN 205782979 U CN205782979 U CN 205782979U CN 201620445819 U CN201620445819 U CN 201620445819U CN 205782979 U CN205782979 U CN 205782979U
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incinerator
salt
fire
firebreak
steel
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CN201620445819.3U
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魏兰
江碧清
陈英斌
吴英来
赵建鑫
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China Petroleum and Chemical Corp
Research Institute of Sinopec Nanjing Chemical Industry Co Ltd
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Jiangsu Kerui Engineering Design Co Ltd
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Abstract

A kind of incinerator for processing high saliferous Waste Sulfuric Acid, it is characterised in that: incinerator is horizontal type structure, by outer and in include external thermal insulation, housing, insulating, fire-resistant acidproof resistance to salt deposit, housing includes cylinder, end plate and bearing;Firebreak it is arranged alternately inside burner hearth;Burner hearth bottom is provided with the fused salt guiding gutter at certain inclination angle, and arranges salt discharge hole in its minimum point;Furnace gas export is arranged on incinerator afterbody;Fire-resistant acidproof resistance to salt deposit uses prefabricated fire-resistant acidproof salt tolerant brick masonry.This utility model is used for processing high saliferous Waste Sulfuric Acid so that Waste Sulfuric Acid cleavage rate is close to 100%;Construct simple and convenient and good integrity;Run more safe and reliable.

Description

A kind of incinerator for processing high saliferous Waste Sulfuric Acid
Technical field
The invention belongs to technical field of environmental protection in chemical industry, be specifically related to a kind of incinerator for processing high saliferous Waste Sulfuric Acid.
Background technology
All kinds of chemical plant installations of China, such as relating to sulfonation, alkylation, hydration hydrolysis, purify and the technique such as dehydration, every year The capital a large amount of Waste Sulfuric Acid of by-product, the most domestic fine chemistry industry and dye industry, all produce a large amount of containing high concentration inorganic salt Waste Sulfuric Acid, the acid of this Waste Sulfuric Acid is dense relatively low, containing organic/inorganic substance and the inorganic salt of high concentration, it is extremely difficult to process.
The processing method of Waste Sulfuric Acid mainly has following several at present: 1. alkali neutralisation, allows sulphuric acid carry out with various inorganic bases Neutralize reaction, extracting sulfuric acid ammonium, magnesium sulfate, calcium sulfate etc..2. concentrate after imurity-removal, by adsorbing, filter, aoxidize, distilling, The mode such as air stripping, extraction removes the organic and inorganic impurity in Waste Sulfuric Acid, is then concentrated to give the dilute sulfuric acid after remove impurity Industrial concentrated sulphuric acid.3. reduction decomposition method, is sulfur dioxide with hydro carbons by Waste Sulfuric Acid reduction decomposition, processes the most further.4. High-temperature cracking method, reclaims sulfur dioxide, sulfur trioxide or sulfur by Waste Sulfuric Acid pyrolytic.All there is technique in these processing methods Complicated, processing cost is high, product quality is uneven, process the problem such as the most thorough.
Compared with above processing method, the method for Waste Sulfuric Acid burning Sulphuric acid can fundamentally solve the process of Waste Sulfuric Acid The advantages such as problem, has processing cost low, and product yield is high, good product quality, production process environmental protection, and by-product is a large amount of Steam, other need the equipment of steam to can be used to generating or supply plant area, have good environmental benefit and economic benefit.
Summary of the invention
Owing to traditional Waste Sulfuric Acid incinerator cannot process high saliferous Waste Sulfuric Acid, the present invention be directed to above-mentioned present situation, and carry A kind of incinerator for processing high saliferous Waste Sulfuric Acid gone out, the high saliferous Waste Sulfuric Acid of suitable treatment various chemical plant installations by-product. The inorganic salt that the Waste Sulfuric Acid that general incinerator processes contains high concentration, the kind of inorganic salt includes the sodium of the first and second main groups Salt, potassium salt, magnesium salt, calcium salt and transition metal salt.By high temperature incineration, Waste Sulfuric Acid cracking in incinerator contains dioxy Changing the flue gas of sulfur, subsequently into follow-up acid making system preparing finished articles sulphuric acid, Organic substance generates carbon dioxide and water, contains in Waste Sulfuric Acid It is pooled to fused salt guiding gutter after some inorganic salts are melted, is then discharged by the salt discharge hole bottom incinerator.
The present invention is achieved like this: for processing the incinerator of high saliferous Waste Sulfuric Acid, it is characterised in that: incinerator is Horizontal type structure, by outer and in include external thermal insulation, housing, insulating, fire-resistant acidproof resistance to salt deposit, housing includes cylinder, end Plate and bearing;Burner end plate is provided with spent sulfuric acid spray gun, main burner, hand hole;Cylinder be provided with explosionproof hole, flame detector, Visor, auxiliary burner, point for measuring temperature, pressure tap, manhole, baker steam vent;Be arranged alternately inside burner hearth perforate firebreak and under Perforate firebreak;Burner hearth bottom is provided with the fused salt guiding gutter at certain inclination angle, and arranges salt discharge hole in its minimum point;Furnace gas export It is arranged on incinerator afterbody;Described fire-resistant acidproof resistance to salt deposit uses prefabricated fire-resistant acidproof salt tolerant brick masonry, described fire-resistant resistance to The resistance to block salt of acid is made for adding metal-oxide in corundum.
Usually, described corundum includes electro-corundum, alundum, and the metal-oxide wherein added includes ZrO2、 Cr2O3、TiO2
Described burner end plate is provided with at least one spent acid spray gun, at least one main burner, a hand hole, and stove transom piece sets There is furnace gas export;Spent acid spray gun use mechanical atomization or compressed air atomization form, the material of spent acid spray gun be carborundum, Rustless steel or other heat-resisting salt tolerant steel alloys;Burner material is rustless steel.
Described external thermal insulation uses composition silicate fiber felt, ceramic fiber blanket or rock wool heat-preservation material.
The material of described housing is carbon steel, rustless steel or other steel alloys;Cylinder is externally provided with several stiffening ring, strengthens ring To soldering stainless steel plate as rain cover;It is welded with hexsteel or anchor studs structure inside cylinder, is used for fixing insulating, The material of hexsteel or anchor studs is carbon steel, rustless steel or other heat-resisting alloy steels, and the form of anchor studs includes Y type, V-type, S Type, Ω type;Being provided with anticorrosive heat insulating layer inside cylinder, anticorrosive heat insulating layer is some all over graphite waterglass anticorrosive coat for first brushing, and then sticks Patch asbestos board or ceramic beaverboard thermal insulation layer, or the coating of brush high temperature-resistant acid-resistant erosion or binding agent.
Before and after described incinerator, the top of cavity is respectively provided with 1 explosionproof hole, and the side of cylinder is provided with at least 1 fire defector Device, at least 1 visor, at least 1 auxiliary burner, at least 1 manhole, at least 2 points for measuring temperature of cylinder top setting, at least 1 Pressure tap, at least 2 baker steam vents, cylinder body bottom arranges at least 1 salt discharge hole.
Described cylinder is at least 4 by seat supports, the number of bearing, and incinerator is placed on some groups of bearing rollers, often Group bearing roller is made up of at least 2 round steel;The material of round steel is carbon steel, rustless steel or other steel alloys.
Described insulating horizontal and vertical on every 1~3m, one expansion joint is set;Between insulating, with And the expansion joint fissure of displacement layout between insulating and fire-resistant acidproof resistance to salt deposit, fissure of displacement distance is more than 100mm;Insulating Material is: aluminate or phosphate make bonding agent, adds aggregate and makes.
The middle part of described incinerator arranges at least 2 road firebreaks, the material of firebreak brick and fire-resistant acidproof resistance to salt deposit phase With;Firebreak includes perforate firebreak and lower perforate firebreak, and two kinds of firebreaks are crisscross arranged, the top of lower perforate firebreak Being provided with several perforates, access path is left in upper perforate firebreak bottom;Firebreak is internal and firebreak is fire-resistant with annular resistance to Between the resistance to salt deposit of acid, expansion joint is set.
Described aggregate is selected from porous clinker, hollow ball, floating bead, kieselguhr, perlite, Vermiculitum, ceramics filling.
Described porous clinker includes siliceous, clayey, High-Alumina, mullite, corundum etc.;Described hollow ball includes oxygen Change aluminum matter, mullite, aluminum chromium matter, chromium matter, zirconium matter etc..
When incinerator is installed, first it is placed on bearing roller, then the pre-embedded steel slab of afterbody with basis is welded and fixed. The corresponding one group of bearing roller of each saddle of incinerator, often group bearing roller is provided with some round steel, and round steel material is the most stainless Steel.
The maximum feature of the present invention is environmental protection, efficient and safety and stability.Burning in-furnace temperature, more than 800 DEG C, is joined Standby spent acid spray gun uses carborundum or the alloy of other high temperature resistant resistance to salt corrosions, not only ensure that atomizing effect but also has extended and makes With the life-span, bigger combustion space also ensure that the furnace gas sufficiently long time of staying so that Waste Sulfuric Acid cleavage rate is close to 100%;Separately Outward, it is contemplated that the corrosivity of acidic high-temperature furnace gas, and the hot, aggressive of fused salt, the fire-resistant acidproof resistance to salt deposit of incinerator uses Acidproof fire-resistant salt tolerant brick masonry;Insulating uses the ramming cast of castable scene, simple and convenient and good integrity of constructing;Every Arranging of hot expansion seam of insulating layer considers that the characteristic of castable does not use straight joint;Incinerator cylinder top arranges explosion-proof diaphragm, this Incinerator is all made to run a bit more safe and reliable.
Accompanying drawing explanation
The following drawings is the structural representation of incinerator of the present invention, and its effect only illustrates to burn for combining above-mentioned word Burn the structure of stove rather than be used for limiting the scope of the present invention.
Fig. 1 is embodiment of the present invention incinerator structural representation.
Fig. 2 is embodiment incinerator furnace head structure schematic diagram.
Fig. 3 is embodiment incinerator stove stern construction schematic diagram.
Fig. 4 is the structural representation of embodiment I type firebreak.
Fig. 5 is the structural representation of embodiment II type firebreak.
In figure, a, visor, b, manhole, c, point for measuring temperature, d, auxiliary burner, e, furnace gas export, f, spent sulfuric acid spray gun, g, main combustion Burner, j, flame detector, k, hand hole, m, standby hole, n, pressure tap, o, steam vent, p, explosionproof hole, s, salt discharge hole, u, fused salt Guiding gutter.
In figure, 1, stiffening ring, 2, external thermal insulation, 3, cylinder, 4, anticorrosive heat insulating layer, 5, insulating, 6, anchor studs, 7, Fire-resistant acidproof resistance to salt deposit, 8, end plate, 9, bearing, 10, bearing roller, 11, strengthen angle steel, 12, access path.
Detailed description of the invention
Below in conjunction with embodiment and accompanying drawing, the present invention is described in detail in.
Embodiment: the high saliferous Waste Sulfuric Acid of the present embodiment suitable treatment various chemical plant installations by-product.Can process containing high The Waste Sulfuric Acid of concentration inorganic salt, the kind of inorganic salt includes the sodium salt of the first and second main groups, potassium salt, magnesium salt, calcium salt and mistake Cross metallic salt.
With reference to accompanying drawing 1, incinerator is horizontal type structure, is placed in by incinerator on bearing roller (10) during installation.Incinerator Primary structure by outer and in include external thermal insulation (2), housing, insulating (5), fire-resistant acidproof resistance to salt deposit (7);Burner end plate It is provided with spent sulfuric acid spray gun (f), main burner (g), hand hole (k);Cylinder (3) be provided with explosionproof hole (p), flame detector (j), Visor (a), auxiliary burner (d), point for measuring temperature (c), pressure tap (n), manhole (b), baker steam vent (o);Alternately set inside burner hearth Put perforate firebreak (II type) and lower perforate firebreak (I type);Burner hearth bottom is provided with the fused salt guiding gutter at certain inclination angle (u), and salt discharge hole (s) is set in its minimum point;Furnace gas export (e) is arranged on incinerator afterbody.Fire-resistant acidproof resistance to salt deposit uses Prefabricated fire-resistant acidproof salt tolerant brick masonry, main material is for adding metal in corundum (including electro-corundum, alundum) Oxide is to improve its acidproof, salt corrosion and thermal shock resistance.
The fire-resistant acidproof main material of resistance to block salt is corundum (including electro-corundum, alundum), the metal oxygen wherein added Compound is ZrO2、Cr2O3、TiO2
Burner end plate is provided with at least one spent acid spray gun (f), at least one main burner (g), a hand hole (k), stove tail End plate is provided with furnace gas export (e).Spent acid spray gun uses mechanical atomization or the form of compressed air atomization, the material of spent acid spray gun For carborundum, rustless steel or other heat-resisting salt tolerant steel alloys.Burner material is rustless steel.
Incinerator is provided with external thermal insulation (2), and external thermal insulation can use composition silicate fiber felt, ceramic fiber blanket or rock The insulation materials such as cotton;Rainproof heat-insulation can also be played at stiffening ring (1) the hoop soldering stainless steel plate of pyrolysis furnace as rain cover Effect.
One of primary structure of incinerator is housing, and the material of housing can be carbon steel, rustless steel or other steel alloys.Shell Body is made up of cylinder (3), end plate (8) and bearing (9) etc..Cylinder (3) is externally provided with several stiffening ring (1);The welding of cylinder (3) inner side Having hexsteel or anchor studs (6) structure, be used for fixing insulating (5), the material of hexsteel or anchor studs (6) can be carbon Steel, rustless steel or other heat-resisting alloy steels, the form of anchor studs (6) can be Y type, V-type, S type, Ω type etc..
Cylinder (3) inner side is provided with anticorrosive heat insulating layer (4), first brushes some all over graphite waterglass anticorrosive coat, then pastes asbestos The thermal insulation layer such as plate or ceramic beaverboard;Can also the coating of one layer of high temperature-resistant acid-resistant of brush erosion or binding agent.
Cylinder (3) is provided with explosionproof hole (p), flame detector (j), visor (a), manhole (b), auxiliary burner (d), baker Steam vent (o), point for measuring temperature (c), pressure tap (n) and salt discharge hole (s) etc..Before and after incinerator the top of cavity be respectively provided with 1 explosion-proof Hole (p);The side of cylinder is provided with at least 1 flame detector (j), at least 1 visor (a), at least 1 auxiliary burner (d), At least 1 manhole (b);Cylinder top arranges at least 2 points for measuring temperature (c), at least 1 pressure tap (n), at least 2 baker aerofluxuss Hole (o);Cylinder body bottom arranges at least 1 salt discharge hole (s).
Incinerator cylinder (3) is supported by bearing (9), and material can be carbon steel, rustless steel or other steel alloys.Bearing (9) Number be at least 4, specifically determined by incinerator structure and length.
One of incinerator structure is some groups of bearing rollers (10), and often group bearing roller is made up of at least 2 round steel;Round steel Material can be carbon steel, rustless steel or other steel alloys.
One of structure of incinerator is insulating (5), and its material is: aluminate or phosphate make bonding agent, adds Porous clinker (including siliceous, clayey, High-Alumina, mullite, corundum etc.), hollow ball (include aluminum oxide, mullite Matter, aluminum chromium matter, chromium matter, zirconium matter etc.), floating bead, kieselguhr, perlite, Vermiculitum, the filler such as haydite.
Insulating (5) horizontal and vertical on every 1~3m, one expansion joint is set;Between insulating (5), And the expansion joint between insulating (5) and fire-resistant acidproof resistance to salt deposit (7) answers the fissure of displacement to arrange, fissure of displacement distance must be more than 100mm。
The middle part of incinerator arranges at least 2 road firebreaks, in order to increase gas stream in the stove turbulence.The material of firebreak brick with Fire-resistant acidproof resistance to salt deposit is identical;Firebreak has bottom perforate (I type) and top perforate (II type) two kinds, two kinds of firebreaks to interlock and set Putting, concrete structure is shown in schematic diagram;The top of I type firebreak is provided with several perforates, and access path is left in II type firebreak bottom (12);Between firebreak inside and firebreak and the fire-resistant acidproof resistance to salt deposit of annular, expansion joint is set.

Claims (9)

1. the incinerator being used for processing high saliferous Waste Sulfuric Acid, it is characterised in that: incinerator is horizontal type structure, by outer and interior bag Including external thermal insulation, housing, insulating, fire-resistant acidproof resistance to salt deposit, housing includes cylinder, end plate and bearing;On burner end plate It is provided with spent sulfuric acid spray gun, main burner, hand hole;Cylinder is provided with explosionproof hole, flame detector, visor, auxiliary burner, thermometric Point, pressure tap, manhole, baker steam vent;Perforate firebreak and lower perforate firebreak it is arranged alternately inside burner hearth;Burner hearth bottom It is provided with the fused salt guiding gutter at certain inclination angle, and salt discharge hole is set in its minimum point;Furnace gas export is arranged on incinerator afterbody;Institute State fire-resistant acidproof resistance to salt deposit and use prefabricated fire-resistant acidproof salt tolerant brick masonry.
Incinerator the most according to claim 1, it is characterised in that: burner end plate is provided with at least one spent acid spray gun, at least One main burner, a hand hole, stove transom piece is provided with furnace gas export;Spent acid spray gun uses mechanical atomization or compressed air mist The form changed, the material of spent acid spray gun is carborundum, rustless steel or other heat-resisting salt tolerant steel alloys;Burner material is stainless Steel.
Incinerator the most according to claim 1, it is characterised in that: external thermal insulation uses composition silicate fiber felt, pottery Fiber felt or rock wool heat-preservation material.
Incinerator the most according to claim 1, it is characterised in that: the material of housing is carbon steel, rustless steel or other alloys Steel;Cylinder is externally provided with several stiffening ring, and stiffening ring hoop soldering stainless steel plate is as rain cover;Hexsteel it is welded with inside cylinder Or anchor studs structure, the material being used for fixing insulating, hexsteel or anchor studs is carbon steel, rustless steel or other resistance to heat seals Jin Gang, the form of anchor studs includes Y type, V-type, S type, Ω type;Being provided with anticorrosive heat insulating layer inside cylinder, anticorrosive heat insulating layer is for first to brush Some all over graphite waterglass anticorrosive coats, then paste asbestos board or ceramic beaverboard thermal insulation layer, or the erosion of brush high temperature-resistant acid-resistant Coating or binding agent.
Incinerator the most according to claim 1, it is characterised in that: before and after incinerator the top of cavity be respectively provided with 1 explosion-proof Hole, the side of cylinder is provided with at least 1 flame detector, at least 1 visor, at least 1 auxiliary burner, at least 1 manhole, Cylinder top arranges at least 2 points for measuring temperature, at least 1 pressure tap, at least 2 baker steam vents, and cylinder body bottom arranges at least 1 Salt discharge hole.
Incinerator the most according to claim 1, it is characterised in that: cylinder is by seat supports, and the number of bearing is at least 4 Individual, incinerator is placed on some groups of bearing rollers, and often group bearing roller is made up of at least 2 round steel;The material of round steel be carbon steel, Rustless steel or other steel alloys.
Incinerator the most according to claim 1, it is characterised in that: insulating horizontal and vertical on every 1~3m One expansion joint is set;Between insulating, and the expansion joint fissure of displacement between insulating and fire-resistant acidproof resistance to salt deposit Arranging, fissure of displacement distance is more than 100mm;Heat-insulation and heat-preservation layer material is: aluminate or phosphate make bonding agent, adds aggregate and makes.
Incinerator the most according to claim 1, it is characterised in that: the middle part of incinerator arranges at least 2 road firebreaks, gear fire The material of wall brick is identical with fire-resistant acidproof resistance to salt deposit;Firebreak includes perforate firebreak and lower perforate firebreak, two kinds of gears Wall with flues is crisscross arranged, and the top of lower perforate firebreak is provided with several perforates, and access path is left in upper perforate firebreak bottom;Gear Between wall with flues inside and firebreak and the fire-resistant acidproof resistance to salt deposit of annular, expansion joint is set.
Incinerator the most according to claim 1, it is characterised in that described aggregate is selected from porous clinker, hollow ball, floating bead, silicon Diatomaceous earth, perlite, Vermiculitum, ceramics filling.
CN201620445819.3U 2016-05-17 2016-05-17 A kind of incinerator for processing high saliferous Waste Sulfuric Acid Active CN205782979U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107416775A (en) * 2017-09-19 2017-12-01 江苏科瑞工程设计有限公司 A kind of low nitrogen cracking technology of sour gas containing ammonia and Waste Sulfuric Acid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107416775A (en) * 2017-09-19 2017-12-01 江苏科瑞工程设计有限公司 A kind of low nitrogen cracking technology of sour gas containing ammonia and Waste Sulfuric Acid

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Effective date of registration: 20210714

Address after: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699

Patentee after: SINOPEC NANJING CHEMICAL RESEARCH INSTITUTE Co.,Ltd.

Address before: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699

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Patentee after: SINOPEC NANJING CHEMICAL RESEARCH INSTITUTE Co.,Ltd.

Address before: Liuhe District of Nanjing City, Jiangsu province 210048 geguan Road No. 699

Patentee before: SINOPEC NANJING CHEMICAL RESEARCH INSTITUTE Co.,Ltd.

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