CN205774813U - Sanitizer generating apparatus - Google Patents

Sanitizer generating apparatus Download PDF

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Publication number
CN205774813U
CN205774813U CN201620587962.6U CN201620587962U CN205774813U CN 205774813 U CN205774813 U CN 205774813U CN 201620587962 U CN201620587962 U CN 201620587962U CN 205774813 U CN205774813 U CN 205774813U
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China
Prior art keywords
disinfectant
generating apparatus
pump
water
sodium chloride
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CN201620587962.6U
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褚连成
谢溢明
何帅
张倩倩
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Guangzhou Ganges River Environmental Protection Design And Research Institute Ltd By Share Ltd
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Guangzhou Ganges River Environmental Protection Design And Research Institute Ltd By Share Ltd
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Abstract

This utility model relates to a kind of sanitizer generating apparatus, including disinfectant generation system, sodium chloride solution jettison system, temperature control system, disinfectant stocking system, power supply and robot control system(RCS), wherein, described disinfectant generation system includes electrolysis bath, this electrolysis bath includes anode chamber and the cathode chamber separated with asymmetric corrosion-resistant electrolyte membrane, described anode chamber is provided with anode, and for receiving the sodium chloride solution that described sodium chloride solution jettison system is thrown in, described cathode chamber is provided with negative electrode, described negative electrode and anode are respectively connecting to described power supply, to carry out cell reaction.This sanitizer generating apparatus, electrolytic chlorination sodium solution can be made to prepare the process controllable precise of disinfectant, different types of disinfectant can be prepared as required, disinfectant productivity is high, energy consumption is low, and apparatus structure is simple, it is simple to manufacturing, service life is long, safe and reliable to operation, can be with large scale application.

Description

Sanitizer generating apparatus
Technical field
This utility model relates to water treatment facilities, particularly relates to a kind of sanitizer generating apparatus.
Background technology
At present, for the kind of water disinfectant, there are chlorine, sodium hypochlorite, bleaching powder, sym-closene, dioxy Change chlorine, hydrogen peroxide, ozone etc., in addition with some means such as disinfection by ultraviolet lights.Wherein, sodium hypochlorite and chlorine dioxide are workers and peasants Industry produces and two kinds of strong oxidizers relatively common in daily life, and they are the chemical substance of non-naturally-occurring, have and kill Go out antibacterial and virus function, be widely used in disinfection of tap water, swimming-pool water sterilizing, rainwater treatment, recirculated water except algae and doctor The every field such as medicine health and epidemic prevention.
Sodium hypochlorite and chlorine dioxide are all the disinfectant of broad-spectrum high efficacy, but the pluses and minuses of being respectively arranged with:
Sodium hypochlorite as a kind of real efficiently, wide spectrum, the strength sterilizing of safety, kill the virus medicament, its affine with water Property fine, can dissolve each other with water arbitrarily ratio, there is not the potential safety hazard of the medicament such as liquid chlorine, chlorine dioxide, and its Disinfection Effect quilt in it It is known as suitable with chlorine.The topmost model of action of hypochlorite disinfectant is the hypochlorous acid that hydrolyzes to form by it, hypochlorous acid Further being decomposed to form nascent oxygen [O], the extremely strong oxidisability of nascent oxygen makes the materials such as the protein in thalline and virus Degeneration, thus lethal sex pheromone;Secondly, hypochlorous acid, during sterilization, killing the virus, not only may act on cell wall, disease Poison shell, and because hypochlorous acid molecule is little, neutral, also can penetrate into bacterium (viral) internal, with bacterium (viral) body protein, core The organic polymer generation oxidation reactions such as acid and enzyme, thus kill pathogenic microorganism;Again, the chloride ion that hypochlorous acid produces is also The osmotic pressure of antibacterial and virion can be significantly changed, make cell loss activity and dead, exactly because also this feature, so it Disinfection Effect is good, adds accurately, operates safety, easy to use, to environment nonhazardous, there is not deflation leakage, can any ring Add under the working condition of border.But sodium hypochlorite is easier to decompose, be difficult to store and transport, can only formed in-situ, and sodium hypochlorite Sterilization process based on chlorination, it is easy to Organic substance generates the harmful substance such as chloroform.
The molecular formula of chlorine dioxide is ClO2, ClO 2 solution is yellow or weak yellow liquid, and available chlorine content is 2.63, chlorine dioxide exists in water with molecular state, and its molecule is to realize the high penetrating power of microbial cell and strong oxidizing property Killing microorganisms rapidly.Chlorine dioxide is efficient as forth generation, wide-spectrum bactericide, and sterilization process is redox reaction, sterilization Speed is fast, and soluble in water at chlorine dioxide, not with water generation chemical reaction, its dissolubility is 5 times of chlorine and does not produce three halogen The disinfection byproduct (DBP) such as methane, chlorine dioxide is not consumed with compound effects such as ammonia nitrogens, therefore has higher chlorine residue, and sterilization disappears Toxic effect fruit is more higher than chlorine, and during pH=6.5, the sterilizing efficiency of chlorine is higher than chlorine dioxide, and along with pH improves, the sterilizing of chlorine dioxide Efficiency will quickly exceed chlorine.But chlorine dioxide has explosive, volatile characteristic, unsuitable shipping storage, typically uses scene Produce and use.
Based on this, prior art generally uses electrolysis unit to carry out being prepared in situ and making of sodium hypochlorite or chlorine dioxide With, but the current existing most structure of disinfectant electrolysis unit is complicated, manufacturing technology requires height, and generally cannot be to electrolytic process Effectively control and regulate, can be only used for preparing the disinfectant of single kind.
Utility model content
Based on this, it is necessary to provide the sanitizer generating apparatus that a kind of simple in construction, electrolytic process are controlled.
A kind of sanitizer generating apparatus, including disinfectant generation system, sodium chloride solution jettison system, temperature control system, disappears Toxic agent stocking system, power supply and robot control system(RCS), wherein,
Described disinfectant generation system includes electrolysis bath, and this electrolysis bath includes separating with asymmetric corrosion-resistant electrolyte membrane Anode chamber and cathode chamber, described anode chamber is provided with anode, and for receiving the chlorine that described sodium chloride solution jettison system is thrown in Changing sodium solution, described cathode chamber is provided with negative electrode, and described negative electrode and anode are respectively connecting to described power supply, to carry out cell reaction Generate disinfectant;
Described temperature control system is for regulating the temperature of cell reaction described in described electrolysis bath;
Described disinfectant stocking system is for collecting the disinfectant generated through described cell reaction;
Described robot control system(RCS) controls described sodium chloride solution jettison system, temperature control system through connecting the most respectively System, disinfectant stocking system and power supply.
Principle of the present utility model is as follows:
When the method using electrolytic sodium chloride aqueous solution prepares disinfectant, negative electrode and anode are substantially carried out as bottom electrode is anti- Should:
Anode reaction:
Cathode reaction is:
This utility model rationally arranges each system structure, utilizes sodium chloride solution delivery device to throw in chlorination in electrolysis bath Sodium solution, sodium chloride solution carries out above-mentioned cell reaction in a cell, generates disinfectant, and this disinfectant is circulated to disinfectant storage Deposit system stores, and is thrown to water body to be sterilized as required, to water body disinfection, realizes the scene of disinfectant with this Produce and onsite application, and each system structure is compact, simple in construction, it is simple to manufacture.
This utility model, by arranging the cell reaction temperature of temperature control system regulation sodium chloride solution further, thus coordinates Different concentration of sodium chloride solution, can realize the preparation of variety classes disinfectant: as temperature controlled between 5 DEG C-40 DEG C, chlorination Sodium solution concentration is when 3%-5%, and this device mainly produces sodium hypochlorite;Temperature is controlled at 40 DEG C-70 DEG C, sodium chloride solution When concentration reaches saturated, this device mainly produces chlorine dioxide and a small amount of side-product (chlorine, hydrogen peroxide and ozone) thereof.
Meanwhile, said system is regulated and controled by this utility model also by arranging robot control system(RCS), can realize disinfectant and prepare In the controllable precise of each step procedure.
Wherein in an embodiment, described sodium chloride solution jettison system includes for accommodating saturated nacl aqueous solution Brine tank, brine pump, water tank and water pump, described robot control system(RCS) through the most respectively connect control described brine pump and Water pump,
Described water tank is connected to described brine tank by pipeline, and described water pump is for being delivered to institute by the water in described water tank State brine tank;Described brine tank is connected to described anode chamber by pipeline, and described brine pump is for by the chlorine in described brine tank Change sodium solution and be thrown to described anode chamber.Thus according to required disinfectant kind, the sodium chloride of preparation variable concentrations is molten automatically Liquid.
Wherein in an embodiment, described brine tank and/or water tank are provided with liquid level controller, described brine pump and/ Or water pump is dosing pump.
Wherein in an embodiment, described disinfectant stocking system includes explosive box and dosing pump, described robot control system(RCS) Through wiredly and/or wirelessly connecting the described dosing pump of control, described explosive box is used for collecting described disinfectant, and described dosing pump is used for Disinfectant in described explosive box is thrown to water body to be sterilized.
Wherein in an embodiment, described explosive box is provided with liquid level controller, and described dosing pump is dosing pump.
Wherein in an embodiment, the material of described explosive box is not plasticized polyvinyl chloride (UPVC).UPVC material is strong Degree is high, be easy to processing, and stable in properties, does not reacts with the electrolyte comprising disinfectant, it is ensured that the quality of disinfectant.
Wherein in an embodiment, also include that purging system, described purging system include clarified water pump and clear equipped with water Water tank, described robot control system(RCS) is through wiredly and/or wirelessly connecting the described clarified water pump of control, and described filtered water tank is connected to institute by pipeline Stating electrolysis bath, described clarified water pump is for being delivered to described electrolysis bath by the water in described filtered water tank.Thus described electrolysis bath is entered Row cleans, and when device quits work, prevents barrier film and electrode fouling, the service life of extension fixture.
Wherein in an embodiment, described asymmetric corrosion-resistant electrolyte membrane is porous ceramic film.Porous ceramic film has Have the following advantages: high temperature resistant, use temperature 1300 degrees Celsius;Acid-alkali-corrosive-resisting, has stronger resistance to highly basic;Porous material, Hole diameter is little and size is homogeneous;Manufacturing process is superior, any surface finish, and service life is long.
Wherein in an embodiment, described electrolysis bath is tube type electrolytic tank.Thus can be carried out continuously cell reaction to prepare Disinfectant, improves electrolytic efficiency.
Wherein in an embodiment, described power supply is silicon controlled rectifier electrolysis power.This electrolysis power have high electric current, The advantage of low-voltage, while ensureing electrolytic efficiency, safe and reliable to operation.
Compared with prior art, this utility model has the advantages that
This utility model rationally arranges each system structure of sanitizer generating apparatus so that the preparation sterilization of electrolytic chlorination sodium solution The process controllable precise of agent, can prepare different types of disinfectant as required, and disinfectant productivity is high, energy consumption is low, and device knot Structure is simple, it is simple to manufacturing, service life is long, safe and reliable to operation, can be with large scale application.
Accompanying drawing explanation
Fig. 1 is the structural representation of sanitizer generating apparatus described in the utility model.
Detailed description of the invention
Below in conjunction with specific embodiment, sanitizer generating apparatus of the present utility model is described in further detail.
The asymmetric corrosion-resistant electrolyte membrane that this utility model uses is corrosion-and high-temp-resistant porous ceramic film, purchased from Beijing Hua Jing International Trading Company Ltd;
Silicon controlled rectifier electrolysis power is purchased from Guangzhou Jian Tong automation control appliance company limited, KZ series.
The present embodiment one sanitizer generating apparatus, structure is as it is shown in figure 1, include that electrolysis bath, sodium chloride solution throw in system System, temperature control system, purging system, explosive box, dosing pump, DC micro-electric power supply and automatic control cabinet.
Described electrolysis bath is tube type electrolytic tank, including the anode tube separated with corrosion-and high-temp-resistant porous ceramic film and negative electrode Pipe, sodium chloride solution is injected by anode tube and infiltrates in cathode tube through described corrosion-and high-temp-resistant porous ceramic film, described the moon Pole pipe and anode tube are respectively communicated to described DC micro-electric power supply, are carried out continuously cell reaction with this, produce hydrogen in cathode tube Gas, hydrogen passes through airway discharger, generates disinfectant (such as NaClO, ClO in anode tube simultaneously2、Cl2、O3、H2O2Deng), so After the electrolyte comprising disinfectant is delivered to continuously described explosive box, and be thrown under the effect of dosing pump further equipped with In the sterilization pool of water body to be sterilized, water body is carried out disinfection.
Described temperature control system is used for regulating the temperature of cell reaction in described tube type electrolytic tank, and owing to cell reaction is usual Can be highly exothermic, the most described temperature control system is mainly cooling system, and this cooling system utilizes tubular type electricity described in chilled water modulation Solve the temperature of cell reaction described in groove, on the one hand control the temperature of tube type electrolytic tank less than 80 DEG C, it is to avoid high temperature resistant corrosion resistant The pipeline of the conveying electrolyte of erosion porous ceramic film generation degeneration and UPVC material and the intensity of explosive box decline;On the other hand, By regulating the cell reaction temperature of sodium chloride solution, thus coordinate different concentration of sodium chloride solution, variety classes can be realized and disappear The preparation of toxic agent: as temperature controlled between 5 DEG C-40 DEG C, sodium chloride concentration is when 3%-5%, and this device mainly produces secondary Sodium chlorate;Temperature being controlled at 40 DEG C-70 DEG C, when brine strength reaches saturated, this device mainly produces chlorine dioxide and lacks Amount side-product (chlorine, hydrogen peroxide and ozone).
Sodium chloride solution jettison system includes the brine tank equipped with saturated nacl aqueous solution, brine pump, water tank equipped with water And water pump, by described water pump, the water in described water tank is pumped into described brine tank, the most automatically prepare the chlorination of variable concentrations Sodium solution, more continuously described sodium chloride solution is pumped into described anode tube by described brine pump, prepare different types of sterilization Agent.
Described purging system includes clarified water pump and the filtered water tank equipped with water, after stopping cell reaction, by described clarified water pump Water in described filtered water tank is pumped into described electrolysis bath, described electrolysis bath is carried out, thus quit work period at device, Prevent barrier film and electrode fouling, the service life of extension device.
Above-mentioned brine tank, water tank, filtered water tank are provided with liquid level controller, in order to water level therein is observed and is controlled System;Above-mentioned brine pump, water pump, clarified water pump are dosing pump, in order to accurately control the addition of each liquid.
The devices such as above-mentioned temperature control system, brine pump, water pump, clarified water pump, dosing pump, DC micro-electric power supply are respectively through cable even It is connected to described automatic control cabinet, is controlled the operational factor of each device, thus each to cell reaction by described automatic control cabinet Step procedure accurately controls.
Above-mentioned DC micro-electric power supply specifically can use silicon controlled rectifier electrolysis power, and this electrolysis power has high electric current, low The advantage of voltage, while ensureing electrolytic efficiency, safe and reliable to operation.
It is understood that connection pipeline and brine tank, water tank, filtered water tank between each device also can specifically use UPVC makes.
Above-mentioned sanitizer generating apparatus is by rationally arranging the structure of each system of sanitizer generating apparatus, and apparatus structure is simple Single, it is simple to manufacture, make electrolytic chlorination sodium solution prepare the process controllable precise of disinfectant simultaneously, can prepare not as required Congener disinfectant, uses above-mentioned sanitizer generating apparatus to carry out sodium hypochlorite or time chlorine dioxide prepares, technical specification and Operational factor can be the most as shown in table 1:
Table 1
As can be seen here, use this utility model can carry out particular kind of disinfectant and prepare, and disinfectant productivity is high, energy consumption Low, service life is long, safe and reliable to operation, can be with large scale application.
Each technical characteristic of embodiment described above can combine arbitrarily, for making description succinct, not to above-mentioned reality The all possible combination of each technical characteristic executed in example is all described, but, as long as the combination of these technical characteristics is not deposited In contradiction, all it is considered to be the scope that this specification is recorded.
Embodiment described above only have expressed several embodiments of the present utility model, and it describes more concrete and detailed, But therefore can not be interpreted as the restriction to utility model patent scope.It should be pointed out that, for the common skill of this area For art personnel, without departing from the concept of the premise utility, it is also possible to make some deformation and improvement, these broadly fall into Protection domain of the present utility model.Therefore, the protection domain of this utility model patent should be as the criterion with claims.

Claims (10)

1. a sanitizer generating apparatus, it is characterised in that include disinfectant generation system, sodium chloride solution jettison system, temperature Ore-controlling Role, disinfectant stocking system, power supply and robot control system(RCS), wherein,
Described disinfectant generation system includes electrolysis bath, and this electrolysis bath includes the anode separated with asymmetric corrosion-resistant electrolyte membrane Room and cathode chamber, described anode chamber is provided with anode, and for receiving the sodium chloride that described sodium chloride solution jettison system is thrown in Solution, described cathode chamber is provided with negative electrode, and described negative electrode and anode are respectively connecting to described power supply, to carry out cell reaction generation Disinfectant;
Described temperature control system is for regulating the temperature of cell reaction described in described electrolysis bath;
Described disinfectant stocking system is for collecting the disinfectant generated through described cell reaction;
Described robot control system(RCS) is through connecting control described sodium chloride solution jettison system, temperature control system the most respectively, disappearing Toxic agent stocking system and power supply.
Sanitizer generating apparatus the most according to claim 1, it is characterised in that described sodium chloride solution jettison system includes For accommodating the brine tank of saturated nacl aqueous solution, brine pump, water tank and water pump, described robot control system(RCS) is through wiredly and/or wirelessly Connect respectively and control described brine pump and water pump,
Described water tank is connected to described brine tank by pipeline, and described water pump is for being delivered to described salt by the water in described water tank Water tank;Described brine tank is connected to described anode chamber by pipeline, and described brine pump is for by the sodium chloride in described brine tank Solution is thrown to described anode chamber.
Sanitizer generating apparatus the most according to claim 2, it is characterised in that described brine tank and/or water tank are provided with Liquid level controller, described brine pump and/or water pump are dosing pump.
Sanitizer generating apparatus the most according to claim 1, it is characterised in that described disinfectant stocking system includes drug storage Case and dosing pump, described robot control system(RCS) is through wiredly and/or wirelessly connecting the described dosing pump of control, and described explosive box is used for collecting institute Stating disinfectant, described dosing pump is for being thrown to water body to be sterilized by the disinfectant in described explosive box.
Sanitizer generating apparatus the most according to claim 4, it is characterised in that described explosive box is provided with Liquid level Device, described dosing pump is dosing pump.
Sanitizer generating apparatus the most according to claim 4, it is characterised in that the material of described explosive box is unplasticised poly- Vinyl chloride.
Sanitizer generating apparatus the most according to claim 1, it is characterised in that also include purging system, described cleaning system System includes clarified water pump and the filtered water tank equipped with water, and described robot control system(RCS) is through wiredly and/or wirelessly connecting the described clarified water pump of control, institute Stating filtered water tank and be connected to described electrolysis bath by pipeline, described clarified water pump is for being delivered to described electricity by the water in described filtered water tank Solve groove.
8. according to the sanitizer generating apparatus described in any one of claim 1-7, it is characterised in that described asymmetric anti-corrosion electric Solution barrier film is porous ceramic film.
9. according to the sanitizer generating apparatus described in any one of claim 1-7, it is characterised in that described electrolysis bath is tubular type electricity Solve groove.
10. according to the sanitizer generating apparatus described in any one of claim 1-7, it is characterised in that described power supply is controllable silicon Rectification electrolysis power.
CN201620587962.6U 2016-06-16 2016-06-16 Sanitizer generating apparatus Active CN205774813U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111422952A (en) * 2019-01-09 2020-07-17 台湾可林生化科技有限公司 Automatic change electrolytic device
CN115094462A (en) * 2022-05-11 2022-09-23 上海交通大学 Chlorine dioxide gas generating device based on foamed titanium monatomic integral electrode

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111422952A (en) * 2019-01-09 2020-07-17 台湾可林生化科技有限公司 Automatic change electrolytic device
CN115094462A (en) * 2022-05-11 2022-09-23 上海交通大学 Chlorine dioxide gas generating device based on foamed titanium monatomic integral electrode

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