CN205760582U - Limestone-plaster wet desulfurizing system - Google Patents

Limestone-plaster wet desulfurizing system Download PDF

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Publication number
CN205760582U
CN205760582U CN201620652657.0U CN201620652657U CN205760582U CN 205760582 U CN205760582 U CN 205760582U CN 201620652657 U CN201620652657 U CN 201620652657U CN 205760582 U CN205760582 U CN 205760582U
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China
Prior art keywords
limestone
flue gas
slurry
gypsum
slurry pool
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Expired - Fee Related
Application number
CN201620652657.0U
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Chinese (zh)
Inventor
曹明峰
殷绪斌
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Shandong Department Of Industrial Technology Co Ltd
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Shandong Department Of Industrial Technology Co Ltd
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Priority to CN201620652657.0U priority Critical patent/CN205760582U/en
Application granted granted Critical
Publication of CN205760582U publication Critical patent/CN205760582U/en
Expired - Fee Related legal-status Critical Current
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Abstract

This utility model is seen and is disclosed a kind of limestone-plaster wet desulfurizing system, including SO2Absorption plant, flue gas device, lime stone slurry preparation facilities, gypsum dewatering equipment, emptying and accident serosity device, boiler smoke can be carried out desulfurization, except mist process after directly discharge, the gypsum slurries of generation is directly recycled after processed simultaneously.This utility model is provided with flue gas device, can realize that desulfurizer is properly functioning and bypass runs during fault, and be furnished with sealing system, it is to avoid flue gas is revealed and polluted environment;The employing of demister purging system automatically controls, intermitten service, and its operation maintenance is convenient.This utility model sulfur removal technology realize that fool proof reliably its operation maintenance is convenient, the high-quality to desulfuration byproduct can be realized simultaneously and recycle.

Description

Wet desulfurization of flue gas by limestone-gypsum method system
Technical field
This utility model relates to flue gas desulphurization system field, especially relates to a kind of wet desulfurization of flue gas by limestone-gypsum method System.
Background technology
Wet desulfurization of flue gas by limestone-gypsum method technology is that development at present is more ripe, and widely used wet flue gas takes off One of sulfur technology, its desulfuration efficiency is up to more than 95%.Wet desulfurization of flue gas by limestone-gypsum method technology tool desulfuration efficiency is high, de- The advantages such as sulfur agent raw material simple, the desulfuration byproduct recoverable of preparation, but there is also desulphurization system investment simultaneously and run Maintenance cost is high, flue gas is revealed and caused the limitation such as environmental pollution.
Utility model content
This utility model is contemplated to solve the deficiencies in the prior art, it is provided that a kind of wet desulfurization of flue gas by limestone-gypsum method System, this utility model can reliably and securely realize flue gas desulfurization technique, and system operation maintenance is convenient, can realize desulfurization The high-quality of side-product recycles;Flue gas device sealing property is reliable, when the design of by-pass damper door provides failure condition The operation passage of flue gas, improve the safety of apparatus system, it is to avoid flue gas is revealed the pollution to environment and destroyed;Demister is clear System of washing uses and automatically controls, intermitten service, and its operation maintenance is convenient, safe and reliable.
This utility model solves the technical scheme of technical problem:
A kind of wet desulfurization of flue gas by limestone-gypsum method system, including SO2Absorption plant, flue gas device, lime stone slurry system Standby device, gypsum dewatering equipment, emptying and accident serosity device, described SO2Absorption plant include desulfurizing tower, slurry circulating pump, Oxidation fan, sets gradually slurry pool, spraying layer, demister from lower to upper inside described desulfurizing tower;Desulfurizing tower is provided with into cigarette Mouth and outlet flue, smoke inlet is between slurry pool and spraying layer, and outlet flue is positioned at above demister;Serosity outside desulfurizing tower Circulating pump connects slurry pool and spraying layer by pipeline;Oxidation fan outside desulfurizing tower is connected with slurry pool by pipeline;Slurry Agitator it is provided with in liquid pool.
Described flue gas device includes former gas baffle door, neat stress baffle door, by-pass damper door, bypass flue, described former Gas baffle door is positioned at desulfurizing tower smoke inlet, and neat stress baffle door is positioned at desulfurizing tower outlet flue, and by-pass damper door is positioned at bypass cigarette Road.
Described lime stone slurry preparation facilities includes limestone powder bin, limestone slurry flow container, limestone slurry liquid pump, described stone Lime stone powder cabin connects limestone slurry flow container, and limestone slurry flow container is connected with slurry pool by limestone slurry liquid pump;Set in serum pot There is agitator.
Described gypsum dewatering equipment includes Gypsum Fibrosum excavationg pump, Gypsum Fibrosum hydrocyclone, vacuum belt dewaterer, gas-liquid separation Device, vacuum pump, Gypsum Fibrosum storehouse, slurry pool connects Gypsum Fibrosum hydrocyclone, Gypsum Fibrosum hydrocyclone effluent head by Gypsum Fibrosum excavationg pump Connection accident slurry pool, Gypsum Fibrosum hydrocyclone underflow end connects vacuum belt dewaterer;Vacuum belt dewaterer passes through vacuum Pipeline connects gas-liquid separator, and gas-liquid separator liquid stream end is connected with accident slurry pool by vacuum pump;
Described emptying and accident serosity device include accident slurry pool, Gypsum Fibrosum hydrocyclone, and accident slurry pool connects stone Cream hydrocyclone, Gypsum Fibrosum hydrocyclone underflow end connection accident slurry pool, Gypsum Fibrosum hydrocyclone effluent head connects waste water Processing system;It is provided with agitator in accident slurry pool.
Further, described former gas baffle door, neat stress baffle door, by-pass damper door are equipped with sealing system, and adopt With venetian blind type double containment baffle arrangement, it is ensured that " zero " reveals.
Further, described demister is designed as upper and lower two-stage, and two-stage demister is equipped with demister purging system, institute State demister purging system and include washer jet and pipeline, washer jet be respectively arranged in one-level demister above and below with And below two grades of demisters.
The wet desulfurization of flue gas by limestone-gypsum method system that this utility model provides provides the benefit that:
1, described flue gas device sealing property is reliable, the operation of flue gas when the design of by-pass damper door provides failure condition Passage, improve the safety of apparatus system, it is to avoid flue gas is revealed the pollution to environment and destroyed.
2, described demister purging system uses and automatically controls, intermitten service, and its operation maintenance is convenient, safe and reliable.
3, it is equipped with agitator in described slurry pool, limestone slurry flow container and accident slurry pool, can the most anti-locking system Device entoplasm liquid precipitate causes waste, and then affects desulfuration efficiency.
Accompanying drawing explanation
Fig. 1 is utility model structure chart.
In figure: 1 slurry pool;2 spraying layers;3 demisters;4 slurry circulating pumps;5 oxidation fans;6 limestone slurry flow containers;7 stones Lime stone powder cabin;8 vacuum belt dewaterers;9 gas-liquid separators;10 Gypsum Fibrosum hydrocyclones;11 Gypsum Fibrosum hydrocyclones;12 accidents Slurry pool.
Detailed description of the invention
As it is shown in figure 1, protection main body of the present utility model and embodiment are as follows:
The flue gas desulphurization system that this utility model provides, including SO2Prepared by absorption plant, flue gas device, lime stone slurry Device, gypsum dewatering equipment, emptying and accident serosity device, described SO2Absorption plant includes desulfurizing tower, slurry circulating pump 4, oxygen Wind-transformation machine 5, sets gradually slurry pool 1, spraying layer 2, demister 3 from lower to upper inside described desulfurizing tower;Desulfurizing tower be provided with into Mouth and outlet flue, smoke inlet is between slurry pool and spraying layer, and outlet flue is positioned at above demister;Slurry outside desulfurizing tower Liquid circulating pump connects slurry pool and spraying layer by pipeline;Oxidation fan outside desulfurizing tower is connected with slurry pool by pipeline; Agitator it is provided with in slurry pool.
Further, demister is designed as upper and lower two-stage, and two-stage demister is equipped with demister purging system, described removes Day with fog purging system includes washer jet and pipeline, washer jet be respectively arranged in one-level demister above and below and two Below level demister.
Described flue gas device includes former gas baffle door, neat stress baffle door, by-pass damper door, bypass flue, described former Gas baffle door is positioned at desulfurizing tower smoke inlet, and neat stress baffle door is positioned at desulfurizing tower outlet flue, and by-pass damper door is positioned at bypass cigarette In road.Former gas baffle door, neat stress baffle door, by-pass damper door are equipped with sealing system, and use venetian blind type double containment Baffle arrangement, it is ensured that " zero " reveals.
Described lime stone slurry preparation facilities includes limestone powder bin 7, limestone slurry flow container 6, limestone slurry liquid pump, described Limestone powder bin connects limestone slurry flow container, and limestone slurry flow container is connected with slurry pool by limestone slurry liquid pump;Limestone slurry Agitator it is provided with in flow container.
Described gypsum dewatering equipment includes Gypsum Fibrosum excavationg pump, Gypsum Fibrosum hydrocyclone 10, vacuum belt dewaterer 8, gas-liquid Separator 9, vacuum pump, Gypsum Fibrosum storehouse, slurry pool connects Gypsum Fibrosum hydrocyclone by Gypsum Fibrosum excavationg pump, and Gypsum Fibrosum hydrocyclone overflows Stream end connection accident slurry pool, Gypsum Fibrosum hydrocyclone underflow end connects vacuum belt dewaterer;Vacuum belt dewaterer passes through Vacuum pipe connects gas-liquid separator, and gas-liquid separator liquid stream end is connected with accident slurry pool by vacuum pump.
Described emptying and accident serosity device include accident slurry pool 12, Gypsum Fibrosum hydrocyclone 11, and accident slurry pool is even Connecing Gypsum Fibrosum hydrocyclone, Gypsum Fibrosum hydrocyclone underflow end connection accident slurry pool, Gypsum Fibrosum hydrocyclone effluent head connects Waste Water Treatment;It is provided with agitator in accident slurry pool.
Sweetening process of the present utility model is as follows:
Agstone is stored in limestone powder bin 7, and makes concentration 15~the serosity of 20%, is stored in lime stone slurry In tank 6, limestone slurry flow container 6 is equipped with agitator to prevent serosity from precipitating.
According to system needs, limestone slurry liquid pump serosity being sent into desulphurization tower slurry pool 1, slurry pool 1 serosity is through slurry Desulfurizing tower spraying layer 2 delivered to by liquid circulating pump 4, and is that fine drop sprays downwards through nozzle atomization.Meanwhile, boiler smoke from Boiler induced-draft fan is discharged, and enters desulfurizing tower after intensified blower fan traction, and in desulfurizing tower, flue gas is up, sprays downwards with spraying layer 2 The fine drop adverse current of the serosity gone out, both are fully contacted, and remove the SO in flue gas by chemical reaction2、SO3And HCl, HF Deng sour gas.
Flue gas after spraying layer 2 desulfurization continues up, removes the drop carried secretly in flue gas through demister 3, by desulfurization The outlet flue of tower is discharged.Meanwhile, occurring the drop after chemical reaction to fall into desulphurization tower slurry pool 1, slurry pool 1 is furnished with stirring Device, and it is passed through oxidation air by oxidation fan 5, in slurry pool 1, serosity reacts further, and oxidizing and crystallizing is CaSO4·2H2O Grain, forms gypsum slurries.
When properly functioning, the former gas baffle door of flue gas device and neat stress baffle door are opened, and by-pass damper door is closed, cigarette Gas passes through SO2Absorption plant realizes discharging after desulfurization processes.In case of a fault, flue gas device by-pass damper door is opened, former cigarette Gas baffle door and neat stress baffle door are closed, and flue gas is then expelled directly out by bypass flue.
Further, cause demister 3 fault for avoiding the solid particle in flue gas to be adsorbed in demister 3 surface, profit With industry water, demister 3 is carried out.Industry water sprays to demister 3 through demister 3 purging system from washer jet strength, band Walk the solid particle of absorption on demister 3 following current face and adverse current face, because demister 3 purging system washer jet is respectively arranged in one Above and below and below two grades of demisters 3 of level demister 3, therefore demister 3 purging system is to one-level demister 3 The bottom of top and bottom and two grades of demisters 3 is carried out, and it operates to intermitten service, and employing automatically controls.
According to CaSO in gypsum slurries in desulphurization tower slurry pool 14·2H2The change of O granule content, Gypsum Fibrosum excavationg pump is discharged A certain amount of gypsum slurries is sent into Gypsum Fibrosum hydrocyclone 10 and is carried out preliminary hydro-extraction.Gypsum slurries takes off through Gypsum Fibrosum hydrocyclone 10 Overflow feeding accident slurry pool 12 after water, vacuum belt dewaterer 8 is delivered in underflow.Gypsum slurries on vacuum belt dewaterer 8 Carrying out sucking filtration under the effect of vacuum motive force, filtrate enters gas-liquid separator 9 through vacuum pipe, and the Gypsum Fibrosum of generation sends into Gypsum Fibrosum Storehouse, can be directly as the raw materials for production in cement plant or construction material.Filtrate after gas-liquid separator 9 carries out gas-liquid separation, its liquid Flow through vacuum pump and be recycled to accident slurry pool 12.
Further, for the content of the compositions such as chloride ion in control desulfurated plaster, calcium plaster on vacuum belt dewaterer 8 When liquid carries out vacuum filtration, industry water is utilized gypsum slurries on vacuum belt dewaterer 8 to be rinsed, to eliminate soluble chlorine Compound, it is achieved the high-quality of desulfuration byproduct is recycled.
Accident slurry pool 12 recirculated water part is delivered to Gypsum Fibrosum hydrocyclone 11 and is dehydrated further, Gypsum Fibrosum hydrocyclone 11 Underflow be recycled to accident slurry pool 12, the overflow of Gypsum Fibrosum hydrocyclone 11 is delivered to power plant or municipal wastewater as waste water and is processed System.Accident slurry pool 12 recirculated water returns limestone slurry flow container 6 reuse, thus realizes recycling of desulphurization system, saves Cost.Additionally, be provided with agitator work in accident slurry pool 12, it is to avoid in pond, serosity deposition causes waste, and then affects desulfurization Efficiency.
Embodiment described above is only to be described preferred implementation of the present utility model, not to this practicality Novel scope is defined, and on the premise of without departing from this utility model design spirit, relevant technical staff in the field is to this The various deformation of utility model and improvement, all should expand in protection domain as determined by this utility model claims.

Claims (6)

1. a wet desulfurization of flue gas by limestone-gypsum method system, including SO2Prepared by absorption plant, flue gas device, lime stone slurry Device, gypsum dewatering equipment, emptying and accident serosity device, it is characterised in that described SO2Absorption plant includes desulfurizing tower, slurry Liquid circulating pump, oxidation fan, set gradually slurry pool, spraying layer, demister, on desulfurizing tower from lower to upper inside described desulfurizing tower Being provided with smoke inlet and outlet flue, smoke inlet is between slurry pool and spraying layer, and outlet flue is positioned at above demister, outside desulfurizing tower The slurry circulating pump in portion connects slurry pool and spraying layer by pipeline, and the oxidation fan outside desulfurizing tower passes through pipeline and slurry pool Connection;
Described flue gas device includes former gas baffle door, neat stress baffle door, by-pass damper door, bypass flue, described former flue gas Baffle door is positioned at desulfurizing tower smoke inlet, and neat stress baffle door is positioned at desulfurizing tower outlet flue, and by-pass damper door is positioned at bypass flue;
Described lime stone slurry preparation facilities includes limestone powder bin, limestone slurry flow container, limestone slurry liquid pump, described limestone Powder cabin connects limestone slurry flow container, and limestone slurry flow container is connected with slurry pool by limestone slurry liquid pump;
Described gypsum dewatering equipment include Gypsum Fibrosum excavationg pump, Gypsum Fibrosum hydrocyclone, vacuum belt dewaterer, gas-liquid separator, Vacuum pump, Gypsum Fibrosum storehouse, slurry pool connects Gypsum Fibrosum hydrocyclone by Gypsum Fibrosum excavationg pump, and Gypsum Fibrosum hydrocyclone effluent head connects Accident slurry pool, Gypsum Fibrosum hydrocyclone underflow end connects vacuum belt dewaterer, and vacuum belt dewaterer passes through vacuum pipe Connecting gas-liquid separator, gas-liquid separator liquid stream end is connected with accident slurry pool by vacuum pump;
Described emptying and accident serosity device include accident slurry pool, Gypsum Fibrosum hydrocyclone, and accident slurry pool connects parget water Power cyclone, Gypsum Fibrosum hydrocyclone underflow end connection accident slurry pool, Gypsum Fibrosum hydrocyclone effluent head connects waste water and processes System.
Wet desulfurization of flue gas by limestone-gypsum method system the most according to claim 1, it is characterised in that described former flue gas keeps off Plate door, neat stress baffle door, by-pass damper door are equipped with sealing system.
Wet desulfurization of flue gas by limestone-gypsum method system the most according to claim 1 and 2, it is characterised in that described former flue gas Baffle door, neat stress baffle door, by-pass damper door use venetian blind type double containment baffle arrangement.
Wet desulfurization of flue gas by limestone-gypsum method system the most according to claim 1, it is characterised in that described demister divides For upper and lower two-stage, two-stage demister is equipped with demister purging system.
Wet desulfurization of flue gas by limestone-gypsum method system the most according to claim 4, it is characterised in that described demister is clear The system of washing includes washer jet and pipeline, washer jet be respectively arranged in one-level demister above and below and two grades except mist Below device.
Wet desulfurization of flue gas by limestone-gypsum method system the most according to claim 1, it is characterised in that described slurry pool, stone It is equipped with agitator in lime stone serum pot and accident slurry pool.
CN201620652657.0U 2016-06-27 2016-06-27 Limestone-plaster wet desulfurizing system Expired - Fee Related CN205760582U (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106904711A (en) * 2017-04-20 2017-06-30 盐城工学院 A kind of calcium carbonate waste water circulation recovery system and calcium carbonate circulating purification system
CN107998865A (en) * 2018-01-17 2018-05-08 青岛科技大学 A kind of flue-gas dust-removing and desulfurization cleaning system
CN109224827A (en) * 2018-10-22 2019-01-18 内蒙古锦联铝材有限公司 A kind of Highway in Electrolytic Aluminium Production System flue gas becomes zero-emission wet desulfurization system
CN109908736A (en) * 2019-04-02 2019-06-21 江苏鑫华能环保工程股份有限公司 Limestone-gypsum wet desulfuration device
CN111099756A (en) * 2019-12-27 2020-05-05 浙江德创环保科技股份有限公司 Solid reducing process and system for wastewater for limestone-gypsum wet desulphurization
CN112441764A (en) * 2020-11-30 2021-03-05 天津中材工程研究中心有限公司 Improved structure of gypsum dewatering system of cement wet desulphurization process in cement industry
CN113877402A (en) * 2021-11-02 2022-01-04 福建龙净环保股份有限公司 Wet desulphurization process system and wet desulphurization process method with ultralow wastewater discharge
CN109908736B (en) * 2019-04-02 2024-04-30 江苏鑫华能环保工程股份有限公司 Limestone gypsum wet desulfurization device

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106904711A (en) * 2017-04-20 2017-06-30 盐城工学院 A kind of calcium carbonate waste water circulation recovery system and calcium carbonate circulating purification system
CN107998865A (en) * 2018-01-17 2018-05-08 青岛科技大学 A kind of flue-gas dust-removing and desulfurization cleaning system
CN109224827A (en) * 2018-10-22 2019-01-18 内蒙古锦联铝材有限公司 A kind of Highway in Electrolytic Aluminium Production System flue gas becomes zero-emission wet desulfurization system
CN109908736A (en) * 2019-04-02 2019-06-21 江苏鑫华能环保工程股份有限公司 Limestone-gypsum wet desulfuration device
CN109908736B (en) * 2019-04-02 2024-04-30 江苏鑫华能环保工程股份有限公司 Limestone gypsum wet desulfurization device
CN111099756A (en) * 2019-12-27 2020-05-05 浙江德创环保科技股份有限公司 Solid reducing process and system for wastewater for limestone-gypsum wet desulphurization
CN111099756B (en) * 2019-12-27 2022-08-26 浙江德创环保科技股份有限公司 Solid reducing process and system for wastewater for limestone-gypsum wet desulphurization
CN112441764A (en) * 2020-11-30 2021-03-05 天津中材工程研究中心有限公司 Improved structure of gypsum dewatering system of cement wet desulphurization process in cement industry
CN112441764B (en) * 2020-11-30 2022-07-12 天津中材工程研究中心有限公司 Improved structure of gypsum dewatering system of cement wet desulphurization process in cement industry
CN113877402A (en) * 2021-11-02 2022-01-04 福建龙净环保股份有限公司 Wet desulphurization process system and wet desulphurization process method with ultralow wastewater discharge
CN113877402B (en) * 2021-11-02 2023-07-14 福建龙净环保股份有限公司 Wet desulfurization process system and wet desulfurization process method with ultralow wastewater discharge capacity

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Granted publication date: 20161207

Termination date: 20180627