CN205759800U - Combined type Multi-stage rotary packed bed mass transfer reaction device - Google Patents
Combined type Multi-stage rotary packed bed mass transfer reaction device Download PDFInfo
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- CN205759800U CN205759800U CN201620455703.8U CN201620455703U CN205759800U CN 205759800 U CN205759800 U CN 205759800U CN 201620455703 U CN201620455703 U CN 201620455703U CN 205759800 U CN205759800 U CN 205759800U
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Abstract
This utility model belongs to mixing, mass transfer and reaction unit field, it is specifically related to a kind of combined type Multi-stage rotary packed bed mass transfer reaction device, solves existing super-gravity device and can not realize carrying out, after liquid-liquid diphase needs first hybrid reaction abundant, quick, the problem that gas-liquid two-phase absorbs course of reaction strengthening again.Setting reaction zone, top and lower reaction zone in its revolving bed shell, be respectively provided with the filler rotor that some levels are coaxially disposed in reaction zone, upper and lower part, top and the bottom are arranged by liquid device between reaction zone.This utility model carries out gas-liquid two-phase reaction immediately and is integrated in same table apparatus after liquid-liquid diphase is sufficiently mixed reaction, it is achieved Integrated design, and the equipment that effectively reduces takes up an area space.Bottom filler rotor medial slope design, is conducive to accepting from the liquid being distributed as liquid re-distributor by liquid device.
Description
Technical field
This utility model belongs to mixing, mass transfer and reaction unit field, is specifically related to a kind of combined type Multi-stage rotary packed bed mass transfer and reaction unit, can apply to mix, absorbs, the strengthening of the process such as reaction.
Background technology
Along with the development of modern chemical industry, process intensification becomes chemical field and effectively reduces cost, energy-conservation, the important means of reduction of discharging.
High-gravity technology (High Gravity Technology,
Higee) as a kind of novel process intensification technology, there is incorporation time short, the advantage such as mix homogeneously.Its ultimate principle is to utilize the packed bed simulation super gravity field of high speed rotating, during filler high speed rotating, liquid is had broken, shear, the effect such as tear, greatly increase alternate contact area, accelerate boundary renewal rate, thus it is greatly improved phase boundary mass transfer rate, strengthen micro mixing.
Research shows, the mass-transfer efficiency of cross_flow rotating packed bed is 3 times of tradition tower, and volume is the most only the 1/10 of tradition tower.Therefore, cross_flow rotating packed bed is also referred to as " transistor " of modern chemical industry.The most biphase to liquid-liquid, or the microcosmic mixing between gas-liquid two-phase flow, mass transfer, reaction, cross_flow rotating packed bed all plays the invigoration effect that tradition tower, agitator are incomparable.At present, the process intensification of the chemical field such as high-gravity technology is successfully applied to distillation, prepared by absorption, depositing dust, desulfurization, nano-particle.
In existing super-gravity device, most equipment are biphase for liquid-liquid or mixing between vapor-liquid two phases, the strengthening of mass transfer and reaction, and for liquid-liquid is biphase need first hybrid reaction abundant, quick after carry out vapor-liquid two phases again to absorb the strengthening device of reaction few.Disclosing a kind of Impinging Stream-Rotating Packed Bed reaction unit in patent CN 1425493 A, this device can realize the mixing between the multiphase flow such as liquid-liquid, solution-air and reaction by increasing shock nozzle.But vapor-liquid two phases reaction is carried out with liquid-liquid two-phase mixtures simultaneously, in the case of the mixing that liquid-liquid is biphase is not sufficient, i.e. carry out vapor-liquid two phases reaction, do not reach intended strengthening effect.
Summary of the invention
This utility model can not realize biphase need of liquid-liquid first carry out the problem that vapor-liquid two phases absorbs course of reaction strengthening again after hybrid reaction abundant, quick to solve existing super-gravity device, it is provided that a kind of combined type Multi-stage rotary packed bed mass transfer reaction device.
For achieving the above object, the technical solution adopted in the utility model is:
Combined type Multi-stage rotary packed bed mass transfer reaction device, including the revolving bed shell being provided with inlet, liquid outlet, air inlet and gas outlet and the percussion flow device entered from top inlet, reaction zone, top and lower reaction zone is set in it is characterized in that revolving bed shell, being respectively provided with the filler rotor that some levels are coaxially disposed in reaction zone, upper and lower part, top and the bottom are arranged by liquid device between reaction zone.The liquid flowed down from outer casing inner wall is collected by liquid device.
Reaction zone, top is liquid-liquid reactions district, and lower reaction zone is gas-liquid reaction district, and the top, lower reaction zone arranges gas outlet.
Described is taper liquid-receiving plate by liquid device, is circular flat disk bottom taper liquid-receiving plate, and square position is evenly equipped with some liquid distributing holes, and taper liquid-receiving plate outer is connected with revolving bed shell.
Described taper liquid-receiving plate inclination angle is 5 °～45 °, and described taper liquid-receiving plate bottom circular square position percent opening is 30%～60%.
Having for inclined-plane inside the filler rotor in gas-liquid reaction district, inclined-plane is provided with some with holes swash plate 22 angled with inclined-plane, accepts and redistribution in order to liquid.The filler rotor medial slope in gas-liquid reaction district and vertical design angle are 15 °～45 °, swash plate 22 with holes and inclined design angle 60 °～90 °.Swash plate with holes is accepted and redistribution in order to liquid.
Percussion flow device is provided with nozzle I by two root bottom parts, the feed pipe I of nozzle II 16, feed pipe II form, feed pipe I, feed pipe II connect different raw material reservoir I, raw material reservoir II respectively, and liquid-liquid reactions district and solution-air reaction zone have one group of filler rotor respectively.Described filler is structured packing or dumped packing.
The reaction method that this utility model completes, needs are first sufficiently mixed two strands of initial materials of reaction dissolve respectively and be placed in reservoir I and reservoir II, two strands of initial materials are squeezed into percussion flow device from feed pipe, feed pipe II by pump I and pump II respectively after fluid flowmeter I and flow meter II measure, spraying at a high speed the first Fast Collision of laggard row through the nozzle I of percussion flow device and nozzle II, mix, react, the filler rotor I of the high speed rotating of liquid entrance subsequently carries out secondary deep hybrid reaction；After liquid-liquid two-phase mixtures has reacted, liquid is got rid of to revolving bed outer casing inner wall, flow to by liquid device, liquid distributing hole redistribute on filler rotor II inner band hole deviation plate along inwall under gravity；Liquid is thrown under the influence of centrifugal force in filler rotor II and throws away from inside to outside, and gas is entered by air inlet, carries out adverse current with liquid or cross-flow contacts in filler rotor II；After completing mass transfer between vapor-liquid two phases, reaction, gas is discharged from gas outlet, and liquid is then expelled to reservoir III by liquid outlet.
The beneficial effects of the utility model are: by biphase for liquid-liquid be sufficiently mixed reaction after carry out immediately vapor-liquid two phases reaction be integrated in same table apparatus, it is achieved Integrated design, effectively reduce equipment take up an area space.Bottom filler rotor medial slope design, is conducive to accepting from the liquid being distributed as liquid re-distributor by liquid device.Utilize this utility model device can realize the mixing dosing of two strands of initial materials, carry out absorbing the process intensification of reaction subsequently.Can also realize first carrying out the hybrid reaction of initial material, then carry out the process intensification of mass transfer reaction between vapor-liquid two phases.
Accompanying drawing explanation
Fig. 1 is the use process chart of a kind of combined type Multi-stage rotary packed bed mass transfer described in the utility model and reaction unit.
In figure: 1-reservoir I;2-pump I;3-fluid flowmeter I;4-combined type Multi-stage rotary packed bed;5-reservoir II;6-pump II;7-fluid flowmeter II;8-motor I;9-reservoir III;10-oxygen cylinder;11-ozonator;12-gas flowmeter;13-exhaust gas processing device.
Fig. 2 is a kind of combined type Multi-stage rotary packed bed mass transfer described in the utility model and reaction unit main body schematic diagram.
In figure: 14-inlet;15-feed pipe;16-nozzle;17-shell;18-gas outlet;19-air inlet;20-liquid outlet;21-rotary shaft;22-swash plate with holes;23-filler rotor II;24-is by liquid device;25-impingement region;26-filler rotor I.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, this utility model is described in further details, but this utility model content is not limited to by following embodiment.
As shown in Figure 2, a kind of combined type Multi-stage rotary packed bed mass transfer and reaction unit, including: it is provided with the revolving bed shell 17 of inlet 14, liquid outlet 20, air inlet 19 and gas outlet 18, the percussion flow device entered from top inlet 14, the feed pipe 15 that percussion flow device is provided with nozzle 16 by two root bottom parts forms, and feed pipe 15 connects different raw material reservoirs 1,5；The two-stage filler rotor I 26 being co-axially located in rotary shaft 21 and filler rotor II 23, filler rotor II 23 medial slope becomes 15 ° with vertical, and the swash plate with holes on inclined-plane becomes 75 ° with inclined-plane, and all fillers are stainless steel cloth filler in bulk；It is 30 ° by liquid device 24 inclination angle, circular flat disk is evenly equipped with liquid distributing hole.
In the filler rotor of described bottom, the way of contact of vapor-liquid two phases is counter current contacting.
As shown in Figure 1, a kind of method using this utility model to complete, comprise the steps: first to be sufficiently mixed by needs two strands of initial materials of reaction to dissolve respectively and be placed in reservoir I, II, two strands of initial materials are squeezed into percussion flow device from two feed pipes I, II by pump I, II respectively after fluid flowmeter I, II measures, through nozzle I, II carrying out at a high speed first Fast Collision after ejection in impingement region 25, mix, react, the filler rotor I 26 of the high speed rotating of liquid entrance subsequently carries out secondary deep hybrid reaction；After liquid-liquid two-phase mixtures has reacted, liquid is got rid of to revolving bed shell 17 inwall, flow to by liquid device 24, liquid distributing hole redistribute on bottom filler rotor II 23 inner band hole deviation plate 22 along inwall under gravity；Liquid is thrown under the influence of centrifugal force in filler rotor II 23 and throws away from inside to outside, and gas is entered by air inlet 19, carries out counter current contacting with liquid in filler rotor II 23；After completing mass transfer between vapor-liquid two phases, reaction, gas is discharged from gas outlet 18, and liquid is then expelled to reservoir III 9 by liquid outlet 20.
For in nitrobenzene waste water processing procedure, synchronizing fully to be reduced into Nitrobenzol aniline in the preparation process of nano zero valence iron, recycling ozone oxidation is by the method for degrading aniline subsequently, it is possible to use device described in the utility model carries out process intensification.
Utilizing technological process shown in Fig. 1, processing at 20 DEG C containing initial concentration is 200 mg L-1Nitrobenzene waste water.By ferrous sulfate (FeSO4·7H2O) being dissolved in the nitrobenzene waste water in reservoir I 1, compound concentration is 0.05 mol L-1Containing ferrous salt nitrobenzene waste water；With tap water by NaBH4Being dissolved in reservoir II 5, being made into concentration is 0.15 mol L-1NaBH4Aqueous solution.Two strands of liquid are squeezed into percussion flow device from two feed pipes I, II by pump I, II respectively after fluid flowmeter I, II measures, with 5 m s after nozzle I, II 16 high speed ejections-1Shock initial velocity in impingement region 25, carry out first Fast Collision, mix, react, liquid enters the filler rotor I 26 that rotating speed is 1200 rpm and carries out secondary deep hybrid reaction subsequently；After hybrid reaction completes, liquid is got rid of to revolving bed shell 17 inwall, flow to by liquid device 24, liquid distributing hole redistribute on bottom filler rotor II 23 inner band hole deviation plate 22 along inwall under gravity；It is in 1200 rpm filler rotors II 23 and to throw away from inside to outside that liquid is thrown to rotating speed under the influence of centrifugal force；Oxygen from oxygen cylinder 10 out after be transformed into ozone through ozonator 11, through gas flowmeter 12 measure to flow be 75 L h-1, gas phase ozone concentration is 50 mg L-1After, enter from air inlet 19, in bottom filler rotor II 23, carry out counter current contacting with waste water；After completing ozone oxidation reaction, gas is discharged to exhaust gas processing device 13 from gas outlet 18, and liquid enters reservoir III 9 from liquid outlet 20.
After single treatment, Nitrobenzol clearance 99%, COD clearance reaches more than 75%.Compared with conventional method, this device not only treatment effeciency is high, the process time is greatly shortened, and simplifies handling process, reduces intermediate operation step, and equipment takes up an area spatial volume and greatly reduces, it is possible to effectively reduce processing cost.
Claims (7)
1. a combined type Multi-stage rotary packed bed mass transfer reaction device, including the revolving bed shell being provided with inlet, liquid outlet, air inlet and gas outlet and the percussion flow device entered from top inlet, reaction zone, top and lower reaction zone is set in it is characterized in that revolving bed shell, being respectively provided with the filler rotor that some levels are coaxially disposed in reaction zone, upper and lower part, top and the bottom are arranged by liquid device between reaction zone.
Combined type Multi-stage rotary packed bed mass transfer reaction device the most according to claim 1, it is characterised in that reaction zone, top is liquid-liquid reactions district, and lower reaction zone is gas-liquid reaction district, and the top, lower reaction zone arranges gas outlet.
Combined type Multi-stage rotary packed bed mass transfer reaction device the most according to claim 2, it is characterized in that described is taper liquid-receiving plate by liquid device, it is circular flat disk bottom taper liquid-receiving plate, square position is evenly equipped with some liquid distributing holes, taper liquid-receiving plate outer and revolving bed shell
(17) connect.
Combined type Multi-stage rotary packed bed mass transfer reaction device the most according to claim 3, it is characterised in that described taper liquid-receiving plate inclination angle is 5 °～45 °, described taper liquid-receiving plate bottom circular square position percent opening is 30%～60%.
5. according to the combined type Multi-stage rotary packed bed mass transfer reaction device described in Claims 2 or 3 or 4, it is characterised in that having for inclined-plane inside the filler rotor in gas-liquid reaction district, inclined-plane is provided with some with holes swash plate angled with inclined-plane.
Combined type Multi-stage rotary packed bed mass transfer reaction device the most according to claim 5, it is characterised in that the filler rotor medial slope in gas-liquid reaction district and vertical design angle are 15 °～45 °, swash plate with holes and inclined design angle 60 °～90 °.
Combined type Multi-stage rotary packed bed mass transfer reaction device the most according to claim 6, it is characterized in that percussion flow device is provided with nozzle I by two root bottom parts, the feed pipe I of nozzle II, feed pipe II form, feed pipe I, feed pipe II connect different raw material reservoir I, raw material reservoir II respectively, and liquid-liquid reactions district and solution-air reaction zone have one group of filler rotor respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620455703.8U CN205759800U (en) | 2016-05-18 | 2016-05-18 | Combined type Multi-stage rotary packed bed mass transfer reaction device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620455703.8U CN205759800U (en) | 2016-05-18 | 2016-05-18 | Combined type Multi-stage rotary packed bed mass transfer reaction device |
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| CN205759800U true CN205759800U (en) | 2016-12-07 |
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| CN201620455703.8U Withdrawn - After Issue CN205759800U (en) | 2016-05-18 | 2016-05-18 | Combined type Multi-stage rotary packed bed mass transfer reaction device |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105854332A (en) * | 2016-05-18 | 2016-08-17 | 中北大学 | Combined type multi-stage rotating packed bed mass transfer reaction device and completed reaction method thereof |
| CN108176198A (en) * | 2018-02-14 | 2018-06-19 | 湖南湘达环保工程有限公司 | A kind of exhaust gas-absorbing liquid is pre-mixed the absorption plant and method of more peripheric jet flows |
| CN110339796A (en) * | 2019-06-28 | 2019-10-18 | 中北大学 | A kind of reaction unit and method preparing gasoline alkylate for sulfuric acid alkylation method |
| CN112023666A (en) * | 2020-08-31 | 2020-12-04 | 厦门恒绿环保工业有限公司 | Desulfurizing tower device |
-
2016
- 2016-05-18 CN CN201620455703.8U patent/CN205759800U/en not_active Withdrawn - After Issue
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105854332A (en) * | 2016-05-18 | 2016-08-17 | 中北大学 | Combined type multi-stage rotating packed bed mass transfer reaction device and completed reaction method thereof |
| CN105854332B (en) * | 2016-05-18 | 2018-12-11 | 中北大学 | Combined type Multi-stage rotary packed bed mass transfer reaction device and its reaction method of completion |
| CN108176198A (en) * | 2018-02-14 | 2018-06-19 | 湖南湘达环保工程有限公司 | A kind of exhaust gas-absorbing liquid is pre-mixed the absorption plant and method of more peripheric jet flows |
| CN110339796A (en) * | 2019-06-28 | 2019-10-18 | 中北大学 | A kind of reaction unit and method preparing gasoline alkylate for sulfuric acid alkylation method |
| CN110339796B (en) * | 2019-06-28 | 2021-04-02 | 中北大学 | Reaction device and method for preparing alkylated gasoline by sulfuric acid alkylation method |
| CN112023666A (en) * | 2020-08-31 | 2020-12-04 | 厦门恒绿环保工业有限公司 | Desulfurizing tower device |
| CN112023666B (en) * | 2020-08-31 | 2021-08-10 | 厦门恒绿环保工业有限公司 | Desulfurizing tower device |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20161207 Effective date of abandoning: 20181211 |
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| AV01 | Patent right actively abandoned |