CN205740377U - A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation - Google Patents
A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation Download PDFInfo
- Publication number
- CN205740377U CN205740377U CN201620597852.8U CN201620597852U CN205740377U CN 205740377 U CN205740377 U CN 205740377U CN 201620597852 U CN201620597852 U CN 201620597852U CN 205740377 U CN205740377 U CN 205740377U
- Authority
- CN
- China
- Prior art keywords
- white carbon
- ozone oxidation
- equipment
- situ
- carbon black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 45
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 35
- 239000006229 carbon black Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 230000003647 oxidation Effects 0.000 title claims abstract description 17
- 239000010920 waste tyre Substances 0.000 title claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 27
- 238000001035 drying Methods 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 238000001291 vacuum drying Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 2
- 239000002912 waste gas Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 230000016507 interphase Effects 0.000 abstract 1
- 238000005336 cracking Methods 0.000 description 7
- 239000003738 black carbon Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000002296 pyrolytic carbon Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 238000009688 liquid atomisation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
This utility model relates to a kind of equipment that waste tyre pyrolytic white carbon black carries out the modified also in-situ preparation white carbon of ozone oxidation, ozone oxidation reaction device, silica in situ generating means and the drying equipment connected including head and the tail；Ozone oxidation reaction device side is connected with ozonator；The outlet of ozone oxidation reaction device connects silica in situ generating means feed(raw material)inlet；The outlet of silica in situ generating means connects the entrance of drying equipment.The modified white carbon black of this utility model equipment is applied in butadiene-styrene rubber, good dispersion, and filler strengthens with rubber interphase interaction, and physical and mechanical properties improves, and black-reinforced effect is greatly enhanced.
Description
Technical field
This utility model relates to pyrolytic carbon black technical field of modification, is specifically related to one and carries out smelly to waste tyre pyrolytic white carbon black
Oxygen oxidation modification the equipment of in-situ preparation white carbon.
Background technology
Pyrolytic carbon black is junked tire solid under conditions of anaerobic or a small amount of oxygen exist obtained by Pintsch process
Product, cracking black carbon filler for rubber at aspects such as production cost, energy resource consumption, environmental conservation, with tradition reinforcing agent
White carbon black, white carbon are compared, and have the biggest advantage.But the powder characteristic of this pyrolytic carbon black obtained by high temperature pyrolytic cracking (HTP),
Surface property and general hard carbon black have a certain distance, and this reinforcing property just determining cracking black carbon is not very strong, not
Can directly utilize in rubber, need by process for treating surface, use physics, the method for chemistry to be changed by cracking black carbon
Property process, can improve the value of cracking black carbon, expand the application of cracking black carbon, improve the application layer of cracking black carbon
Secondary, reach environmental protection purpose.
The selection of filling kind is one of key factor determining rubber composite final performance.Different fillers are filled
The properties that rubber composite is shown is the most completely different, in rubber industry, balances and promotes rubber composite
Combination property is the main drive advancing filler development.In recent years, super-normal structure black, nano carbon black, white carbon and charcoal
In succession succeeding in developing before keeping tire tread glue low-rolling-resistance of the new varieties filleies such as black-and-white white carbon black two-phase filler
Put, improve the wearability of tire, make tire combination property be improved, promoted the development of green tire.
Prior art lacks a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment.
Utility model content
The purpose of this utility model is for the deficiencies in the prior art, it is provided that waste tyre pyrolytic white carbon black is carried out smelly by one
Oxygen oxidation modification the equipment of in-situ preparation white carbon.
The purpose of this utility model is achieved through the following technical solutions:
The technical solution of the utility model is: one carries out the modified also in-situ preparation of ozone oxidation to waste tyre pyrolytic white carbon black
The equipment of white carbon, ozone oxidation reaction device, silica in situ generating means and the drying equipment connected including head and the tail；Ozone
Oxidation reactor side is connected with ozonator；The outlet of ozone oxidation reaction device connects silica in situ generating means raw material
Entrance；The outlet of silica in situ generating means connects the entrance of drying equipment.
Preferably: ozone oxidation reaction device top arranges heating mantle.
Preferably: bottom silica in situ generating means, heating mantle is set.
Preferably: ozonator arranges oxygen intake and compressed air inlet, the outlet of ozonator is led to successively
The ozone inlet of ozone oxidation reaction device is connected after crossing exsiccator and effusion meter.
Preferably: silica in situ generating means top arranges liquid atomiser, bottom liquid atomiser arrange with
The liquid outlet of silica in situ generating means connection.
Preferably: silica in situ generating means is internal to be arranged and silica in situ generating means horizontal center line
Coaxial stirs tooth shaft.
Preferably: drying equipment includes vacuum drying oven and vacuum pump, the entrance of drying equipment is arranged on vacuum drying
The top side of case, the opposite side bottom vacuum drying oven arranges discharging opening.
Preferably: also include the gas recovery device being arranged on vacuum pump top.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model, wherein:
1-air compressor；2-oxygen bottle；3-ozonator；4-exsiccator；5-effusion meter；6-ozone oxidation reaction
Device；7-charging aperture；8,11-heating mantle；9-liquid atomiser；10-silica in situ generating means；12-vacuum drying oven；
13-vacuum pump；14-waste gas recovering device；15-products export.
Detailed description of the invention
A kind of equipment that waste tyre pyrolytic white carbon black carries out the modified also in-situ preparation white carbon of ozone oxidation, connects including head and the tail
Ozone oxidation reaction device 6, silica in situ generating means 10 and the drying equipment connect；Ozone oxidation reaction device 6 side is with smelly
Oxygen Generator 3 connects；Ozone oxidation reaction device 6 outlet connects silica in situ generating means 10 feed(raw material)inlet；Silicon dioxide
In-situ preparation device 10 outlet connects the entrance of drying equipment.Ozone oxidation reaction device 6 top arranges heating mantle 8.Silicon dioxide
Heating mantle 11 is set bottom in-situ preparation device 10.Ozonator 3 arranges oxygen intake and compressed air inlet, oxygen intake
Connecting oxygen bottle 2, compressed air inlet connects air compressor 1；The outlet of ozonator 3 passes sequentially through exsiccator 4 He
The ozone inlet of ozone oxidation reaction device 6 is connected after effusion meter 5.Silica in situ generating means 10 top arranges liquid atomization
Device 9, arranges the liquid outlet connected with silica in situ generating means 10 bottom liquid atomiser 9.Silica in situ is raw
What the internal setting of one-tenth device 10 was coaxial with silica in situ generating means 10 horizontal center line stirs tooth shaft.Drying equipment bag
Include vacuum drying oven 12, the entrance of vacuum pump 13 drying equipment is arranged on the top side of vacuum drying oven 12, vacuum drying oven
Opposite side bottom 12 arranges products export 15；Vacuum pump 13 top arranges gas recovery device 14.
Work process of the present utility model is: the oxygen from oxygen bottle produces ozone through ozonator, with air
Compressor produce air mixing after, drying device be dried with effusion meter measure after, enter reactor, liquid dispensing apparatus by than
Example spray water, TEOS (tetraethyl orthosilicate), ammonia respectively, under the constantly mixing stirring dentation shaft, make pyrolytic carbon black reach
Moisture state, concurrent biochemical reaction, at the active site in-situ preparation silicon dioxide of carbon blacksurface.By vacuum pump evacuation also
Vacuum drying oven heat drying, obtains finished product.
Claims (8)
1. the equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation, it is characterised in that:
Ozone oxidation reaction device, silica in situ generating means and the drying equipment connected including head and the tail；Ozone oxidation reaction device one
Side is connected with ozonator；The outlet of ozone oxidation reaction device connects silica in situ generating means feed(raw material)inlet；Titanium dioxide
The outlet of silicon in-situ preparation device connects the entrance of drying equipment.
It is a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment, it is characterised in that: ozone oxidation reaction device top arranges heating mantle.
It is a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment, it is characterised in that: bottom silica in situ generating means, heating mantle is set.
It is a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment, it is characterised in that: ozonator arranges oxygen intake and compressed air inlet, and the outlet of ozonator passes sequentially through
The ozone inlet of ozone oxidation reaction device is connected after exsiccator and effusion meter.
It is a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment, it is characterised in that: silica in situ generating means top arranges liquid atomiser, arranges and two bottom liquid atomiser
The liquid outlet of silicon oxide in-situ preparation device connection.
It is a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment, it is characterised in that: silica in situ generating means is internal to be arranged and silica in situ generating means horizontal center line
Coaxial stirs tooth shaft.
7. the one as described in claim 1-6 is arbitrary carries out ozone oxidation modification to waste tyre pyrolytic white carbon black and in-situ preparation is white
The equipment of white carbon black, it is characterised in that: drying equipment includes vacuum drying oven and vacuum pump, and the entrance of drying equipment is arranged on vacuum
The top side of drying baker, the opposite side bottom vacuum drying oven arranges discharging opening.
It is a kind of that waste tyre pyrolytic white carbon black carries out ozone oxidation is modified and in-situ preparation white carbon
Equipment, it is characterised in that: vacuum drying oven afterbody arranges waste gas recovering device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620597852.8U CN205740377U (en) | 2016-06-17 | 2016-06-17 | A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620597852.8U CN205740377U (en) | 2016-06-17 | 2016-06-17 | A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205740377U true CN205740377U (en) | 2016-11-30 |
Family
ID=57386878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201620597852.8U Expired - Fee Related CN205740377U (en) | 2016-06-17 | 2016-06-17 | A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205740377U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114395276A (en) * | 2021-12-30 | 2022-04-26 | 宁波德泰化学有限公司 | Janus structure carbon black and preparation method thereof |
-
2016
- 2016-06-17 CN CN201620597852.8U patent/CN205740377U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114395276A (en) * | 2021-12-30 | 2022-04-26 | 宁波德泰化学有限公司 | Janus structure carbon black and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106221297B (en) | The method for improving the surface organic process of titanium dioxide dispersibility | |
| CN105255218B (en) | The Nano calcium carbonate dedicated surface treatment method of polyurethane sealant | |
| CN105419009B (en) | A kind of method that semi-open type superheated steam spray drying process prepares high filled composite rubber master batch | |
| CN104194415B (en) | Synthetic mica of a kind of hydrophobic oleophilic oil modification and preparation method thereof | |
| CN102634062B (en) | Method for preparing high-tenacity reclaimed rubber by adding coupling agent | |
| CN205740377U (en) | A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of ozone oxidation | |
| CN106946262B (en) | A kind of method preparing hydrophobic type silica aerogel material and its method for preparing VIP evacuated panel and powder | |
| CN104959104B (en) | A kind of processing method of corrosion-resistant filling | |
| CN106831515A (en) | The method that tetra-benzyl thiram disulfide is continuously prepared using micro-reaction device | |
| CN206207919U (en) | Color sand production system | |
| CN207259450U (en) | A kind of rubber asphalt prepares storage device | |
| CN205627861U (en) | A agitating unit for middle level fat liquid recycle | |
| CN105692704B (en) | A kind of preparation method of heatproof iron oxide yellow | |
| CN104028245B (en) | A kind of have modified nano-titanium dioxide of better adsorption effect and preparation method thereof | |
| CN105368096A (en) | Preparation method for special activation powder for nanoscale painting by using coal-series kaolin | |
| CN205740378U (en) | A kind of equipment that waste tyre pyrolytic white carbon black is carried out the modified also in-situ preparation white carbon of plasma oxidation | |
| CN106629742A (en) | Hydrophobic fumed silica preparation method | |
| CN207153546U (en) | It is a kind of for nutritive cream production can quantitative raw material mixer | |
| CN104891505B (en) | A kind of preparation method of high-dispersity white carbon black | |
| CN205687849U (en) | A kind of waste tyre pyrolytic white carbon black is carried out the integration apparatus that ozone oxidation is modified and mixes with latex | |
| CN205803373U (en) | A kind of waste tyre pyrolytic white carbon black is carried out the integration apparatus that plasma oxidation is modified and mixes with latex | |
| CN205948791U (en) | Blending tank is used in metal powder coating production | |
| CN204911496U (en) | Polysilazane's preparation facilities | |
| CN104249997B (en) | A kind of method producing phosphorus ammonium | |
| CN204111624U (en) | A kind of propylene oxidation acrolein, acrolein test device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161130 Termination date: 20170617 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |