CN205687634U - A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system - Google Patents

A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system Download PDF

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Publication number
CN205687634U
CN205687634U CN201620642698.1U CN201620642698U CN205687634U CN 205687634 U CN205687634 U CN 205687634U CN 201620642698 U CN201620642698 U CN 201620642698U CN 205687634 U CN205687634 U CN 205687634U
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denitrification
anaerobic
reative cell
anammox
anaerobic digestion
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CN201620642698.1U
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Chinese (zh)
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郑平
丁阿强
张萌
赵旦
丁锋
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Zhejiang University ZJU
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Zhejiang University ZJU
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

The open a kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system of this utility model.System is made up of with external circuit two parts three chamber microbiological electrochemical reactors.Three chamber microbiological electrochemical reactors include three independent reative cells, and each reative cell arranges inert electrode, inoculate anaerobically digested sludge, short-cut denitrification mud and anaerobic ammonium oxidation sludge respectively, are separated by by ion exchange membrane between reative cell.Inert electrode is connected with external circuit.External circuit is connected two and is switched and a power supply, for the break-make of control circuit.This utility model switching by denitrification fuel cell and Anammox electrolyzer, can realize high COD, high nitrate nitrogen and the Combined Treatment of high ammonia-nitrogen wastewater, and has and efficiently process pollutant, reclaims the remarkable advantage of the energy.

Description

A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system
Technical field
This utility model ownership biological wastewater treatment field, is specifically related to a kind of anaerobic digestion denitrification anaerobic ammoxidation raw Thing electro-chemical systems.
Background technology
At present, frequently with anaerobic digestion techniques, the Organic substance in high-COD waste water is changed into methane and carbon dioxide, with reality Existing waste water de-carbon;It is respectively adopted denitrification and Anammox technology and the high nitrate nitrogen in waste water and high ammonia nitrogen be converted into nitrogen Gas, to realize denitrogenation of waste water.Along with the research and development of microbiological fuel cell (MFC) Yu microorganism electrolysis cell (MEC), by microorganism electricity The group technology that chemical technology combines with biological de-carbon and bio-denitrification technology arises at the historic moment.
Owing to biological de-carbon and denitrogenation technology are different to the requirement of waste water substrate, to combination microorganism electrochemical technology New technology research, currently mainly concentrate on bio electrochemistry technology respectively with biological de-carbon technology and the group of bio-denitrification technology Closing, main purpose is the recovery energy while pollution treatment.Combination process for the purpose of simultaneously processing multiple pollutant is so far Rare report.Biology de-carbon technology and bio-denitrification technology, with bioelectrochemical system as intermediary, are had by this utility model Machine couples, and develops a kind of new bio electro-chemical systems.
Summary of the invention
The purpose of this utility model is to solve the function singleness problem that prior art exists, it is provided that a kind of anti-nitre of anaerobic digestion Change Anammox bioelectrochemical system.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system, its agent set is three chamber microbiological electrifications Learn reactor, including anaerobic digestion reative cell, anti-nitration reaction room and three the independent reactions of Anammox reative cell District;Separated by cation exchange membrane between anaerobic digestion reative cell and anti-nitration reaction room, anti-nitration reaction room and anaerobism ammonia Separated by anion exchange membrane between oxidation reaction chamber;Anaerobic digestion reative cell, anti-nitration reaction room, Anammox reaction Room is inserted with inert electrode, inert electrode II, inert electrode III respectively;Divide on inert electrode I, inert electrode II, inert electrode III It is not enriched with anaerobically digested sludge, short-cut denitrification mud and anaerobic ammonium oxidation sludge;Described inert electrode I and inert electrode II Being connected by wire, described inert electrode II, inert electrode III pass through wire respectively and connect negative pole and the positive pole of regulated power supply.
As preferably, the wire between described inert electrode I and inert electrode II is provided with switch I, switch I and inertia Wire between electrode II is connected to the negative pole of regulated power supply by switch II.
As preferably, the wire of each reaction zone being positioned at three chamber microbiological electrochemical reactors all uses titanium silk.
Further, anaerobic digestion reative cell and anti-nitration reaction room can form denitrification fuel cell, anti-nitration reaction Room and Anammox reative cell can form Anammox electrolyzer, and three chamber microbiological electrochemical reactors are Microbial fuel Battery is integrated with microorganism electrolysis cell, can carry out denitrification fuel cell and Anammox electricity by switch I and switch II Switching between Xie Chi.
As preferably, anaerobic digestion reative cell, the ratio of anti-nitration reaction room and the volume of Anammox reative cell three Room For 1:1:1, it is respectively used to carry out oxidation operation, nitrate reduction and ammoxidation reaction.
As preferably, anaerobic digestion reative cell, anti-nitration reaction room respectively set water inlet with Anammox reative cell in bottom Mouthful, top respectively sets out the mouth of a river.
Further, denitrification fuel cell is shared by the switching of switch I and switch II with Anammox electrolyzer Anti-nitration reaction room;In denitrification fuel cell, anti-nitration reaction room receives the conveying of anaerobic digestion reative cell as negative electrode Electronics and carry out short-cut denitrification reaction (nitrate reduction becomes nitrite);In Anammox electrolyzer, anaerobism ammonia oxygen Changing the reative cell oxidation reaction as anode generation ammonia, anti-nitration reaction room receives the conveying of Anammox reative cell as negative electrode Electronics and carry out the reduction reaction of nitrite.
As preferably, described inert electrode I, inert electrode II, inert electrode III all use carbon felt electrode.
The beneficial effects of the utility model are:
(1) by the switching of microbiological fuel cell and microorganism electrolysis cell, can process simultaneously high COD, high nitrate nitrogen with And high three kinds of pollutant of ammonia nitrogen.
(2) microbiological fuel cell and microorganism electrolysis cell are incorporated in same system, can effectively reduce occupation of land Area and processing cost.
(3) energy can be reclaimed in wastewater treatment process.
Accompanying drawing explanation
Fig. 1 is anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system schematic diagram;
In figure: three chamber microbiological electrochemical reactors 1, external circuit 2, anaerobic digestion reative cell 3, anti-nitration reaction room 4, detest Anaerobic ammonium oxidation reative cell 5, inert electrode I 6, inert electrode II 7, inert electrode III 8, cation exchange membrane 9, anion exchange membrane 10, switch I 11, switch II 12, regulated power supply 13, anaerobic digestion water inlet 14, denitrification water inlet 15, Anammox is intake Mouth 16, outlet 17, titanium silk 18.
Detailed description of the invention
With embodiment, this utility model is further elaborated below in conjunction with the accompanying drawings.Technical characteristic in this utility model, In addition to having conflict, all can be mutually combined, not be construed as limiting.
As it is shown in figure 1, a kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system, its agent set is by three Room Microorganism electrochemical reactor 1 and external circuit 2 form (dividing with dotted line frame in scheming).Three chamber microbiological electrochemical reactors 1 by Lucite or other resistant materials make, and inside includes anaerobic digestion reative cell 3, anti-nitration reaction room 4 and anaerobism ammonia oxygen Change 5 three independent reaction zones of reative cell.By cation exchange membrane 9 between anaerobic digestion reative cell 3 and anti-nitration reaction room 4 Separate, separated by anion exchange membrane 10 between anti-nitration reaction room 4 and Anammox reative cell 5.Anaerobic digestion is reacted Room 3, anti-nitration reaction room 4, Anammox reative cell 5 are inserted with inert electrode I 6, inert electrode II 7, inert electrode successively III 8 (three electrodes can use the inert electrode being not involved in reaction, preferably carbon felt electrode).Inert electrode I 6, inert electrode II 7, anaerobically digested sludge, short-cut denitrification mud and anaerobic ammonium oxidation sludge it are enriched with on inert electrode III 8 the most in advance.External circuit A regulated power supply 13, switch I 11 and switch II 12 it is provided with in 2.In order in preventing reaction zone, wire is caused corruption by liquid environment Erosion, three electrodes are connected with external circuit 2 by titanium silk 18, and titanium silk end is positioned at outside reaction zone.Inert electrode I 6 and inert electrode The titanium silk 18 of II 7 is electrically connected by wire, and arranges switch on this conducting line segment and I 11 carry out cut-offfing control.Switch I 11 electric with inertia Wire between pole II 7 is connected to the negative pole of regulated power supply 13 by switch II 12.Inert electrode III 8 is connected to regulated power supply 13 Positive pole, power supply be powered.
Anaerobic digestion reative cell 3 and anti-nitration reaction room 4 can form denitrification fuel cell, anti-nitration reaction room 4 with detest Anaerobic ammonium oxidation reative cell 5 can form Anammox electrolyzer.As can be seen here, three chamber microbiological electrochemistry of the present utility model are anti- That answers that device 1 is microbiological fuel cell with microorganism electrolysis cell is integrated, and can carry out denitrification by switch I 11 and switch II 12 Switching between fuel cell and Anammox electrolyzer.
Anaerobic digestion reative cell 3, anti-nitration reaction room 4 are 1:1:1 with the ratio of the volume of Anammox reative cell 5, can Carry out oxidation operation, nitrate reduction and ammoxidation reaction respectively, under this volume ratio, be suitable for high COD, high nitrate nitrogen and height The removal of ammonia nitrogen.
Anaerobic digestion reative cell 3, anti-nitration reaction room 4 and Anammox reative cell 5 respectively set water inlet 14, enter in bottom The mouth of a river 15, water inlet 16, top respectively sets out the mouth of a river 17, passes through cation between anaerobic digestion reative cell 3 and anti-nitration reaction room 4 Exchange membrane 9 separates, and is separated by anion exchange membrane 10 between anti-nitration reaction room 4 and Anammox reative cell 5.
Denitrification fuel cell shares anti-nitration reaction with Anammox electrolyzer by the switching of switch I and switch II Room;In denitrification fuel cell, anti-nitration reaction room receives the electronics of anaerobic digestion reative cell conveying as negative electrode and carries out Short-cut denitrification reaction (nitrate reduction becomes nitrite);In Anammox electrolyzer, Anammox reative cell 5 is made For the oxidation reaction of anode generation ammonia, anti-nitration reaction room 4 as negative electrode receive Anammox reative cell 5 conveying electronics and Carry out the reduction reaction of nitrite.
In denitrification fuel cell, anti-nitration reaction room is controlled to carry out short-cut denitrification (nitrate reduction becomes nitrous acid Salt);In Anammox electrolyzer, Anammox reative cell carries out ammoxidation, and anti-nitration reaction room 4 carries out nitrite Reduction reaction, under external power effect, Anammox has been worked in coordination with in Anammox reative cell and anti-nitration reaction room.Specifically Step is as follows:
First, shown in Fig. 1, assemble electro-chemical systems, add height by the water inlet 14 of anaerobic digestion reative cell 3 COD waste water, adds high nitrate nitrogen waste water by the water inlet 15 of anti-nitration reaction room 4, by the water inlet of Anammox reative cell 5 Mouthfuls 16 add high ammonia-nitrogen wastewaters, it is ensured that attachment anaerobic digestion, short-cut denitrification, anaerobic ammonium oxidation sludge three electrodes the most right Should high COD, high nitrate nitrogen, three kinds of waste water of high ammonia nitrogen.The pollutant levels that in this step, each reative cell is corresponding should be tried one's best height, with more Reaction is conducive to carry out.
Secondly, Guan Bi switch I 11, open switch II 12, anaerobic digestion reative cell 3 and anti-nitration reaction room 4 form anti-nitre Changing fuel cell, anaerobic digestion reative cell 3 carries out organic oxidation reaction as anode, and anti-nitration reaction room 4 is as negative electrode Carrying out the reduction reaction of nitrate, the electronics that anode reaction produces is delivered to negative electrode by external circuit, improves anaerobic digestion simultaneously With the efficiency of short-cut denitrification, and produce electric current.The electric current produced can be carried out the energy by electric current recycle device to return Receive and utilize.
Again, opening switch I 11, Guan Bi switch II 12, regulation regulated power supply is to suitable voltage, anti-nitration reaction room 4 Forming Anammox electrolyzer with Anammox reative cell 5, anti-nitration reaction room 4 carries out going back of nitrite as negative electrode Former reaction, Anammox reative cell 5 carries out the oxidation reaction of ammonia as anode.By previous step in anti-nitration reaction room 4 The nitrite that nitrate reduction produces, is acted through anion exchange membrane 9 by regulated power supply and shifts to Anammox and react Room 5, and at Anammox reative cell 5 and ammonia nitrogen in high density generation Anammox, generate nitrogen;
Finally, treated waste water is reacted with Anammox by anaerobic digestion reative cell 3, anti-nitration reaction room 4 The respective outlet in room 5 17 discharges system.Whole process can synchronize to realize the combined removal to COD Yu nitrogen pollutant, simultaneously Reclaim again the energy.
The foregoing is only preferred embodiment of the present utility model, not in order to limit this utility model, all at this Any amendment, equivalent and the improvement etc. made within the spirit of utility model and principle, should be included in this utility model Protection domain within.

Claims (8)

1. an anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system, it is characterised in that: agent set is that three Room are micro- Bio-electrochemical reactor (1), reacts with Anammox including anaerobic digestion reative cell (3), anti-nitration reaction room (4) Independent reaction zone, (5) three, room;Cation exchange membrane is passed through between anaerobic digestion reative cell (3) and anti-nitration reaction room (4) (9) separate, separated by anion exchange membrane (10) between anti-nitration reaction room (4) and Anammox reative cell (5);Anaerobism Digestion reaction room (3), anti-nitration reaction room (4), Anammox reative cell (5) are inserted with inert electrode I (6), inertia electricity respectively Pole II (7), inert electrode III (8);Anaerobism it is enriched with respectively on inert electrode I (6), inert electrode II (7), inert electrode III (8) Digested sludge, short-cut denitrification mud and anaerobic ammonium oxidation sludge;Described inert electrode I (6) passes through with inert electrode II (7) Wire is connected, and described inert electrode II (7), inert electrode III (8) pass through wire respectively and connect the negative pole of regulated power supply (13) And positive pole.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system the most according to claim 1, its feature exists In: the wire between described inert electrode I (6) and inert electrode II (7) is provided with switch I (11), switch I (11) and inertia Wire between electrode II (7) is connected to the negative pole of regulated power supply (13) by switch II (12).
3. a kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system as claimed in claim 2, it is characterised in that: The wire of each reaction zone being positioned at three chamber microbiological electrochemical reactors (1) all uses titanium silk.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system the most according to claim 2, its feature exists In: anaerobic digestion reative cell (3) and anti-nitration reaction room (4) can form denitrification fuel cell, anti-nitration reaction room (4) with detest Anaerobic ammonium oxidation reative cell (5) can form Anammox electrolyzer, and three chamber microbiological electrochemical reactors (1) are Microbial fuel Battery is integrated with microorganism electrolysis cell, can carry out denitrification fuel cell and anaerobism by switch I (11) and switch II (12) Switching between ammoxidation electrolyzer.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system the most according to claim 1, its feature exists In: anaerobic digestion reative cell (3), anti-nitration reaction room (4) they are 1:1 with the ratio of the volume of Anammox reative cell (5) three Room: 1, it is respectively used to carry out oxidation operation, nitrate reduction and ammoxidation reaction.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system the most according to claim 1, its feature exists In: anaerobic digestion reative cell (3), anti-nitration reaction room (4) respectively set water inlet with Anammox reative cell (5) in bottom, top Portion respectively sets out the mouth of a river.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system the most according to claim 2, its feature exists In: denitrification fuel cell shares denitrification with Anammox electrolyzer by the switching of switch I (11) and switch II (12) Reative cell (4);In denitrification fuel cell, anti-nitration reaction room (4) receive anaerobic digestion reative cell (3) conveying as negative electrode Electronics and carry out short-cut denitrification reaction;In Anammox electrolyzer, Anammox reative cell (5) is sent out as anode The oxidation reaction of ammonifying, anti-nitration reaction room (4) receive Anammox reative cell (5) electronics that carries as negative electrode and carry out The reduction reaction of nitrite.
A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system the most according to claim 1, its feature exists In: described inert electrode I (6), inert electrode II (7), inert electrode III (8) all use carbon felt electrode.
CN201620642698.1U 2016-06-23 2016-06-23 A kind of anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system Withdrawn - After Issue CN205687634U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105948222A (en) * 2016-06-23 2016-09-21 浙江大学 Anaerobic digestion, denitrification and anaerobic ammonium oxidation bioelectrochemical system and method
CN110204033A (en) * 2019-05-08 2019-09-06 南开大学 A kind of method that microorganism electrochemical ammoniumization recycles nitrate nitrogen in waste water
CN111573834A (en) * 2020-05-22 2020-08-25 盐城工学院 Reactor based on short-cut denitrification electrode is in coordination with anaerobic ammonia oxidation denitrogenation

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105948222A (en) * 2016-06-23 2016-09-21 浙江大学 Anaerobic digestion, denitrification and anaerobic ammonium oxidation bioelectrochemical system and method
CN105948222B (en) * 2016-06-23 2018-09-07 浙江大学 Anaerobic digestion denitrification anaerobic ammoxidation bioelectrochemical system and method
CN110204033A (en) * 2019-05-08 2019-09-06 南开大学 A kind of method that microorganism electrochemical ammoniumization recycles nitrate nitrogen in waste water
CN110204033B (en) * 2019-05-08 2021-07-23 南开大学 Method for recovering nitrate nitrogen in wastewater through microbial electrochemical ammonification
CN111573834A (en) * 2020-05-22 2020-08-25 盐城工学院 Reactor based on short-cut denitrification electrode is in coordination with anaerobic ammonia oxidation denitrogenation

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