CN205522386U - Titanium dioxide extinction spinning production system is added in polylactic acid section - Google Patents
Titanium dioxide extinction spinning production system is added in polylactic acid section Download PDFInfo
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- CN205522386U CN205522386U CN201620315598.8U CN201620315598U CN205522386U CN 205522386 U CN205522386 U CN 205522386U CN 201620315598 U CN201620315598 U CN 201620315598U CN 205522386 U CN205522386 U CN 205522386U
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Abstract
Titanium dioxide extinction spinning production system is added in polylactic acid section, including aggregation framework, agitator tank, just gather jar, gather eventually jar, pelleter, cooling tank, vulcanization crystallization bed, drying tower, first feed bin, second feed bin, compress air system, spinning screw extruder and spinning box, bottom the agitator tank through first conveying pipeline with just gather tank deck portion and be connected, be equipped with polylactic acid pre -polymerization compounding device on the first conveying pipeline, the discharge gate of spinning screw extruder passes through the fuse -element pipeline to be connected with the spinning box, is equipped with the integrative pipeline formula compounding device of sound on the fuse -element pipeline. The utility model discloses ensure the downward flow under the constant speed state of the intraductal fuse -element of prepolymerization to it is also unanimous basically to make the intraductal fuse -element temperature of prepolymerization, the utility model discloses direct set up on the third conveying pipeline a plurality of groups compounding unit can, saved installation compounding system on pipeline, practiced thrift the cost, reach the purpose of even compounding, transport and compounding efficiency improve greatly.
Description
Technical field
This utility model belongs to poly lactic acid polymerized technical field, particularly relates to a kind of polylactic acid slice and adds titanium dioxide delustring spinning production system.
Background technology
Poly lactic acid polymerized operation includes pre-polymerization and gathers eventually.The melt needing polymerization first has to through pre-polymerization, and the equipment of pre-polymerization is the tank body of a vertical type cylinder shape, and tank body top is vertically provided with prepolymerization pipe.Prepolymerized melt is needed quantitatively to enter in prepolymerization pipe from the upper end of prepolymerization pipe, by self gravitation and the most steadily flow down in tank body.Due to the friction factor of melt Yu prepolymerization tube wall, the melt of the prepolymerization tube hub speed flowing velocity more downward than the melt at prepolymerization tube wall that flow downward is fast, and the temperature of the temperature at prepolymerization tube wall and prepolymerization tube hub also has difference.And preferably situation is；1, melt flows downward under constant speed state；2, when in prepolymerization pipe, melt flows downward, the tube wall of each aspect and the solution temperature of prepolymerization tube hub are desirably also；3, due to longer for carrying the conveyance conduit of polylactic acid after gathering eventually, the biggest near the high polymer molten viscosity of tube wall, molecular weight of high polymer wider distribution (uneven) problem that polylactic acid melt causes because melt flow is uneven in course of conveying, impurity can not effectively filter out, thus has influence on spinning quality.For reaching this purpose, need in prepolymerization pipe to assemble array batch mixing preheater, to meet the requirement of polymerization technique.
Utility model content
This utility model is in order to solve weak point of the prior art, it is provided that a kind of basic constant speed can be kept to flow downward prepolymerization inside pipe wall and the melt of center and prepolymerization inside pipe wall can be swapped mixing with the melt of center keeping temperature polylactic acid slice interpolation titanium dioxide delustring spinning production system consistent, that mix homogeneously in the most poly-rear course of conveying.
nullFor solving above-mentioned technical problem，This utility model adopts the following technical scheme that polylactic acid slice adds titanium dioxide delustring spinning production system，Including aggregation framework、Pelleter、Cooling bay、Vulcanize crystallizing bed、Drying tower、First feed bin、Second feed bin、Compressed air system、Spinning screw extruder and spinning manifold，Agitator tank it is sequentially provided with from top to bottom in aggregation framework、First poly-tank and eventually poly-tank，It is connected with first poly-tank top by the first conveying pipeline bottom agitator tank，First conveying pipeline is provided with polylactic acid pre-polymerization mixing device、First autocontrol valve and the first dosing pump，First poly-pot bottom is connected with poly-tank top eventually by the second conveying pipeline，Second conveying pipeline is provided with the second autocontrol valve and the second dosing pump，Poly-pot bottom connects eventually the 3rd conveying pipeline，3rd conveying pipeline is provided with the 3rd dosing pump，The discharging opening of the 3rd conveying pipeline connects the polylactic acid melt extrusion orifice plate being positioned at above cooling bay，Cooling water it is loaded with in cooling bay，The working end of pelleter is located in cooling bay，The discharge end of pelleter is positioned at outside cooling bay and is connected by the feed end that conveyer is crystallizing bed with sulfuration，Vulcanize crystallizing bed discharge end to be connected with the charging aperture of drying tower，The discharging opening of drying tower and the charging aperture of the second feed bin connect；
The discharging opening of the second feed bin is connected by the charging aperture of main tremie pipe with spinning screw extruder, tilt to be provided with airduct between air outlet and the main tremie pipe of compressed air system, airduct is connected the position of end and is connected the position of end higher than airduct with main tremie pipe with compressed air system, airduct is provided with the adjusting air valve of neighbouring compressed air system, the discharging opening of the first feed bin is connected with airduct by mix tube, mix tube is provided with powder quantifier, the discharging opening of spinning screw extruder is connected with spinning manifold by melt pipe, melt pipe is provided with sound integrated pipeline formula mixing device, spinning pump and filament spinning component it is provided with in spinning manifold, in the discharging opening of melt pipe extend into spinning manifold and it is connected with the charging aperture of spinning pump, spinning measuring delivery side of pump is connected with the import of filament spinning component；
Polylactic acid pre-polymerization mixing device includes the prepolymerization pipe being arranged in vertical, and from top to bottom at least provided with two batch mixing preheaters in prepolymerization pipe, all of equal structure of batch mixing preheater is identical；
Each batch mixing preheater all includes having the first upper conical guide shell of same centrage, the second upper conical guide shell, the first inferior pyramidal guide shell, the second inferior pyramidal guide shell, upper shunting cone cylinder and lower shunting cone cylinder；
nullFirst upper conical guide shell and the first inferior pyramidal guide shell are upper coarse and lower fine and upper and lower permeable structures，First upper conical guide shell bottom diameter is more than the second upper conical guide shell bottom diameter，Second upper conical guide shell and the second inferior pyramidal guide shell are up-thin-low-thick and upper and lower permeable structures，First upper conical guide shell bottom diameter and the second upper conical guide shell upper-end inner diameter are equal，First inferior pyramidal guide shell bottom diameter and the second inferior pyramidal guide shell upper-end inner diameter are equal，First outer, upper conical guide shell upper end、Second outer, upper conical guide shell lower end、First edge, inferior pyramidal guide shell upper end and the second edge, inferior pyramidal guide shell lower end are fixedly connected with at prepolymerization inside pipe wall，The fixing connection in first upper conical edge, guide shell lower end and the second edge, upper conical guide shell upper end，The fixing connection in first upper conical edge, guide shell lower end and the second edge, upper conical guide shell upper end，The fixing connection in first edge, inferior pyramidal guide shell lower end and the second edge, inferior pyramidal guide shell upper end；
Upper shunting cone cylinder is the structure that top sharply blocks, bottom is uncovered, lower shunting cone cylinder is the sharp-pointed closure in bottom, the structure of open top, upper shunting cone cylinder bottom diameter is equal to lower shunting cone cylinder upper-end inner diameter, upper shunting cone cylinder bottom diameter is less than prepolymerization bore, and edge, upper shunting cone cylinder lower end is fixing with edge, lower shunting cone cylinder upper end to be connected；Upper shunting cone cylinder and lower spreader drum outer wall are connected by heating agent conduit and prepolymerization inside pipe wall are fixing；
The upper end of upper shunting cone cylinder is higher than the first edge, upper conical guide shell upper end, and the lower end of lower shunting cone cylinder flushes with the second edge, inferior pyramidal guide shell upper end；
Form circulation road under tube wall melt between upper spreader tube outer surface and the first inferior pyramidal guide shell outer surface, between lower spreader tube outer surface and the first inferior pyramidal guide shell outer surface, form circulation road under blend melt；
Upper spreader tube outer surface is provided with central melt flow dividing structure, and the lower end of central melt flow dividing structure crosses with circulation road lower end under tube wall melt.
Sound integrated pipeline formula mixing device includes fixed-piping and batch mixing unit, batch mixing unit includes static batch mixing pipeline and the dynamic mixture pipeline of coaxial setting, the left end of dynamic mixture pipeline and the right-hand member Flange joint of static batch mixing pipeline, dynamic screw dividing plate it is provided with in dynamic mixture pipeline, dynamic mixture pipe interior is in axial direction separated into the first semicircle helical duct and the second semicircle helical duct, dynamic screw dividing plate and dynamic mixture inner-walls of duct matched in clearance by dynamic screw dividing plate；Being provided with static ribbon dividing plate in static batch mixing pipeline, static state batch mixing pipeline axially inside direction is separated into the 3rd semicircle helical duct and the 4th semicircle helical duct by static ribbon dividing plate, and static ribbon dividing plate is fixing with static batch mixing inner-walls of duct to be connected；
The plane at the place, both ends of dynamic screw dividing plate and static ribbon dividing plate is each perpendicular to the central axis of dynamic mixture pipeline, center, dynamic screw dividing plate right part is provided with dynamic cone tank, center, dynamic screw dividing plate left part is provided with the most top, center, static ribbon dividing plate right part is provided with static cone tank, center, static ribbon dividing plate left part is provided with static top, and dynamic top left end withstands in static cone tank；
Fixed-piping left end and dynamic mixture pipeline right-hand member Flange joint, be provided with support in fixed-piping, support is provided with stationary center, and stationary center left end withstands in dynamic cone tank.
The quantity of batch mixing unit is more than or equal to two groups, and Flange joint between two adjacent groups batch mixing unit, the top left end of static state of one group of batch mixing unit withstands in the dynamic cone tank of adjacent one group batch mixing unit, and fixed-piping is connected with one group of batch mixing unit of low order end.
The length of static batch mixing pipeline is less than the length of dynamic mixture pipeline.
Central melt flow dividing structure includes a shunt cylinder and several isocons, shunt cylinder and isocon are each provided in shunting cone cylinder, shunt cylinder open top, edge, shunt cylinder upper end level, isocon is wide at the top and narrow at the bottom, the all isocons of isocon are evenly arranged along upper shunting cone cylinder circumferencial direction, and isocon upper end connects with shunt cylinder lower end, and isocon lower port is positioned at circulation road lower end and the outside of circulation road upper end intersection under blend melt under tube wall melt.
Upper shunting cone cylinder is internally formed preheating cavity with lower shunting cone cylinder, and preheating cavity under being internally formed of the first inferior pyramidal guide shell and the second inferior pyramidal guide shell has all been passed through hot circulating fluid medium in upper preheating cavity and lower preheating cavity；Heating agent conduit is inner and upper preheating cavity connects, and heating agent external catheter end stretches out outside prepolymerization pipe.
nullUse technique scheme，First conveying pipeline arranges polylactic acid pre-polymerization mixing device carry out batch mixing warm and be: melt flows downward in prepolymerization pipe，Melt A at prepolymerization tube hub enters into shunt cylinder along upper shunting cone surface，Melt A flows to circulation road lower end and the outside of the intersection of circulation road upper end under blend melt under tube wall melt automatically by isocon again，Meanwhile，Melt B near prepolymerization tube wall enters under tube wall melt in circulation road through the first upper conical guide shell，Flow to be positioned at behind circulation road lower end under tube wall melt the top of melt A，Under i.e. melt A and melt B entrance blend melt after circulation road，Melt A is positioned at lower floor，Melt B is positioned at upper strata，Until melt A and melt B flow to circulation road lower end outlet under blend melt，Melt B is positioned in the middle of melt A，I.e. melt A is transformed into by center and continues to flow downward along tube wall，Melt B is transformed into center and continues to flow downward by being close to tube wall，During transposition，Melt A and melt B have been also carried out mixing definitely.
During melt mixed replaces, being all passed through hot circulating fluid medium in upper preheating cavity and lower preheating cavity, hot circulating fluid medium can add thermal medium such as according to technological requirement；Biphenyl Ether, conduction oil etc., preheat melt, to facilitate control prepolymerization process.This utility model all takes in the junction of all parts and designs without dead angle.Many group batch mixing preheaters can be installed in a piece prepolymerization pipe from top to bottom.
nullMelt pipe arranges sound integrated pipeline formula mixing device，Have the advantages that under the discharge pressure effect of spinning screw extruder，Polylactic acid melt after polymerization is entered by fixed-piping，When the melt of thickness under high pressure passes through dynamic mixture pipeline when，Dynamic screw dividing plate starts to rotate under the promotion of melt，The dynamic screw dividing plate that viscous melt on the inwall of dynamic mixture pipeline is rotated scrapes，The viscous melt scraped is diluter that melt mixes with dynamic mixture pipeline centre，And mix in pushing ahead the 3rd semicircle helical duct in static batch mixing pipeline and the 4th semicircle helical duct，Above-mentioned batch mixing process is repeated in entering back into dynamic mixture pipeline after mixing，After some groups of batch mixing unit，Uniform polylactic acid melt enters polylactic acid melt extrusion orifice plate，Polylactic acid melt extrusion orifice plate carries out water-cooled after polylactic acid melt is sprayed into tape，The rotating blade of pelleter is close to polylactic acid melt extrusion orifice plate rotation simultaneously，Polylactic acid melt tape is cut off and forms polylactic acid slice by rotating blade.Due to the first semicircle helical duct and the second semicircle helical duct is longer and the most in the axial direction for the hand of spiral arrange, thus can when pressurized melt is passed through, drive dynamic screw dividing plate rotate；The top form with the press-fit of cone tank top of rotary material of dynamic screw dividing plate, is not only easy to manufacture and assembling, and frictional force is less in rotary course, thus improve the efficiency of dynamic screw dividing plate scraper.The length of static batch mixing pipeline, less than the length of dynamic mixture pipeline, so can make most of length of the pipeline of whole conveying polylactic acid all can be wiped off by king-sized for the viscosity adhered on tube wall polylactic acid, fully improves the uniformity of mixing.
In sum, this utility model scientific in principle, reasonable in design, simple in construction, guarantee that the melt in prepolymerization pipe flows downward under constant speed state, and when making melt in prepolymerization pipe flow downward, the tube wall of each aspect is the most basically identical with the solution temperature of prepolymerization tube hub, thus meet the requirement of polymerization technique.Directly arranging some groups of batch mixing unit on melt pipe, eliminate installation mixing system on conveyance conduit, saved cost, reach the purpose of uniform batch mixing, conveying and batch mixing efficiency are greatly improved.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model；
Fig. 2 is the structural representation of the present utility model in Fig. 1 with one group of batch mixing unit；
Fig. 3 is the perspective view of dynamic screw dividing plate in Fig. 2；
Fig. 4 is the perspective view of static ribbon dividing plate in Fig. 2；
Fig. 5 is the structural representation of polylactic acid pre-polymerization mixing device in Fig. 1；
Fig. 6 is the top view of the central melt flow dividing structure in Fig. 5.
Detailed description of the invention
nullAs shown in figs 1 to 6，Polylactic acid slice of the present utility model adds titanium dioxide delustring spinning production system，Including aggregation framework 16、Pelleter 17、Cooling bay 18、Vulcanize crystallizing bed 60、Drying tower 61、First feed bin 62、Second feed bin 63、Compressed air system 64、Spinning screw extruder 65 and spinning manifold 66，Agitator tank 19 it is sequentially provided with from top to bottom in aggregation framework 16、First poly-tank 20 and eventually poly-tank 21，It is connected with first poly-tank 20 top by the first conveying pipeline 22 bottom agitator tank 19，First conveying pipeline 22 is provided with polylactic acid pre-polymerization mixing device 40、First autocontrol valve 23 and the first dosing pump 24，It is connected with poly-tank 21 top eventually by the second conveying pipeline 25 bottom first poly-tank 20，Second conveying pipeline 25 is provided with the second autocontrol valve 26 and the second dosing pump 27，Connect bottom poly-tank 21 eventually and have the 3rd conveying pipeline 28，3rd conveying pipeline 28 is provided with the 3rd dosing pump 29，The discharging opening of the 3rd conveying pipeline 28 connects the polylactic acid melt extrusion orifice plate 32 being positioned at above cooling bay 18，Cooling water it is loaded with in cooling bay 18，The working end of pelleter 17 is located in cooling bay 18，The discharge end of pelleter 17 is positioned at outer and by conveyer with sulfuration crystallizing bed 60 the feed end of cooling bay 18 and is connected，Vulcanize the discharge end of crystallizing bed 60 to be connected with the charging aperture of drying tower 61，The discharging opening of drying tower 61 and the charging aperture of the second feed bin 63 connect.
nullThe discharging opening of the second feed bin 63 is connected with the charging aperture of spinning screw extruder 65 by main tremie pipe 67，Tilt to be provided with airduct 68 between air outlet and the main tremie pipe 67 of compressed air system 64，Airduct 68 is connected the position of end and is connected the position of end higher than airduct 68 with main tremie pipe 67 with compressed air system 64，Airduct 68 is provided with the adjusting air valve 69 of neighbouring compressed air system 64，The discharging opening of the first feed bin 62 is connected with airduct 68 by mix tube 70，Mix tube 70 is provided with powder quantifier 71，The discharging opening of spinning screw extruder 65 is connected with spinning manifold 66 by melt pipe 72，Melt pipe 72 is provided with sound integrated pipeline formula mixing device 31，Spinning pump 73 and filament spinning component 74 it is provided with in spinning manifold 66，In the discharging opening of melt pipe 72 extend into spinning manifold 66 and it is connected with the charging aperture of spinning pump 73，The outlet of spinning pump 73 is connected with the import of filament spinning component 74.
Sound integrated pipeline formula mixing device 31 includes fixed-piping 1 and batch mixing unit, batch mixing unit includes static batch mixing pipeline 2 and the dynamic mixture pipeline 3 of coaxial setting, the left end of dynamic mixture pipeline 3 and the right-hand member Flange joint of static batch mixing pipeline 2, dynamic screw dividing plate 4 it is provided with in dynamic mixture pipeline 3, dynamic mixture pipeline 3 axially inside direction is separated into the first semicircle helical duct 5 and the second semicircle helical duct 6, dynamic screw dividing plate 4 and dynamic mixture pipeline 3 inwall matched in clearance by dynamic screw dividing plate 4；Being provided with static ribbon dividing plate 7 in static batch mixing pipeline 2, static state batch mixing pipeline 2 axially inside direction is separated into the 3rd semicircle helical duct 8 and the 4th semicircle helical duct 9 by static ribbon dividing plate 7, and static ribbon dividing plate 7 is fixing with static batch mixing pipeline 2 inwall to be connected.
The plane at the place, both ends of dynamic screw dividing plate 4 and static ribbon dividing plate 7 is each perpendicular to the central axis of dynamic mixture pipeline 3, center, dynamic screw dividing plate 4 right part is provided with dynamic cone tank 10, center, dynamic screw dividing plate 4 left part is provided with the most top 11, center, static ribbon dividing plate 7 right part is provided with static cone tank 12, center, static ribbon dividing plate 7 left part is provided with static top 13, and the most top 11 left ends withstand in static cone tank 12.
Fixed-piping 1 left end and dynamic mixture pipeline 3 right-hand member Flange joint, be provided with support 14 in fixed-piping 1, support 14 is provided with stationary center 15, and stationary center 15 left end withstands in dynamic cone tank 10.
The quantity of batch mixing unit is more than or equal to two groups, and Flange joint between two adjacent groups batch mixing unit, top 13 left ends of static state of one group of batch mixing unit withstand in the dynamic cone tank 10 of adjacent one group batch mixing unit, and fixed-piping 1 is connected with one group of batch mixing unit of low order end.The length of static batch mixing pipeline 2 is less than the length of dynamic mixture pipeline 4.
Polylactic acid pre-polymerization mixing device 40 includes the prepolymerization pipe 41 being arranged in vertical, prepolymerization pipe 41 two ends are fixedly connected on the first conveying pipeline 22, or can be using the first conveying pipeline 22 as prepolymerization pipe 41, from top to bottom at least provided with two batch mixing preheaters in prepolymerization pipe 41, all of equal structure of batch mixing preheater is identical；In this utility model, prepolymerization pipe 41 can use the first conveying pipeline 22 to replace；
Each batch mixing preheater all includes having first upper conical guide shell 42, second upper conical guide shell the 43, first inferior pyramidal guide shell the 44, second inferior pyramidal guide shell 45 of same centrage, upper shunting cone cylinder 46 and lower shunting cone cylinder 47；
nullFirst upper conical guide shell 42 and the first inferior pyramidal guide shell 44 are upper coarse and lower fine and upper and lower permeable structures，First upper conical guide shell 42 bottom diameter is more than the second upper conical guide shell 43 bottom diameter，Second upper conical guide shell 43 and the second inferior pyramidal guide shell 45 are up-thin-low-thick and upper and lower permeable structures，First upper conical guide shell 42 bottom diameter and the second upper conical guide shell 43 upper-end inner diameter are equal，First inferior pyramidal guide shell 44 bottom diameter and the second inferior pyramidal guide shell 45 upper-end inner diameter are equal，First outer, upper conical guide shell 42 upper end、Second outer, upper conical guide shell 43 lower end、First edge, inferior pyramidal guide shell 44 upper end and the second edge, inferior pyramidal guide shell 45 lower end are fixedly connected with at prepolymerization pipe 41 inwall，The fixing connection in first upper conical edge, guide shell 42 lower end and the second edge, upper conical guide shell 43 upper end，The fixing connection in first upper conical edge, guide shell 42 lower end and the second edge, upper conical guide shell 43 upper end，The fixing connection in first edge, inferior pyramidal guide shell 44 lower end and the second edge, inferior pyramidal guide shell 45 upper end；
The structure that upper shunting cone cylinder 46 sharply blocks for top, bottom is uncovered, lower shunting cone cylinder 47 sharply blocks for bottom, the structure of open top, upper shunting cone cylinder 46 bottom diameter is equal to lower shunting cone cylinder 47 upper-end inner diameter, upper shunting cone cylinder 46 bottom diameter is less than prepolymerization pipe 41 internal diameter, and edge, upper shunting cone cylinder 46 lower end is fixing with edge, lower shunting cone cylinder 47 upper end to be connected；Upper shunting cone cylinder 46 and lower shunting cone cylinder 47 outer wall are connected by heating agent conduit and prepolymerization pipe 41 inwall are fixing；
The upper end of upper shunting cone cylinder 46 is higher than the first edge, upper conical guide shell 42 upper end, and the lower end of lower shunting cone cylinder 47 flushes with the second edge, inferior pyramidal guide shell 45 upper end；
Form circulation road 48 under tube wall melt between upper shunting cone cylinder 46 outer surface and the first inferior pyramidal guide shell 44 outer surface, between lower shunting cone cylinder 47 outer surface and the first inferior pyramidal guide shell 44 outer surface, form circulation road 49 under blend melt；
Upper shunting cone cylinder 46 outer surface is provided with central melt flow dividing structure 50, and the lower end of central melt flow dividing structure 50 crosses with circulation road 48 lower end under tube wall melt.
Central melt flow dividing structure 50 includes a shunt cylinder 51 and several isocons 52, shunt cylinder 51 and isocon 52 are each provided in shunting cone cylinder 46, shunt cylinder 51 open top, edge, shunt cylinder 51 upper end level, isocon 52 is wide at the top and narrow at the bottom, the all isocons of isocon 52 52 are evenly arranged along upper shunting cone cylinder 46 circumferencial direction, isocon 52 upper end connects with shunt cylinder 51 lower end, and isocon 52 lower port is positioned at circulation road 48 lower end and the outside of circulation road 49 upper end intersection under blend melt under tube wall melt.
Upper shunting cone cylinder 46 is internally formed preheating cavity 53, preheating cavity 54 under being internally formed of the first inferior pyramidal guide shell 44 and the second inferior pyramidal guide shell 45 with lower shunting cone cylinder 47, has all been passed through hot circulating fluid medium in upper preheating cavity 53 and lower preheating cavity 54.Heating agent conduit is inner and upper preheating cavity 53 connects, and heating agent external catheter end stretches out outside prepolymerization pipe.Heating agent conduit is circulated water conservancy diversion to the hot circulating fluid medium in upper preheating cavity 53, and plays support location upper shunting cone cylinder 46 and the effect of lower shunting cone cylinder 47.Wherein heating agent conduit is not illustrated out in the drawings.
nullFirst conveying pipeline arranges polylactic acid pre-polymerization mixing device 40 carry out batch mixing warm and be: melt flows downward in prepolymerization pipe 41，The melt A of prepolymerization pipe 41 center enters into shunt cylinder 51 along upper shunting cone cylinder 46 surface，Melt A flows to circulation road 48 lower end and the outside of the intersection of circulation road 49 upper end under blend melt under tube wall melt automatically by isocon 52 again，Meanwhile，Melt B near prepolymerization pipe 41 tube wall enters under tube wall melt in circulation road 48 through the first upper conical guide shell 42，Flow to be positioned at behind circulation road 48 lower end under tube wall melt the top of melt A，Under i.e. melt A and melt B entrance blend melt after circulation road 49，Melt A is positioned at lower floor，Melt B is positioned at upper strata，Until melt A and melt B flow to circulation road 49 lower end outlet under blend melt，Melt B is positioned in the middle of melt A，I.e. melt A is transformed into by center and continues to flow downward along tube wall，Melt B is transformed into center and continues to flow downward by being close to tube wall，During transposition，Melt A and melt B have been also carried out mixing definitely.The flow direction being oriented to melt A of Fig. 5 hollow core arrow, the flow direction being oriented to melt B of filled arrows.
During melt mixed replaces, being all passed through hot circulating fluid medium in upper preheating cavity 53 and lower preheating cavity 54, hot circulating fluid medium can add thermal medium such as according to technological requirement；Biphenyl Ether, conduction oil etc., preheat melt, to facilitate control prepolymerization process.This utility model all takes in the junction of all parts and designs without dead angle.Many group batch mixing preheaters can be installed in a piece prepolymerization pipe 41 from top to bottom.
null3rd conveying pipeline 28 arranges sound integrated pipeline formula mixing device 31，Have the advantages that under the effect of spinning screw extruder 65，Polylactic acid after polymerization is entered by fixed-piping 1，When the melt of thickness under high pressure passes through dynamic mixture pipeline 3 when，Dynamic screw dividing plate 4 starts to rotate under the promotion of melt，The dynamic screw dividing plate 4 that viscous melt on the inwall of dynamic mixture pipeline 3 is rotated scrapes，The viscous melt scraped is diluter that melt mixes with dynamic mixture pipeline 3 centre，And mix in pushing ahead the 3rd semicircle helical duct 8 in static batch mixing pipeline 2 and the 4th semicircle helical duct 9，Above-mentioned batch mixing process is repeated in entering back into dynamic mixture pipeline 3 after mixing，After some groups of batch mixing unit，Uniform polylactic acid melt enters polylactic acid melt extrusion orifice plate 32，Polylactic acid melt extrusion orifice plate 32 carries out water-cooled after polylactic acid melt is sprayed into tape，After water-cooled is solidified to room temperature，Operation of cutting into slices is carried out through pelleter 17.Due to the first semicircle helical duct 5 and the second semicircle spiral lead to 6 roads longer and the most in the axial direction for the hand of spiral arrange, thus can when pressurized melt is passed through, drive dynamic screw dividing plate 4 rotate；The top form with the press-fit of cone tank top of rotary material of dynamic screw dividing plate 4, is not only easy to manufacture and assembling, and frictional force is less in rotary course, thus improve the efficiency of dynamic screw dividing plate 4 scraper.The length of static batch mixing pipeline 2 is less than the length of dynamic mixture pipeline 3, whole melt pipe 72(so can be made to be made up of static batch mixing pipeline 2 and dynamic mixture pipeline 3) most of length all king-sized for viscosity adhere on tube wall polylactic acid can be wiped off, fully improve the uniformity mixed.
Use specifically comprising the following steps that of spinning production technology of the present utility model
(1), the catalyst of participation polymerization, the fusion of stabilizer equal solvent are become suspension, suspension is injected in agitator tank 19, in agitator tank, injects lactide melt simultaneously, open agitator tank work, stirring melt 20～40min, until stopping stirring after mix homogeneously；
(2), open the first autocontrol valve 23 bottom agitator tank 19, by the first dosing pump 24, lactide melt mixture is carried out preliminary polymerization operation in the first conveying pipeline 22 drops into first poly-tank 20, under the effect of lactide melt mixture self gravitation, lactide melt mixture by carry out during polylactic acid pre-polymerization mixing device pre-hot mixing laggard enter just in poly-tank 20, carry out in first poly-tank 20 preliminary polymerization operation be temperature be 100～150 DEG C, the time of preliminary polymerization operation is 1～2h, pressure is 0.2MPa, after preliminary polymerization operation, lactide, the mixture of titanium dioxide and solvent is aggregated into the polylactic acid melt into thickness；
(3), the second autocontrol valve 26 bottom first poly-tank 20 is opened, by the second dosing pump 27, polylactic acid melt is finally polymerized operation in the second conveying pipeline 25 drops into whole poly-tank 21, final polymerization operation be temperature be 150～280 DEG C, the time of final polymerization operation is 1～6h, and pressure is 0.3MPa；
(4), the 3rd autocontrol valve bottom whole poly-tank 21 is opened, polylactic acid melt in poly-tank 21 is discharged through the 3rd conveying pipeline 28 eventually, the power that the 3rd dosing pump 29 arranged on 3rd conveying pipeline 28 provides metering for polylactic acid melt, filters and carry, totally, the polylactic acid melt of mix homogeneously be extruded as band strip by polylactic acid melt extrusion orifice plate 32, then polylactic acid melt is carried out water-cooled；
(5) operate pelleter 17 after, polylactic acid melt water-cooled is solidified to room temperature and carry out operation of cutting into slices; the polylactic acid melt of band strip is cut into polylactic acid slice (granular) by pelleter 17; being transported to vulcanize on crystallizing bed 60 by polylactic acid slice by conveyer and crystallize, after crystallization, polylactic acid slice is transported to drying tower 61 and is dried；
(6), by dried polylactic acid do section to be stored in the second feed bin 63, dry titanium dioxide dry powder is stored in the first feed bin 62, be connected with the charging aperture of spinning screw extruder 65 by main tremie pipe 67 bottom the second feed bin 63；
(7) the titanium dioxide dry powder, in the first feed bin 62 drops in powder quantifier 71 by gravity, and titanium dioxide dry powder is measured by powder quantifier 71；While the dry section of polylactic acid in the second feed bin 63 is fallen in main tremie pipe 67 by gravity, compressed air system 64 is blown into dry compressed air in airduct 68, the titanium dioxide dry powder measured by powder quantifier 71 is blown in main tremie pipe 67, wind speed size can be adjusted by adjusting air valve 69, do the mixing of section different proportion adapting to titanium dioxide dry powder and polylactic acid, titanium dioxide dry powder do with polylactic acid main tremie pipe 67 in cut into slices mix after drop in spinning screw extruder 65；
(8), titanium dioxide dry powder and polylactic acid are done section and are heated to 200-300 DEG C and make polylactic acid melt by spinning screw extruder 65；
(9), under the discharge pressure of spinning screw extruder 65, the polylactic acid melt after filtration is fed in spinning manifold 66 by melt pipe 72, and the sound integrated pipeline formula mixing device 31 that melt pipe 72 is installed the most uniformly mixes polylactic acid melt；
(10) spinning pump 73, in spinning manifold 66 enters into filament spinning component 74 after polylactic acid melt is measured supercharging, and polylactic acid melt is spun into delustring or semi-dull acid fiber by polylactic by filament spinning component 74.
Using production technology of the present utility model, this utility model first produces polylactic acid slice, adds the fibre-grade titanium dioxide (TiO of certain proportion (0.2%～3%) in polylactic acid slice material further according to fiber properties this utility model2), the feel of fiber improves significantly, and has more greatly light (not add TiO2) the significantly soft many of acid fiber by polylactic.Secondly, dyeing kinetics substantially reduce, dyeing uniformity is improved.
Shape of the present utility model, material, structure etc. are not made any pro forma restriction by the present embodiment; every any simple modification, equivalent variations and modification made above example according to technical spirit of the present utility model, belongs to the protection domain of technical solutions of the utility model.
Claims (6)
- null1. polylactic acid slice adds titanium dioxide delustring spinning production system，It is characterized in that: include aggregation framework、Pelleter、Cooling bay、Vulcanize crystallizing bed、Drying tower、First feed bin、Second feed bin、Compressed air system、Spinning screw extruder and spinning manifold，Agitator tank it is sequentially provided with from top to bottom in aggregation framework、First poly-tank and eventually poly-tank，It is connected with first poly-tank top by the first conveying pipeline bottom agitator tank，First conveying pipeline is provided with polylactic acid pre-polymerization mixing device、First autocontrol valve and the first dosing pump，First poly-pot bottom is connected with poly-tank top eventually by the second conveying pipeline，Second conveying pipeline is provided with the second autocontrol valve and the second dosing pump，Poly-pot bottom connects eventually the 3rd conveying pipeline，3rd conveying pipeline is provided with the 3rd dosing pump，The discharging opening of the 3rd conveying pipeline connects the polylactic acid melt extrusion orifice plate being positioned at above cooling bay，Cooling water it is loaded with in cooling bay，The working end of pelleter is located in cooling bay，The discharge end of pelleter is positioned at outside cooling bay and is connected by the feed end that conveyer is crystallizing bed with sulfuration，Vulcanize crystallizing bed discharge end to be connected with the charging aperture of drying tower，The discharging opening of drying tower and the charging aperture of the second feed bin connect；The discharging opening of the second feed bin is connected by the charging aperture of main tremie pipe with spinning screw extruder, tilt to be provided with airduct between air outlet and the main tremie pipe of compressed air system, airduct is connected the position of end and is connected the position of end higher than airduct with main tremie pipe with compressed air system, airduct is provided with the adjusting air valve of neighbouring compressed air system, the discharging opening of the first feed bin is connected with airduct by mix tube, mix tube is provided with powder quantifier, the discharging opening of spinning screw extruder is connected with spinning manifold by melt pipe, melt pipe is provided with sound integrated pipeline formula mixing device, spinning pump and filament spinning component it is provided with in spinning manifold, in the discharging opening of melt pipe extend into spinning manifold and it is connected with the charging aperture of spinning pump, spinning measuring delivery side of pump is connected with the import of filament spinning component；Polylactic acid pre-polymerization mixing device includes the prepolymerization pipe being arranged in vertical, and from top to bottom at least provided with two batch mixing preheaters in prepolymerization pipe, all of equal structure of batch mixing preheater is identical；Each batch mixing preheater all includes having the first upper conical guide shell of same centrage, the second upper conical guide shell, the first inferior pyramidal guide shell, the second inferior pyramidal guide shell, upper shunting cone cylinder and lower shunting cone cylinder；nullFirst upper conical guide shell and the first inferior pyramidal guide shell are upper coarse and lower fine and upper and lower permeable structures，First upper conical guide shell bottom diameter is more than the second upper conical guide shell bottom diameter，Second upper conical guide shell and the second inferior pyramidal guide shell are up-thin-low-thick and upper and lower permeable structures，First upper conical guide shell bottom diameter and the second upper conical guide shell upper-end inner diameter are equal，First inferior pyramidal guide shell bottom diameter and the second inferior pyramidal guide shell upper-end inner diameter are equal，First outer, upper conical guide shell upper end、Second outer, upper conical guide shell lower end、First edge, inferior pyramidal guide shell upper end and the second edge, inferior pyramidal guide shell lower end are fixedly connected with at prepolymerization inside pipe wall，The fixing connection in first upper conical edge, guide shell lower end and the second edge, upper conical guide shell upper end，The fixing connection in first upper conical edge, guide shell lower end and the second edge, upper conical guide shell upper end，The fixing connection in first edge, inferior pyramidal guide shell lower end and the second edge, inferior pyramidal guide shell upper end；Upper shunting cone cylinder is the structure that top sharply blocks, bottom is uncovered, lower shunting cone cylinder is the sharp-pointed closure in bottom, the structure of open top, upper shunting cone cylinder bottom diameter is equal to lower shunting cone cylinder upper-end inner diameter, upper shunting cone cylinder bottom diameter is less than prepolymerization bore, and edge, upper shunting cone cylinder lower end is fixing with edge, lower shunting cone cylinder upper end to be connected；Upper shunting cone cylinder and lower spreader drum outer wall are connected by heating agent conduit and prepolymerization inside pipe wall are fixing；The upper end of upper shunting cone cylinder is higher than the first edge, upper conical guide shell upper end, and the lower end of lower shunting cone cylinder flushes with the second edge, inferior pyramidal guide shell upper end；Form circulation road under tube wall melt between upper spreader tube outer surface and the first inferior pyramidal guide shell outer surface, between lower spreader tube outer surface and the first inferior pyramidal guide shell outer surface, form circulation road under blend melt；Upper spreader tube outer surface is provided with central melt flow dividing structure, and the lower end of central melt flow dividing structure crosses with circulation road lower end under tube wall melt.
- Polylactic acid slice the most according to claim 1 adds titanium dioxide delustring spinning production system, it is characterized in that: sound integrated pipeline formula mixing device includes fixed-piping and batch mixing unit, batch mixing unit includes static batch mixing pipeline and the dynamic mixture pipeline of coaxial setting, the left end of dynamic mixture pipeline and the right-hand member Flange joint of static batch mixing pipeline, dynamic screw dividing plate it is provided with in dynamic mixture pipeline, dynamic mixture pipe interior is in axial direction separated into the first semicircle helical duct and the second semicircle helical duct by dynamic screw dividing plate, dynamic screw dividing plate and dynamic mixture inner-walls of duct matched in clearance；Being provided with static ribbon dividing plate in static batch mixing pipeline, static state batch mixing pipeline axially inside direction is separated into the 3rd semicircle helical duct and the 4th semicircle helical duct by static ribbon dividing plate, and static ribbon dividing plate is fixing with static batch mixing inner-walls of duct to be connected；The plane at the place, both ends of dynamic screw dividing plate and static ribbon dividing plate is each perpendicular to the central axis of dynamic mixture pipeline, center, dynamic screw dividing plate right part is provided with dynamic cone tank, center, dynamic screw dividing plate left part is provided with the most top, center, static ribbon dividing plate right part is provided with static cone tank, center, static ribbon dividing plate left part is provided with static top, and dynamic top left end withstands in static cone tank；Fixed-piping left end and dynamic mixture pipeline right-hand member Flange joint, be provided with support in fixed-piping, support is provided with stationary center, and stationary center left end withstands in dynamic cone tank.
- Polylactic acid slice the most according to claim 2 adds titanium dioxide delustring spinning production system, it is characterized in that: the quantity of batch mixing unit is more than or equal to two groups, Flange joint between two adjacent groups batch mixing unit, the top left end of static state of one group of batch mixing unit withstands in the dynamic cone tank of adjacent one group batch mixing unit, and fixed-piping is connected with one group of batch mixing unit of low order end.
- 4. add titanium dioxide delustring spinning production system according to the polylactic acid slice described in Claims 2 or 3, it is characterised in that: the length of static batch mixing pipeline is less than the length of dynamic mixture pipeline.
- Polylactic acid slice the most according to claim 1 adds titanium dioxide delustring spinning production system, it is characterized in that: central melt flow dividing structure includes a shunt cylinder and several isocons, shunt cylinder and isocon are each provided in shunting cone cylinder, shunt cylinder open top, edge, shunt cylinder upper end level, isocon is wide at the top and narrow at the bottom, the all isocons of isocon are evenly arranged along upper shunting cone cylinder circumferencial direction, isocon upper end connects with shunt cylinder lower end, and isocon lower port is positioned at circulation road lower end and the outside of circulation road upper end intersection under blend melt under tube wall melt.
- Polylactic acid slice the most according to claim 5 adds titanium dioxide delustring spinning production system, it is characterized in that: above shunting cone cylinder and lower shunting cone cylinder be internally formed preheating cavity, hot circulating fluid medium all it has been passed through in preheating cavity under being internally formed of the first inferior pyramidal guide shell and the second inferior pyramidal guide shell, upper preheating cavity and lower preheating cavity；Heating agent conduit is inner and upper preheating cavity connects, and heating agent external catheter end stretches out outside prepolymerization pipe.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620315598.8U CN205522386U (en) | 2016-04-15 | 2016-04-15 | Titanium dioxide extinction spinning production system is added in polylactic acid section |
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| CN201620315598.8U CN205522386U (en) | 2016-04-15 | 2016-04-15 | Titanium dioxide extinction spinning production system is added in polylactic acid section |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105690702A (en) * | 2016-04-15 | 2016-06-22 | 河南省龙都生物科技有限公司 | Dulling spinning production system capable of adding titanium dioxide in polylactic acid slices |
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2016
- 2016-04-15 CN CN201620315598.8U patent/CN205522386U/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105690702A (en) * | 2016-04-15 | 2016-06-22 | 河南省龙都生物科技有限公司 | Dulling spinning production system capable of adding titanium dioxide in polylactic acid slices |
| CN105690702B (en) * | 2016-04-15 | 2017-11-10 | 河南省龙都生物科技有限公司 | Polylactic acid slice adds titanium dioxide delustring spinning production system |
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